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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3,3-di[(phenylsulfanyl)methyl]cyclobutanone 938436-13-6 C18H18OS2
    3,3-di[(phenylsulfanyl)methyl]cyclobutanone
    —— (2R,3S)-N,N-diallyl-3-hydroxy-2,4-dimethylpentanethioamide 1283722-04-2 C13H23NOS
    (2R,3S)-N,N-diallyl-3-hydroxy-2,4-dimethylpentanethioamide
    —— 4,5-dihydro-3-(1-hydroxybutyl)-3-phenylthio-3H-furan-2-one —— C14H18O3S
    4,5-dihydro-3-(1-hydroxybutyl)-3-phenylthio-3H-furan-2-one
    —— 5-(2-nitro-1-phenylethyl)-3-phenylthiofuran-2(5H)-one 1280709-98-9 C18H15NO4S
    5-(2-nitro-1-phenylethyl)-3-phenylthiofuran-2(5H)-one
    —— (1E,3E)-1-bromo-4-phenylthio-1,3-butadiene 161944-20-3 C10H9BrS
    (1E,3E)-1-bromo-4-phenylthio-1,3-butadiene
    —— (2R,3S)-N,N-diallyl-3-cyclohexyl-3-hydroxy-2-methylpropanethioamide 1283722-11-1 C16H27NOS
    (2R,3S)-N,N-diallyl-3-cyclohexyl-3-hydroxy-2-methylpropanethioamide
    —— 2-[4-[2-[(Z)-hex-4-enyl]-1,3-dithian-2-yl]butoxy]oxane 246034-85-5 C19H34O2S2
    2-[4-[2-[(Z)-hex-4-enyl]-1,3-dithian-2-yl]butoxy]oxane
    —— (2R,3S)-N,N-diallyl-3-hydroxy-2-methyldecanethioamide 1283722-14-4 C17H31NOS
    (2R,3S)-N,N-diallyl-3-hydroxy-2-methyldecanethioamide
    —— 3-phenylthio-4-(1'-dimethylphenylsilylmethylethenyl)dihydro-2(3H)-furanone 144602-80-2 C21H24O2SSi
    3-phenylthio-4-(1'-dimethylphenylsilylmethylethenyl)dihydro-2(3H)-furanone
    —— α-chloro-α-(phenylthio)-γ-butyrolactone 62675-47-2 C10H9ClO2S
    α-chloro-α-(phenylthio)-γ-butyrolactone
    —— 4,5-Bis(4-methoxyphenyl)-2-(2-thienylthio)-thiazol 88264-15-7 C21H17NO2S3
    4,5-Bis(4-methoxyphenyl)-2-(2-thienylthio)-thiazol
    —— 4,5-dihydro-3-(1-hydroxymethyl)-3-phenylthio-3H-furan-2-one 109765-91-5 C11H12O3S
    4,5-dihydro-3-(1-hydroxymethyl)-3-phenylthio-3H-furan-2-one
    —— methyl 1-(phenylthio)cyclopropanecarboxylate 342624-00-4 C11H12O2S
    methyl 1-(phenylthio)cyclopropanecarboxylate
    —— Trimethyl-((E)-4-phenylsulfanyl-but-3-en-1-ynyl)-silane 161944-19-0 C13H16SSi
    Trimethyl-((E)-4-phenylsulfanyl-but-3-en-1-ynyl)-silane
    —— 2,5-dibromo-3-(methylthio)thiophene 94781-42-7 C5H4Br2S2
    2,5-dibromo-3-(methylthio)thiophene
    —— (2-allyl-3,5-dimethylphenyl)(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)sulfide 1338723-53-7 C21H17F17S
    (2-allyl-3,5-dimethylphenyl)(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)sulfide
    —— 1,2,3-Trithia-cycloheptan 6576-92-7 C4H8S3
    1,2,3-Trithia-cycloheptan
