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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-[[2-Amino-5-(4-chlorophenyl)sulfanylpyrimidin-4-yl]amino]phenol —— C16H13ClN4OS
    4-[[2-Amino-5-(4-chlorophenyl)sulfanylpyrimidin-4-yl]amino]phenol
    —— 4-[2-Amino-5-(4-ethylphenyl)sulfanylpyrimidin-4-yl]cyclohexan-1-one —— C18H21N3OS
    4-[2-Amino-5-(4-ethylphenyl)sulfanylpyrimidin-4-yl]cyclohexan-1-one
    —— 3-[(1-Methylimidazol-2-yl)sulfanylmethyl]-2-(pyridin-4-ylsulfanylmethyl)pyridine —— C16H16N4S2
    3-[(1-Methylimidazol-2-yl)sulfanylmethyl]-2-(pyridin-4-ylsulfanylmethyl)pyridine
    —— Allyl [(4-amino-5-benzyl-2-pyrimidinyl)sulfanyl]acetate —— C16H17N3O2S
    Allyl [(4-amino-5-benzyl-2-pyrimidinyl)sulfanyl]acetate
    —— 4-[2-[2-(1-Methylpyrrol-2-yl)sulfanylethoxy]ethylsulfanyl]phenol —— C15H19NO2S2
    4-[2-[2-(1-Methylpyrrol-2-yl)sulfanylethoxy]ethylsulfanyl]phenol
    —— (5-benzylsulfanyl-1<i>H</i>-[1,2,4]triazol-3-yl)-<i>p</i>-tolyl-amine 4288-96-4 C16H16N4S
    (5-benzylsulfanyl-1<i>H</i>-[1,2,4]triazol-3-yl)-<i>p</i>-tolyl-amine
    —— 4,5-dichloro-2-(3-chlorophenyl)sulfanyl-1H-imidazole —— C9H5Cl3N2S
    4,5-dichloro-2-(3-chlorophenyl)sulfanyl-1H-imidazole
    —— 4,5-dichloro-2-(4-propan-2-ylphenyl)sulfanyl-1H-imidazole —— C12H12Cl2N2S
    4,5-dichloro-2-(4-propan-2-ylphenyl)sulfanyl-1H-imidazole
    —— 3-(2-methylbutylsulfanyl)-N-(4-methylphenyl)-1H-1,2,4-triazol-5-amine —— C14H20N4S
    3-(2-methylbutylsulfanyl)-N-(4-methylphenyl)-1H-1,2,4-triazol-5-amine
    —— 2-phenylsulfanyl-4-bromothiophene —— C10H7BrS2
    2-phenylsulfanyl-4-bromothiophene
    —— 1-(5-Phenylsulfanylthiophen-2-yl)ethanone —— C12H10OS2
    1-(5-Phenylsulfanylthiophen-2-yl)ethanone
    —— 4,5-dichloro-2-(4-fluorophenyl)sulfanyl-1H-imidazole —— C9H5Cl2FN2S
    4,5-dichloro-2-(4-fluorophenyl)sulfanyl-1H-imidazole
    —— N-phenyl-3-thiophen-3-ylsulfanyl-1H-1,2,4-triazol-5-amine —— C12H10N4S2
    N-phenyl-3-thiophen-3-ylsulfanyl-1H-1,2,4-triazol-5-amine
    —— 6-Methyl-2-[1-(methylamino)hexan-3-ylsulfanyl]pyridine-3-carbonitrile —— C14H21N3S
    6-Methyl-2-[1-(methylamino)hexan-3-ylsulfanyl]pyridine-3-carbonitrile
    —— 2-[2-(2-Aminoethylsulfanyl)ethylsulfanyl]ethanethiol —— C6H15NS3
    2-[2-(2-Aminoethylsulfanyl)ethylsulfanyl]ethanethiol
    —— 6-methyl-4-[(E)-(4-methylsulfanylphenyl)methylideneamino]-3-sulfanylidene-2H-1,2,4-triazin-5-one —— C12H12N4OS2
    6-methyl-4-[(E)-(4-methylsulfanylphenyl)methylideneamino]-3-sulfanylidene-2H-1,2,4-triazin-5-one
    —— 3-[(2E)-2-{[4-(Methylsulfanyl)phenyl]methylidene}hydrazin-1-YL]-5-phenyl-1,2,4-triazine —— C17H15N5S
    3-[(2E)-2-{[4-(Methylsulfanyl)phenyl]methylidene}hydrazin-1-YL]-5-phenyl-1,2,4-triazine
    —— N-[(Z)-[4-(4-methylsulfanylphenyl)-3-prop-2-enyl-1,3-thiazol-2-ylidene]amino]adamantane-1-carboxamide —— C24H29N3OS2
    N-[(Z)-[4-(4-methylsulfanylphenyl)-3-prop-2-enyl-1,3-thiazol-2-ylidene]amino]adamantane-1-carboxamide
    —— N'-{[5-(1,3-benzothiazol-2-ylsulfanyl)-2-furyl]methylene}-2-(1-naphthyloxy)acetohydrazide —— C24H17N3O3S2
