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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 6-chloro-4-(2-hydroxyethylamino)-2-methylthiopyrimidine-5-carbonitrile 192519-70-3 C8H9ClN4OS
    6-chloro-4-(2-hydroxyethylamino)-2-methylthiopyrimidine-5-carbonitrile
    —— 1-(5-ethoxy-pentylsulfanyl)-2-methyl-propene 62162-15-6 C11H22OS
    1-(5-ethoxy-pentylsulfanyl)-2-methyl-propene
    —— rac-1-(2-(2-hydroxypropan-2-yl)azetidin-1-yl)-2,2-dimethylpropane-1-thione 1228452-84-3 C11H21NOS
    rac-1-(2-(2-hydroxypropan-2-yl)azetidin-1-yl)-2,2-dimethylpropane-1-thione
    —— N-thiopivaloyl azetidine 1228452-72-9 C8H15NS
    N-thiopivaloyl azetidine
    —— [(R)-1-(4-ethyl-5-methylsulfanyl-4H-[1,2,4]triazol-3-yl)ethyl]-carbamic acid t-butyl ester 875569-04-3 C12H22N4O2S
    [(R)-1-(4-ethyl-5-methylsulfanyl-4H-[1,2,4]triazol-3-yl)ethyl]-carbamic acid t-butyl ester
    —— 1-But-3-enylsulfanyl-2-methyl-3-vinyl-cyclopropane 62162-27-0 C10H16S
    1-But-3-enylsulfanyl-2-methyl-3-vinyl-cyclopropane
    —— 4-isocyanato-2-methylsulfanyl-5-phenylsulfanyl-pyrimidine 61727-15-9 C12H9N3OS2
    4-isocyanato-2-methylsulfanyl-5-phenylsulfanyl-pyrimidine
    —— N-methyl-2-(4'-ethenyl-2'-nitrophenylthio)benzamide 851974-55-5 C16H14N2O3S
    N-methyl-2-(4'-ethenyl-2'-nitrophenylthio)benzamide
    —— benzyl 5-(4-fluorophenyl)sulfanylspiro[indoline-3,4'-piperidine]-1'-carboxylate 1421708-18-0 C26H25FN2O2S
    benzyl 5-(4-fluorophenyl)sulfanylspiro[indoline-3,4'-piperidine]-1'-carboxylate
    —— N-methyl-2-(2'-amino-4'-ethenylphenylthio)benzylamine 851974-56-6 C16H18N2S
    N-methyl-2-(2'-amino-4'-ethenylphenylthio)benzylamine
    —— 3-(4,4-difluorobut-3-enylthio)-5-propyl-1,2,4-triazine 172935-57-8 C10H13F2N3S
    3-(4,4-difluorobut-3-enylthio)-5-propyl-1,2,4-triazine
    —— (1,4-Dimethyl-cyclohex-3-enyl)-methanethiol 61860-19-3 C9H16S
    (1,4-Dimethyl-cyclohex-3-enyl)-methanethiol
    —— 1-methoxycarbonyl-4-[3-(methylthio)phenyl]-1,2,3,6-tetrahydropyridine 346688-69-5 C14H17NO2S
    1-methoxycarbonyl-4-[3-(methylthio)phenyl]-1,2,3,6-tetrahydropyridine
    —— (2-Ethoxy-propylsulfanyl)-benzene 62162-24-7 C11H16OS
    (2-Ethoxy-propylsulfanyl)-benzene
    —— 5-(2-methyl-propenylsulfanyl)-pent-1-ene 62162-14-5 C9H16S
    5-(2-methyl-propenylsulfanyl)-pent-1-ene
    —— 2H-Pyran, 2-(ethenylthio)-3,4-dihydro-4-methyl- 61645-67-8 C8H12OS