    —— 4-Methylthiobenzolphosphonsaeure 46061-42-1 C7H9O3PS
    4-Methylthiobenzolphosphonsaeure
    —— <bis(phenylthio)methyl>trimethylsilane 37891-39-7 C16H20S2Si
    <bis(phenylthio)methyl>trimethylsilane
    —— 4-Methylthiophenylphosphonic dichloride 77918-52-6 C7H7Cl2OPS
    4-Methylthiophenylphosphonic dichloride
    —— P-[(phenylthio)[13C]methyl]-phosphonic acid diethyl ester 1190788-52-3 C11H17O3PS
    P-[(phenylthio)[13C]methyl]-phosphonic acid diethyl ester
    —— trithiacyclononane 61775-36-8 C6H12S3
    trithiacyclononane
    —— 2-mercapto-4-methyl-3-penten-1-ol 78585-28-1 C6H12OS
    2-mercapto-4-methyl-3-penten-1-ol
    —— <i>N</i>-ethoxycarbonyl-thioglycine amide 146538-11-6 C5H10N2O2S
    <i>N</i>-ethoxycarbonyl-thioglycine amide
    —— 1,4-bis-methanethio-2-butyne 26842-67-1 C6H10S2
    1,4-bis-methanethio-2-butyne
    —— 4-methylpent-3-ene-1-thiol 127480-87-9 C6H12S
    4-methylpent-3-ene-1-thiol
    —— 1-Phenylthio-1-(trimethylsilyl)-1-nonene 115993-80-1 C18H30SSi
    1-Phenylthio-1-(trimethylsilyl)-1-nonene
    —— 4-(phenylmethylthio)thiazole 89501-98-4 C10H9NS2
    4-(phenylmethylthio)thiazole
    —— 2-(2-Hydroxy-ethylsulfanyl)-pyridin-3-ol 77764-11-5 C7H9NO2S
    2-(2-Hydroxy-ethylsulfanyl)-pyridin-3-ol
    —— 6-amino-2-phenylthiobenzothiazole 76006-91-2 C13H10N2S2
    6-amino-2-phenylthiobenzothiazole
    —— 6-amino-1,4,7,9-tetraazabenzo<b>phenothiazine 77708-95-3 C12H8N6S
    6-amino-1,4,7,9-tetraazabenzo<b>phenothiazine
    —— 2-<1-(4-Chlorphenylthio)heptyliden>-6,6-dimethylcyclohexanon 90474-98-9 C21H29ClOS
    2-<1-(4-Chlorphenylthio)heptyliden>-6,6-dimethylcyclohexanon
    —— O-ethyl S-{4-[5-(hydroxymethyl)thien-2-yl]-1,3-thiazol-2-yl} thiocarbonate 1027417-59-9 C11H11NO3S3
    O-ethyl S-{4-[5-(hydroxymethyl)thien-2-yl]-1,3-thiazol-2-yl} thiocarbonate
    —— (2S,3R,4S,5R)-3,4,5-trimethoxy-2-(phenylthio)tetrahydro-2H-pyran 870096-05-2 C14H20O4S
    (2S,3R,4S,5R)-3,4,5-trimethoxy-2-(phenylthio)tetrahydro-2H-pyran
    —— 7-Methyl-3-thiophen-2-yl-6-[3-(trifluoromethyl)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazine 1428566-39-5 C17H11F3N4S2
    7-Methyl-3-thiophen-2-yl-6-[3-(trifluoromethyl)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazine
    —— 8-Methyl-3-thiophen-2-yl-6-[3-(trifluoromethyl)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazine 1428566-40-8 C17H11F3N4S2
    8-Methyl-3-thiophen-2-yl-6-[3-(trifluoromethyl)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazine
