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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Oxo-3-(phenylsulfanyl)propyl pivalate 115413-23-5 C14H18O3S
    2-Oxo-3-(phenylsulfanyl)propyl pivalate
    —— 3-(benzothiazol-2'-ylthio)-6-imino-1-(p-methoxylphenyl)-4-methyl-1,6-dihydropyridazine-5-carbonitrile 1306604-99-8 C20H15N5OS2
    3-(benzothiazol-2'-ylthio)-6-imino-1-(p-methoxylphenyl)-4-methyl-1,6-dihydropyridazine-5-carbonitrile
    —— 4-cyclohexylmethylsulfanyl-phenylamine 76253-35-5 C13H19NS
    4-cyclohexylmethylsulfanyl-phenylamine
    —— 5-amino-1-(benzothiazol-2'-ylthio)-4-imino-3-(p-methoxyphenyl)-7-phenyl-3,4-dihydrophthalazine-6,6(7H)-dicarbonitrile hydrochloride 1306605-03-7 C30H21N7OS2*ClH
    5-amino-1-(benzothiazol-2'-ylthio)-4-imino-3-(p-methoxyphenyl)-7-phenyl-3,4-dihydrophthalazine-6,6(7H)-dicarbonitrile hydrochloride
    —— 3-(benzothiazol-2'-ylthio)-6-imino-4-methyl-1-(p-nitrophenyl)-1,6-dihydropyridazine-6-carbonitrile 1306830-98-7 C19H12N6O2S2
    3-(benzothiazol-2'-ylthio)-6-imino-4-methyl-1-(p-nitrophenyl)-1,6-dihydropyridazine-6-carbonitrile
    —— 3-(benzothiazol-2'-ylthio)-4-methyl-1-(p-methylphenyl)-6-oxo-1,6-dihydropyridazine-5-carbonitrile hydrochloride 1306604-98-7 C20H14N4OS2*ClH
    3-(benzothiazol-2'-ylthio)-4-methyl-1-(p-methylphenyl)-6-oxo-1,6-dihydropyridazine-5-carbonitrile hydrochloride
    —— 3-(benzothiazol-2'-ylthio)-4-methyl-6-oxo-1-phenyl-1,6-dihydropyridazine-5-carbonitrile 1306604-96-5 C19H12N4OS2
    3-(benzothiazol-2'-ylthio)-4-methyl-6-oxo-1-phenyl-1,6-dihydropyridazine-5-carbonitrile
    —— 5-benzamido-3-(benzothiazol-2'-ylthio)-1-(p-methoxyphenyl)-4-methyl-6-oxo-1,6-dihydropyridazine hydrochloride 1306605-06-0 C26H20N4O3S2*ClH
    5-benzamido-3-(benzothiazol-2'-ylthio)-1-(p-methoxyphenyl)-4-methyl-6-oxo-1,6-dihydropyridazine hydrochloride
    —— 3-(benzothiazol-2'-ylthio)-4-methyl-1-(p-methylphenyl)-6-oxo-1,6-dihydropyridazine-5-carbonitrile 1306830-97-6 C20H14N4OS2
    3-(benzothiazol-2'-ylthio)-4-methyl-1-(p-methylphenyl)-6-oxo-1,6-dihydropyridazine-5-carbonitrile
    —— 5-benzamido-3-(benzothiazol-2'-ylthio)-4-methyl-1-(p-nitrophenyl)-3-oxo-1,6-dihydropyridazine hydrochloride 1306605-08-2 C25H17N5O4S2*ClH
    5-benzamido-3-(benzothiazol-2'-ylthio)-4-methyl-1-(p-nitrophenyl)-3-oxo-1,6-dihydropyridazine hydrochloride
    —— 1,5-Bis(phenylthio)-3-pentanone 119352-90-8 C17H18OS2
    1,5-Bis(phenylthio)-3-pentanone
    —— 4-(2-methyl-allylsulfanyl)-phenylamine 27955-23-3 C10H13NS
    4-(2-methyl-allylsulfanyl)-phenylamine
