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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-methyl-5-phenylsulfanylmethyl-imidazolidine-2,4-dione 24956-71-6 C11H12N2O2S
    5-methyl-5-phenylsulfanylmethyl-imidazolidine-2,4-dione
    —— 4-chloro-6-(4-iodophenylamino)-2-(methylthio)pyrimidin-5-carbonitrile 1374159-81-5 C12H8ClIN4S
    4-chloro-6-(4-iodophenylamino)-2-(methylthio)pyrimidin-5-carbonitrile
    —— 2-(4-aminophenylthio)-4-(trifluoromethyl)pyrimidine 1270110-63-8 C11H8F3N3S
    2-(4-aminophenylthio)-4-(trifluoromethyl)pyrimidine
    —— 4-(phenylthio)-1,3-phenylenediamine 6264-74-0 C12H12N2S
    4-(phenylthio)-1,3-phenylenediamine
    —— 2,5-dichloro-4-(methylthio)pyrimidine 1245830-98-1 C5H4Cl2N2S
    2,5-dichloro-4-(methylthio)pyrimidine
    —— [[3-(trimethylsilyl)propyl]thio]benzene 19185-59-2 C12H20SSi
    [[3-(trimethylsilyl)propyl]thio]benzene
    —— (1R)-1-methyl-N-[(S)-1-phenylethyl]-2-phenylsulfanylethylamine 261729-90-2 C17H21NS
    (1R)-1-methyl-N-[(S)-1-phenylethyl]-2-phenylsulfanylethylamine
    —— N-(4-Cyano-3-phenylthiophenyl)-3,3,3,-trifluoro-2-hydroxy-2-methyl propanamide 148301-97-7 C17H13F3N2O2S
    N-(4-Cyano-3-phenylthiophenyl)-3,3,3,-trifluoro-2-hydroxy-2-methyl propanamide
    —— 2-acetamido-5-phenylthiothiazole 91137-89-2 C11H10N2OS2
    2-acetamido-5-phenylthiothiazole
    —— 6-nitro-2-phenylsulfanylbenzothiazole 38420-80-3 C13H8N2O2S2
    6-nitro-2-phenylsulfanylbenzothiazole
    —— 5-(phenylthio)-pyridine-2-thione 67743-64-0 C11H9NS2
    5-(phenylthio)-pyridine-2-thione
    —— N-[(S)-1-methyl-2-phenylsulfanylethyl]-N-[(R)-1-phenylethyl]formamide 261729-92-4 C18H21NOS
    N-[(S)-1-methyl-2-phenylsulfanylethyl]-N-[(R)-1-phenylethyl]formamide
    —— (1R)-1-methyl-N-[(R)-1-phenylethyl]-2-phenylsulfanylethylamine 261729-91-3 C17H21NS
    (1R)-1-methyl-N-[(R)-1-phenylethyl]-2-phenylsulfanylethylamine
    —— 1-(phenylthio)-2-cyclohexene-1-carboxaldehyde 108139-15-7 C13H14OS
    1-(phenylthio)-2-cyclohexene-1-carboxaldehyde
    —— Trimethyl[3-(phenylsulfanyl)undecyl]silane 89373-23-9 C20H36SSi
    Trimethyl[3-(phenylsulfanyl)undecyl]silane
    —— 1-Phenylthio-3-(2-tetrahydropyranyloxy)-2-propanol 115413-18-8 C14H20O3S
    1-Phenylthio-3-(2-tetrahydropyranyloxy)-2-propanol
    —— dimethyl (2R,3R)-2-methyl-3-phenylsultanylsuccinate 369365-15-1 C13H16O4S
    dimethyl (2R,3R)-2-methyl-3-phenylsultanylsuccinate
    —— 2-<(phenylthio)methyl>cyclohexanecarboxylic acid 76358-97-9 C14H18O2S
    2-<(phenylthio)methyl>cyclohexanecarboxylic acid
