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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2Z)-2-iodo-4-(phenylthio)-2-buten-1-ol 158300-18-6 C10H11IOS
    (2Z)-2-iodo-4-(phenylthio)-2-buten-1-ol
    —— (2S,5S,6S,1'R)-2-(1'-hydroxy-3'-(phenylsulfanyl)propyl)-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxane-2-carboxylic acid methyl ester 1042925-98-3 C19H28O7S
    (2S,5S,6S,1'R)-2-(1'-hydroxy-3'-(phenylsulfanyl)propyl)-5,6-dimethoxy-5,6-dimethyl-[1,4]dioxane-2-carboxylic acid methyl ester
    —— (3-methoxyphenyl)(2,4,6-trimethoxyphenyl)sulfane 1242673-93-3 C16H18O4S
    (3-methoxyphenyl)(2,4,6-trimethoxyphenyl)sulfane
    —— 4-{[(3-pyridyl)methyl]sulfanyl}aniline 125382-42-5 C12H12N2S
    4-{[(3-pyridyl)methyl]sulfanyl}aniline
    —— (2R,4R)-2,4-dimethyl-1-phenylthio-hexane 177420-68-7 C14H22S
    (2R,4R)-2,4-dimethyl-1-phenylthio-hexane
    —— (2S,4R)-2,4-dimethyl-5-phenylthio-1-pentanol 177420-67-6 C13H20OS
    (2S,4R)-2,4-dimethyl-5-phenylthio-1-pentanol
    —— 3-Methyl-5-methylsulfanyl-4-(2-phenylamino-pyrimidin-4-yl)-thiophene-2-carbonitrile 473530-72-2 C17H14N4S2
    3-Methyl-5-methylsulfanyl-4-(2-phenylamino-pyrimidin-4-yl)-thiophene-2-carbonitrile
    —— 4-(3-dimethylamino-acryloyl)-3-methyl-5-methylsulfanyl-thiophene-2-carbonitrile 1098622-19-5 C12H14N2OS2
    4-(3-dimethylamino-acryloyl)-3-methyl-5-methylsulfanyl-thiophene-2-carbonitrile
    —— {4-[4-methyl-2-methylsulfanyl-5-(4-methyl-thiazol-2-yl)-thiophen-3-yl]-pyrimidin-2-yl}-phenylamine 473530-82-4 C20H18N4S3
    {4-[4-methyl-2-methylsulfanyl-5-(4-methyl-thiazol-2-yl)-thiophen-3-yl]-pyrimidin-2-yl}-phenylamine
    —— 3-dimethylamino-1-[4-methyl-2-methylsulfanyl-5-(4-methyl-thiazol-2-yl)-thiophen-3-yl]-propenone 1098622-18-4 C15H18N2OS3
    3-dimethylamino-1-[4-methyl-2-methylsulfanyl-5-(4-methyl-thiazol-2-yl)-thiophen-3-yl]-propenone
    —— 5-acetyl-2-methylsulfanyl-4-(4-chloro-phenyl)-thiophene-3-carbonitrile 63244-11-1 C14H10ClNOS2
    5-acetyl-2-methylsulfanyl-4-(4-chloro-phenyl)-thiophene-3-carbonitrile
    —— 3-(2-<i>tert</i>-butylsulfanyl-phenyl)-oxiranecarboxylic acid ethyl ester 65924-67-6 C15H20O3S
    3-(2-<i>tert</i>-butylsulfanyl-phenyl)-oxiranecarboxylic acid ethyl ester
    —— 1,4-Bis-<N,N-dimethyl-thiocarbamoylmercapto>-benzol 13512-06-6 C12H16N2O2S2
    1,4-Bis-<N,N-dimethyl-thiocarbamoylmercapto>-benzol
    —— 3-('-Methylphenyl)-2-methylmercapto-4-(3H)pyrimidone 80306-55-4 C12H12N2OS
