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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2,2,4,4-Tetrabrom-1,3-dithietan-1,1-dioxid 73090-25-2 C2Br4O2S2
    2,2,4,4-Tetrabrom-1,3-dithietan-1,1-dioxid
    —— N,N'-Dimethylmalonsaeuredithioamid 10394-26-0 C5H10N2S2
    N,N'-Dimethylmalonsaeuredithioamid
    —— 8-ethoxycarbonyl-tris(2,2,6,6-tetramethylbenzo[1,2-d;4,5-d']bis[1,3]dithiol-4-yl)methanol 910912-06-0 C40H44O3S12
    8-ethoxycarbonyl-tris(2,2,6,6-tetramethylbenzo[1,2-d;4,5-d']bis[1,3]dithiol-4-yl)methanol
    —— ethyl 2-(o-tolylthio)acetate 14738-25-1 C11H14O2S
    ethyl 2-(o-tolylthio)acetate
    —— 2-(o-tolylthio)acetohydrazide 14738-28-4 C9H12N2OS
    2-(o-tolylthio)acetohydrazide
    —— 6-ethyl-7-methanesulfonyloxy-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidin-5-one 72211-63-3 C9H12N2O4S2
    6-ethyl-7-methanesulfonyloxy-2,3-dihydro-thiazolo[3,2-<i>a</i>]pyrimidin-5-one
    —— trans-1-(phenylthio)-2-moroholinoethylene 179670-28-1 C12H15NOS
    trans-1-(phenylthio)-2-moroholinoethylene
    —— 1,2,4-Triazin-5(4H)-one, 4-amino-3-(methylthio)- 62036-62-8 C4H6N4OS
    1,2,4-Triazin-5(4H)-one, 4-amino-3-(methylthio)-
    —— dioxolanne de l'α-phenylthioacetaldehyde 179669-44-4 C10H12O2S
    dioxolanne de l'α-phenylthioacetaldehyde
    —— 6-Ethyl-7-Ethoxy-2,3,4,5-Tetrahydrothiazolo<3,2-a>Pyrimidin-5-on 72211-59-7 C10H14N2O2S
    6-Ethyl-7-Ethoxy-2,3,4,5-Tetrahydrothiazolo<3,2-a>Pyrimidin-5-on
    —— [(3-methylsulfanyl-phenyl)ethyl]carbamic acid tert-butyl ester 372938-32-4 C14H21NO2S
    [(3-methylsulfanyl-phenyl)ethyl]carbamic acid tert-butyl ester
    —— 4-Fluoro-4'-(trifluoromethyl)diphenyl Sulfide 42917-48-6 C13H8F4S
    4-Fluoro-4'-(trifluoromethyl)diphenyl Sulfide
    —— 1-(4-chlorophenylmercapto)-2,2-dimethyl-butan-3-one 80783-23-9 C12H15ClOS
    1-(4-chlorophenylmercapto)-2,2-dimethyl-butan-3-one
    —— 4-(4-chlorophenylsulphenyl)-3,3-dimethyl-1-(imidazol-1-yl)-butan-2-one 84105-47-5 C15H17ClN2OS
    4-(4-chlorophenylsulphenyl)-3,3-dimethyl-1-(imidazol-1-yl)-butan-2-one
    —— C-methylsulfanyl-methanediamine hydroiodide 464213-18-1 C2H8N2S*HI
    C-methylsulfanyl-methanediamine hydroiodide
    —— 1-bromo-4-(4-chlorophenylmercapto)-3,3-dimethyl-butan-2-one 81058-89-1 C12H14BrClOS
    1-bromo-4-(4-chlorophenylmercapto)-3,3-dimethyl-butan-2-one
    —— 7-Chlor-6-Ethyl-2,3,4,5-Tetrahydrothiazolo<3,2-a>Pyrimidin-5-on 72211-61-1 C8H9ClN2OS
    7-Chlor-6-Ethyl-2,3,4,5-Tetrahydrothiazolo<3,2-a>Pyrimidin-5-on