    N'-{[5-(1,3-benzothiazol-2-ylsulfanyl)-2-furyl]methylene}-2-(1-naphthyloxy)acetohydrazide
    —— (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-phenylethylideneamino]propanamide —— C23H26N6OS
    (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-phenylethylideneamino]propanamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-thiophen-2-ylmethylideneamino]acetamide —— C13H11ClN2OS2
    2-(4-chlorophenyl)sulfanyl-N-[(E)-thiophen-2-ylmethylideneamino]acetamide
    —— N-[(E)-(2-chlorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide —— C15H12Cl2N2OS
    N-[(E)-(2-chlorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-1-pyridin-2-ylethylideneamino]acetamide —— C15H14ClN3OS
    2-(4-chlorophenyl)sulfanyl-N-[(E)-1-pyridin-2-ylethylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-cyclohexylmethylideneamino]acetamide —— C15H19ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(E)-cyclohexylmethylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-thiophen-3-ylmethylideneamino]acetamide —— C13H11ClN2OS2
    2-(4-chlorophenyl)sulfanyl-N-[(E)-thiophen-3-ylmethylideneamino]acetamide
    —— N-[(E)-(2-chloro-6-fluorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide —— C15H11Cl2FN2OS
    N-[(E)-(2-chloro-6-fluorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-1-pyridin-3-ylethylideneamino]acetamide —— C15H14ClN3OS
    2-(4-chlorophenyl)sulfanyl-N-[(E)-1-pyridin-3-ylethylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-furan-2-ylmethylideneamino]acetamide —— C13H11ClN2O2S
    2-(4-chlorophenyl)sulfanyl-N-[(E)-furan-2-ylmethylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-(3-fluorophenyl)methylideneamino]acetamide —— C15H12ClFN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(E)-(3-fluorophenyl)methylideneamino]acetamide
    —— (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(5-methylthiophen-2-yl)methanimine —— C15H13ClN4S2
    (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(5-methylthiophen-2-yl)methanimine
    —— (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(2-methyl-1,3-thiazol-4-yl)methanimine —— C14H12ClN5S2
    (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(2-methyl-1,3-thiazol-4-yl)methanimine
    —— (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(2,4,6-trimethylphenyl)methanimine —— C19H19ClN4S
    (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(2,4,6-trimethylphenyl)methanimine
    —— (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(2,4-dimethylphenyl)methanimine —— C18H17ClN4S
    (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(2,4-dimethylphenyl)methanimine
    —— (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(3-fluorophenyl)methanimine —— C16H12ClFN4S
    (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(3-fluorophenyl)methanimine
    —— (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(2,4-difluorophenyl)methanimine —— C16H11ClF2N4S
