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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— dimethyl 2,2'-[(3-nitropyridine-2,6-diyl)disulfanediyl]diacetate 259792-96-6 C11H12N2O6S2
    dimethyl 2,2'-[(3-nitropyridine-2,6-diyl)disulfanediyl]diacetate
    —— di-n-propyl 2,2'-[(3-nitropyridine-2,6-diyl)disulfanediyl]diacetate 1378234-61-7 C15H20N2O6S2
    di-n-propyl 2,2'-[(3-nitropyridine-2,6-diyl)disulfanediyl]diacetate
    —— 2-[6-(Carboxymethylsulfanyl)-5-nitropyridin-2-yl]sulfanylacetic acid 1378233-36-3 C9H8N2O6S2
    2-[6-(Carboxymethylsulfanyl)-5-nitropyridin-2-yl]sulfanylacetic acid
    —— <i>N</i>-methyl-<i>N</i>'-(1,1,3,3-tetramethyl-butyl)-thiourea 86375-16-8 C10H22N2S
    <i>N</i>-methyl-<i>N</i>'-(1,1,3,3-tetramethyl-butyl)-thiourea
    —— non-6-en-2-one-thioketal 146405-08-5 C11H20S2
    non-6-en-2-one-thioketal
    —— 3,6-dioctyl-4,5-(o-xylylenedithio)phthalonitrile 885694-89-3 C32H42N2S2
    3,6-dioctyl-4,5-(o-xylylenedithio)phthalonitrile
    —— 3,6-dibutyl-4,5-(o-xylylenedithio)phthalonitrile 885694-88-2 C24H26N2S2
    3,6-dibutyl-4,5-(o-xylylenedithio)phthalonitrile
    —— 3-(Methylsulfanyl)-5,6-bis(trifluoromethyl)-1,2,4-triazine 120943-60-4 C6H3F6N3S
    3-(Methylsulfanyl)-5,6-bis(trifluoromethyl)-1,2,4-triazine
    —— 1-[4-[Methyl(diphenyl)silyl]-4-oxobutyl]-6-phenylsulfanylpiperidin-2-one 185098-95-7 C28H31NO2SSi
    1-[4-[Methyl(diphenyl)silyl]-4-oxobutyl]-6-phenylsulfanylpiperidin-2-one
    —— 1,3-dithiolo<4,5-f><1,3,5>trithiepin-2-thione 102567-30-6 C5H4S6
    1,3-dithiolo<4,5-f><1,3,5>trithiepin-2-thione
    —— bis<thiobis(methylenethio)>tetrathiafulvalene 88682-20-6 C10H8S10
    bis<thiobis(methylenethio)>tetrathiafulvalene
    —— Acetoxyethylenedithio-1,3-dithiole-2-thione 110789-37-2 C7H6O2S5
    Acetoxyethylenedithio-1,3-dithiole-2-thione
    —— (phenyl-[1,3,4]thiadiazol-2-ylmercapto)-acetic acid ethyl ester 64145-10-4 C12H12N2O2S2
    (phenyl-[1,3,4]thiadiazol-2-ylmercapto)-acetic acid ethyl ester
    —— 3-(4-phenylethynyl-phenylsulfanyl)propionic acid 2-ethylhexyl ester 881664-11-5 C25H30O2S
    3-(4-phenylethynyl-phenylsulfanyl)propionic acid 2-ethylhexyl ester
    —— 3-(4-bromophenylsulfanyl)propionic acid 2-ethylhexyl ester 881664-08-0 C17H25BrO2S
    3-(4-bromophenylsulfanyl)propionic acid 2-ethylhexyl ester
    —— Methyl 3-[methoxy(phenylsulfanyl)methyl]tetradec-2-enoate 89171-42-6 C23H36O3S
    Methyl 3-[methoxy(phenylsulfanyl)methyl]tetradec-2-enoate
    —— 1-Methoxy-1-(phenylsulfanyl)tridecan-2-one 89171-36-8 C20H32O2S
