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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— CNS 5161 160754-76-7 C16H18ClN3S2
    CNS 5161
    —— 2,3,5-trifluoro-6-(methylthio)pyridine 1257072-14-2 C6H4F3NS
    2,3,5-trifluoro-6-(methylthio)pyridine
    —— 2,2'-(pentane-1,5-disulfonyl)-bis-ethanol 57100-56-8 C9H20O6S2
    2,2'-(pentane-1,5-disulfonyl)-bis-ethanol
    —— bis-1,5-(20chloroethylthio)pentane 142868-94-8 C9H18Cl2S2
    bis-1,5-(20chloroethylthio)pentane
    —— 2-isopropyl-2-<1-hydroxy-3,3-(1,3-dioxocyclopentyl)butyl>-1,3-dithiane 137853-40-8 C13H24O3S2
    2-isopropyl-2-<1-hydroxy-3,3-(1,3-dioxocyclopentyl)butyl>-1,3-dithiane
    —— 3-Methylthio-6-(4-methylphenyl)-1,2,4,5-tetrazin 72116-53-1 C10H10N4S
    3-Methylthio-6-(4-methylphenyl)-1,2,4,5-tetrazin
    —— 2-(1-phenylthiooctyl)cyclohex-2-enone 157584-94-6 C20H28OS
    2-(1-phenylthiooctyl)cyclohex-2-enone
    —— 2-(1-hydroxyoctyl)-3-phenylsulfanylcyclohexanone 157584-93-5 C20H30O2S
    2-(1-hydroxyoctyl)-3-phenylsulfanylcyclohexanone
    —— cis-2,6-dihexylsulfonyl-1,4-dithiafulvene 74057-79-7 C16H28O4S4
    cis-2,6-dihexylsulfonyl-1,4-dithiafulvene
    —— 2-methylthio-5-methyl-6-[1-(4-dimethylaminophenyl)-1-hydroxymethyl]-4(3H)-pyrimidinone 948859-54-9 C15H19N3O2S
    2-methylthio-5-methyl-6-[1-(4-dimethylaminophenyl)-1-hydroxymethyl]-4(3H)-pyrimidinone
    —— 2-(benzylthio)-5-(2-fluorophenyl)-1,3,4-oxadiazole 459846-23-2 C15H11FN2OS
    2-(benzylthio)-5-(2-fluorophenyl)-1,3,4-oxadiazole
    —— 2-methylthio-5-methyl-6-formyl-4(3H)-pyrimidinone 948859-52-7 C7H8N2O2S
    2-methylthio-5-methyl-6-formyl-4(3H)-pyrimidinone
    —— 1-(dimethylsulfamoyl)-5-(2-ethyl-6-methylphenylthio)pyrazole 143535-28-8 C14H19N3O2S2
    1-(dimethylsulfamoyl)-5-(2-ethyl-6-methylphenylthio)pyrazole
    —— 1-[(E)-3-(2-Thienyl)prop-2-en-1-yl]-6-(phenylthio)thymine 157401-07-5 C18H16N2O2S2
    1-[(E)-3-(2-Thienyl)prop-2-en-1-yl]-6-(phenylthio)thymine
    —— (Z)-3-methylpent-2-en-4-ybyl thiocyanate 342883-59-4 C7H7NS
    (Z)-3-methylpent-2-en-4-ybyl thiocyanate
    —— 4-methyl-1-phenylsulfonylnaphthalene 430430-72-1 C17H14S
    4-methyl-1-phenylsulfonylnaphthalene
    —— 4-Acetyl-1-[3-[(2-aminothiazol-5-yl)thio]benzoyl]piperazine 439578-81-1 C16H18N4O2S2
    4-Acetyl-1-[3-[(2-aminothiazol-5-yl)thio]benzoyl]piperazine
