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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N,N-dimethyl-3-(3-hydroxyphenylthio)benzylamine 141357-98-4 C15H17NOS
    N,N-dimethyl-3-(3-hydroxyphenylthio)benzylamine
    —— N,N-dimethyl-3-(4-chlorophenylthio)benzamide 141358-15-8 C15H14ClNOS
    N,N-dimethyl-3-(4-chlorophenylthio)benzamide
    —— N,N-dimethyl-3-(3-methoxyphenylthio)benzylamine 141357-97-3 C16H19NOS
    N,N-dimethyl-3-(3-methoxyphenylthio)benzylamine
    —— Methyl [2-(methoxycarbonyldisulfanyl)ethyldisulfanyl]formate 71370-11-1 C6H10O4S4
    Methyl [2-(methoxycarbonyldisulfanyl)ethyldisulfanyl]formate
    —— 1-(2-Chloro-5,5-dimethylhex-3-ynyl)sulfanyl-4-methylbenzene 70819-12-4 C15H19ClS
    1-(2-Chloro-5,5-dimethylhex-3-ynyl)sulfanyl-4-methylbenzene
    —— (2S,6S)-8-(O-tert-butyldiphenylsilyl)-1,2-(O-isopropylidene)-4-(trimethylenedithio)octane-1,2,6,8-tetrol 120341-82-4 C30H44O4S2Si
    (2S,6S)-8-(O-tert-butyldiphenylsilyl)-1,2-(O-isopropylidene)-4-(trimethylenedithio)octane-1,2,6,8-tetrol
    —— 3-(3-methoxyphenylthio)benzoic acid 141358-08-9 C14H12O3S
    3-(3-methoxyphenylthio)benzoic acid
    —— 2,2-Bis-(phenylthio)-hexan-3-on 71221-35-7 C18H20OS2
    2,2-Bis-(phenylthio)-hexan-3-on
    —— 1-Bicyclo[2.2.1]hept-5-en-2-yl-ethanethione 78357-17-2 C9H12S
    1-Bicyclo[2.2.1]hept-5-en-2-yl-ethanethione
    —— [3-Chloro-4-(4-methylphenyl)sulfanylbut-1-ynyl]-trimethylsilane 70819-14-6 C14H19ClSSi
    [3-Chloro-4-(4-methylphenyl)sulfanylbut-1-ynyl]-trimethylsilane
    —— bis-(2-vinylsulfanyl-ethyl)-sulfane 6791-33-9 C8H14S3
    bis-(2-vinylsulfanyl-ethyl)-sulfane
    —— 5,6,7,8-tetrahydro-2-oxa-2aλ<sup>4</sup>,3-dithia-1,4-diaza-cyclopenta[<i>cd</i>]azulene 70820-87-0 C7H8N2OS2
    5,6,7,8-tetrahydro-2-oxa-2aλ<sup>4</sup>,3-dithia-1,4-diaza-cyclopenta[<i>cd</i>]azulene
    —— 3-(4-chlorophenylthio)benzoic acid 141358-07-8 C13H9ClO2S
    3-(4-chlorophenylthio)benzoic acid
    —— 2-Ethyl-2-phenylthiopentan-3-on 71221-45-9 C13H18OS
    2-Ethyl-2-phenylthiopentan-3-on
    —— 3,3'-thiodibenzoic acid 22452-72-8 C14H10O4S
    3,3'-thiodibenzoic acid
    —— N-(2-cyclopentenyl)thioethanamide 127310-77-4 C7H11NS
    N-(2-cyclopentenyl)thioethanamide
    —— 2-Ethylsulfanyl-5-(3-fluorophenyl)-1,3,4-oxadiazole 460723-99-3 C10H9FN2OS
    2-Ethylsulfanyl-5-(3-fluorophenyl)-1,3,4-oxadiazole
