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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-(butan-2-yl)-2-{[3-cyano-4-(methoxymethyl)-6-methylpyridin-2-yl]sulfanyl}acetamide —— C15H21N3O2S
    N-(butan-2-yl)-2-{[3-cyano-4-(methoxymethyl)-6-methylpyridin-2-yl]sulfanyl}acetamide
    —— 2-[(4-fluorophenyl)methylsulfanyl]-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione —— C12H8FN3O2S2
    2-[(4-fluorophenyl)methylsulfanyl]-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione
    —— 2-[(2-methylphenyl)methylsulfanyl]-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione —— C13H11N3O2S2
    2-[(2-methylphenyl)methylsulfanyl]-4H-[1,3]thiazolo[4,5-d]pyrimidine-5,7-dione
    —— N-cyclohexyl-2-{[5-(furan-2-yl)-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C17H24N4O2S
    N-cyclohexyl-2-{[5-(furan-2-yl)-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— 2-((4-Allyl-5-propyl-4H-1,2,4-triazol-3-yl)thio)acetic acid —— C10H15N3O2S
    2-((4-Allyl-5-propyl-4H-1,2,4-triazol-3-yl)thio)acetic acid
    —— 4-ethyl-2-propylsulfanyl-1H-pyrimidin-6-one —— C9H14N2OS
    4-ethyl-2-propylsulfanyl-1H-pyrimidin-6-one
    —— 2-[(3S)-7-(methoxymethyl)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid —— C10H12N2O4S
    2-[(3S)-7-(methoxymethyl)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid
    —— 5-Butoxy-2-(2,4-dinitro-phenylsulfanyl)-1H-benzoimidazole —— C17H16N4O5S
    5-Butoxy-2-(2,4-dinitro-phenylsulfanyl)-1H-benzoimidazole
    —— 2-[(3R)-7-(furan-2-yl)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid —— C12H10N2O4S
    2-[(3R)-7-(furan-2-yl)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid
    —— 2-[(3S)-5-oxo-7-thiophen-2-yl-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid —— C12H10N2O3S2
    2-[(3S)-5-oxo-7-thiophen-2-yl-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid
    —— 2-[(3S)-7-(furan-2-yl)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid —— C12H10N2O4S
    2-[(3S)-7-(furan-2-yl)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid
    —— 2-[(3R)-7-(methoxymethyl)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid —— C10H12N2O4S
    2-[(3R)-7-(methoxymethyl)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid
    —— 2-[(3R)-5-oxo-7-thiophen-2-yl-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid —— C12H10N2O3S2
    2-[(3R)-5-oxo-7-thiophen-2-yl-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetic acid
    —— 2-(Difluoro(p-tolylthio)methyl)-5-methyl-1,3,4-oxadiazole —— C11H10F2N2OS
    2-(Difluoro(p-tolylthio)methyl)-5-methyl-1,3,4-oxadiazole
    —— 2-(Difluoro-phenylsulfanyl-methyl)-[1,3,4]oxadiazole —— C9H6F2N2OS
    2-(Difluoro-phenylsulfanyl-methyl)-[1,3,4]oxadiazole
    —— 2-(Difluoro-phenylsulfanyl-methyl)-5-methyl-[1,3,4]oxadiazole —— C10H8F2N2OS
    2-(Difluoro-phenylsulfanyl-methyl)-5-methyl-[1,3,4]oxadiazole
    —— 2-(Difluoro-p-tolylsulfanyl-methyl)-[1,3,4]oxadiazole —— C10H8F2N2OS
    2-(Difluoro-p-tolylsulfanyl-methyl)-[1,3,4]oxadiazole
    —— 2-(((4-Chlorophenyl)thio)difluoromethyl)-1,3,4-oxadiazole —— C9H5ClF2N2OS
    2-(((4-Chlorophenyl)thio)difluoromethyl)-1,3,4-oxadiazole
    —— 2-(((4-Chlorophenyl)thio)difluoromethyl)-5-methyl-1,3,4-oxadiazole —— C10H7ClF2N2OS
    2-(((4-Chlorophenyl)thio)difluoromethyl)-5-methyl-1,3,4-oxadiazole
    —— {[3-(Methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}acetonitrile —— C5H5N3S3
    {[3-(Methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}acetonitrile
    —— 4-(Methoxymethyl)-6-methyl-2-[(5-nitropyridin-2-yl)sulfanyl]pyridine-3-carbonitrile —— C14H12N4O3S
    4-(Methoxymethyl)-6-methyl-2-[(5-nitropyridin-2-yl)sulfanyl]pyridine-3-carbonitrile
    —— 5-(2-Methoxy-ethyl)-2-methylsulfanyl-pyrimidin-4-ol —— C8H12N2O2S
    5-(2-Methoxy-ethyl)-2-methylsulfanyl-pyrimidin-4-ol
    —— 2-{[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-YL]sulfanyl}-5-nitropyridine —— C13H7ClN4O3S
    2-{[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-YL]sulfanyl}-5-nitropyridine
    —— 2-{[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}-3-nitropyridine —— C13H7ClN4O3S
    2-{[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}-3-nitropyridine
    —— 4-({4-methyl-5-[(5-nitropyridin-2-yl)sulfanyl]-4H-1,2,4-triazol-3-yl}methyl)morpholine —— C13H16N6O3S
