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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[[2-[[(1,1-Dimethylethoxy)carbonyl]amino]thiazol-5-yl]thio]benzoic Acid 439578-79-7 C15H16N2O4S2
    3-[[2-[[(1,1-Dimethylethoxy)carbonyl]amino]thiazol-5-yl]thio]benzoic Acid
    —— {5-[3-(4-Acetyl-piperazine-1-carbonyl)-phenylsulfanyl]-thiazol-2-yl}-carbamic acid tert-butyl ester 439578-80-0 C21H26N4O4S2
    {5-[3-(4-Acetyl-piperazine-1-carbonyl)-phenylsulfanyl]-thiazol-2-yl}-carbamic acid tert-butyl ester
    —— 2-[(2-Bromophenyl)sulfanylmethyl]furan 123100-41-4 C11H9BrOS
    2-[(2-Bromophenyl)sulfanylmethyl]furan
    —— 1-(4-((4-chlorophenyl)thio)phenyl)-3-ethylurea 54457-31-7 C15H15ClN2OS
    1-(4-((4-chlorophenyl)thio)phenyl)-3-ethylurea
    —— N-[4-(4-chlorophenyl)sulfanylphenyl]-N-methylformamide 77711-37-6 C14H12ClNOS
    N-[4-(4-chlorophenyl)sulfanylphenyl]-N-methylformamide
    —— N-[4-(4-chlorophenyl)sulfanylphenyl]-2-(diethylamino)-N-methylacetamide 77711-68-3 C19H23ClN2OS
    N-[4-(4-chlorophenyl)sulfanylphenyl]-2-(diethylamino)-N-methylacetamide
    —— 4-Chlor-4'-isothiocyanatodiphenylsulfid 25057-76-5 C13H8ClNS2
    4-Chlor-4'-isothiocyanatodiphenylsulfid
    —— 2-chloro-N-[4-(4-chlorophenyl)sulfanylphenyl]-N-methylacetamide 77711-39-8 C15H13Cl2NOS
    2-chloro-N-[4-(4-chlorophenyl)sulfanylphenyl]-N-methylacetamide
    —— 2-phenylthiofuro<3,2-b>pyridine 142502-96-3 C13H9NOS
    2-phenylthiofuro<3,2-b>pyridine
    —— 1-[4-(4-Chloro-phenylsulfanyl)-phenyl]-3-methyl-urea 54457-30-6 C14H13ClN2OS
    1-[4-(4-Chloro-phenylsulfanyl)-phenyl]-3-methyl-urea
    —— 4-Chloracetylamino-4'-chlordiphenylsulfid 36161-08-7 C14H11Cl2NOS
    4-Chloracetylamino-4'-chlordiphenylsulfid
    —— 2-benzo[1,3]dithiol-2-ylidene-cyclopent-4-ene-1,3-dione 62576-02-7 C12H6O2S2
    2-benzo[1,3]dithiol-2-ylidene-cyclopent-4-ene-1,3-dione
    —— N-[4-(4-chlorophenyl)sulfanylphenyl]cyclopropanecarboxamide 32631-18-8 C16H14ClNOS
    N-[4-(4-chlorophenyl)sulfanylphenyl]cyclopropanecarboxamide
    —— N-(4-((4-Chlorophenyl)thio)phenyl)-N-methyl-2-(4-methylpiperazin-1-yl)acetamide 77711-69-4 C20H24ClN3OS
    N-(4-((4-Chlorophenyl)thio)phenyl)-N-methyl-2-(4-methylpiperazin-1-yl)acetamide
    —— 1-(4-((4-chlorophenyl)thio)phenyl)-3-(pyridin-3-ylmethyl)urea 1363155-24-1 C19H16ClN3OS
    1-(4-((4-chlorophenyl)thio)phenyl)-3-(pyridin-3-ylmethyl)urea
    —— [4-(4-chlorophenylsulfanyl)phenyl]-(4,5-dihydro-1H-imidazol-2-yl)amine 71576-74-4 C15H14ClN3S