    —— 2,2,6,6-tetramethyl-1-[(phenylthio)methyl]cyclohexane 852988-98-8 C17H26S
    2,2,6,6-tetramethyl-1-[(phenylthio)methyl]cyclohexane
    —— N-benzyl-N-[(S)-1-methyl-2-phenylsulfanylethyl]formamide 261729-82-2 C17H19NOS
    N-benzyl-N-[(S)-1-methyl-2-phenylsulfanylethyl]formamide
    —— (3-Hydroxy-2-phenylthio)propyl N,N-dimethylcarbamate 115413-00-8 C12H17NO3S
    (3-Hydroxy-2-phenylthio)propyl N,N-dimethylcarbamate
    —— (3-Phenylthio-2-hydroxy)propyl N,N-dimethylcarbamate 115413-17-7 C12H17NO3S
    (3-Phenylthio-2-hydroxy)propyl N,N-dimethylcarbamate
    —— 2-(Methoxycarbonylamino) 6-(p-chlorosulfonylphenylthio) imidazo [1,2-a] pyridine 76911-36-9 C15H12ClN3O4S2
    2-(Methoxycarbonylamino) 6-(p-chlorosulfonylphenylthio) imidazo [1,2-a] pyridine
    —— 5-phenylsulfanyl-thiazol-2-ylamine 59278-80-7 C9H8N2S2
    5-phenylsulfanyl-thiazol-2-ylamine
    —— (+)-(1S,6R)-2,2,6-trimethyl-1-[(phenylthio)methyl]cyclohexane 139406-53-4 C16H24S
    (+)-(1S,6R)-2,2,6-trimethyl-1-[(phenylthio)methyl]cyclohexane
    —— (-)-(1R,6S)-2,2,6-trimethyl-1-[(phenylthio)methyl]cyclohexane 139364-97-9 C16H24S
    (-)-(1R,6S)-2,2,6-trimethyl-1-[(phenylthio)methyl]cyclohexane
    —— N-[(S)-1-methyl-2-phenylsulfanylethyl]-N-[(S)-1-phenylethyl]formamide 261729-93-5 C18H21NOS
    N-[(S)-1-methyl-2-phenylsulfanylethyl]-N-[(S)-1-phenylethyl]formamide
    —— N-benzyl-N-[(R)-1-methyl-2-phenylsulfanylethyl]formamide 261729-83-3 C17H19NOS
    N-benzyl-N-[(R)-1-methyl-2-phenylsulfanylethyl]formamide
    —— 1-(1-phenylthio-2-cyclohexenyl)-1-heptanone 108139-05-5 C19H26OS
    1-(1-phenylthio-2-cyclohexenyl)-1-heptanone
    —— (1S)-1-methyl-N-[(R)-1-phenylethyl]-2-phenylsulfanylethylamine 261729-88-8 C17H21NS
    (1S)-1-methyl-N-[(R)-1-phenylethyl]-2-phenylsulfanylethylamine
    —— 5-benzamido-3-(benzothiazol-2'-ylthio)-4-methyl-1-(p-nitrophenyl)-3-oxo-1,6-dihydropyridazine 1306831-02-6 C25H17N5O4S2
    5-benzamido-3-(benzothiazol-2'-ylthio)-4-methyl-1-(p-nitrophenyl)-3-oxo-1,6-dihydropyridazine
    —— (1S)-1-methyl-N-[(S)-1-phenylethyl]-2-phenylsulfanylethylamine 261729-89-9 C17H21NS
    (1S)-1-methyl-N-[(S)-1-phenylethyl]-2-phenylsulfanylethylamine
    —— N-[(R)-1-methyl-2-phenylsulfanylethyl]-N-[(R)-1-phenylethyl]formamide 261729-95-7 C18H21NOS
    N-[(R)-1-methyl-2-phenylsulfanylethyl]-N-[(R)-1-phenylethyl]formamide
    —— (2-oxo-3-phenylsulfanylpropyl) N,N-dimethylcarbamate 115413-24-6 C12H15NO3S
    (2-oxo-3-phenylsulfanylpropyl) N,N-dimethylcarbamate
