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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-ethyl 2-(1'-hydroxyethyl-1')-1,3-dithiane 129650-83-5 C8H16OS2
    2-ethyl 2-(1'-hydroxyethyl-1')-1,3-dithiane
    —— methanebis(sulphenyl chloride) 114079-01-5 CH2Cl2S2
    methanebis(sulphenyl chloride)
    —— 2-Allylthio-4-methylpyrimidin 61767-97-3 C8H10N2S
    2-Allylthio-4-methylpyrimidin
    —— 3-hydroxy-4-methyl-4-(4'-butylphenyl)sulfanyl-pentanamide 910865-20-2 C16H25NO2S
    3-hydroxy-4-methyl-4-(4'-butylphenyl)sulfanyl-pentanamide
    —— 2-(4-butyl-phenylsulfanyl)-2-methyl-propionaldehyde 910865-16-6 C14H20OS
    2-(4-butyl-phenylsulfanyl)-2-methyl-propionaldehyde
    —— 4,6-di(methylthio)-2-phenylpyrimidine 19068-91-8 C12H12N2S2
    4,6-di(methylthio)-2-phenylpyrimidine
    —— Pyrimidine, 2-[(1-methylethyl)thio]-5-nitro- 62095-14-1 C7H9N3O2S
    Pyrimidine, 2-[(1-methylethyl)thio]-5-nitro-
    —— Pyrimidine, 2-[(2-methylpropyl)thio]-5-nitro- 62095-15-2 C8H11N3O2S
    Pyrimidine, 2-[(2-methylpropyl)thio]-5-nitro-
    —— 4-[(2-pyrimidinyl)thio]benzenamine 133303-78-3 C10H9N3S
    4-[(2-pyrimidinyl)thio]benzenamine
    —— 4-(4-aminophenylthio)-N-benzylpicolinamide 1061639-82-4 C19H17N3OS
    4-(4-aminophenylthio)-N-benzylpicolinamide
    —— 4-(4-aminophenyl)sulfanyl-N-prop-2-enylpyridine-2-carboxamide 1061639-81-3 C15H15N3OS
    4-(4-aminophenyl)sulfanyl-N-prop-2-enylpyridine-2-carboxamide
    —— chlorocyclopropylmethyl phenyl sulfide 131758-68-4 C10H11ClS
    chlorocyclopropylmethyl phenyl sulfide
    —— 3-(phenylthio)butan-1-ol 102211-98-3 C10H14OS
    3-(phenylthio)butan-1-ol
    —— (E)-4-chloro-1-(phenylthio)but-1-ene 131758-70-8 C10H11ClS
    (E)-4-chloro-1-(phenylthio)but-1-ene
    —— 4-methyl-5-phenylthiohex-3-en-2-one 108378-33-2 C13H16OS
    4-methyl-5-phenylthiohex-3-en-2-one
    —— 3,5-dimethyl-3-phenylthiohex-5-en-2-ol 108362-34-1 C14H20OS
    3,5-dimethyl-3-phenylthiohex-5-en-2-ol
    —— 5,6-bis(4-fluorophenyl)-3-(methylthio)-1,2,4-triazine 59663-52-4 C16H11F2N3S
    5,6-bis(4-fluorophenyl)-3-(methylthio)-1,2,4-triazine
    —— Pyrimidine, 4-methyl-2-[(2-methylpropyl)thio]- 61767-96-2 C9H14N2S
    Pyrimidine, 4-methyl-2-[(2-methylpropyl)thio]-
    —— (6-<i>tert</i>-butyl-5-oxo-4,5-dihydro-[1,2,4]triazin-3-ylmercapto)-acetic acid 114960-69-9 C9H13N3O3S
    (6-<i>tert</i>-butyl-5-oxo-4,5-dihydro-[1,2,4]triazin-3-ylmercapto)-acetic acid
    —— 6-methyl-7-phenylthio-oct-5-en-3-yne 108378-37-6 C15H18S
    6-methyl-7-phenylthio-oct-5-en-3-yne
    —— 4,5-dimethyl-4-(phenylthio)-4,5-dihydrofuran-2(3H)-one 65263-92-5 C12H14O2S
    4,5-dimethyl-4-(phenylthio)-4,5-dihydrofuran-2(3H)-one
    —— 5-(4-chloro-phenylsulfanyl)-2-methylsulfanyl-pyrimidine 61727-21-7 C11H9ClN2S2
    5-(4-chloro-phenylsulfanyl)-2-methylsulfanyl-pyrimidine
    —— 5,7-dimethyl-4-oxo-5-(phenylthio)octanonitrile 153029-08-4 C16H21NOS
    5,7-dimethyl-4-oxo-5-(phenylthio)octanonitrile
    —— bis(2,5-dimethylpyrrolo[3,4-d])tetrathiafulvalene 117860-14-7 C14H14N2S4