    4-({4-methyl-5-[(5-nitropyridin-2-yl)sulfanyl]-4H-1,2,4-triazol-3-yl}methyl)morpholine
    —— 2-((4-isopropyl-6-oxo-1,6-dihydropyrimidin-2-yl)thio)propanoic acid —— C10H14N2O3S
    2-((4-isopropyl-6-oxo-1,6-dihydropyrimidin-2-yl)thio)propanoic acid
    —— Methyl 4-bromo-5-(phenylthio)furan-2-carboxylate —— C12H9BrO3S
    Methyl 4-bromo-5-(phenylthio)furan-2-carboxylate
    —— 4-Bromo-5-phenylsulfanyl-furan-2-carboxylic acid —— C11H7BrO3S
    4-Bromo-5-phenylsulfanyl-furan-2-carboxylic acid
    —— 5-Phenylmercaptomethyl-furfural 3260-99-9 C12H10O2S
    5-Phenylmercaptomethyl-furfural
    —— 1-(5-Bromothiophen-2-yl)-2-[(5,6-dipyridin-2-yl-1,2,4-triazin-3-yl)sulfanyl]ethanone —— C19H12BrN5OS2
    1-(5-Bromothiophen-2-yl)-2-[(5,6-dipyridin-2-yl-1,2,4-triazin-3-yl)sulfanyl]ethanone
    —— N-Cyclohexyl-2-(6-methyl-5-oxo-4,5-dihydro-[1,2,4]triazin-3-ylsulfanyl)-propionamide —— C13H20N4O2S
    N-Cyclohexyl-2-(6-methyl-5-oxo-4,5-dihydro-[1,2,4]triazin-3-ylsulfanyl)-propionamide
    —— 5-(Pyridin-2-ylsulfanylmethyl)-furan-2-carbaldehyde 685904-13-6 C11H9NO2S
    5-(Pyridin-2-ylsulfanylmethyl)-furan-2-carbaldehyde
    —— N-[2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]oxolane-2-carboxamide —— C17H22N4O2S
    N-[2-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]oxolane-2-carboxamide
    —— 2-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-(4-methylpiperazin-1-yl)ethanone —— C16H20N4O2S
    2-[(5-Benzyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-(4-methylpiperazin-1-yl)ethanone
    —— 3-[4-Ethyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]-1-methylsulfonylpiperidine —— C16H29N5O2S2
    3-[4-Ethyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]-1-methylsulfonylpiperidine
    —— 1-Benzyl-3-[(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]urea —— C14H19N5OS
    1-Benzyl-3-[(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]urea
    —— 1-Cyclohexyl-3-[2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]urea —— C14H25N5OS
    1-Cyclohexyl-3-[2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]urea
    —— 3-[1-(Furan-2-ylmethyl)pyrrolidin-2-yl]-4-methyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazole —— C18H27N5OS
    3-[1-(Furan-2-ylmethyl)pyrrolidin-2-yl]-4-methyl-5-(2-pyrrolidin-1-ylethylsulfanyl)-1,2,4-triazole
    —— N-[2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]-4-methylcyclohexan-1-amine —— C14H26N4S
    N-[2-(5-ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)ethyl]-4-methylcyclohexan-1-amine
    —— [2-(5-Ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-(4-methoxycyclohexyl)methanone —— C17H28N4O2S
    [2-(5-Ethylsulfanyl-4-methyl-1,2,4-triazol-3-yl)pyrrolidin-1-yl]-(4-methoxycyclohexyl)methanone
    —— 1-Cyclohexyl-3-[2-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethyl]urea —— C14H25N5OS
    1-Cyclohexyl-3-[2-(4-ethyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethyl]urea
    —— 3-[[3-(5-Ethylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)piperidin-1-yl]methyl]pyridine —— C18H27N5S
    3-[[3-(5-Ethylsulfanyl-4-propan-2-yl-1,2,4-triazol-3-yl)piperidin-1-yl]methyl]pyridine
    —— 1-Benzyl-3-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]urea —— C13H17N5OS
    1-Benzyl-3-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]urea
    —— 1-(Isothiocyanatomethyl)-3-methylcyclobutane —— C7H11NS
    1-(Isothiocyanatomethyl)-3-methylcyclobutane
    —— N-cycloheptyl-2-[[5-(5-methyl-1,2-oxazol-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C15H20N4O3S
    N-cycloheptyl-2-[[5-(5-methyl-1,2-oxazol-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (3-Methylcyclobutyl)methylthiourea —— C7H14N2S
    (3-Methylcyclobutyl)methylthiourea
    —— 1-(Methoxymethyl)cyclobutane-1-carbothioamide —— C7H13NOS
    1-(Methoxymethyl)cyclobutane-1-carbothioamide
    —— 1-Phenylsulfanylmethyl-cyclobutanecarboxylic acid —— C12H14O2S
    1-Phenylsulfanylmethyl-cyclobutanecarboxylic acid
    —— 2-Isobutylsulfanyl-pyrimidine-5-carbaldehyde —— C9H12N2OS
    2-Isobutylsulfanyl-pyrimidine-5-carbaldehyde
    —— 1-(Phenylsulfanylmethyl)cyclobutane-1-carbonitrile —— C12H13NS
    1-(Phenylsulfanylmethyl)cyclobutane-1-carbonitrile