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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(4'-Pentenyl)-2-<2"-(1,3-dioxolanyl)ethyl>-1,3-dithiane 113410-48-3 C14H24O2S2
    2-(4'-Pentenyl)-2-<2"-(1,3-dioxolanyl)ethyl>-1,3-dithiane
    —— 1-bromo-2-(butylthio)benzene 74642-19-6 C10H13BrS
    1-bromo-2-(butylthio)benzene
    —— 2-(4'-Pentenyl)-2-(3"-oxopropyl)-1,3-dithiane 146353-06-2 C12H20OS2
    2-(4'-Pentenyl)-2-(3"-oxopropyl)-1,3-dithiane
    —— Methyl[4-(2-methyl-4,4,4-trifluoro-1-butenyl)phenyl] sulfide 209518-79-6 C12H13F3S
    Methyl[4-(2-methyl-4,4,4-trifluoro-1-butenyl)phenyl] sulfide
    —— 3,3'-Sulfanediylbis(2,4,6-trimethylbenzene-1-thiol) 63398-38-9 C18H22S3
    3,3'-Sulfanediylbis(2,4,6-trimethylbenzene-1-thiol)
    —— 4-tert-Butyl-N-[4-(3-methoxy-phenylsulfanyl)-5-(4-oxo-butyl)-isoxazol-3-yl]-benzenesulfonamide 188940-39-8 C24H28N2O5S2
    4-tert-Butyl-N-[4-(3-methoxy-phenylsulfanyl)-5-(4-oxo-butyl)-isoxazol-3-yl]-benzenesulfonamide
    —— 4-tert-Butyl-N-[5-(3-hydroxy-propyl)-4-(3-methoxy-phenylsulfanyl)-isoxazol-3-yl]-benzenesulfonamide 188940-48-9 C23H28N2O5S2
    4-tert-Butyl-N-[5-(3-hydroxy-propyl)-4-(3-methoxy-phenylsulfanyl)-isoxazol-3-yl]-benzenesulfonamide
    —— 4-[3-(4-tert-Butyl-benzenesulfonylamino)-4-(3-methoxy-phenylsulfanyl)-isoxazol-5-yl]-butyric acid 302957-80-8 C24H28N2O6S2
    4-[3-(4-tert-Butyl-benzenesulfonylamino)-4-(3-methoxy-phenylsulfanyl)-isoxazol-5-yl]-butyric acid
    —— 2-ethoxy-1,1-bis-methanesulfonyl-ethene 51022-25-4 C6H12O5S2
    2-ethoxy-1,1-bis-methanesulfonyl-ethene
    —— 1-[(tert-butyldimethylsilyl)oxy]-5-(phenylthio)oct-7-en-4-one 1589514-43-1 C20H32O2SSi
    1-[(tert-butyldimethylsilyl)oxy]-5-(phenylthio)oct-7-en-4-one
    —— 4-[3-(4-tert-Butyl-benzenesulfonylamino)-4-(3-methoxy-phenylsulfanyl)-isoxazol-5-yl]-butyric acid methyl ester 302957-81-9 C25H30N2O6S2
    4-[3-(4-tert-Butyl-benzenesulfonylamino)-4-(3-methoxy-phenylsulfanyl)-isoxazol-5-yl]-butyric acid methyl ester
    —— 4-tert-Butyl-N-[5-(3-cyano-propyl)-4-(3-methoxy-phenylsulfanyl)-isoxazol-3-yl]-benzenesulfonamide 188940-50-3 C24H27N3O4S2
    4-tert-Butyl-N-[5-(3-cyano-propyl)-4-(3-methoxy-phenylsulfanyl)-isoxazol-3-yl]-benzenesulfonamide
    —— 3-Methyl-6-nitro-2,3-dihydro-1-benzothiophene 62077-37-6 C9H9NO2S
    3-Methyl-6-nitro-2,3-dihydro-1-benzothiophene
    —— 3-Methyl-2,3-dihydro-1-benzothiophen-6-amine 62077-40-1 C9H11NS
    3-Methyl-2,3-dihydro-1-benzothiophen-6-amine
    —— bis(2,2'-thiobis-3,4,5,6-pentafluorophenyl)germane 19739-94-7 C24F16GeS2
    bis(2,2'-thiobis-3,4,5,6-pentafluorophenyl)germane
    —— Bis-<3.4.5.6-tetrafluor-phenyl>-sulfid 19638-36-9 C12H2F8S