    —— 1,3-Dimethyl-2-acetonylthio-Δ<sup>4</sup>-imidazolinium-iodid 70529-90-7 C8H13N2OS*I
    1,3-Dimethyl-2-acetonylthio-Δ<sup>4</sup>-imidazolinium-iodid
    —— 5,6-Dihydro-4H-thieno[2,3-b]thiopyran 33892-71-6 C7H8S2
    5,6-Dihydro-4H-thieno[2,3-b]thiopyran
    —— .4-[(2,4-dichloro-5-methylphenyl)sulfanyl]-3,5-dinitrobenzonitrile 1137560-51-0 C14H7Cl2N3O4S
    .4-[(2,4-dichloro-5-methylphenyl)sulfanyl]-3,5-dinitrobenzonitrile
    —— 4-(4-Methoxyphenyl)sulfanyl-3,5-dinitrobenzonitrile 1137560-59-8 C14H9N3O5S
    4-(4-Methoxyphenyl)sulfanyl-3,5-dinitrobenzonitrile
    —— 2-(methylthio)-2-imidazoline hydriodide 6313-69-5 C4H6N2S*HI
    2-(methylthio)-2-imidazoline hydriodide
    —— 7-tert-butyl-2,3-dihydro-3,3-dimethyl-5-nitro-benzothiophene 194299-09-7 C14H19NO2S
    7-tert-butyl-2,3-dihydro-3,3-dimethyl-5-nitro-benzothiophene
    —— 4,5-Bis(trifluormethyl)-1,3-dithiol-2-carbonsaeure 156251-53-5 C6H2F6O2S2
    4,5-Bis(trifluormethyl)-1,3-dithiol-2-carbonsaeure
    —— 4,5-Bis(trifluormethyl)-1,3-dithiol-2,2-dicarbonsaeure-diethylester 156251-51-3 C11H10F6O4S2
    4,5-Bis(trifluormethyl)-1,3-dithiol-2,2-dicarbonsaeure-diethylester
    —— 2-(4-fluorophenyl)-3-[4-(methylthio)phenyl]thiophene 88149-83-1 C17H13FS2
    2-(4-fluorophenyl)-3-[4-(methylthio)phenyl]thiophene
    —— 2-Methyl-[1,3]dithiane-2-carbonitrile N-oxide 188841-14-7 C6H9NOS2
    2-Methyl-[1,3]dithiane-2-carbonitrile N-oxide
    —— Ethyl-dithiocarbamic acid phenyl ester 51098-07-8 C9H11NS2
    Ethyl-dithiocarbamic acid phenyl ester
    —— (3,5-dibromophenyl)(methyl)sulfane 141938-37-6 C7H6Br2S
    (3,5-dibromophenyl)(methyl)sulfane
    —— 1-methyl-4-phenylsulfanylpiperidine 738568-03-1 C12H17NS
    1-methyl-4-phenylsulfanylpiperidine
    —— 1-<4-(ethoxycarbonylthio)-3-(1,1-dimethylethyl)-1,2-oxazol-5-yl>-3-methylurea 118097-86-2 C12H19N3O4S
    1-<4-(ethoxycarbonylthio)-3-(1,1-dimethylethyl)-1,2-oxazol-5-yl>-3-methylurea
    —— 3-amino-5-butylsulfanyl-N-methyl-1,2,4-triazole-4-carboxamide 79742-10-2 C8H15N5OS
    3-amino-5-butylsulfanyl-N-methyl-1,2,4-triazole-4-carboxamide
    —— phenyl 2-deoxy-3,4-di-O-diethylisopropylsilyl-2-N-methylamino-1-thio-α-D-xylopyranoside 1342295-11-7 C26H49NO3SSi2
    phenyl 2-deoxy-3,4-di-O-diethylisopropylsilyl-2-N-methylamino-1-thio-α-D-xylopyranoside
    —— 5-(4-chloro-benzyl)-6-methyl-2-methylsulfanyl-3<i>H</i>-pyrimidin-4-one 63204-37-5 C13H13ClN2OS