    3-('-Methylphenyl)-2-methylmercapto-4-(3H)pyrimidone
    —— 6-amino-3-isobutoxy-2-<(4-tert-butylphenyl)thio>benzonitrile 1026449-09-1 C21H26N2OS
    6-amino-3-isobutoxy-2-<(4-tert-butylphenyl)thio>benzonitrile
    —— 6-amino-3-ethoxy-2-<(4-tert-butylphenyl)thio>benzonitrile 1027190-49-3 C19H22N2OS
    6-amino-3-ethoxy-2-<(4-tert-butylphenyl)thio>benzonitrile
    —— Benzyl-p-tolylsulfanylmethyl-amine; hydrochloride 33711-32-9 C15H17NS*ClH
    Benzyl-p-tolylsulfanylmethyl-amine; hydrochloride
    —— phenyl<2'-(phenylthiomethylene)cyclohex-1-yl>methanol 125334-87-4 C20H22OS
    phenyl<2'-(phenylthiomethylene)cyclohex-1-yl>methanol
    —— 1-phenyl-2-phenylthio-2-cyclohex-1-enylethanol 125334-86-3 C20H22OS
    1-phenyl-2-phenylthio-2-cyclohex-1-enylethanol
    —— N,N-dibutylthiocarbamic acid 57442-69-0 C9H18NOS*H
    N,N-dibutylthiocarbamic acid
    —— Benzyl-phenylsulfanylmethyl-amine; hydrochloride 65502-69-4 C14H15NS*ClH
    Benzyl-phenylsulfanylmethyl-amine; hydrochloride
    —— (Z)-1-methoxy-3-methyl-1-(phenylthio)but-1-ene 93500-16-4 C12H16OS
    (Z)-1-methoxy-3-methyl-1-(phenylthio)but-1-ene
    —— [(3-Methyl-2-nitrobut-3-en-1-yl)sulfanyl]benzene 65912-13-2 C11H13NO2S
    [(3-Methyl-2-nitrobut-3-en-1-yl)sulfanyl]benzene
    —— 4-{1-[difluoro(phenylthio)methyl]cyclohex-1-yl}morpholine 1357268-68-8 C17H23F2NOS
    4-{1-[difluoro(phenylthio)methyl]cyclohex-1-yl}morpholine
    —— (2-chloro-4-methyl-5-((2,2,2-trifluoroethyl)thio)phenyl)boronic acid 1416349-29-5 C9H9BClF3O2S
    (2-chloro-4-methyl-5-((2,2,2-trifluoroethyl)thio)phenyl)boronic acid
    —— 2-aminophenyl piperidine-1-carbodithioate 1269796-05-5 C12H16N2S2
    2-aminophenyl piperidine-1-carbodithioate
    —— N-Cyclohexyl-2,2-dimethyl-thiopropionamide 65726-22-9 C11H21NS
    N-Cyclohexyl-2,2-dimethyl-thiopropionamide
    —— 2-((phenylthio)benzyl)cyclohex-2-en-1-one 157584-97-9 C19H18OS
    2-((phenylthio)benzyl)cyclohex-2-en-1-one
    —— 2-[Hydroxy(phenyl)methyl]-3-phenylsulfanylcyclohexan-1-one 157584-95-7 C19H20O2S
    2-[Hydroxy(phenyl)methyl]-3-phenylsulfanylcyclohexan-1-one
    —— Pent-2-en-4-inylthiol 26068-33-7 C5H6S
    Pent-2-en-4-inylthiol
    —— 2',4'-Diamino-3-hydroxy-diphenylsulfid 27848-32-4 C12H12N2OS
    2',4'-Diamino-3-hydroxy-diphenylsulfid
    —— 6-bromohexylthiol 342401-51-8 C6H13BrS
    6-bromohexylthiol
    —— Diisobutyl-thiocarbamic acid 71261-27-3 C9H19NOS
    Diisobutyl-thiocarbamic acid
    —— N-heptyldithiocarbamic acid 22292-13-3 C8H17NS2