    (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-(2,4-difluorophenyl)methanimine
    —— (2R)-2-amino-2-(2-methylsulfanylpyrimidin-4-yl)ethanol —— C7H11N3OS
    (2R)-2-amino-2-(2-methylsulfanylpyrimidin-4-yl)ethanol
    —— (NZ)-N-[1-[2-[5-amino-6-(dimethylamino)pyrimidin-4-yl]sulfanyl-5-nitrophenyl]ethylidene]hydroxylamine —— C14H16N6O3S
    (NZ)-N-[1-[2-[5-amino-6-(dimethylamino)pyrimidin-4-yl]sulfanyl-5-nitrophenyl]ethylidene]hydroxylamine
    —— 2-(2-fluorophenyl)sulfanyl-N-[(E)-1-pyridin-3-ylethylideneamino]acetamide —— C15H14FN3OS
    2-(2-fluorophenyl)sulfanyl-N-[(E)-1-pyridin-3-ylethylideneamino]acetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(E)-(3-methylthiophen-2-yl)methylideneamino]acetamide —— C14H13FN2OS2
    2-(2-fluorophenyl)sulfanyl-N-[(E)-(3-methylthiophen-2-yl)methylideneamino]acetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(E)-1-(furan-2-yl)ethylideneamino]acetamide —— C14H13FN2O2S
    2-(2-fluorophenyl)sulfanyl-N-[(E)-1-(furan-2-yl)ethylideneamino]acetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(E)-thiophen-2-ylmethylideneamino]acetamide —— C13H11FN2OS2
    2-(2-fluorophenyl)sulfanyl-N-[(E)-thiophen-2-ylmethylideneamino]acetamide
    —— N-[(E)-(2-bromophenyl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C15H12BrFN2OS
    N-[(E)-(2-bromophenyl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— 2-(2-fluorophenyl)sulfanyl-N-[(E)-pyridin-4-ylmethylideneamino]acetamide —— C14H12FN3OS
    2-(2-fluorophenyl)sulfanyl-N-[(E)-pyridin-4-ylmethylideneamino]acetamide
    —— N-[(E)-(2-fluorophenyl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide —— C15H12F2N2OS
    N-[(E)-(2-fluorophenyl)methylideneamino]-2-(2-fluorophenyl)sulfanylacetamide
    —— 1-[(E)-(4-methylsulfanylphenyl)methylideneamino]-3-(2-morpholin-4-ylethyl)thiourea —— C15H22N4OS2
    1-[(E)-(4-methylsulfanylphenyl)methylideneamino]-3-(2-morpholin-4-ylethyl)thiourea
    —— 2-(2-fluorophenyl)sulfanyl-N-[(E)-[4-[2-hydroxyethyl(methyl)amino]phenyl]methylideneamino]acetamide —— C18H20FN3O2S
    2-(2-fluorophenyl)sulfanyl-N-[(E)-[4-[2-hydroxyethyl(methyl)amino]phenyl]methylideneamino]acetamide
    —— 1-[4-(difluoromethylsulfanyl)phenyl]-3-[(E)-1-(5-methylfuran-2-yl)ethylideneamino]thiourea —— C15H15F2N3OS2
    1-[4-(difluoromethylsulfanyl)phenyl]-3-[(E)-1-(5-methylfuran-2-yl)ethylideneamino]thiourea
    —— N-[(E)-(3-bromophenyl)methylideneamino]-3-[(3-methylphenyl)methylsulfanyl]-1H-1,2,4-triazol-5-amine —— C17H16BrN5S
    N-[(E)-(3-bromophenyl)methylideneamino]-3-[(3-methylphenyl)methylsulfanyl]-1H-1,2,4-triazol-5-amine
    —— N-cyclopropyl-2-[[5-[(2E)-2-(furan-2-ylmethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C12H14N6O2S
    N-cyclopropyl-2-[[5-[(2E)-2-(furan-2-ylmethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 3-[(2-chlorophenyl)methylsulfanyl]-N-[(E)-furan-2-ylmethylideneamino]-1H-1,2,4-triazol-5-amine —— C14H12ClN5OS
    3-[(2-chlorophenyl)methylsulfanyl]-N-[(E)-furan-2-ylmethylideneamino]-1H-1,2,4-triazol-5-amine