    [4-(4-chlorophenylsulfanyl)phenyl]-(4,5-dihydro-1H-imidazol-2-yl)amine
    —— acetic acid-[4-(4-chloro-phenylsulfanyl)-anilide] 90309-20-9 C14H12ClNOS
    acetic acid-[4-(4-chloro-phenylsulfanyl)-anilide]
    —— 4-Chlor-N-methyl-2-phenylthiothiobenzamid 60253-30-7 C14H12ClNS2
    4-Chlor-N-methyl-2-phenylthiothiobenzamid
    —— S-methyl-O-n-butyl monothiocarbonate 116423-15-5 C6H12O2S
    S-methyl-O-n-butyl monothiocarbonate
    —— Ethyl 7-cyano-6-methylsulfanyl-4-oxothieno[3,2-d][1,3]oxazine-2-carboxylate 218968-02-6 C11H8N2O4S2
    Ethyl 7-cyano-6-methylsulfanyl-4-oxothieno[3,2-d][1,3]oxazine-2-carboxylate
    —— 2-phenylthio-3-bromofuro<3,2-b>pyridine 142502-99-6 C13H8BrNOS
    2-phenylthio-3-bromofuro<3,2-b>pyridine
    —— 2-(phenylthioethynyl)-3-pyridinol 142503-08-0 C13H9NOS
    2-(phenylthioethynyl)-3-pyridinol
    —— 3-Ethoxycarbonylamino-5-methylsulfanyl-thiophen-4-carbonitril 663905-20-2 C9H10N2O2S2
    3-Ethoxycarbonylamino-5-methylsulfanyl-thiophen-4-carbonitril
    —— N',N-Dimethyl-N-(2-cyanethyl)-thioharnstoff 4983-32-8 C6H11N3S
    N',N-Dimethyl-N-(2-cyanethyl)-thioharnstoff
    —— 2-Methyl-6-methylsulfanyl-4-oxothieno[3,2-d][1,3]oxazine-7-carbonitrile 133386-07-9 C9H6N2O2S2
    2-Methyl-6-methylsulfanyl-4-oxothieno[3,2-d][1,3]oxazine-7-carbonitrile
    —— 5-(2-(6-bromopyridin-2-ylamino)thiazol-5-ylthio)-N-(2-cyanoethyl)-N,2-dimethylbenzamide 1012060-85-3 C20H18BrN5OS2
    5-(2-(6-bromopyridin-2-ylamino)thiazol-5-ylthio)-N-(2-cyanoethyl)-N,2-dimethylbenzamide
    —— 3-{[4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylmethyl]methylamino}propionitrile 1185190-03-7 C19H22IN3OS
    3-{[4-(3,5-dimethylphenylsulfanyl)-5-iodo-2-methyl-6-oxo-1,6-dihydropyridin-3-ylmethyl]methylamino}propionitrile
    —— (5R)-5-(2-methoxyethoxymethoxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione 199927-76-9 C10H14O3S5
    (5R)-5-(2-methoxyethoxymethoxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiine-2-thione
    —— 2-Phenyl-5,6-dihydro-4H-thieno<2,3-d><1,3>oxazin-4-on 79750-97-3 C12H9NO2S
    2-Phenyl-5,6-dihydro-4H-thieno<2,3-d><1,3>oxazin-4-on
    —— 2,2'-m-Phenylenbis(6,7-dihydro-4H-thieno<2,3-d><1,3>oxazin-4-on) 81930-86-1 C18H12N2O4S2
    2,2'-m-Phenylenbis(6,7-dihydro-4H-thieno<2,3-d><1,3>oxazin-4-on)
    —— 2-Isopropyl-5,6-dihydro-4H-thieno<2,3-d><1,3>oxazin-4-on 79750-98-4 C9H11NO2S
    2-Isopropyl-5,6-dihydro-4H-thieno<2,3-d><1,3>oxazin-4-on
    —— 2-Phenyl-6,7-dihydro-4H,5H-thiopyrano<2,3-d><1,3>oxazin-4-on 79750-96-2 C13H11NO2S
    2-Phenyl-6,7-dihydro-4H,5H-thiopyrano<2,3-d><1,3>oxazin-4-on
