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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-{2-[(4-Methylphenyl)sulfanyl]ethylidene}hydrazinecarboximidamide —— C10H14N4S
    2-{2-[(4-Methylphenyl)sulfanyl]ethylidene}hydrazinecarboximidamide
    —— 5-[(2E)-2-benzylidenehydrazinyl]-3-(benzylsulfanyl)-1,2-thiazole-4-carbonitrile —— C18H14N4S2
    5-[(2E)-2-benzylidenehydrazinyl]-3-(benzylsulfanyl)-1,2-thiazole-4-carbonitrile
    —— 4-Oxo-2-(phenylthio)-4H-pyrido(1,2-A)pyrimidine-3-carbaldehyde semicarbazone —— C16H13N5O2S
    4-Oxo-2-(phenylthio)-4H-pyrido(1,2-A)pyrimidine-3-carbaldehyde semicarbazone
    —— tert-butyl 2-[(E)-[2-(4,6-dimethoxypyrimidin-2-yl)sulfanylphenyl]methylideneamino]oxyacetate —— C19H23N3O5S
    tert-butyl 2-[(E)-[2-(4,6-dimethoxypyrimidin-2-yl)sulfanylphenyl]methylideneamino]oxyacetate
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-N'-[(E)-(2,5-difluorophenyl)methylidene]-1H-1,2,3-triazole-4-carbohydrazide —— C19H13ClF2N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-N'-[(E)-(2,5-difluorophenyl)methylidene]-1H-1,2,3-triazole-4-carbohydrazide
    —— 2-nitro-N-[(E)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]benzamide —— C21H12N6O7S2
    2-nitro-N-[(E)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]benzamide
    —— N,N'-bis[(E)-(4-methylsulfanylphenyl)methylideneamino]pentanediamide —— C21H24N4O2S2
    N,N'-bis[(E)-(4-methylsulfanylphenyl)methylideneamino]pentanediamide
    —— 2-[(E)-(2-{[1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-{[(4-methylphenyl)sulfanyl]methyl}-1H-1,2,3-triazol-4-yl]carbonyl}hydrazinylidene)methyl]-4-chlorophenolate —— C20H17ClN8O3S
    2-[(E)-(2-{[1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-{[(4-methylphenyl)sulfanyl]methyl}-1H-1,2,3-triazol-4-yl]carbonyl}hydrazinylidene)methyl]-4-chlorophenolate
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-{(E)-[4-(diethylamino)-2-hydroxyphenyl]methylidene}-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide —— C23H25N9O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-{(E)-[4-(diethylamino)-2-hydroxyphenyl]methylidene}-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(1E)-1-(2-hydroxyphenyl)ethylidene]-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide —— C17H17N11O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(1E)-1-(2-hydroxyphenyl)ethylidene]-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(2-hydroxyphenyl)methylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide —— C19H16N8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(2-hydroxyphenyl)methylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide
    —— 2-[(1E)-1-(2-{[1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-1H-1,2,3-triazol-4-yl]carbonyl}hydrazinylidene)ethyl]phenolate —— C20H17ClN8O3S
    2-[(1E)-1-(2-{[1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-1H-1,2,3-triazol-4-yl]carbonyl}hydrazinylidene)ethyl]phenolate
    —— 4-[(1E)-1-(2-{[1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-{[(4-methylphenyl)sulfanyl]methyl}-1H-1,2,3-triazol-4-yl]carbonyl}hydrazinylidene)ethyl]phenolate —— C21H20N8O3S
