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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1,2,3,5,6-Pentathiepane, 4,7-dimethyl, #1 —— C4H8S5
    1,2,3,5,6-Pentathiepane, 4,7-dimethyl, #1
    —— Phenyl thiolcarbamic acid, 5-anilino-1,3,4-thia-diazol-2-yl ester —— C15H12N4OS2
    Phenyl thiolcarbamic acid, 5-anilino-1,3,4-thia-diazol-2-yl ester
    —— 4,7,13,16-Tetraoxa-1,10-dithia-cyclooctadecan-disulfon 108846-58-8 C12H24O8S2
    4,7,13,16-Tetraoxa-1,10-dithia-cyclooctadecan-disulfon
    —— 1,2,3,5,6-Pentathiepane, 4,7-dimethyl, #2 —— C4H8S5
    1,2,3,5,6-Pentathiepane, 4,7-dimethyl, #2
    —— 1-cyclopropyl-1-[(2S,3R)-3-methylpentan-2-yl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea —— C17H32N2O3S
    1-cyclopropyl-1-[(2S,3R)-3-methylpentan-2-yl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea
    —— 1,2,4,7,9,10-Hexathiacyclododecane —— C7H14S5
    1,2,4,7,9,10-Hexathiacyclododecane
    —— 1-[4-[(3R)-2,3-dihydro-1-benzothiophene-3-carbonyl]piperazin-1-yl]ethanone —— C15H18N2O2S
    1-[4-[(3R)-2,3-dihydro-1-benzothiophene-3-carbonyl]piperazin-1-yl]ethanone
    —— 1-cyclopropyl-1-[(2R,3S)-3-methylpentan-2-yl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea —— C17H32N2O3S
    1-cyclopropyl-1-[(2R,3S)-3-methylpentan-2-yl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea
    —— 4-(Hydroxymethyl)-1,2-dithiepane —— C6H12OS2
    4-(Hydroxymethyl)-1,2-dithiepane
    —— Propyl hydrodisulfide —— C3H8S2
    Propyl hydrodisulfide
    —— 6-Ethyl-4,5,7,8-tetrathiaundecane —— C9H20S4
    6-Ethyl-4,5,7,8-tetrathiaundecane
    —— (7E)-4-thiophen-2-yl-7-(thiophen-2-ylmethylidene)-2-[(3R)-3,5,5-trimethylheptyl]sulfanyl-5,6-dihydrocyclopenta[b]pyridine-3-carbonitrile —— C28H32N2S3
    (7E)-4-thiophen-2-yl-7-(thiophen-2-ylmethylidene)-2-[(3R)-3,5,5-trimethylheptyl]sulfanyl-5,6-dihydrocyclopenta[b]pyridine-3-carbonitrile
    —— 1-cyclopropyl-1-[(2R,3R)-3-methylpentan-2-yl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea —— C17H32N2O3S
    1-cyclopropyl-1-[(2R,3R)-3-methylpentan-2-yl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea
    —— Isoxazole, 5-bromomethyl-3-(5-ethylsulfanylthiophen-2-yl)-4,5-dihydro- —— C10H12BrNOS2
    Isoxazole, 5-bromomethyl-3-(5-ethylsulfanylthiophen-2-yl)-4,5-dihydro-
    —— Carbamodithioic acid, diethyl-, 3,5-dichloro-2-(trichloromethyl)-4-pyridinyl ester —— C11H11Cl5N2S2
    Carbamodithioic acid, diethyl-, 3,5-dichloro-2-(trichloromethyl)-4-pyridinyl ester
    —— (7E)-4-thiophen-2-yl-7-(thiophen-2-ylmethylidene)-2-[(3S)-3,5,5-trimethylheptyl]sulfanyl-5,6-dihydrocyclopenta[b]pyridine-3-carbonitrile —— C28H32N2S3
    (7E)-4-thiophen-2-yl-7-(thiophen-2-ylmethylidene)-2-[(3S)-3,5,5-trimethylheptyl]sulfanyl-5,6-dihydrocyclopenta[b]pyridine-3-carbonitrile
    —— (2,6-Dimethyl-4-morpholine)carbodithioic acid, 2,3,5,6-tetrachloro-4-pyridinyl ester —— C12H12Cl4N2OS2
    (2,6-Dimethyl-4-morpholine)carbodithioic acid, 2,3,5,6-tetrachloro-4-pyridinyl ester
