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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-bromo-6-(phenylthio)-benzyl chloride 52548-52-4 C13H10BrClS
    3-bromo-6-(phenylthio)-benzyl chloride
    —— 1.1-Bis(ethylthio)allen 79159-22-1 C7H12S2
    1.1-Bis(ethylthio)allen
    —— (R)-5-methyl-2-(phenylthio)cyclohex-2-en-1-one 157639-01-5 C13H14OS
    (R)-5-methyl-2-(phenylthio)cyclohex-2-en-1-one
    —— (2-methylsulfanyl-phenylsulfanyl)-acetic acid 18619-27-7 C9H10O2S2
    (2-methylsulfanyl-phenylsulfanyl)-acetic acid
    —— 2-[3,5-dichloro-4-(4-chloro-phenylsulfanyl)-phenyl]-2<i>H</i>-[1,2,4]triazine-3,5-dione 38560-74-6 C15H8Cl3N3O2S
    2-[3,5-dichloro-4-(4-chloro-phenylsulfanyl)-phenyl]-2<i>H</i>-[1,2,4]triazine-3,5-dione
    —— (1R,3S,4S,5R,9S,12R)-8,8,12-trimethyl-5-(phenylsulfanylmethyl)-4-prop-1-en-2-yl-2-oxa-7-azatricyclo[7.4.0.03,7]tridecan-6-one 634589-11-0 C24H33NO2S
    (1R,3S,4S,5R,9S,12R)-8,8,12-trimethyl-5-(phenylsulfanylmethyl)-4-prop-1-en-2-yl-2-oxa-7-azatricyclo[7.4.0.03,7]tridecan-6-one
    —— 1-[3,5-Dichloro-4-(4-chloro-phenylsulfanyl)-phenyl]-3-propyl-urea 54456-81-4 C16H15Cl3N2OS
    1-[3,5-Dichloro-4-(4-chloro-phenylsulfanyl)-phenyl]-3-propyl-urea
    —— {Ag(thiourea)}(1+) 44204-51-5 Ag*CH4N2S
    {Ag(thiourea)}(1+)
    —— methyl 3-methyl-6-(phenylthio)-benzoate 52548-16-0 C15H14O2S
    methyl 3-methyl-6-(phenylthio)-benzoate
    —— 3-methyl-6-(phenylthio)-benzyl chloride 52548-18-2 C14H13ClS
    3-methyl-6-(phenylthio)-benzyl chloride
    —— 3-methyl-6-(phenylthio)-phenylacetic acid 52548-20-6 C15H14O2S
    3-methyl-6-(phenylthio)-phenylacetic acid
    —— 3-methyl-6-(phenylthio)-benzyl alcohol 52548-17-1 C14H14OS
    3-methyl-6-(phenylthio)-benzyl alcohol
    —— 3-methyl-6-(phenylthio)-phenylacetonitrile 52548-19-3 C15H13NS
    3-methyl-6-(phenylthio)-phenylacetonitrile
    —— 2-hydroxymethyl-2-mercaptomethyl-1,3-propanediol 183371-00-8 C5H12O3S
    2-hydroxymethyl-2-mercaptomethyl-1,3-propanediol
    —— 3-(4-fluorophenyl)-6-methyl-1,2,4-triazolo[3,4-b][2H-1,3,4]thiadiazine 442670-70-4 C11H9FN4S
    3-(4-fluorophenyl)-6-methyl-1,2,4-triazolo[3,4-b][2H-1,3,4]thiadiazine
    —— 4-(2,6-difluoro-phenylamino)-2-methylsulfanyl-pyrimidine-5-carbaldehyde 1001128-50-2 C12H9F2N3OS
    4-(2,6-difluoro-phenylamino)-2-methylsulfanyl-pyrimidine-5-carbaldehyde
    —— 3-[2-(4-hydroxyphenyl)ethyl]-6-(4-fluorophenyl)-7H-1,2,4-triazolo[3,4-b]-1,3,4-thiadiazine 1346462-14-3 C18H15FN4OS