    —— 4-Methoxy-3,5-dimethyl-2-(5-thiophen-2-yl-[1,3,4]oxadiazol-2-ylsulfanylmethyl)-pyridine 197371-68-9 C15H15N3O2S2
    4-Methoxy-3,5-dimethyl-2-(5-thiophen-2-yl-[1,3,4]oxadiazol-2-ylsulfanylmethyl)-pyridine
    —— 3-Thiophen-2-yl-6-[3-(trifluoromethyl)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazine 1428565-56-3 C16H9F3N4S2
    3-Thiophen-2-yl-6-[3-(trifluoromethyl)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazine
    —— 3-(2-Thienyl)-4-methyl-5-methylthio-4H-1,2,4-triazole 116850-51-2 C8H9N3S2
    3-(2-Thienyl)-4-methyl-5-methylthio-4H-1,2,4-triazole
    —— ethyl 2-((6-chloropyridazin-3-yl)thio)propanoate 89981-29-3 C8H9ClN2O2S
    ethyl 2-((6-chloropyridazin-3-yl)thio)propanoate
    —— 1-Methylsulfanyl-3-(3-methylsulfanyl-[1,2,4]triazin-5-yl)-5,6,7,8,9,10-hexahydro-cycloocta[c]pyridine 501117-58-4 C16H20N4S2
    1-Methylsulfanyl-3-(3-methylsulfanyl-[1,2,4]triazin-5-yl)-5,6,7,8,9,10-hexahydro-cycloocta[c]pyridine
    —— tert-Butoxycarbonyl-isothiocyanat 78366-57-1 C6H9NO2S
    tert-Butoxycarbonyl-isothiocyanat
    —— 3,3'-bis(methylsulfanyl)-5,5'-bi-1,2,4-triazine 42836-88-4 C8H8N6S2
    3,3'-bis(methylsulfanyl)-5,5'-bi-1,2,4-triazine
    —— N-(2-Amino-ethyl)-N'-(5-chloro-2-phenylsulfanyl-phenyl)-propane-1,3-diamine 180145-05-5 C17H22ClN3S
    N-(2-Amino-ethyl)-N'-(5-chloro-2-phenylsulfanyl-phenyl)-propane-1,3-diamine
    —— 1-Methylsulfanyl-3-(3-methylsulfanyl-[1,2,4]triazin-5-yl)-6,7,8,9-tetrahydro-5H-cyclohepta[c]pyridine 287102-87-8 C15H18N4S2
    1-Methylsulfanyl-3-(3-methylsulfanyl-[1,2,4]triazin-5-yl)-6,7,8,9-tetrahydro-5H-cyclohepta[c]pyridine
    —— 1-Methylsulfanyl-3-(3-methylsulfanyl-1,2,4-triazin-5-yl)-5,6,7,8-tetrahydroisoquinoline 287102-86-7 C14H16N4S2
    1-Methylsulfanyl-3-(3-methylsulfanyl-1,2,4-triazin-5-yl)-5,6,7,8-tetrahydroisoquinoline
    —— 1-methylsulfanyl-3-(3-methylsulfanyl-1,2,4-triazin-5-yl)-6,7-dihydro-5H-cyclopenta[c]pyridine 287102-85-6 C13H14N4S2
    1-methylsulfanyl-3-(3-methylsulfanyl-1,2,4-triazin-5-yl)-6,7-dihydro-5H-cyclopenta[c]pyridine
    —— 3,4-bis(methylthio)isothiazole-5-carbonitrile 75083-17-9 C6H6N2S3
    3,4-bis(methylthio)isothiazole-5-carbonitrile
    —— N-[3-[4-(2-aminoethyl)piperazin-1-yl]propyl]-5-chloro-2-phenylsulfanylaniline 180145-13-5 C21H29ClN4S
    N-[3-[4-(2-aminoethyl)piperazin-1-yl]propyl]-5-chloro-2-phenylsulfanylaniline
    —— 1-Methyl-3-(3-methylmercaptoisothiazol-5-yl)urea 108281-24-9 C6H9N3OS2
    1-Methyl-3-(3-methylmercaptoisothiazol-5-yl)urea