    5-(4-chloro-benzyl)-6-methyl-2-methylsulfanyl-3<i>H</i>-pyrimidin-4-one
    —— 8,11-Bis(4-chlorphenylthio)tricyclo<4.3.3.0<sup>1,6</sup>>dodeca-7,10-dien 119657-29-3 C24H22Cl2S2
    8,11-Bis(4-chlorphenylthio)tricyclo<4.3.3.0<sup>1,6</sup>>dodeca-7,10-dien
    —— 6-methyl-2-(methylthio)-5-propylpyrimidin-4(3H)-one 59144-22-8 C9H14N2OS
    6-methyl-2-(methylthio)-5-propylpyrimidin-4(3H)-one
    —— 5-butyl-4-methyl-2-methylsulfanyl-1H-pyrimidin-6-one 29113-42-6 C10H16N2OS
    5-butyl-4-methyl-2-methylsulfanyl-1H-pyrimidin-6-one
    —— 5-(4-methyl-benzyl)-2-methylsulfanyl-3<i>H</i>-pyrimidin-4-one 63204-31-9 C13H14N2OS
    5-(4-methyl-benzyl)-2-methylsulfanyl-3<i>H</i>-pyrimidin-4-one
    —— 8,11-Bis(phenylthio)tricyclo<4.3.3.0<sup>1,6</sup>>dodeca-7,10-dien 119657-27-1 C24H24S2
    8,11-Bis(phenylthio)tricyclo<4.3.3.0<sup>1,6</sup>>dodeca-7,10-dien
    —— 5-(4-fluorobenzyl)-2-methylthio-4-pyrimidone 92712-82-8 C12H11FN2OS
    5-(4-fluorobenzyl)-2-methylthio-4-pyrimidone
    —— 1-Methyl-3-methylthio-1,2,4-triazol 35102-22-8 C4H7N3S
    1-Methyl-3-methylthio-1,2,4-triazol
    —— 3-methylsulfanyl-6-pyridin-3-ylmethyl-4<i>H</i>-[1,2,4]triazin-5-one 68262-26-0 C10H10N4OS
    3-methylsulfanyl-6-pyridin-3-ylmethyl-4<i>H</i>-[1,2,4]triazin-5-one
    —— 5-(3-chlorobenzyl)-2-methylthio-4-pyrimidone 63204-33-1 C12H11ClN2OS
    5-(3-chlorobenzyl)-2-methylthio-4-pyrimidone
    —— 5-(2-chlorobenzyl)-2-methylthio-4-pyrimidone 63204-42-2 C12H11ClN2OS
    5-(2-chlorobenzyl)-2-methylthio-4-pyrimidone
    —— 2-methylsulfanyl-5-phenethyl-3<i>H</i>-pyrimidin-4-one 63204-29-5 C13H14N2OS
    2-methylsulfanyl-5-phenethyl-3<i>H</i>-pyrimidin-4-one
    —— 5-<2>Thiazolylmethyl-2-methylthio-4-pyrimidon 64107-62-6 C9H9N3OS2
    5-<2>Thiazolylmethyl-2-methylthio-4-pyrimidon
    —— 2-methylsulfanyl-5-(4-phenyl-butyl)-3<i>H</i>-pyrimidin-4-one 63204-43-3 C15H18N2OS
    2-methylsulfanyl-5-(4-phenyl-butyl)-3<i>H</i>-pyrimidin-4-one
    —— Methyl [9-(methoxycarbonyldisulfanyl)nonyldisulfanyl]formate 71370-17-7 C13H24O4S4
    Methyl [9-(methoxycarbonyldisulfanyl)nonyldisulfanyl]formate
    —— 5-chloro-3-nitro-2-phenylsulfanyl-pyridine 103646-10-2 C11H7ClN2O2S
    5-chloro-3-nitro-2-phenylsulfanyl-pyridine
    —— [2-(4-Chloro-2-fluoro-phenylsulfanyl)-phenyl]-methanol 73129-18-7 C13H10ClFOS
    [2-(4-Chloro-2-fluoro-phenylsulfanyl)-phenyl]-methanol