    4-[(1E)-1-(2-{[1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-{[(4-methylphenyl)sulfanyl]methyl}-1H-1,2,3-triazol-4-yl]carbonyl}hydrazinylidene)ethyl]phenolate
    —— 2-[(1E)-1-(2-{[1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-{[(4-methylphenyl)sulfanyl]methyl}-1H-1,2,3-triazol-4-yl]carbonyl}hydrazinylidene)ethyl]phenolate —— C21H20N8O3S
    2-[(1E)-1-(2-{[1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-{[(4-methylphenyl)sulfanyl]methyl}-1H-1,2,3-triazol-4-yl]carbonyl}hydrazinylidene)ethyl]phenolate
    —— 4-[(1E)-1-(2-{[1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-1H-1,2,3-triazol-4-yl]carbonyl}hydrazinylidene)ethyl]phenolate —— C20H17ClN8O3S
    4-[(1E)-1-(2-{[1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-1H-1,2,3-triazol-4-yl]carbonyl}hydrazinylidene)ethyl]phenolate
    —— 2-[[5-cyclohexyl-4-[(E)-[2,5-dimethyl-1-(2-methylpropyl)pyrrol-3-yl]methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C21H31N5O2S
    2-[[5-cyclohexyl-4-[(E)-[2,5-dimethyl-1-(2-methylpropyl)pyrrol-3-yl]methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 3,5-dichloro-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]pyridin-2-amine —— C13H11Cl2N3S
    3,5-dichloro-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]pyridin-2-amine
    —— 2-[(E)-(4-methylsulfanylphenyl)methylideneamino]oxy-N-(4-phenylbutan-2-yl)propanamide —— C21H26N2O2S
    2-[(E)-(4-methylsulfanylphenyl)methylideneamino]oxy-N-(4-phenylbutan-2-yl)propanamide
    —— 1-[4-(difluoromethylsulfanyl)phenyl]-3-[(E)-[1-(2-methoxyethyl)-2,5-dimethylpyrrol-3-yl]methylideneamino]thiourea —— C18H22F2N4OS2
    1-[4-(difluoromethylsulfanyl)phenyl]-3-[(E)-[1-(2-methoxyethyl)-2,5-dimethylpyrrol-3-yl]methylideneamino]thiourea
    —— 3-(difluoromethyl)-5-(methylsulfanyl)-N-[(E)-(5-methylthiophen-2-yl)methylidene]-4H-1,2,4-triazol-4-amine —— C10H10F2N4S2
    3-(difluoromethyl)-5-(methylsulfanyl)-N-[(E)-(5-methylthiophen-2-yl)methylidene]-4H-1,2,4-triazol-4-amine
    —— 3-(difluoromethyl)-N-[(E)-(3-fluorophenyl)methylidene]-5-(methylsulfanyl)-4H-1,2,4-triazol-4-amine —— C11H9F3N4S
    3-(difluoromethyl)-N-[(E)-(3-fluorophenyl)methylidene]-5-(methylsulfanyl)-4H-1,2,4-triazol-4-amine
    —— N-[(E)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-4-nitroaniline —— C18H13N5O3S
    N-[(E)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-4-nitroaniline
    —— N-[(E)-{5-[(4-bromo-3-nitro-1H-pyrazol-1-yl)methyl]furan-2-yl}methylidene]-3-(difluoromethyl)-5-(methylsulfanyl)-4H-1,2,4-triazol-4-amine —— C13H10BrF2N7O3S
    N-[(E)-{5-[(4-bromo-3-nitro-1H-pyrazol-1-yl)methyl]furan-2-yl}methylidene]-3-(difluoromethyl)-5-(methylsulfanyl)-4H-1,2,4-triazol-4-amine
    —— N-[3-(Difluoromethyl)-5-(methylsulfanyl)-4H-1,2,4-triazol-4-YL]-N-[(E)-1-(1-ethyl-5-methyl-1H-pyrazol-4-YL)methylidene]amine —— C11H14F2N6S
    N-[3-(Difluoromethyl)-5-(methylsulfanyl)-4H-1,2,4-triazol-4-YL]-N-[(E)-1-(1-ethyl-5-methyl-1H-pyrazol-4-YL)methylidene]amine