    —— 5-benzamido-3-(benzothiazol-2'-ylthio)-4-methyl-6-oxo-1-phenyl-1,6-dihydropyridazine 1306831-00-4 C25H18N4O2S2
    5-benzamido-3-(benzothiazol-2'-ylthio)-4-methyl-6-oxo-1-phenyl-1,6-dihydropyridazine
    —— trans-2-Chlor-4-phenylmercapto-buten-(2) 51637-56-0 C10H11ClS
    trans-2-Chlor-4-phenylmercapto-buten-(2)
    —— 3,6-bis-phenylthiopyridine-2-carboxylic acid 85330-73-0 C18H13NO2S2
    3,6-bis-phenylthiopyridine-2-carboxylic acid
    —— 4-Cyano-3-phenylthiobenzenamine 147696-60-4 C13H10N2S
    4-Cyano-3-phenylthiobenzenamine
    —— [(difluorophenylmethyl)sulfanyl]benzene 22235-32-1 C13H10F2S
    [(difluorophenylmethyl)sulfanyl]benzene
    —— 3-fluoro-4-(phenylthio)nitrobenzene 147696-80-8 C12H8FNO2S
    3-fluoro-4-(phenylthio)nitrobenzene
    —— 2-bromo-3-chloro-propane-1-thiol 5521-81-3 C3H6BrClS
    2-bromo-3-chloro-propane-1-thiol
    —— 1,2,μ-trithio-dicarbonic acid dimethylamide-methylamide 25691-01-4 C5H10N2S3
    1,2,μ-trithio-dicarbonic acid dimethylamide-methylamide
    —— 2,3,5,6-tetrachloro-4-trifluoromethylthiopyridine 129626-65-9 C6Cl4F3NS
    2,3,5,6-tetrachloro-4-trifluoromethylthiopyridine
    —— bis-methanesulfonylmercapto-selane 60411-22-5 C2H6O4S4Se
    bis-methanesulfonylmercapto-selane
    —— 1,4-Bis(chloromethyl)-2-phenylsulfanylbenzene 67666-85-7 C14H12Cl2S
    1,4-Bis(chloromethyl)-2-phenylsulfanylbenzene
    —— 1,μ-dithio-dicarbonic acid-1-dimethylamide-2-isopropyl ester 31676-30-9 C7H13NO2S2
    1,μ-dithio-dicarbonic acid-1-dimethylamide-2-isopropyl ester
    —— 1,μ-dithio-dicarbonic acid-2-ethyl ester-1-dimethylamide 54796-84-8 C6H11NO2S2
    1,μ-dithio-dicarbonic acid-2-ethyl ester-1-dimethylamide
    —— 5-(N,N-dimethylthiocarbamoylthio)-6-chloro-7-cyano-1,3-dithiolo<4,5-b>pyridin-2-one 130825-58-0 C10H6ClN3OS4
    5-(N,N-dimethylthiocarbamoylthio)-6-chloro-7-cyano-1,3-dithiolo<4,5-b>pyridin-2-one
    —— methyl N-(dimethylcarbamothioylsulfanyl)carbamate 138906-01-1 C5H10N2O2S2
    methyl N-(dimethylcarbamothioylsulfanyl)carbamate
    —— 3-methylthio-5-(3-fluorophenyl)-1,2,4-thiadiazole 476315-97-6 C9H7FN2S2
    3-methylthio-5-(3-fluorophenyl)-1,2,4-thiadiazole
    —— 6-dimethylamino-3,5-dinitropyridyl-2-dimethyldithiocarbamate 81587-59-9 C10H13N5O4S2
    6-dimethylamino-3,5-dinitropyridyl-2-dimethyldithiocarbamate
    —— 3,5-dinitropyridyl-2-dimethyldithiocarbamate 81587-47-5 C8H8N4O4S2
    3,5-dinitropyridyl-2-dimethyldithiocarbamate
    —— Carbamodithioic acid, dimethyl-, 3,5-dichloro-6-cyano-2-pyridinyl ester 159324-91-1 C9H7Cl2N3S2