    —— ethyl-1-deoxy-1-ethylsulfonato-3,4,5-tri-O-methyl-2-thio-α-L-fuco-hept-2-ulopyranoside 286860-85-3 C14H28O7S2
    ethyl-1-deoxy-1-ethylsulfonato-3,4,5-tri-O-methyl-2-thio-α-L-fuco-hept-2-ulopyranoside
    —— 2,2,2-Trifluoroethyl ethylsulfanylformate 71674-19-6 C5H7F3O2S
    2,2,2-Trifluoroethyl ethylsulfanylformate
    —— 9-<1-(methylthio)ethylidene>bicyclo<4.2.1>nonane 83463-49-4 C12H20S
    9-<1-(methylthio)ethylidene>bicyclo<4.2.1>nonane
    —— 2-amino-2-methyl-thiopropanamide 16256-14-7 C4H10N2S
    2-amino-2-methyl-thiopropanamide
    —— ethyl 4-[4-(3-[2,2,2-trifluoroethyl]thioureido)pyrimid-2-ylthio]butyrate 84545-81-3 C13H17F3N4O2S2
    ethyl 4-[4-(3-[2,2,2-trifluoroethyl]thioureido)pyrimid-2-ylthio]butyrate
    —— 9-<1-(methylthio)ethylidene>bicyclo<4.2.1>nona-2,4,7-triene 83463-34-7 C12H14S
    9-<1-(methylthio)ethylidene>bicyclo<4.2.1>nona-2,4,7-triene
    —— cis-2,6-dibutylsulfonyl-1,4-dithiafulvene 74057-77-5 C12H20O4S4
    cis-2,6-dibutylsulfonyl-1,4-dithiafulvene
    —— 9-<1-(methylthio)ethylidene>bicyclo<4.2.1>nona-2,4-diene 83463-38-1 C12H16S
    9-<1-(methylthio)ethylidene>bicyclo<4.2.1>nona-2,4-diene
    —— 3-[(3-Nitro-4-pyridinyl)thio]propanoic acid 136742-84-2 C8H8N2O4S
    3-[(3-Nitro-4-pyridinyl)thio]propanoic acid
    —— 2-Ethoxyethylmethylsulfoxid 28525-29-3 C5H12O2S
    2-Ethoxyethylmethylsulfoxid
    —— 4-[(6-Methoxy-1H-benzimidazol-2-yl)thio]-3-pyridinamine 1039833-29-8 C13H12N4OS
    4-[(6-Methoxy-1H-benzimidazol-2-yl)thio]-3-pyridinamine
    —— cis-2,6-dipropylsulfonyl-1,4-dithiafulvene 74057-75-3 C10H16O4S4
    cis-2,6-dipropylsulfonyl-1,4-dithiafulvene
    —— methyl 2-(4-tetrahydropyran-4-ylsulfanylphenyl)acetate 1328997-80-3 C14H18O3S
    methyl 2-(4-tetrahydropyran-4-ylsulfanylphenyl)acetate
    —— 4-[(4-bromophenyl)sulfanyl]tetrahydro-2H-pyran 165119-50-6 C11H13BrOS
    4-[(4-bromophenyl)sulfanyl]tetrahydro-2H-pyran
    —— 7-hydroxy-2,3-dihydro-2,2-dimethylbenzo[b]thiophene 59705-21-4 C10H12OS
    7-hydroxy-2,3-dihydro-2,2-dimethylbenzo[b]thiophene
    —— 2,3-dihydro-2,2-dimethyl-7-benzo[b]thienyl N-methylcarbamate 59705-22-5 C12H15NO2S
    2,3-dihydro-2,2-dimethyl-7-benzo[b]thienyl N-methylcarbamate
    —— 5-(methylthio)-3,6-dihydro-2H-1,4-thiazine 343268-17-7 C5H9NS2
    5-(methylthio)-3,6-dihydro-2H-1,4-thiazine
    —— (1'S,2'R,5'S,6'R)-spiro[1,3-dithiane-2,4'-tricyclo[4.2.1.02,5]non-7-ene]-3'-one 193467-05-9 C12H14OS2
