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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [2-(4-Chloro-3-methoxy-phenylsulfanyl)-4-methoxy-phenyl]-acetic acid 61150-74-1 C16H15ClO4S
    [2-(4-Chloro-3-methoxy-phenylsulfanyl)-4-methoxy-phenyl]-acetic acid
    —— tert-butyl-dimethyl-[(E)-1-(3-methylpyridin-2-yl)sulfanylprop-1-enoxy]silane 146362-77-8 C15H25NOSSi
    tert-butyl-dimethyl-[(E)-1-(3-methylpyridin-2-yl)sulfanylprop-1-enoxy]silane
    —— S-(1-cyclopropylethyl) S-methyl dithiocarbonate 111661-14-4 C7H12OS2
    S-(1-cyclopropylethyl) S-methyl dithiocarbonate
    —— 2-(4-chloro-3-methoxyphenylthio)-4-methoxyphenylacetonitrile 61150-73-0 C16H14ClNO2S
    2-(4-chloro-3-methoxyphenylthio)-4-methoxyphenylacetonitrile
    —— 1-(3-methyl-pyridin-2-yl)-2-(2-aminobenzylthio)imidazole 135126-13-5 C16H16N4S
    1-(3-methyl-pyridin-2-yl)-2-(2-aminobenzylthio)imidazole
    —— 2-(4-chloro-3-methoxyphenylthio)phenylacetic acid 61150-53-6 C15H13ClO3S
    2-(4-chloro-3-methoxyphenylthio)phenylacetic acid
    —— 2-(4-chloro-3-methoxyphenylthio)benzoic acid 61150-49-0 C14H11ClO3S
    2-(4-chloro-3-methoxyphenylthio)benzoic acid
    —— 2-<<2-(dimethylamino)benzyl>thio>-1-<2-(3-methylpyridyl)>imidazole 117348-09-1 C18H20N4S
    2-<<2-(dimethylamino)benzyl>thio>-1-<2-(3-methylpyridyl)>imidazole
    —— 2-(4-chloro-3-methoxyphenylthio)benzyl alcohol 61150-50-3 C14H13ClO2S
    2-(4-chloro-3-methoxyphenylthio)benzyl alcohol
    —— ethyl 3-oxo-4-(phenylthio)cyclohexanecarboxylate 907211-56-7 C15H18O3S
    ethyl 3-oxo-4-(phenylthio)cyclohexanecarboxylate
    —— 2-[(E)-1-(4-methylsulfanylphenyl)ethylideneamino]oxyacetic acid 63564-08-9 C11H13NO3S
    2-[(E)-1-(4-methylsulfanylphenyl)ethylideneamino]oxyacetic acid
    —— 5-(4-chloro-phenyl)-3-methylsulfanyl-isoxazole-4-carbonitrile 68364-89-6 C11H7ClN2OS
    5-(4-chloro-phenyl)-3-methylsulfanyl-isoxazole-4-carbonitrile
    —— 3-hydroxy-N,N-dimethylbutanethioamide 103660-95-3 C6H13NOS
    3-hydroxy-N,N-dimethylbutanethioamide
    —— benzo[<i>b</i>]pyrido[2,3-<i>e</i>][1,4]thiazine-10-carboxylic acid 1-methyl-piperidin-4-yl ester 98471-17-1 C18H19N3O2S
    benzo[<i>b</i>]pyrido[2,3-<i>e</i>][1,4]thiazine-10-carboxylic acid 1-methyl-piperidin-4-yl ester
    —— (R)-3-hydroxy-N,N,4-trimethylpentanethioamide 103660-97-5 C8H17NOS
    (R)-3-hydroxy-N,N,4-trimethylpentanethioamide
    —— 4-[5-fluoro-3-(4-methyl-3-oxo-2,3-dihydro-4H-pyrido[3,2-b][1,4]oxazin-7-ylthio)phenyl]-4-methoxytetrahydropyran 139502-92-4 C20H21FN2O4S
    4-[5-fluoro-3-(4-methyl-3-oxo-2,3-dihydro-4H-pyrido[3,2-b][1,4]oxazin-7-ylthio)phenyl]-4-methoxytetrahydropyran