    bis(2,5-dimethylpyrrolo[3,4-d])tetrathiafulvalene
    —— (phenylthio)methaneboronic acid 67975-88-6 C7H9BO2S
    (phenylthio)methaneboronic acid
    —— 3,5-dimethyl-3-(phenylthio)hexan-2-one 153029-07-3 C14H20OS
    3,5-dimethyl-3-(phenylthio)hexan-2-one
    —— 3,6-Dimethyl-3-phenylthio-5-hepten-2-on 66032-84-6 C15H20OS
    3,6-Dimethyl-3-phenylthio-5-hepten-2-on
    —— 1-Methyl-2-phenylthiobutyl-phenylsulfid 66165-10-4 C17H20S2
    1-Methyl-2-phenylthiobutyl-phenylsulfid
    —— 4-methyl-5-phenylthiohex-3-en-1-yne 108378-32-1 C13H14S
    4-methyl-5-phenylthiohex-3-en-1-yne
    —— 3,6-Dimethyl-3-phenylthio-2-trimethylsilyloxy-1,5-heptadien 66032-87-9 C18H28OSSi
    3,6-Dimethyl-3-phenylthio-2-trimethylsilyloxy-1,5-heptadien
    —— (Z,3R)-1-phenyl-4-phenylsulfanylnon-4-en-3-ol 206278-61-7 C21H26OS
    (Z,3R)-1-phenyl-4-phenylsulfanylnon-4-en-3-ol
    —— (Z)-1-phenyl-4-phenylsulfanylnon-4-en-3-one 206278-55-9 C21H24OS
    (Z)-1-phenyl-4-phenylsulfanylnon-4-en-3-one
    —— 3,3-Bis-(phenylthio)-pentan-2-ol 61173-87-3 C17H20OS2
    3,3-Bis-(phenylthio)-pentan-2-ol
    —— 3,5-dimethyl-3-phenylthiohex-5-en-2-one 108362-33-0 C14H18OS
    3,5-dimethyl-3-phenylthiohex-5-en-2-one
    —— 4-ethyl-5-methyl-4-(phenylthio)-4,5-dihydrofuran-2(3H)-one 79749-92-1 C13H16O2S
    4-ethyl-5-methyl-4-(phenylthio)-4,5-dihydrofuran-2(3H)-one
    —— 3-methyl-3-phenylthio-oct-5-yn-2-ol 108378-36-5 C15H20OS
    3-methyl-3-phenylthio-oct-5-yn-2-ol
    —— 3-Methyl-3-phenylthio-5-hexen-2-on 66032-83-5 C13H16OS
    3-Methyl-3-phenylthio-5-hexen-2-on
    —— (E) 3-phenylthiopent-3-en-2-one 109328-61-2 C11H12OS
    (E) 3-phenylthiopent-3-en-2-one
    —— 3-methyl-3-phenylthio-oct-5-yn-2-one 108378-35-4 C15H18OS
    3-methyl-3-phenylthio-oct-5-yn-2-one
    —— 3-methyl-3-phenylthiohex-5-yn-2-ol 108378-29-6 C13H16OS
    3-methyl-3-phenylthiohex-5-yn-2-ol
    —— 3-methyl-3-(phenylthio)pentan-2-one 66032-82-4 C12H16OS
    3-methyl-3-(phenylthio)pentan-2-one
    —— 1-Methyl-2-(phenylthio)propyl-phenylsulfid 69813-61-2 C16H18S2
    1-Methyl-2-(phenylthio)propyl-phenylsulfid
    —— 3,6-Dimethyl-3-(phenylthio)-heptan-2-on 63996-43-0 C15H22OS
    3,6-Dimethyl-3-(phenylthio)-heptan-2-on
    —— 4,5-dimethyl-4-(phenylthio)-4,5-dihydrofuran-2(3H)-one 65263-92-5 C12H14O2S
    4,5-dimethyl-4-(phenylthio)-4,5-dihydrofuran-2(3H)-one
    —— 3-Methyl-3-phenylthio-2-trimethylsilyloxy-1,5-hexadien 66032-86-8 C16H24OSSi
    3-Methyl-3-phenylthio-2-trimethylsilyloxy-1,5-hexadien
    —— 3-Methyl-3-phenylthio-2-trimethylsilyloxy-1-penten 66032-85-7 C15H24OSSi
    3-Methyl-3-phenylthio-2-trimethylsilyloxy-1-penten
    —— 3,3-Bis-(phenylthio)-butan-2-ol 62870-18-2 C16H18OS2
    3,3-Bis-(phenylthio)-butan-2-ol
    —— (E)-2-acetoxy-3-phenylthiobut-2-ene 123630-50-2 C12H14O2S
    (E)-2-acetoxy-3-phenylthiobut-2-ene
    —— (1RS,2RS)-1-methyl-2-phenylthiocycloheptanol 101704-32-9 C14H20OS
    (1RS,2RS)-1-methyl-2-phenylthiocycloheptanol
    —— 1-[Nitro(phenylsulfanyl)methyl]cyclohexan-1-ol 117543-15-4 C13H17NO3S
    1-[Nitro(phenylsulfanyl)methyl]cyclohexan-1-ol