    Carbamodithioic acid, dimethyl-, 3,5-dichloro-6-cyano-2-pyridinyl ester
    —— 5-[[(1-Methyl-1H-pyrazol-4-yl)methyl]thio]-1,3,4-thiadiazol-2-amine 1152605-24-7 C7H9N5S2
    5-[[(1-Methyl-1H-pyrazol-4-yl)methyl]thio]-1,3,4-thiadiazol-2-amine
    —— 2,3-dimethyl-but-2-ene-1-thiol 50369-32-9 C6H12S
    2,3-dimethyl-but-2-ene-1-thiol
    —— <2-Methylamino-ethyl>-vinyl-sulfid 108723-44-0 C5H11NS
    <2-Methylamino-ethyl>-vinyl-sulfid
    —— N-(4-chlorophenylmethylene)-2-phenylthiobenzenamine 142505-33-7 C19H14ClNS
    N-(4-chlorophenylmethylene)-2-phenylthiobenzenamine
    —— (+)-(1S,2S)-2-(2-aminophenylsulfanyl)cyclohexylamine 1351099-55-2 C12H18N2S
    (+)-(1S,2S)-2-(2-aminophenylsulfanyl)cyclohexylamine
    —— 1-(2-aminophenylthio)octan-2-ol 98793-13-6 C14H23NOS
    1-(2-aminophenylthio)octan-2-ol
    —— 8-Acetylamino-3H-pyridazino-benzothiazin-4(10H)-on 68434-24-2 C12H10N4O2S
    8-Acetylamino-3H-pyridazino-benzothiazin-4(10H)-on
    —— 5-[(1,2,4-Oxadiazol-3-ylmethyl)thio]-2-thiazolamine 1042778-07-3 C6H6N4OS2
    5-[(1,2,4-Oxadiazol-3-ylmethyl)thio]-2-thiazolamine
    —— 2-(2-(p-tolylthio)phenyl)benzo[d]thiazole 1235453-36-7 C20H15NS2
    2-(2-(p-tolylthio)phenyl)benzo[d]thiazole
    —— methyl 3-(2-aminophenylthio)propanoate 91012-42-9 C10H13NO2S
    methyl 3-(2-aminophenylthio)propanoate
    —— 4-methylthio-5-acetyl-1,6-dimethyl-1H-pyrimidin-2-one 864174-96-9 C9H12N2O2S
    4-methylthio-5-acetyl-1,6-dimethyl-1H-pyrimidin-2-one
    —— 2H,4H-1,3,4-benzodithiazine-3,3-dioxide 143184-95-6 C7H7NO2S2
    2H,4H-1,3,4-benzodithiazine-3,3-dioxide
    —— gwx-927 1174708-88-3 C14H14ClNOS
    gwx-927
    —— 1-cyano-2-methyl-3-propargylisothiourea 69591-59-9 C6H7N3S
    1-cyano-2-methyl-3-propargylisothiourea
    —— (3,4,5-trifluorophenyl)-2-aminophenylsulfide 1229514-43-5 C12H8F3NS
    (3,4,5-trifluorophenyl)-2-aminophenylsulfide
    —— 5-((6-chloro-3-pyridinyl)sulfanyl)-2-pyridinamine 1450622-58-8 C10H8ClN3S
    5-((6-chloro-3-pyridinyl)sulfanyl)-2-pyridinamine
    —— tert-butyl ({5-[(6-chloropyridin-3-yl)thio]-4-(2-fluoropyridin-3-yl)-1,3-thiazol-2-yl}methyl)methylcarbamate 1138035-63-8 C20H20ClFN4O2S2
    tert-butyl ({5-[(6-chloropyridin-3-yl)thio]-4-(2-fluoropyridin-3-yl)-1,3-thiazol-2-yl}methyl)methylcarbamate
    —— 5-((4-bromophenyl)sulfanyl)-2-chloropyridine 1361221-42-2 C11H7BrClNS
    5-((4-bromophenyl)sulfanyl)-2-chloropyridine
    —— 4-methylthio-5-acetyl-1-ethyl-6-methyl-1H-pyrimidin-2-one 140118-70-3 C10H14N2O2S
    4-methylthio-5-acetyl-1-ethyl-6-methyl-1H-pyrimidin-2-one