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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-methylthiocyclohexylamide 89332-93-4 C8H15NS
    N-methylthiocyclohexylamide
    —— α-Hydroxy-cyclohexancarbaldehyd-diphenylthioacetal 13307-57-8 C19H22OS2
    α-Hydroxy-cyclohexancarbaldehyd-diphenylthioacetal
    —— 1-cycloheptenylmethyl phenyl sulfide 104281-70-1 C14H18S
    1-cycloheptenylmethyl phenyl sulfide
    —— 2-Methyl-2-phenylthiocycloheptanone 80344-83-8 C14H18OS
    2-Methyl-2-phenylthiocycloheptanone
    —— 6-(2-amino-phenyl)-3-butylsulfanyl-2(4)<i>H</i>-[1,2,4]triazin-5-one 41383-89-5 C13H16N4OS
    6-(2-amino-phenyl)-3-butylsulfanyl-2(4)<i>H</i>-[1,2,4]triazin-5-one
    —— 2-Methylthio-5-(4-tolylthio)pyrimidin 61727-20-6 C12H12N2S2
    2-Methylthio-5-(4-tolylthio)pyrimidin
    —— 1-(2-methylsulfanyl-pyrrol-3-yl)-ethanone 61201-14-7 C7H9NOS
    1-(2-methylsulfanyl-pyrrol-3-yl)-ethanone
    —— spiro[1,3-dioxolane-2,2'-11-oxa-8,14-dithia-19,20-diazatricyclo[13.3.1.13,7]icosa-1(19),3(20),4,6,15,17-hexaene] 90867-69-9 C17H18N2O3S2
    spiro[1,3-dioxolane-2,2'-11-oxa-8,14-dithia-19,20-diazatricyclo[13.3.1.13,7]icosa-1(19),3(20),4,6,15,17-hexaene]
    —— 1-Ethylsulfanyl-2-methyl-3-vinyl-cyclopropane 62162-29-2 C8H14S
    1-Ethylsulfanyl-2-methyl-3-vinyl-cyclopropane
    —— 3-Methylmercapto-4-p-tolyl-5-oxo-6-phenyl-4,5-dihydro-1,2,4-triazine 60438-36-0 C17H15N3OS
    3-Methylmercapto-4-p-tolyl-5-oxo-6-phenyl-4,5-dihydro-1,2,4-triazine
    —— 1-Methyl-2-pent-4-enylsulfanyl-3-vinyl-cyclopropane 62162-28-1 C11H18S
    1-Methyl-2-pent-4-enylsulfanyl-3-vinyl-cyclopropane
    —— 6-(2-Aminophenyl)-3-(benzylsulfanyl)-1,2,4-triazin-5-ol 55625-11-1 C16H14N4OS
    6-(2-Aminophenyl)-3-(benzylsulfanyl)-1,2,4-triazin-5-ol
    —— 2-methylsulfanyl-5-phenylsulfanyl-pyrimidine-4-carbonyl chloride 61727-11-5 C12H9ClN2OS2
    2-methylsulfanyl-5-phenylsulfanyl-pyrimidine-4-carbonyl chloride
    —— 4-propylsulfanyl-hex-1-ene 62162-21-4 C9H18S
    4-propylsulfanyl-hex-1-ene
    —— 6-(2-Aminophenyl)-3-[(4-chlorobenzyl)sulfanyl]-1,2,4-triazin-5-ol 354786-75-7 C16H13ClN4OS
    6-(2-Aminophenyl)-3-[(4-chlorobenzyl)sulfanyl]-1,2,4-triazin-5-ol
    —— N-[5-methyl-2-(phenylsulfanyl)phenyl]-1-benzofuran-2-sulfonamide 1451261-71-4 C21H17NO3S2
    N-[5-methyl-2-(phenylsulfanyl)phenyl]-1-benzofuran-2-sulfonamide
    —— 5-(4-bromo-phenylsulfanyl)-2-methylsulfanyl-pyrimidine 61727-22-8 C11H9BrN2S2