    —— 4-bromo-3-[(E)-{[3-(difluoromethyl)-5-(methylsulfanyl)-4H-1,2,4-triazol-4-yl]imino}methyl]phenol —— C11H9BrF2N4OS
    4-bromo-3-[(E)-{[3-(difluoromethyl)-5-(methylsulfanyl)-4H-1,2,4-triazol-4-yl]imino}methyl]phenol
    —— 3-(difluoromethyl)-N-{(E)-[4-(dimethylamino)phenyl]methylidene}-5-(methylsulfanyl)-4H-1,2,4-triazol-4-amine —— C13H15F2N5S
    3-(difluoromethyl)-N-{(E)-[4-(dimethylamino)phenyl]methylidene}-5-(methylsulfanyl)-4H-1,2,4-triazol-4-amine
    —— N-[3-(Difluoromethyl)-5-(methylsulfanyl)-4H-1,2,4-triazol-4-YL]-N-[(E)-1-(1-ethyl-1H-pyrazol-4-YL)methylidene]amine —— C10H12F2N6S
    N-[3-(Difluoromethyl)-5-(methylsulfanyl)-4H-1,2,4-triazol-4-YL]-N-[(E)-1-(1-ethyl-1H-pyrazol-4-YL)methylidene]amine
    —— 3-(difluoromethyl)-5-(methylsulfanyl)-N-[(E)-(3-methylthiophen-2-yl)methylidene]-4H-1,2,4-triazol-4-amine —— C10H10F2N4S2
    3-(difluoromethyl)-5-(methylsulfanyl)-N-[(E)-(3-methylthiophen-2-yl)methylidene]-4H-1,2,4-triazol-4-amine
    —— 2-({4-ethyl-5-[1-methyl-5-(trifluoromethyl)-1H-pyrazol-3-yl]-4H-1,2,4-triazol-3-yl}sulfanyl)-N'-[(E)-(2-fluorophenyl)methylidene]acetohydrazide —— C18H17F4N7OS
    2-({4-ethyl-5-[1-methyl-5-(trifluoromethyl)-1H-pyrazol-3-yl]-4H-1,2,4-triazol-3-yl}sulfanyl)-N'-[(E)-(2-fluorophenyl)methylidene]acetohydrazide
    —— N'-[(1E)-1-(4-hydroxyphenyl)ethylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide —— C20H20N4O2S3
    N'-[(1E)-1-(4-hydroxyphenyl)ethylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide
    —— N'-[(E)-(2-bromophenyl)methylidene]-2-(phenylsulfanyl)acetohydrazide —— C15H13BrN2OS
    N'-[(E)-(2-bromophenyl)methylidene]-2-(phenylsulfanyl)acetohydrazide
    —— N-[(E)-benzylideneamino]-2-(4-methyl-6-morpholin-4-ylpyrimidin-2-yl)sulfanylacetamide —— C18H21N5O2S
    N-[(E)-benzylideneamino]-2-(4-methyl-6-morpholin-4-ylpyrimidin-2-yl)sulfanylacetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-cyclohex-3-en-1-ylmethylideneamino]acetamide —— C15H17ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(E)-cyclohex-3-en-1-ylmethylideneamino]acetamide
    —— (E)-1,7,7-trimethyl-N-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]bicyclo[2.2.1]heptan-2-imine —— C20H24N6O2S
    (E)-1,7,7-trimethyl-N-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]bicyclo[2.2.1]heptan-2-imine
    —— 2-methyl-2-(phenylsulfanyl)propanal O-(4-chlorobenzyl)oxime —— C17H18ClNOS
    2-methyl-2-(phenylsulfanyl)propanal O-(4-chlorobenzyl)oxime
    —— (2E)-2-{[2-(1,3-benzothiazol-2-ylsulfanyl)-9-methyl-4-oxo-4H-pyrido[1,2-a]pyrimidin-3-yl]methylidene}hydrazinecarbothioamide —— C18H14N6OS3
    (2E)-2-{[2-(1,3-benzothiazol-2-ylsulfanyl)-9-methyl-4-oxo-4H-pyrido[1,2-a]pyrimidin-3-yl]methylidene}hydrazinecarbothioamide
    —— 2-(5-aminotetrazol-1-yl)-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C11H13N7OS
    2-(5-aminotetrazol-1-yl)-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— 2-[(2E)-2-[[2-(1,3-benzothiazol-2-ylsulfanyl)-9-methyl-4-oxopyrido[1,2-a]pyrimidin-3-yl]methylidene]hydrazinyl]benzoic acid —— C24H17N5O3S2
    2-[(2E)-2-[[2-(1,3-benzothiazol-2-ylsulfanyl)-9-methyl-4-oxopyrido[1,2-a]pyrimidin-3-yl]methylidene]hydrazinyl]benzoic acid