    (1'S,2'R,5'S,6'R)-spiro[1,3-dithiane-2,4'-tricyclo[4.2.1.02,5]non-7-ene]-3'-one
    —— 4,6-dichloro-5-(2-methoxyphenyl)thiopyrimidine 374600-17-6 C11H8Cl2N2OS
    4,6-dichloro-5-(2-methoxyphenyl)thiopyrimidine
    —— 5-(2-methoxyphenyl)thiopyrimidine-4,6-diol 167403-89-6 C11H10N2O3S
    5-(2-methoxyphenyl)thiopyrimidine-4,6-diol
    —— 2-(methylthio)-4-((pyridin-3-ylmethyl)amino) pyrimidine-5-carbaldehyde 1082600-06-3 C12H12N4OS
    2-(methylthio)-4-((pyridin-3-ylmethyl)amino) pyrimidine-5-carbaldehyde
    —— (1'R,2'S,5'R,6'S)-spiro[1,3-dithiane-2,4'-tricyclo[4.2.1.02,5]non-7-ene]-3'-one 193467-04-8 C12H14OS2
    (1'R,2'S,5'R,6'S)-spiro[1,3-dithiane-2,4'-tricyclo[4.2.1.02,5]non-7-ene]-3'-one
    —— 1,5,9,13-Tetrathiadispiro[5.1.58.16]tetradecan-14-one 1018781-77-5 C10H14OS4
    1,5,9,13-Tetrathiadispiro[5.1.58.16]tetradecan-14-one
    —— Bicyclo<5.1.1>nonane-3,4,5-trione 4-(propylene dithioketal) 166803-19-6 C12H16O2S2
    Bicyclo<5.1.1>nonane-3,4,5-trione 4-(propylene dithioketal)
    —— (E)-3,3-Dimethyl-1-(methylsulfonyl)-1-(methylthio)-2-butanone O-<(methylamino)carbonyl>oxime 73926-62-2 C10H20N2O4S2
    (E)-3,3-Dimethyl-1-(methylsulfonyl)-1-(methylthio)-2-butanone O-<(methylamino)carbonyl>oxime
    —— Pentalene, 3,6-bis(phenylthio)-3a,6a-dimethyl-1,3a,4,6a-tetrahydro- 84451-80-9 C22H22S2
    Pentalene, 3,6-bis(phenylthio)-3a,6a-dimethyl-1,3a,4,6a-tetrahydro-
    —— 1-phenylsulfonyl-3-phenylthio-2-chloromethylindole 868081-88-3 C21H16ClNO2S2
    1-phenylsulfonyl-3-phenylthio-2-chloromethylindole
    —— 5-methyl-4-methylsulfanyl-5<i>H</i>-imidazo[4,5-<i>d</i>][1,2,3]triazine 69093-64-7 C6H7N5S
    5-methyl-4-methylsulfanyl-5<i>H</i>-imidazo[4,5-<i>d</i>][1,2,3]triazine
    —— 3-(2-Phenylsulfanyl-phenyl)-propionic acid 73149-87-8 C15H14O2S
    3-(2-Phenylsulfanyl-phenyl)-propionic acid
    —— 5',5'-Dimethyl-2'-phenylspiro[1,3-benzodithiole-2,4'-oxolane]-2'-ol 74255-37-1 C18H18O2S2
    5',5'-Dimethyl-2'-phenylspiro[1,3-benzodithiole-2,4'-oxolane]-2'-ol
    —— 4,4'-Sulfanediyldi(benzene-1-diazonium) dichloride 13954-65-9 C12H8Cl2N4S
    4,4'-Sulfanediyldi(benzene-1-diazonium) dichloride
    —— 1<i>t</i>-ethylsulfanyl-3-methyl-buta-1,3-diene 16627-77-3 C7H12S
    1<i>t</i>-ethylsulfanyl-3-methyl-buta-1,3-diene
    —— (1E)-1-butylsulfanyl-3-methylbuta-1,3-diene 87745-45-7 C9H16S
    (1E)-1-butylsulfanyl-3-methylbuta-1,3-diene