    1-Methoxy-1-(phenylsulfanyl)tridecan-2-one
    —— 3-[Methoxy(phenylsulfanyl)methyl]tetradec-2-en-1-ol 89171-52-8 C22H36O2S
    3-[Methoxy(phenylsulfanyl)methyl]tetradec-2-en-1-ol
    —— (E)-3-(5-Methylsulfanyl-furan-2-yl)-acrylic acid 111252-38-1 C8H8O3S
    (E)-3-(5-Methylsulfanyl-furan-2-yl)-acrylic acid
    —— 1-benzyl-3-phenylsulfanyl-pyrrolidin-2-one 64330-40-1 C17H17NOS
    1-benzyl-3-phenylsulfanyl-pyrrolidin-2-one
    —— E-3,6-Dimethyl-2-(phenylthio)-hept-3-en 63996-71-4 C15H22S
    E-3,6-Dimethyl-2-(phenylthio)-hept-3-en
    —— (2R,3S,5S)-3-[tert-butyl(diphenyl)silyl]oxy-5-methyl-6-(2-methyl-1,3-dithian-2-yl)hexane-1,2-diol 218439-23-7 C28H42O3S2Si
    (2R,3S,5S)-3-[tert-butyl(diphenyl)silyl]oxy-5-methyl-6-(2-methyl-1,3-dithian-2-yl)hexane-1,2-diol
    —— (3E,5E)-2,5-dimethyl-3-(ethoxycarbonyl)-6-thiophenyl-3,5-hexadienoic acid 382150-24-5 C17H20O4S
    (3E,5E)-2,5-dimethyl-3-(ethoxycarbonyl)-6-thiophenyl-3,5-hexadienoic acid
    —— (3E,5E)-3-(ethoxycarbonyl)-5-methyl-6-thiophenyl-3,5-hexadienoic acid 382150-21-2 C16H18O4S
    (3E,5E)-3-(ethoxycarbonyl)-5-methyl-6-thiophenyl-3,5-hexadienoic acid
    —— (E,Z)-3-thiophenylpropenal 78998-83-1 C9H8OS
    (E,Z)-3-thiophenylpropenal
    —— 5-Methyl-2-methylsulfanyl-1-phenyl-pyrimidin-1-ium; iodide 64577-81-7 C12H13N2S*I
    5-Methyl-2-methylsulfanyl-1-phenyl-pyrimidin-1-ium; iodide
    —— 3,6-Dimethyl-3-(phenylthio)-heptan-2-ol 63996-45-2 C15H24OS
    3,6-Dimethyl-3-(phenylthio)-heptan-2-ol
    —— Methyl 2-[(4-oxo-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d][1,3]oxazin-2-yl)sulfanyl]acetate 207744-05-6 C13H13NO4S2
    Methyl 2-[(4-oxo-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d][1,3]oxazin-2-yl)sulfanyl]acetate
    —— benzo[<i>b</i>]pyrido[2,3-<i>e</i>][1,4]thiazine-10-carboxylic acid 2-diisopropylamino-ethyl ester 100150-48-9 C20H25N3O2S
    benzo[<i>b</i>]pyrido[2,3-<i>e</i>][1,4]thiazine-10-carboxylic acid 2-diisopropylamino-ethyl ester
    —— 2-Methylsulfanyl-5,6,7,8-tetrahydro-benzo[4,5]thieno[2,3-d][1,3]oxazin-4-one 207744-02-3 C11H11NO2S2
    2-Methylsulfanyl-5,6,7,8-tetrahydro-benzo[4,5]thieno[2,3-d][1,3]oxazin-4-one
    —— 2-methyl-6-(phenylsulfonyl)-3-(phenylthio)pyridin-4-ol 1103494-83-2 C18H15NO3S2
    2-methyl-6-(phenylsulfonyl)-3-(phenylthio)pyridin-4-ol
    —— 2-methyl-6-(phenylsulfonyl)-3-(m-tolylthio)pyridin-4-ol 1103494-86-5 C19H17NO3S2
    2-methyl-6-(phenylsulfonyl)-3-(m-tolylthio)pyridin-4-ol
    —— 2-methoxy-6-(phenylsulfonyl)-3-(phenylthio)pyridin-4-ol 1103494-84-3 C18H15NO4S2