    —— 2-amino-6-(phenylthio)pyridine 5620-25-7 C11H10N2S
    2-amino-6-(phenylthio)pyridine
    —— (E)-ethyl 6-oxo-6-(2-(3-(2-(pyridin-2-yl)vinyl)-1H-indazol-6-ylthio)phenylamino)hexanoate 1133966-19-4 C28H28N4O3S
    (E)-ethyl 6-oxo-6-(2-(3-(2-(pyridin-2-yl)vinyl)-1H-indazol-6-ylthio)phenylamino)hexanoate
    —— (2-chloro-phenyl)-(2,4,5-trichloro-phenyl)-sulfide 105908-69-8 C12H6Cl4S
    (2-chloro-phenyl)-(2,4,5-trichloro-phenyl)-sulfide
    —— 6-<(2,4,5-trichlorophenyl)thio>-2,4-pteridinediamine 77900-94-8 C12H7Cl3N6S
    6-<(2,4,5-trichlorophenyl)thio>-2,4-pteridinediamine
    —— 6-(2,4,5-Trichlorophenyl)sulfanylpyrido[3,2-d]pyrimidine-2,4-diamine 95095-93-5 C13H8Cl3N5S
    6-(2,4,5-Trichlorophenyl)sulfanylpyrido[3,2-d]pyrimidine-2,4-diamine
    —— 4-(2,4,5-trichloro-phenylsulfanyl)-aniline 90309-24-3 C12H8Cl3NS
    4-(2,4,5-trichloro-phenylsulfanyl)-aniline
    —— 2,4-diamino-5-methyl-6-(2',4',5'-trichlorophenylthio)pyrrolo[2,3-d]pyrimidine 1221521-89-6 C13H10Cl3N5S
    2,4-diamino-5-methyl-6-(2',4',5'-trichlorophenylthio)pyrrolo[2,3-d]pyrimidine
    —— (4-nitro-phenyl)-(2,4,5-trichloro-phenyl)-sulfide 90309-42-5 C12H6Cl3NO2S
    (4-nitro-phenyl)-(2,4,5-trichloro-phenyl)-sulfide
    —— Tert-butyl 2-(2,4,5-trichlorophenyl)sulfanylacetate 208512-60-1 C12H13Cl3O2S
    Tert-butyl 2-(2,4,5-trichlorophenyl)sulfanylacetate
    —— p-chlorophenyl 2,4,5-trichlorophenyl trithiocarbonate 1523313-33-8 C13H6Cl4S3
    p-chlorophenyl 2,4,5-trichlorophenyl trithiocarbonate
    —— 2-Benzylthio-4-phenyl-thiazol-3-oxid 76098-75-4 C16H13NOS2
    2-Benzylthio-4-phenyl-thiazol-3-oxid
    —— 1,3-bis-ethylsulfanyl-benzene 861601-60-7 C10H14S2
    1,3-bis-ethylsulfanyl-benzene
    —— 12,21,37,40-Tetramethyl-2,5,8,25,28,31-hexaoxa-15,18,38,39-tetrathia-11,22-diazahexacyclo[30.2.2.111,14.113,16.117,20.119,22]tetraconta-1(35),12,14(40),16,19(37),20,32(36),33-octaene 257884-56-3 C32H40N2O6S4
    12,21,37,40-Tetramethyl-2,5,8,25,28,31-hexaoxa-15,18,38,39-tetrathia-11,22-diazahexacyclo[30.2.2.111,14.113,16.117,20.119,22]tetraconta-1(35),12,14(40),16,19(37),20,32(36),33-octaene
    —— N-methylacetothioacetamide 74697-92-0 C5H9NOS
    N-methylacetothioacetamide
    —— dipropyl N,N'-[thiobis[(methylimino)carbonyloxy]]bis[2,2,2-trifluoroethanimidothioate] 82986-14-9 C14H20F6N4O4S3
    dipropyl N,N'-[thiobis[(methylimino)carbonyloxy]]bis[2,2,2-trifluoroethanimidothioate]
    —— thiodicarb 59669-26-0 C10H18N4O4S3
    thiodicarb