    —— N-[(E)-[5-(1,3-benzoxazol-2-ylsulfanyl)-2-methylpyrazolo[1,5-a]quinazolin-3-yl]methylideneamino]-3-[(2,4-dimethylphenyl)sulfamoyl]benzamide —— C34H27N7O4S2
    N-[(E)-[5-(1,3-benzoxazol-2-ylsulfanyl)-2-methylpyrazolo[1,5-a]quinazolin-3-yl]methylideneamino]-3-[(2,4-dimethylphenyl)sulfamoyl]benzamide
    —— Methyl 2-({2-[(methoxyimino)methyl]-4-nitrophenyl}sulfanyl)benzenecarboxylate —— C16H14N2O5S
    Methyl 2-({2-[(methoxyimino)methyl]-4-nitrophenyl}sulfanyl)benzenecarboxylate
    —— 2-[(2E)-2-[[5-(1,3-benzothiazol-2-ylsulfanyl)-2-methylpyrazolo[1,5-a]quinazolin-3-yl]methylidene]hydrazinyl]-N,N-diethyl-5-nitrobenzenesulfonamide —— C29H26N8O4S3
    2-[(2E)-2-[[5-(1,3-benzothiazol-2-ylsulfanyl)-2-methylpyrazolo[1,5-a]quinazolin-3-yl]methylidene]hydrazinyl]-N,N-diethyl-5-nitrobenzenesulfonamide
    —— 6-[(4-methylphenyl)sulfanyl]imidazo[2,1-b][1,3]thiazole-5-carbaldehyde O-(2,6-dichlorobenzyl)oxime —— C20H15Cl2N3OS2
    6-[(4-methylphenyl)sulfanyl]imidazo[2,1-b][1,3]thiazole-5-carbaldehyde O-(2,6-dichlorobenzyl)oxime
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-methylphenyl)sulfanyl]methyl}-N'-[(E)-(5-methylthiophen-2-yl)methylidene]-1H-1,2,3-triazole-4-carbohydrazide —— C19H18N8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-methylphenyl)sulfanyl]methyl}-N'-[(E)-(5-methylthiophen-2-yl)methylidene]-1H-1,2,3-triazole-4-carbohydrazide
    —— N-[(E)-(4-methylsulfanylphenyl)methylideneamino]pyridin-2-amine —— C13H13N3S
    N-[(E)-(4-methylsulfanylphenyl)methylideneamino]pyridin-2-amine
    —— 2,6-dichlorobenzenecarbaldehyde O-{[5-[(4-bromophenyl)sulfanyl]-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methyl}oxime —— C19H13BrCl2F3N3OS
    2,6-dichlorobenzenecarbaldehyde O-{[5-[(4-bromophenyl)sulfanyl]-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methyl}oxime
    —— N'-(4-(Methylthio)benzylidene)2(5-oxo-4,5-dihydro-1H-pyrazol-3-YL)acetohydrazide —— C13H14N4O2S
    N'-(4-(Methylthio)benzylidene)2(5-oxo-4,5-dihydro-1H-pyrazol-3-YL)acetohydrazide
    —— 2-[(4-chlorophenyl)sulfanyl]-N'-[(E)-pyridin-3-ylmethylidene]propanehydrazide —— C15H14ClN3OS
    2-[(4-chlorophenyl)sulfanyl]-N'-[(E)-pyridin-3-ylmethylidene]propanehydrazide
    —— N'-({4-[(4-chlorophenyl)sulfanyl]-3-nitrophenyl}methylene)-1-methyl-3-(trifluoromethyl)-1H-thieno[2,3-c]pyrazole-5-carbohydrazide —— C21H13ClF3N5O3S2
    N'-({4-[(4-chlorophenyl)sulfanyl]-3-nitrophenyl}methylene)-1-methyl-3-(trifluoromethyl)-1H-thieno[2,3-c]pyrazole-5-carbohydrazide
    —— Methyl 2-{[5-({[(2,4-dichlorobenzyl)oxy]imino}methyl)imidazo[2,1-b][1,3]thiazol-6-yl]sulfanyl}benzenecarboxylate —— C21H15Cl2N3O3S2
    Methyl 2-{[5-({[(2,4-dichlorobenzyl)oxy]imino}methyl)imidazo[2,1-b][1,3]thiazol-6-yl]sulfanyl}benzenecarboxylate
    —— 2-(1,3-benzothiazol-2-ylsulfanyl)-3-{(E)-[2-(4,6-dimethylpyrimidin-2-yl)hydrazinylidene]methyl}-9-methyl-4H-pyrido[1,2-a]pyrimidin-4-one —— C23H19N7OS2
    2-(1,3-benzothiazol-2-ylsulfanyl)-3-{(E)-[2-(4,6-dimethylpyrimidin-2-yl)hydrazinylidene]methyl}-9-methyl-4H-pyrido[1,2-a]pyrimidin-4-one