    Bis-<3.4.5.6-tetrafluor-phenyl>-sulfid
    —— bis(2-jodotetrafluorophenyl)sulfane 19638-37-0 C12F8I2S
    bis(2-jodotetrafluorophenyl)sulfane
    —— 4-[(6,7-dimethoxy-4-quinolyl)sulfanyl]aniline 849937-71-9 C17H16N2O2S
    4-[(6,7-dimethoxy-4-quinolyl)sulfanyl]aniline
    —— 5-<(5-Nitro-2-aminophenyl)-thio>-4-chlor-3(2H)-pyridazinon 62688-67-9 C10H7ClN4O3S
    5-<(5-Nitro-2-aminophenyl)-thio>-4-chlor-3(2H)-pyridazinon
    —— 5-(2-hydroxyethyl)-6-methyl-2-methylthiopyrimidin-4(3H)-one 98489-83-9 C8H12N2O2S
    5-(2-hydroxyethyl)-6-methyl-2-methylthiopyrimidin-4(3H)-one
    —— 2-methylsulfanyl-thiazole-4-carbaldehyde 41029-86-1 C5H5NOS2
    2-methylsulfanyl-thiazole-4-carbaldehyde
    —— 4-ethyl-6-methyl-2-methylsulfanyl-pyrimidine 61640-53-7 C8H12N2S
    4-ethyl-6-methyl-2-methylsulfanyl-pyrimidine
    —— 1,5-dimethyl-1-oxo-1λ<sup>6</sup>-[1,2]thiazine-4-carboxylic acid 60804-07-1 C7H9NO3S
    1,5-dimethyl-1-oxo-1λ<sup>6</sup>-[1,2]thiazine-4-carboxylic acid
    —— [4,6-dichloro-2-(methylthio)pyrimidin-5-yl]methyl pivalate 1137576-51-2 C11H14Cl2N2O2S
    [4,6-dichloro-2-(methylthio)pyrimidin-5-yl]methyl pivalate
    —— α-(phenylthio)maleic anhydride 84649-32-1 C10H6O3S
    α-(phenylthio)maleic anhydride
    —— <i>N</i>-(5-methylsulfanyl-[1,2,4]dithiazol-3-ylidene)-acetamide 40229-43-4 C5H6N2OS3
    <i>N</i>-(5-methylsulfanyl-[1,2,4]dithiazol-3-ylidene)-acetamide
    —— anti-S-Ethyl-O-<N-methylcarbamoyl>-thiopropion-hydroximat 19145-21-2 C7H14N2O2S
    anti-S-Ethyl-O-<N-methylcarbamoyl>-thiopropion-hydroximat
    —— (E)-2-[(amino)-phenylmethylene]-benzo[b]thiophen-3(2H)-one 77946-49-7 C15H11NOS
    (E)-2-[(amino)-phenylmethylene]-benzo[b]thiophen-3(2H)-one
    —— anti(alkylthio)-S-Methyl-thiopropion-hydroximat 19145-18-7 C4H9NOS
    anti(alkylthio)-S-Methyl-thiopropion-hydroximat
    —— anti-S-Methyl-O-<N-methyl-carbamoyl>-thiopropion-hydroximat 19145-19-8 C6H12N2O2S
    anti-S-Methyl-O-<N-methyl-carbamoyl>-thiopropion-hydroximat
    —— 5-<p-(phenylthio)phenyl>-1-ethyl-5-methyldihydro-<1H,7H>-5H-pyrano<3,2-d>oxazole-2,6-dione 145371-52-4 C21H21NO4S
    5-<p-(phenylthio)phenyl>-1-ethyl-5-methyldihydro-<1H,7H>-5H-pyrano<3,2-d>oxazole-2,6-dione
    —— isooctylmercaptan 110502-71-1 C8H18S
    isooctylmercaptan
    —— 2-(6,7-Dimethoxyquinolin-4-ylsulfanyl)thiazol-5-ylamine 417722-27-1 C14H13N3O2S2
    2-(6,7-Dimethoxyquinolin-4-ylsulfanyl)thiazol-5-ylamine
    —— 2-<p-(phenylthio)phenyl>-2-methyl-6-<<(ethylamino)carbonyl>oxy>-3-oxo-3,6-dihydro-2H-pyran 145371-48-8 C21H21NO4S
    2-<p-(phenylthio)phenyl>-2-methyl-6-<<(ethylamino)carbonyl>oxy>-3-oxo-3,6-dihydro-2H-pyran