    5-(4-bromo-phenylsulfanyl)-2-methylsulfanyl-pyrimidine
    —— 5-methyl-2-(phenylthio)aniline 53691-94-4 C13H13NS
    5-methyl-2-(phenylthio)aniline
    —— (2-methylsulfanyl-5-phenylsulfanyl-pyrimidin-4-yl)-methanol 61727-18-2 C12H12N2OS2
    (2-methylsulfanyl-5-phenylsulfanyl-pyrimidin-4-yl)-methanol
    —— 1-(4-ethoxy-butylsulfanyl)-2-methyl-propene 62162-07-6 C10H20OS
    1-(4-ethoxy-butylsulfanyl)-2-methyl-propene
    —— 1-methyl-3,4-dichloro-5-(2-chloroethylthio)pyrazole 93460-25-4 C6H7Cl3N2S
    1-methyl-3,4-dichloro-5-(2-chloroethylthio)pyrazole
    —— 5-cyano-2-(4,4-difluorobut-3-enylthio)pyridine 172935-22-7 C10H8F2N2S
    5-cyano-2-(4,4-difluorobut-3-enylthio)pyridine
    —— (11β,13α,17β)-11,17-epoxy-9-fluoro-17-methyl-13-(phenylthio)-18-norandrosta-1,4-dien-3-one 70094-29-0 C25H27FO2S
    (11β,13α,17β)-11,17-epoxy-9-fluoro-17-methyl-13-(phenylthio)-18-norandrosta-1,4-dien-3-one
    —— N-methyl-2-(4-methyl-2-nitrophenylthio)benzylamine 412015-26-0 C15H16N2O2S
    N-methyl-2-(4-methyl-2-nitrophenylthio)benzylamine
    —— [3-Amino-4-(2-methylaminomethyl-phenylsulfanyl)-phenyl]-methanol 853180-72-0 C15H18N2OS
    [3-Amino-4-(2-methylaminomethyl-phenylsulfanyl)-phenyl]-methanol
    —— 1,8-bis(4-fluorophenylthio)perfluorooctane 130028-67-0 C20H8F18S2
    1,8-bis(4-fluorophenylthio)perfluorooctane
    —— 2-(1-(2,5-dimethylphenyl)ethylthio)-4,6-dimethylpyridine-N-oxide 478620-10-9 C17H21NOS
    2-(1-(2,5-dimethylphenyl)ethylthio)-4,6-dimethylpyridine-N-oxide
    —— Bis[4-[(3,5-dioxo-1,2,4-oxadiazolidin-2-yl)methyl]phenyl]sulfide 163301-01-7 C18H14N4O6S
    Bis[4-[(3,5-dioxo-1,2,4-oxadiazolidin-2-yl)methyl]phenyl]sulfide
    —— 2-[(4-methyl-2-nitrophenyl)thio]benzamide 850662-95-2 C14H12N2O3S
    2-[(4-methyl-2-nitrophenyl)thio]benzamide
    —— 2-[(4-methyl-2-nitrophenyl)thio]benzenemethanamine 850662-96-3 C14H14N2O2S
    2-[(4-methyl-2-nitrophenyl)thio]benzenemethanamine
    —— N-methyl-2-(4'-methyl-2'-aminophenylthio)benzamide 860778-58-1 C15H16N2OS
    N-methyl-2-(4'-methyl-2'-aminophenylthio)benzamide
    —— 2-methylsulfanyl-5-phenylsulfanyl-pyrimidine-4-carboxylic acid ethyl ester 61727-12-6 C14H14N2O2S2
    2-methylsulfanyl-5-phenylsulfanyl-pyrimidine-4-carboxylic acid ethyl ester
    —— N,N-dimethyl-2-[(4-methyl-2-nitrophenyl)thio]benzenemethanamine 411208-43-0 C16H18N2O2S
    N,N-dimethyl-2-[(4-methyl-2-nitrophenyl)thio]benzenemethanamine
    —— 3-methyl-1-phenyl-2,2-bis(phenylsulfanyl)butan-1-ol 61173-90-8 C23H24OS2