    —— 3-(dimethylamino)-N,N-dimethylprop-2-enethioamide 34009-27-3 C7H14N2S
    3-(dimethylamino)-N,N-dimethylprop-2-enethioamide
    —— N,N-dimmethyl hydroxy-3 methyl-3 hexene-4 thioamide 97584-79-7 C9H17NOS
    N,N-dimmethyl hydroxy-3 methyl-3 hexene-4 thioamide
    —— Pentanethioamide, 3-hydroxy-N,N,4-trimethyl- 103660-97-5 C8H17NOS
    Pentanethioamide, 3-hydroxy-N,N,4-trimethyl-
    —— 3-hydroxy-N,N,4,4-tetramethylpentanethioamide 103660-98-6 C9H19NOS
    3-hydroxy-N,N,4,4-tetramethylpentanethioamide
    —— 4-[3-(1,3-dimethyl-2-oxo-2,3-dihydrobenzimidazol-5-ylthio)-5-fluorophenyl]-4-methoxytetrahydropyran 139487-02-8 C21H23FN2O3S
    4-[3-(1,3-dimethyl-2-oxo-2,3-dihydrobenzimidazol-5-ylthio)-5-fluorophenyl]-4-methoxytetrahydropyran
    —— 4-methylthio-5-amino-6-mercaptopyrimidine 37489-41-1 C5H7N3S2
    4-methylthio-5-amino-6-mercaptopyrimidine
    —— 4-[5-fluoro-3-(3-ethoxycarbonylmethylthio-4-nitrophenylthio)phenyl]-4-methoxytetrahydropyran 139503-20-1 C22H24FNO6S2
    4-[5-fluoro-3-(3-ethoxycarbonylmethylthio-4-nitrophenylthio)phenyl]-4-methoxytetrahydropyran
    —— 6-phenylsulfanyl-pyrazine-2-carboxylic acid 66533-84-4 C11H8N2O2S
    6-phenylsulfanyl-pyrazine-2-carboxylic acid
    —— 2-Fluoro-4'-(trifluoromethyl)diphenyl Sulfide 126799-50-6 C13H8F4S
    2-Fluoro-4'-(trifluoromethyl)diphenyl Sulfide
    —— 1-Methyl-4-[2-[2-(trifluoromethyl)phenyl]sulfanylphenoxy]piperidine 126799-53-9 C19H20F3NOS
    1-Methyl-4-[2-[2-(trifluoromethyl)phenyl]sulfanylphenoxy]piperidine
    —— 1-Methyl-4-piperidinyl 2-{[4-(trifluoromethyl)phenyl]sulfanyl}phenyl ether 126799-54-0 C19H20F3NOS
    1-Methyl-4-piperidinyl 2-{[4-(trifluoromethyl)phenyl]sulfanyl}phenyl ether
    —— 1-Methyl-4-(4-(phenylthio)phenoxy)piperidine 126799-52-8 C18H21NOS
    1-Methyl-4-(4-(phenylthio)phenoxy)piperidine
    —— ethyl 2-diazo-2-<2-chloro-5-fluoro-6-(p-tolylthio)nicotinoyl>acetate 133413-97-5 C17H13ClFN3O3S
    ethyl 2-diazo-2-<2-chloro-5-fluoro-6-(p-tolylthio)nicotinoyl>acetate
    —— 1-Methyl-4-(2-(phenylthio)phenoxy)piperidine 126799-51-7 C18H21NOS
    1-Methyl-4-(2-(phenylthio)phenoxy)piperidine
    —— 3-((pyridin-3-ylmethyl)thio)-5,6-di-p-tolyl-1,2,4-triazine 1478982-11-4 C23H20N4S
    3-((pyridin-3-ylmethyl)thio)-5,6-di-p-tolyl-1,2,4-triazine
    —— 4,5,6-trimethyl-2-methylsulfanyl-pyrimidine 65641-62-5 C8H12N2S
    4,5,6-trimethyl-2-methylsulfanyl-pyrimidine
    —— 6-phenylsulfanyl-pyrazine-2-carbonitrile 66533-80-0 C11H7N3S
    6-phenylsulfanyl-pyrazine-2-carbonitrile
    —— 4-[(3-chloro-2-methylphenyl)methyl]-2-(4-morpholinyl)-5-[(phenylthio)methyl][1,3]thiazolo[4,5-d]pyrimidin-7(4H)-one 1256290-08-0 C24H23ClN4O2S2