    —— Diphenyl N,N'-[thiobis[(methylimino)carbonyloxy]]bis[2,2,2-trifluoroethanimidothioate] 82986-16-1 C20H16F6N4O4S3
    Diphenyl N,N'-[thiobis[(methylimino)carbonyloxy]]bis[2,2,2-trifluoroethanimidothioate]
    —— bis(1,1-dimethylethyl) N,N'-[thiobis[(methylimino)carbonyloxy]]bis[2,2,2-trifluoroethanimidothioate] 82986-15-0 C16H24F6N4O4S3
    bis(1,1-dimethylethyl) N,N'-[thiobis[(methylimino)carbonyloxy]]bis[2,2,2-trifluoroethanimidothioate]
    —— 2-Dimethylamino-4-oxo-4,5,6,7-tetrahydrothiazino<3,2-a>-sym-triazine 74468-23-8 C8H12N4OS
    2-Dimethylamino-4-oxo-4,5,6,7-tetrahydrothiazino<3,2-a>-sym-triazine
    —— 1-chloro-2-(4-fluorophenylsulfanyl)-3,5-dimethoxybenzene 1369529-28-1 C14H12ClFO2S
    1-chloro-2-(4-fluorophenylsulfanyl)-3,5-dimethoxybenzene
    —— (3,4,5-trifluorophenyl)-4-fluorophenylsulfide 1229514-23-1 C12H6F4S
    (3,4,5-trifluorophenyl)-4-fluorophenylsulfide
    —— 3-{(4-fluorophenyl)thio}pentane-2,4-dione 561036-91-7 C11H11FO2S
    3-{(4-fluorophenyl)thio}pentane-2,4-dione
    —— 4-(p-fluorophenylthio)octan-2-one 1224975-71-6 C14H19FOS
    4-(p-fluorophenylthio)octan-2-one
    —— Methyl 3-(4-fluorophenyl)sulfanyl-2-methylpropanoate 1154732-63-4 C11H13FO2S
    Methyl 3-(4-fluorophenyl)sulfanyl-2-methylpropanoate
    —— (4-fluorophenyl)(1-phenyl-3-(trifluoromethyl)naphthalen-2-yl)sulfane 1629186-30-6 C23H14F4S
    (4-fluorophenyl)(1-phenyl-3-(trifluoromethyl)naphthalen-2-yl)sulfane
    —— bis((3-bromophenyl)thio)methane 1427730-39-9 C13H10Br2S2
    bis((3-bromophenyl)thio)methane
    —— 4-[S-(3-bromophenyl)-sulfoximino]-5-methylsulfanyl-thiophene-2-carboximidic acid methyl ester 911030-36-9 C13H13BrN2O2S3
    4-[S-(3-bromophenyl)-sulfoximino]-5-methylsulfanyl-thiophene-2-carboximidic acid methyl ester
    —— 2-(4-fluorophenylthio)cyclohexan-1-one 1044049-41-3 C12H13FOS
    2-(4-fluorophenylthio)cyclohexan-1-one
    —— 1-(4-fluorophenylthio)octan-2-ol 1174708-92-9 C14H21FOS
    1-(4-fluorophenylthio)octan-2-ol
    —— 4-((4-fluorophenyl)thio)-4-phenylbutan-2-one 1224975-55-6 C16H15FOS
    4-((4-fluorophenyl)thio)-4-phenylbutan-2-one
    —— 1,1,5,5-Tetraaethyldithiobiuret 54572-22-4 C10H21N3S2
    1,1,5,5-Tetraaethyldithiobiuret
    —— 3-methoxy-5<i>H</i>-dipyridazino[3,4-<i>b</i>;4',5'-<i>e</i>][1,4]thiazine 55271-52-8 C9H7N5OS
    3-methoxy-5<i>H</i>-dipyridazino[3,4-<i>b</i>;4',5'-<i>e</i>][1,4]thiazine
    —— 4-((4-fluorophenyl)thio)butanenitrile 18850-57-2 C10H10FNS
    4-((4-fluorophenyl)thio)butanenitrile