    3-[2-(4-hydroxyphenyl)ethyl]-6-(4-fluorophenyl)-7H-1,2,4-triazolo[3,4-b]-1,3,4-thiadiazine
    —— 3-[2-cyclohexylethyl]-6-(4-fluorophenyl)-7H-1,2,4-triazolo[3,4-b]-1,3,4-thiadiazine 1346462-18-7 C18H21FN4S
    3-[2-cyclohexylethyl]-6-(4-fluorophenyl)-7H-1,2,4-triazolo[3,4-b]-1,3,4-thiadiazine
    —— 2,2,4,4,6,6-tris(tetramethylene)-1,3,5-trithiane 177-61-7 C15H24S3
    2,2,4,4,6,6-tris(tetramethylene)-1,3,5-trithiane
    —— 1-[4-(2,6-Dimethyl-4-nitro-phenylsulfanyl)-phenyl]-3-methyl-urea 54456-65-4 C16H17N3O3S
    1-[4-(2,6-Dimethyl-4-nitro-phenylsulfanyl)-phenyl]-3-methyl-urea
    —— urea, N-(4-{[2-chloro-4-(trifluoromethyl)phenyl]thio}-phenyl)-N'-methyl 54457-19-1 C15H12ClF3N2OS
    urea, N-(4-{[2-chloro-4-(trifluoromethyl)phenyl]thio}-phenyl)-N'-methyl
    —— 1-[3,5-Dichloro-4-(2-methoxy-5-methyl-phenylsulfanyl)-phenyl]-3-methyl-urea 54456-92-7 C16H16Cl2N2O2S
    1-[3,5-Dichloro-4-(2-methoxy-5-methyl-phenylsulfanyl)-phenyl]-3-methyl-urea
    —— 2-benzylsulfanyl-5-hydroxymethyl-thiazole 209473-22-3 C11H11NOS2
    2-benzylsulfanyl-5-hydroxymethyl-thiazole
    —— sodium 4-phenylthio-benzene-1-sulfonate 63316-44-9 C12H9O3S2*Na
    sodium 4-phenylthio-benzene-1-sulfonate
    —— 4-(2-benzylsulfanyl-thiazol-5-ylmethyl)-morpholine 209473-20-1 C15H18N2OS2
    4-(2-benzylsulfanyl-thiazol-5-ylmethyl)-morpholine
    —— 1-[3,5-Dichloro-4-(5-chloro-2-methoxy-phenylsulfanyl)-phenyl]-3-methyl-urea 54456-84-7 C15H13Cl3N2O2S
    1-[3,5-Dichloro-4-(5-chloro-2-methoxy-phenylsulfanyl)-phenyl]-3-methyl-urea
    —— 1-[3,5-Dichloro-4-(5-chloro-2-methyl-phenylsulfanyl)-phenyl]-3-methyl-urea 54456-83-6 C15H13Cl3N2OS
    1-[3,5-Dichloro-4-(5-chloro-2-methyl-phenylsulfanyl)-phenyl]-3-methyl-urea
    —— 1-[3,5-Dichloro-4-(3-ethoxy-phenylsulfanyl)-phenyl]-3-methyl-urea 54456-74-5 C16H16Cl2N2O2S
    1-[3,5-Dichloro-4-(3-ethoxy-phenylsulfanyl)-phenyl]-3-methyl-urea
    —— N-(2,3-Dihydro-6-methylimidazo<2,1-b>thiazol-5-ylmethyl)-N-(p-chlorophenyl)amine 123772-49-6 C13H14ClN3S
    N-(2,3-Dihydro-6-methylimidazo<2,1-b>thiazol-5-ylmethyl)-N-(p-chlorophenyl)amine
    —— diheptyl sulfone 16891-95-5 C14H30O2S
    diheptyl sulfone
    —— 1-pentylsulfanyl-heptane 41233-10-7 C12H26S
    1-pentylsulfanyl-heptane
    —— CGX0774 1219438-96-6 C18H21NOS
    CGX0774
    —— 1-[4-(4-tert-Butyl-phenylsulfanyl)-phenyl]-3-methyl-urea 54456-60-9 C18H22N2OS