    4-[(3-chloro-2-methylphenyl)methyl]-2-(4-morpholinyl)-5-[(phenylthio)methyl][1,3]thiazolo[4,5-d]pyrimidin-7(4H)-one
    —— N,N-Dimethylisovalerothioamide 67797-33-5 C7H15NS
    N,N-Dimethylisovalerothioamide
    —— 4-Butylmercapto-phenylessigsaeure 3583-61-7 C12H16O2S
    4-Butylmercapto-phenylessigsaeure
    —— 2-Methyl-4-phenylsulfanylquinoline;hydrochloride 65246-06-2 C16H14ClNS
    2-Methyl-4-phenylsulfanylquinoline;hydrochloride
    —— (Dimethylamino)-N,N-dimethylethanethioamide 65131-20-6 C6H14N2S
    (Dimethylamino)-N,N-dimethylethanethioamide
    —— (2R)-2-[[2-amino-5-(pyridin-3-ylmethylsulfanyl)-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino]-4-methylpentan-1-ol 1429127-62-7 C17H22N6OS2
    (2R)-2-[[2-amino-5-(pyridin-3-ylmethylsulfanyl)-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino]-4-methylpentan-1-ol
    —— 4-Aethoxy-5H-pyrimidin<4,5-b><1,4>-thiazin-6(7H)-on 25221-51-6 C8H9N3O2S
    4-Aethoxy-5H-pyrimidin<4,5-b><1,4>-thiazin-6(7H)-on
    —— 2-(3-Pyridylmethylthio)pyrimidine-4,6-diamine 95016-51-6 C10H11N5S
    2-(3-Pyridylmethylthio)pyrimidine-4,6-diamine
    —— 1-methyl-2-(β-picolylmercapto)imidazole 87008-56-8 C10H11N3S
    1-methyl-2-(β-picolylmercapto)imidazole
    —— 7-Chloro-4-(3,5-dimethylpyrazol-1-yl)-2-(3-picolylthio)imidazo<4,5-d>pyridazine 85732-89-4 C16H14ClN7S
    7-Chloro-4-(3,5-dimethylpyrazol-1-yl)-2-(3-picolylthio)imidazo<4,5-d>pyridazine
    —— (2S,5S,6S,1'S)-2-(1'-hydroxy-3'-(phenylsulfanyl)propyl)-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxane-2-carboxylic acid methyl ester 1042925-83-6 C19H28O7S
    (2S,5S,6S,1'S)-2-(1'-hydroxy-3'-(phenylsulfanyl)propyl)-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxane-2-carboxylic acid methyl ester
    —— 4-(3,5-Dimethylpyrazol-1-yl)-2-(3-picolylthio)imidazo<4,5-d>pyridazine 85732-98-5 C16H15N7S
    4-(3,5-Dimethylpyrazol-1-yl)-2-(3-picolylthio)imidazo<4,5-d>pyridazine
    —— (Z)-3-(4-chlorophenylthio)but-2-enoic acid 343570-42-3 C10H9ClO2S
    (Z)-3-(4-chlorophenylthio)but-2-enoic acid
    —— ((3aR)-7c-Methoxy-2,2-dimethyl-(3ar,7at)-3a,4,7,7a-tetrahydro-6H-spiro<benzo<1,3>dioxole-5,2'-<1,3>dithian>-4t-yl)methanol 160708-47-4 C14H24O4S2
    ((3aR)-7c-Methoxy-2,2-dimethyl-(3ar,7at)-3a,4,7,7a-tetrahydro-6H-spiro<benzo<1,3>dioxole-5,2'-<1,3>dithian>-4t-yl)methanol
    —— 2-(3-picoliltio)-5-cloroanilina 74462-24-1 C12H11ClN2S
    2-(3-picoliltio)-5-cloroanilina
    —— [Amino(prop-2-enylsulfanyl)methylidene]azanium;iodide 127598-33-8 C4H8N2S*HI
    [Amino(prop-2-enylsulfanyl)methylidene]azanium;iodide
    —— 2-[(3-pyridinylmethyl)thio]4-pyrimidinamine 95016-48-1 C10H10N4S
    2-[(3-pyridinylmethyl)thio]4-pyrimidinamine