    2H-Pyran, 2-(ethenylthio)-3,4-dihydro-4-methyl-
    —— 4-(2-methyl-propenylsulfanyl)-but-1-ene 62162-06-5 C8H14S
    4-(2-methyl-propenylsulfanyl)-but-1-ene
    —— ethyl 2-(4'-ethenyl-2'-nitrophenylthio)benzoate 851974-53-3 C17H15NO4S
    ethyl 2-(4'-ethenyl-2'-nitrophenylthio)benzoate
    —— Ethyl 3-[3-amino-4-[2-(dimethylcarbamoyl)phenyl]sulfanylphenyl]propanoate 860778-54-7 C20H24N2O3S
    Ethyl 3-[3-amino-4-[2-(dimethylcarbamoyl)phenyl]sulfanylphenyl]propanoate
    —— 2-[3-Amino-4-(2-dimethylaminomethyl-phenylsulfanyl)-phenyl]-ethanol 860778-51-4 C17H22N2OS
    2-[3-Amino-4-(2-dimethylaminomethyl-phenylsulfanyl)-phenyl]-ethanol
    —— N,N-dimethyl-2-(4'-ethenyl-2'-nitrophenylthio)benzamide 851974-50-0 C17H16N2O3S
    N,N-dimethyl-2-(4'-ethenyl-2'-nitrophenylthio)benzamide
    —— 3-[3-Amino-4-(2-dimethylaminomethyl-phenylsulfanyl)-phenyl]-propan-1-ol 860778-55-8 C18H24N2OS
    3-[3-Amino-4-(2-dimethylaminomethyl-phenylsulfanyl)-phenyl]-propan-1-ol
    —— (1-Methyl-cyclohex-3-enyl)-methanethiol 61860-18-2 C8H14S
    (1-Methyl-cyclohex-3-enyl)-methanethiol
    —— 5-Ethyl-2-(2-methylaminomethyl-phenylsulfanyl)-phenylamine 851974-57-7 C16H20N2S
    5-Ethyl-2-(2-methylaminomethyl-phenylsulfanyl)-phenylamine
    —— N,N-dimethyl-2-(2'-amino-4'-ethylphenylthio)benzamide 851974-51-1 C17H20N2OS
    N,N-dimethyl-2-(2'-amino-4'-ethylphenylthio)benzamide
    —— ethyl 1-methyl-3-butenyl sulfide 62162-19-0 C7H14S
    ethyl 1-methyl-3-butenyl sulfide
    —— (Z)-thiacyclooct-4-ene 1,1-dioxide 72075-87-7 C7H12O2S
    (Z)-thiacyclooct-4-ene 1,1-dioxide
    —— 2H-Pyran, 2,2'-thiobis[3,4-dihydro- 61645-65-6 C10H14O2S
    2H-Pyran, 2,2'-thiobis[3,4-dihydro-
    —— 4-(methylthio)thiophene-2-carbaldehyde 222554-16-7 C6H6OS2
    4-(methylthio)thiophene-2-carbaldehyde
    —— selenium diethyldithiocarbamate 105618-13-1 C20H40N4S8Se
    selenium diethyldithiocarbamate
    —— Diisopropylthiocarbamoylisothiocyanat 19976-58-0 C8H14N2S2
    Diisopropylthiocarbamoylisothiocyanat
    —— methyl2,2-bis (ethylthio) propanoate 59054-68-1 C8H16O2S2
    methyl2,2-bis (ethylthio) propanoate
    —— 2-trifluoromethyl-2-chloroperfluoropentanethione-3 80436-78-8 C6ClF11S
    2-trifluoromethyl-2-chloroperfluoropentanethione-3
    —— 2-Ethyl-3-phenyl-5-methylmercapto-isoxazolium 61379-17-7 C12H14NOS*I
    2-Ethyl-3-phenyl-5-methylmercapto-isoxazolium