    —— 1-(1-phenylthio-2-cyclopentenyl)-1-heptanone 108139-16-8 C18H24OS
    1-(1-phenylthio-2-cyclopentenyl)-1-heptanone
    —— (Z)-4-(dimethylamino)-3-phenylsulfanyl-1-(2,2,2-trichloroethoxy)but-3-en-2-one 115413-30-4 C14H16Cl3NO2S
    (Z)-4-(dimethylamino)-3-phenylsulfanyl-1-(2,2,2-trichloroethoxy)but-3-en-2-one
    —— 2-Hydroxy-3-(phenylsulfanyl)propyl pivalate 115413-16-6 C14H20O3S
    2-Hydroxy-3-(phenylsulfanyl)propyl pivalate
    —— [(Z)-4-(dimethylamino)-2-oxo-3-phenylsulfanylbut-3-enyl] 2,2-dimethylpropanoate 115412-96-9 C17H23NO3S
    [(Z)-4-(dimethylamino)-2-oxo-3-phenylsulfanylbut-3-enyl] 2,2-dimethylpropanoate
    —— N-[(R)-1-methyl-2-phenylsulfanylethyl]-N-[(S)-1-phenylethyl]formamide 261729-94-6 C18H21NOS
    N-[(R)-1-methyl-2-phenylsulfanylethyl]-N-[(S)-1-phenylethyl]formamide
    —— 3-methyl-3-phenylthio-1-decen-4-one 108139-18-0 C17H24OS
    3-methyl-3-phenylthio-1-decen-4-one
    —— (4,4-dimethylpent-2-ynylsulfanyl)benzene 88096-95-1 C13H16S
    (4,4-dimethylpent-2-ynylsulfanyl)benzene
    —— 1-Phenylsulfanyl-3-(2,2,2-trichloroethoxy)propan-2-one 115413-21-3 C11H11Cl3O2S
    1-Phenylsulfanyl-3-(2,2,2-trichloroethoxy)propan-2-one
    —— O-Aethyl-N-(β-phenylthio-aethyl)-urethan 92147-10-9 C11H15NO2S
    O-Aethyl-N-(β-phenylthio-aethyl)-urethan
    —— 2-amino-4-chloro-6-methylsulfanyl-pyrimidine-5-carbonitrile 54356-39-7 C6H5ClN4S
    2-amino-4-chloro-6-methylsulfanyl-pyrimidine-5-carbonitrile
    —— 5-amino-1-(benzothiazol-2'-ylthio)-4-imino-3-(p-methoxyphenyl)-7-phenyl-3,4-dihydrophthalazine-6,6(7H)-dicarbonitrile 1306830-99-8 C30H21N7OS2
    5-amino-1-(benzothiazol-2'-ylthio)-4-imino-3-(p-methoxyphenyl)-7-phenyl-3,4-dihydrophthalazine-6,6(7H)-dicarbonitrile
    —— (E)-prop-1-ene-1,3-diylbis(phenylsulfane) 80780-63-8 C15H14S2
    (E)-prop-1-ene-1,3-diylbis(phenylsulfane)
    —— 2-Methyl-3-<(phenylthio)methyl>pyridine 76915-54-3 C13H13NS
    2-Methyl-3-<(phenylthio)methyl>pyridine
    —— 1-(1-phenylthio-2-cyclohexenyl)ethanone 108139-14-6 C14H16OS
    1-(1-phenylthio-2-cyclohexenyl)ethanone
    —— 5-benzamido-3-(benzothiazol-2'-ylthio)-4-methyl-6-oxo-1-phenyl-1,6-dihydropyridazine hydrochloride 1306605-04-8 C25H18N4O2S2*ClH
    5-benzamido-3-(benzothiazol-2'-ylthio)-4-methyl-6-oxo-1-phenyl-1,6-dihydropyridazine hydrochloride
    —— 5-benzamido-3-(benzothiazol-2'-ylthio)-1-(p-methoxyphenyl)-4-methyl-6-oxo-1,6-dihydropyridazine 1306831-01-5 C26H20N4O3S2
    5-benzamido-3-(benzothiazol-2'-ylthio)-1-(p-methoxyphenyl)-4-methyl-6-oxo-1,6-dihydropyridazine