    —— tert-butyl N-[5-[3-(4-acetylpiperazine-1-carbonyl)-4-hydroxyphenyl]sulfanyl-1,3-thiazol-2-yl]carbamate 439574-89-7 C21H26N4O5S2
    tert-butyl N-[5-[3-(4-acetylpiperazine-1-carbonyl)-4-hydroxyphenyl]sulfanyl-1,3-thiazol-2-yl]carbamate
    —— 9-phenylthioisocolchicide 182753-96-4 C27H27NO5S
    9-phenylthioisocolchicide
    —— 2,2'-Sulfanediylbis(4-methoxyphenol) 66582-91-0 C14H14O4S
    2,2'-Sulfanediylbis(4-methoxyphenol)
    —— 2-(1-hydroxy-1-methylethyl)-2,3-dihydrobenzo[b]thiophene-7-carboxylic acid 532412-77-4 C12H14O3S
    2-(1-hydroxy-1-methylethyl)-2,3-dihydrobenzo[b]thiophene-7-carboxylic acid
    —— 3-[(2-Aminothiazol-5-yl)thio]-4-methylbenzoic Acid Methyl Ester 439578-88-8 C12H12N2O2S2
    3-[(2-Aminothiazol-5-yl)thio]-4-methylbenzoic Acid Methyl Ester
    —— 2-Methyl-2-[1-(phenylsulfanyl)-3-butenyl]cyclohexanone 83180-94-3 C17H22OS
    2-Methyl-2-[1-(phenylsulfanyl)-3-butenyl]cyclohexanone
    —— α-Phenylthio-β-butyl-γ-butyrolacton 54145-00-5 C14H18O2S
    α-Phenylthio-β-butyl-γ-butyrolacton
    —— (6-methyl-2-methylthiopyrimidin-4-yloxy)acetohydrazide 149876-28-8 C8H12N4O2S
    (6-methyl-2-methylthiopyrimidin-4-yloxy)acetohydrazide
    —— 4-[2-(Furan-2-yl)-1,3-dithian-2-yl]but-1-ynyl-trimethylsilane 1045706-27-1 C15H22OS2Si
    4-[2-(Furan-2-yl)-1,3-dithian-2-yl]but-1-ynyl-trimethylsilane
    —— 1-[3-Chloro-4-(4-nitro-phenylsulfanyl)-phenyl]-3-propyl-urea 54457-21-5 C16H16ClN3O3S
    1-[3-Chloro-4-(4-nitro-phenylsulfanyl)-phenyl]-3-propyl-urea
    —— 5-Cyclopentyliden-3-phenylthio-2(5H)-furanon 59181-54-3 C15H14O2S
    5-Cyclopentyliden-3-phenylthio-2(5H)-furanon
    —— 1-[3-Chloro-4-(4-nitro-phenylsulfanyl)-phenyl]-3-ethyl-urea 54457-15-7 C15H14ClN3O3S
    1-[3-Chloro-4-(4-nitro-phenylsulfanyl)-phenyl]-3-ethyl-urea
    —— acetic acid-[4-(4-amino-phenylsulfanyl)-anilide] 54538-22-6 C14H14N2OS
    acetic acid-[4-(4-amino-phenylsulfanyl)-anilide]
    —— N-{4-[4-(3-Methyl-ureido)-phenylsulfanyl]-phenyl}-acetamide 54456-61-0 C16H17N3O2S
    N-{4-[4-(3-Methyl-ureido)-phenylsulfanyl]-phenyl}-acetamide
    —— 1-[4-(4-Bromo-phenylsulfanyl)-3,5-dimethyl-phenyl]-3-methyl-urea 54456-76-7 C16H17BrN2OS
    1-[4-(4-Bromo-phenylsulfanyl)-3,5-dimethyl-phenyl]-3-methyl-urea
    —— 2-(2-Phenylsulfanyl-phenyl)-acetamide 62551-14-8 C14H13NOS
    2-(2-Phenylsulfanyl-phenyl)-acetamide
    —— 3-chloro-4-methylsulfanyl-phenol 13560-43-5 C7H7ClOS
    3-chloro-4-methylsulfanyl-phenol
    —— NSC-76302 5943-39-5 C12H24N2O6S4
    NSC-76302