    N-heptyldithiocarbamic acid
    —— N-nonyldithiocarbamic acid 738519-76-1 C10H21NS2
    N-nonyldithiocarbamic acid
    —— 6-Amino-dihydrothiazolo<3,2-a>pyridinium 66201-73-8 C7H9N2S*Cl
    6-Amino-dihydrothiazolo<3,2-a>pyridinium
    —— 2-(Dichloromethylidene)-2H-1,3-benzodithiole 64188-91-6 C8H4Cl2S2
    2-(Dichloromethylidene)-2H-1,3-benzodithiole
    —— 1-phenyl-2-(2,4,6-trimethylphenylthio)but-3-en-1-ol 76120-48-4 C19H22OS
    1-phenyl-2-(2,4,6-trimethylphenylthio)but-3-en-1-ol
    —— (Z)-1-phenyl-4-(2,4,6-trimethylphenylthio)but-3-en-1-ol 76120-49-5 C19H22OS
    (Z)-1-phenyl-4-(2,4,6-trimethylphenylthio)but-3-en-1-ol
    —— (4Z,6E)-1-(tert-butyldimethylsilyl)oxy-8-(tert-butyldiphenylsilyl)oxy-5-phenylthio-4,6-octadiene-3-ol 301310-28-1 C36H50O3SSi2
    (4Z,6E)-1-(tert-butyldimethylsilyl)oxy-8-(tert-butyldiphenylsilyl)oxy-5-phenylthio-4,6-octadiene-3-ol
    —— (4Z,6E)-1-(tert-butyldimethylsilyl)oxy-3,8-di[(tert-butyldiphenylsilyl)oxy]-5-phenylthio-4,6-octadiene 301310-29-2 C52H68O3SSi3
    (4Z,6E)-1-(tert-butyldimethylsilyl)oxy-3,8-di[(tert-butyldiphenylsilyl)oxy]-5-phenylthio-4,6-octadiene
    —— (4Z,6E)-3,8-di[(tert-butyldiphenylsilyl)oxy]-5-phenylthio-4,6-octadiene-1-ol 301310-30-5 C46H54O3SSi2
    (4Z,6E)-3,8-di[(tert-butyldiphenylsilyl)oxy]-5-phenylthio-4,6-octadiene-1-ol
    —— (4Z,6E)-1-azido-3,8-di[(tert-butyldiphenylsilyl)oxy]-5-phenylthio-4,6-octadiene 301310-31-6 C46H53N3O2SSi2
    (4Z,6E)-1-azido-3,8-di[(tert-butyldiphenylsilyl)oxy]-5-phenylthio-4,6-octadiene
    —— S-2-Pyridyl (R)-3-tert-butyldimethylsilyloxybutanoate 141781-29-5 C15H25NO2SSi
    S-2-Pyridyl (R)-3-tert-butyldimethylsilyloxybutanoate
    —— N-[5-chloro-2-(phenylsulfanyl)phenyl]-1-benzofuran-2-sulfonamide 1451261-59-8 C20H14ClNO3S2
    N-[5-chloro-2-(phenylsulfanyl)phenyl]-1-benzofuran-2-sulfonamide
    —— N-isopentyldithiocarbamic acid 22292-10-0 C6H13NS2
    N-isopentyldithiocarbamic acid
    —— (3R,8aS)-5-oxo-3-phenyl-6,6-bis(phenylsulfanyl)-2,3,6,7,8,8a-hexahydro-5H-oxazolo[3,2-a]pyridine 602302-24-9 C25H23NO2S2
    (3R,8aS)-5-oxo-3-phenyl-6,6-bis(phenylsulfanyl)-2,3,6,7,8,8a-hexahydro-5H-oxazolo[3,2-a]pyridine
    —— 2-(phenylthio)malonamide 22805-18-1 C9H10N2O2S
    2-(phenylthio)malonamide
    —— 2-(Phenylsulfanyl)prop-1-en-1-one 66977-59-1 C9H8OS
    2-(Phenylsulfanyl)prop-1-en-1-one
    —— Diethyl 2-(phenylsulfanylmethyl)propanedioate 82418-82-4 C14H18O4S
    Diethyl 2-(phenylsulfanylmethyl)propanedioate