    2-methoxy-6-(phenylsulfonyl)-3-(phenylthio)pyridin-4-ol
    —— 2-Ethylsulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d][1,3]oxazin-4-one 207744-03-4 C12H13NO2S2
    2-Ethylsulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d][1,3]oxazin-4-one
    —— 3-phenylsulfanyl-1H-pyrrolo[3,2-b]pyridine-2-carboxylic acid amide 853685-37-7 C14H11N3OS
    3-phenylsulfanyl-1H-pyrrolo[3,2-b]pyridine-2-carboxylic acid amide
    —— 2-Benzylsulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d][1,3]oxazin-4-one 207744-04-5 C17H15NO2S2
    2-Benzylsulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d][1,3]oxazin-4-one
    —— 2-[(phenylsulfanyl)methyl]pentanal 808137-54-4 C12H16OS
    2-[(phenylsulfanyl)methyl]pentanal
    —— 2-[(phenylsulfanyl)methyl]decanal 808137-55-5 C17H26OS
    2-[(phenylsulfanyl)methyl]decanal
    —— 3-(3-fluorophenyl)sulfanyl-1H-pyrrolo[3,2-b]pyridine-2-carboxylic acid amide 853685-38-8 C14H10FN3OS
    3-(3-fluorophenyl)sulfanyl-1H-pyrrolo[3,2-b]pyridine-2-carboxylic acid amide
    —— 2-amino-7-chloro-3<i>H</i>,10<i>H</i>-pyrido[2,3-<i>b</i>]pyrimido[4,5-<i>e</i>][1,4]thiazin-4-one 63931-15-7 C9H6ClN5OS
    2-amino-7-chloro-3<i>H</i>,10<i>H</i>-pyrido[2,3-<i>b</i>]pyrimido[4,5-<i>e</i>][1,4]thiazin-4-one
    —— Bis(2,2,2-trinitroethyl) thionocarbonate 80445-02-9 C5H4N6O14S
    Bis(2,2,2-trinitroethyl) thionocarbonate
    —— 1-(6-Methyl-3,4-dihydro-2H-pyran-3-yl)-ethanethione 65818-68-0 C8H12OS
    1-(6-Methyl-3,4-dihydro-2H-pyran-3-yl)-ethanethione
    —— 2-((1-((triethylsilyl)oxy)oct-1-en-1-yl)thio)pyridine 863783-28-2 C19H33NOSSi
    2-((1-((triethylsilyl)oxy)oct-1-en-1-yl)thio)pyridine
    —— 6-Methylthio-1,2,4,5-tetrazin-3-essigsaeure 64499-99-6 C5H6N4O2S
    6-Methylthio-1,2,4,5-tetrazin-3-essigsaeure
    —— 4,6-dichloro-2-[(3-chloro-2-fluorobenzyl)thio]pyrimidine 654073-10-6 C11H6Cl3FN2S
    4,6-dichloro-2-[(3-chloro-2-fluorobenzyl)thio]pyrimidine
    —— 3,3-Spirobi(benzo<1.5>dithiepan) 64958-42-5 C17H16S4
    3,3-Spirobi(benzo<1.5>dithiepan)
    —— 2-(4-chloro-3-methoxyphenylthio)benzyl chloride 61150-51-4 C14H12Cl2OS
    2-(4-chloro-3-methoxyphenylthio)benzyl chloride
    —— 2-(4-chloro-3-methoxyphenylthio)phenylacetonitrile 61150-52-5 C15H12ClNOS
    2-(4-chloro-3-methoxyphenylthio)phenylacetonitrile
    —— 5-((4-bromophenyl)sulfanyl)-3-methyl-2-pyridinamine 1450622-40-8 C12H11BrN2S
    5-((4-bromophenyl)sulfanyl)-3-methyl-2-pyridinamine
    —— 1-Mercapto-1-cyclopropyl-ethan 98137-18-9 C5H10S
    1-Mercapto-1-cyclopropyl-ethan