    —— tert-Butyl-hydroxybutylsulfoxid 62295-81-2 C8H18O2S
    tert-Butyl-hydroxybutylsulfoxid
    —— 4-Chlor-2-(thiophenoxymethyl)anilin 53165-13-2 C13H12ClNS
    4-Chlor-2-(thiophenoxymethyl)anilin
    —— Z-diethyl(1,2-bis[(1-methyl-1H-tetrazol-5-yl)sulfanyl]ethenyl)phosphonate 1451045-39-8 C10H17N8O3PS2
    Z-diethyl(1,2-bis[(1-methyl-1H-tetrazol-5-yl)sulfanyl]ethenyl)phosphonate
    —— 4-t-Butylsulfonyl-2-methylbutanol 62296-31-5 C9H20O2S
    4-t-Butylsulfonyl-2-methylbutanol
    —— 4-tert.-Butylsulfinyl-pentanol 62296-29-1 C9H20O2S
    4-tert.-Butylsulfinyl-pentanol
    —— 2-ethoxy-3-[4-(2-{[6-({2-[4-(2-ethoxy-2-methoxycarbonyl-ethyl)-phenylsulfanyl]-ethyl}-methyl-amino)-pyridin-2-yl]-methyl-amino}-ethylsulfanyl)-phenyl]-propionic acid methyl ester 719293-23-9 C35H47N3O6S2
    2-ethoxy-3-[4-(2-{[6-({2-[4-(2-ethoxy-2-methoxycarbonyl-ethyl)-phenylsulfanyl]-ethyl}-methyl-amino)-pyridin-2-yl]-methyl-amino}-ethylsulfanyl)-phenyl]-propionic acid methyl ester
    —— Imidazo[1,2-b]pyridazinium, 1-methyl-6-(methylthio)-, iodide 61582-25-0 C8H10IN3S
    Imidazo[1,2-b]pyridazinium, 1-methyl-6-(methylthio)-, iodide
    —— dimethyl 1,2-bis[(1-methyl-1H-1,2,3,4-tetrazol-5-yl)thio]ethenylphosphonate 1421754-59-7 C8H13N8O3PS2
    dimethyl 1,2-bis[(1-methyl-1H-1,2,3,4-tetrazol-5-yl)thio]ethenylphosphonate
    —— 4-t-Butylthio-3-methylbutanol 62296-22-4 C9H20OS
    4-t-Butylthio-3-methylbutanol
    —— 4-Methoxy-1-(m-tolylthio)-2-butanon 56163-59-8 C12H16O2S
    4-Methoxy-1-(m-tolylthio)-2-butanon
    —— 1,4-bis-<i>tert</i>-butylsulfanyl-but-2-yne 14272-28-7 C12H22S2
    1,4-bis-<i>tert</i>-butylsulfanyl-but-2-yne
    —— 1-ethylsulfanyl-but-2-yne 14092-22-9 C6H10S
    1-ethylsulfanyl-but-2-yne
    —— 1-(Bis(phenylthio)methyl)cycloheptanol 57768-32-8 C20H24OS2
    1-(Bis(phenylthio)methyl)cycloheptanol
    —— 3-(thieno[3,2-d]pyrimidin-4-ylthio)thieno[3,2-e][1,2,4]triazolo[4,3-c]pyrimidine 1262236-30-5 C13H6N6S3
    3-(thieno[3,2-d]pyrimidin-4-ylthio)thieno[3,2-e][1,2,4]triazolo[4,3-c]pyrimidine
    —— (1RS,2SR)-1-methyl-2-phenylthiocyclo-octanol 101704-33-0 C15H22OS
    (1RS,2SR)-1-methyl-2-phenylthiocyclo-octanol
    —— 3-(thieno[3,2-d]pyrimidin-4-ylthio)thieno[2,3-e][1,2,4]triazolo[4,3-c]pyrimidine 1262236-36-1 C13H6N6S3
    3-(thieno[3,2-d]pyrimidin-4-ylthio)thieno[2,3-e][1,2,4]triazolo[4,3-c]pyrimidine