    1-[4-(4-tert-Butyl-phenylsulfanyl)-phenyl]-3-methyl-urea
    —— 4-Ethyl-2-methylthio-6-trifluormethylpyrimidin 62772-92-3 C8H9F3N2S
    4-Ethyl-2-methylthio-6-trifluormethylpyrimidin
    —— 1,4-bis(methylthio)-2,3,5,6-tetramethylbenzene 225520-06-9 C12H18S2
    1,4-bis(methylthio)-2,3,5,6-tetramethylbenzene
    —— 3-amino-butane-2-thiol 4146-17-2 C4H11NS
    3-amino-butane-2-thiol
    —— 4-Isopentyl-2-methylthio-6-trifluormethyl-pyrimidin 62773-02-8 C11H15F3N2S
    4-Isopentyl-2-methylthio-6-trifluormethyl-pyrimidin
    —— 2,2-Bis-benzo[1,3]dithiol-2-yl-cyclopent-4-ene-1,3-dione 62576-08-3 C19H12O2S4
    2,2-Bis-benzo[1,3]dithiol-2-yl-cyclopent-4-ene-1,3-dione
    —— {4-chloro-6-[(4-chloro-benzyl)-methyl-amino]-pyrimidin-2-ylsulfanyl}-acetic acid ethyl ester 50892-31-4 C16H17Cl2N3O2S
    {4-chloro-6-[(4-chloro-benzyl)-methyl-amino]-pyrimidin-2-ylsulfanyl}-acetic acid ethyl ester
    —— 4-Isobutyl-2-methylthio-6-trifluormethyl-pyrimidin 62772-99-0 C10H13F3N2S
    4-Isobutyl-2-methylthio-6-trifluormethyl-pyrimidin
    —— methyl 2-(phenylthio)hexadecanoate 111722-89-5 C23H38O2S
    methyl 2-(phenylthio)hexadecanoate
    —— 2-(methylsulfonyl)propanoic acid 809280-27-1 C4H8O4S
    2-(methylsulfonyl)propanoic acid
    —— [[Oxido-di(propan-2-yloxy)phosphaniumyl]-phenylmethyl]sulfanylbenzene 124812-09-5 C19H25O3PS
    [[Oxido-di(propan-2-yloxy)phosphaniumyl]-phenylmethyl]sulfanylbenzene
    —— 3-[1,1-Bis(methylsulfanyl)ethyl]cyclohexan-1-one 53369-95-2 C10H18OS2
    3-[1,1-Bis(methylsulfanyl)ethyl]cyclohexan-1-one
    —— 4-Hydroxy-4-phenyl-3-phenylthiomethylbutan-2-on 40316-17-4 C17H18O2S
    4-Hydroxy-4-phenyl-3-phenylthiomethylbutan-2-on
    —— 2-Aethoxy-1,3-benzodithiol 62432-93-3 C9H10OS2
    2-Aethoxy-1,3-benzodithiol
    —— N-[4-(4-chlorophenyl)sulfanylphenyl]-2-(dimethylamino)-N-methylacetamide 77717-25-0 C17H19ClN2OS
    N-[4-(4-chlorophenyl)sulfanylphenyl]-2-(dimethylamino)-N-methylacetamide
    —— 2-[4-(4-chloro-phenylsulfanyl)-phenyl]-2<i>H</i>-[1,2,4]triazine-3,5-dione 38560-71-3 C15H10ClN3O2S
    2-[4-(4-chloro-phenylsulfanyl)-phenyl]-2<i>H</i>-[1,2,4]triazine-3,5-dione
    —— tris(N,N-diethyldithiocarbamato)aluminium(III) complex 110975-13-8 C15H30AlN3S6
    tris(N,N-diethyldithiocarbamato)aluminium(III) complex
    —— 1H-Imidazol-2-amine, 4,5-dihydro-N-[4-[(4-methylphenyl)thio]phenyl]- 71576-73-3 C16H17N3S
    1H-Imidazol-2-amine, 4,5-dihydro-N-[4-[(4-methylphenyl)thio]phenyl]-