    3-methyl-1-phenyl-2,2-bis(phenylsulfanyl)butan-1-ol
    —— N,N-dimethyl-2-(2-amino-4-methylphenylthio)benzylamine 411208-45-2 C16H20N2S
    N,N-dimethyl-2-(2-amino-4-methylphenylthio)benzylamine
    —— ethyl 2-(4'-methyl-2'-nitrophenylthio)benzoate 860778-56-9 C16H15NO4S
    ethyl 2-(4'-methyl-2'-nitrophenylthio)benzoate
    —— dl-5-chloro-6-ethyl-4-(α-methyl-4-methylthiobenzylamino)pyrimidine 135132-22-8 C15H18ClN3S
    dl-5-chloro-6-ethyl-4-(α-methyl-4-methylthiobenzylamino)pyrimidine
    —— N-methyl-2-(2'-amino-4'-methylphenylthio)benzylamine 412015-27-1 C15H18N2S
    N-methyl-2-(2'-amino-4'-methylphenylthio)benzylamine
    —— 5-(4,4-difluorobut-3-enylthio)-1,3-dimethyl4-nitropyrazole 172933-97-0 C9H11F2N3O2S
    5-(4,4-difluorobut-3-enylthio)-1,3-dimethyl4-nitropyrazole
    —— N-methyl-2-(4'-methyl-2'-nitrophenylthio)benzamide 412015-25-9 C15H14N2O3S
    N-methyl-2-(4'-methyl-2'-nitrophenylthio)benzamide
    —— 2-((2,5-dimethylphenyl)methylthio) pyridine 478620-28-9 C14H15NS
    2-((2,5-dimethylphenyl)methylthio) pyridine
    —— 2-[1-(2,5-dimethylphenyl)ethylthio]-6-chloropyridine-N-oxide 478620-07-4 C15H16ClNOS
    2-[1-(2,5-dimethylphenyl)ethylthio]-6-chloropyridine-N-oxide
    —— 1-Methyl-2-vinyl-3-vinylsulfanyl-cyclopropane 62162-26-9 C8H12S
    1-Methyl-2-vinyl-3-vinylsulfanyl-cyclopropane
    —— 2-(2,4,6-trimethylphenylmethylthio)pyridine N-oxide 60263-81-2 C15H17NOS
    2-(2,4,6-trimethylphenylmethylthio)pyridine N-oxide
    —— 1-chloro-2-heptylmercapto-ethane 24475-71-6 C9H19ClS
    1-chloro-2-heptylmercapto-ethane
    —— ({4-(benzyloxy)-3-[(4-fluorophenyl)sulphanyl]benzyl}oxy)(tert-butyl)dimethylsilane 459430-92-3 C26H31FO2SSi
    ({4-(benzyloxy)-3-[(4-fluorophenyl)sulphanyl]benzyl}oxy)(tert-butyl)dimethylsilane
    —— 1-methyl-4-(phenylthio)-1,2,3,6-tetrahydropyridine 144466-77-3 C12H15NS
    1-methyl-4-(phenylthio)-1,2,3,6-tetrahydropyridine
    —— 4-Pyrimidinecarboxylic acid, 2-(methylthio)-5-(2-naphthalenylthio)- 61727-10-4 C16H12N2O2S2
    4-Pyrimidinecarboxylic acid, 2-(methylthio)-5-(2-naphthalenylthio)-
    —— 5-amino-1-(3-chloro-4-[4-chlorophenylthio]benzyl)-1,2,3-triazole-4-carboxamide 99519-85-4 C16H13Cl2N5OS
    5-amino-1-(3-chloro-4-[4-chlorophenylthio]benzyl)-1,2,3-triazole-4-carboxamide
    —— 2-methylsulfanyl-5-(4-nitro-phenylsulfanyl)-pyrimidine-4-carboxylic acid 61727-09-1 C12H9N3O4S2
    2-methylsulfanyl-5-(4-nitro-phenylsulfanyl)-pyrimidine-4-carboxylic acid