    —— 5-ethyl-1-methyl-5-<4-(phenylthio)phenyl>-6-hydroxyperhydropyrano<3,2-d>oxazole-2-one 145371-64-8 C21H23NO4S
    5-ethyl-1-methyl-5-<4-(phenylthio)phenyl>-6-hydroxyperhydropyrano<3,2-d>oxazole-2-one
    —— lead(II) thiocyanate —— C2N2PbS2
    lead(II) thiocyanate
    —— 1-phenyl-4-phenylthio-3-dodecene 93242-58-1 C24H32S
    1-phenyl-4-phenylthio-3-dodecene
    —— 1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]-thiophen-2-yl}-3-(3-cyanophenyl)-urea 417715-70-9 C25H19N5O3S2
    1-{5-[6-Cyano-7-(2-methoxyethoxy)quinolin-4-ylsulfanyl]-thiophen-2-yl}-3-(3-cyanophenyl)-urea
    —— N-(3-Cyanophenyl)-N'-(5-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiophen-2-yl)urea 417715-25-4 C23H18N4O3S2
    N-(3-Cyanophenyl)-N'-(5-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiophen-2-yl)urea
    —— 5-(6,7-Dimethoxyquinolin-4-ylsulfanyl)thiophen-2-ylamine 417722-24-8 C15H14N2O2S2
    5-(6,7-Dimethoxyquinolin-4-ylsulfanyl)thiophen-2-ylamine
    —— N-(3-Cyanophenyl)-N'-(2-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiazol-5-yl)urea 417715-35-6 C22H17N5O3S2
    N-(3-Cyanophenyl)-N'-(2-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiazol-5-yl)urea
    —— 4-(5-aminothiophen-2-ylsulfanyl)-7-(2-methoxyethoxy)-quinoline-6-carbonitrile 417722-45-3 C17H15N3O2S2
    4-(5-aminothiophen-2-ylsulfanyl)-7-(2-methoxyethoxy)-quinoline-6-carbonitrile
    —— 2-<p-(phenylthio)phenyl>-2-methyl-6-<<(methylamino)carbonyl>oxy>-2H-pyran-3(6H)-one —— C20H19NO4S
    2-<p-(phenylthio)phenyl>-2-methyl-6-<<(methylamino)carbonyl>oxy>-2H-pyran-3(6H)-one
    —— cis-6-Methoxy-2-<p-(phenylthio)phenyl>-2-methyl-2H-pyran-3(6H)-one 102285-72-3 C19H18O3S
    cis-6-Methoxy-2-<p-(phenylthio)phenyl>-2-methyl-2H-pyran-3(6H)-one
    —— 1,5-dimethyl-5<4-(phenylthio)phenyl>-6-hydroxyperhydropyrano<3,2-d>oxazole-2-one 133150-05-7 C20H21NO4S
    1,5-dimethyl-5<4-(phenylthio)phenyl>-6-hydroxyperhydropyrano<3,2-d>oxazole-2-one
    —— 1,5-dimethyl-5-<4-(phenylthio)phenyl>-dihydro<1H,7H>-5H-pyrano<3,2-d>oxazole-2,6-dione 133150-03-5 C20H19NO4S
    1,5-dimethyl-5-<4-(phenylthio)phenyl>-dihydro<1H,7H>-5H-pyrano<3,2-d>oxazole-2,6-dione
    —— 6-hydroxy-2-<p-(phenylthio)phenyl>-2-methyl-2H-pyran-3(6H)-one 102285-67-6 C18H16O3S
    6-hydroxy-2-<p-(phenylthio)phenyl>-2-methyl-2H-pyran-3(6H)-one
    —— 5-<(4-Nitro-2-aminophenyl)-thio>-4-chlor-3(2H)-pyridazinon 62688-70-4 C10H7ClN4O3S
    5-<(4-Nitro-2-aminophenyl)-thio>-4-chlor-3(2H)-pyridazinon
    —— 11-(ω-mercapto)-undecanylamine 155638-19-0 C11H25NS
    11-(ω-mercapto)-undecanylamine
    —— (S)-5-methyl-3-(phenylthio)-3-(10-undecenyl)dihydrofuran-2(3H)-one 862603-45-0 C22H32O2S
    (S)-5-methyl-3-(phenylthio)-3-(10-undecenyl)dihydrofuran-2(3H)-one