    —— 1-cyclopropyl-1-[(2S,3S)-3-methylpentan-2-yl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea —— C17H32N2O3S
    1-cyclopropyl-1-[(2S,3S)-3-methylpentan-2-yl]-3-[(1R,3S)-3-methylsulfonylcyclohexyl]urea
    —— 1-[4-[(3S)-2,3-dihydro-1-benzothiophene-3-carbonyl]piperazin-1-yl]ethanone —— C15H18N2O2S
    1-[4-[(3S)-2,3-dihydro-1-benzothiophene-3-carbonyl]piperazin-1-yl]ethanone
    —— 1-Pyrrolidindithiocarboxylic acid, 2,3,5,6-tetrachloropyrid-4-yl ester —— C10H8Cl4N2S2
    1-Pyrrolidindithiocarboxylic acid, 2,3,5,6-tetrachloropyrid-4-yl ester
    —— N-[(3R)-1-[(2S)-4-phenylsulfanylbutan-2-yl]piperidin-3-yl]propanamide —— C18H28N2OS
    N-[(3R)-1-[(2S)-4-phenylsulfanylbutan-2-yl]piperidin-3-yl]propanamide
    —— N-[(3S)-1-[(2S)-4-phenylsulfanylbutan-2-yl]piperidin-3-yl]propanamide —— C18H28N2OS
    N-[(3S)-1-[(2S)-4-phenylsulfanylbutan-2-yl]piperidin-3-yl]propanamide
    —— Dithiocarbonic acid, o-ethyl ester S-(3,3,4,4,5,5,6,6-octafluoro-1-pentyl-hexyl) ester —— C14H20F8OS2
    Dithiocarbonic acid, o-ethyl ester S-(3,3,4,4,5,5,6,6-octafluoro-1-pentyl-hexyl) ester
    —— Acetamide, N-benzyl-2-(3-cyano-4,5,6-trimethylpyridin-2-ylsulfanyl)-N-ethyl- —— C20H23N3OS
    Acetamide, N-benzyl-2-(3-cyano-4,5,6-trimethylpyridin-2-ylsulfanyl)-N-ethyl-
    —— (2R,6R)-4-[[(2S)-1-[3-(2-chlorophenyl)sulfanylpropyl]pyrrolidin-2-yl]methyl]-2,6-dimethylmorpholine —— C20H31ClN2OS
    (2R,6R)-4-[[(2S)-1-[3-(2-chlorophenyl)sulfanylpropyl]pyrrolidin-2-yl]methyl]-2,6-dimethylmorpholine
    —— (2S,6R)-4-[[(2S)-1-[3-(2-chlorophenyl)sulfanylpropyl]pyrrolidin-2-yl]methyl]-2,6-dimethylmorpholine —— C20H31ClN2OS
    (2S,6R)-4-[[(2S)-1-[3-(2-chlorophenyl)sulfanylpropyl]pyrrolidin-2-yl]methyl]-2,6-dimethylmorpholine
    —— (2S,6S)-4-[[(2S)-1-[3-(2-chlorophenyl)sulfanylpropyl]pyrrolidin-2-yl]methyl]-2,6-dimethylmorpholine —— C20H31ClN2OS
    (2S,6S)-4-[[(2S)-1-[3-(2-chlorophenyl)sulfanylpropyl]pyrrolidin-2-yl]methyl]-2,6-dimethylmorpholine
    —— 2-[[5,6-bis(4-fluorophenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-cyclopentylacetamide —— C22H20F2N4OS
    2-[[5,6-bis(4-fluorophenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-cyclopentylacetamide
    —— N-(1,1-dioxothiolan-3-yl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(2-methylpropyl)acetamide —— C25H28N4O3S2
    N-(1,1-dioxothiolan-3-yl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(2-methylpropyl)acetamide
    —— N-[2-(Cyclohex-1-EN-1-YL)ethyl]-2-[(5,6-diethyl-1,2,4-triazin-3-YL)sulfanyl]acetamide —— C17H26N4OS
    N-[2-(Cyclohex-1-EN-1-YL)ethyl]-2-[(5,6-diethyl-1,2,4-triazin-3-YL)sulfanyl]acetamide
    —— 3-(Pentylsulfanyl)[1,2,4]triazino[5,6-D][3,1]benzoxazepine —— C15H16N4OS
    3-(Pentylsulfanyl)[1,2,4]triazino[5,6-D][3,1]benzoxazepine
    —— N-(2-(3-(allylsulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)-4-chloroaniline —— C15H15ClN4S
    N-(2-(3-(allylsulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)-4-chloroaniline
    —— N-[(E)-2-[[3-[(3-chlorophenyl)methylsulfanyl]-1H-1,2,4-triazol-5-yl]amino]-2-nitroso-1-phenylethenyl]hydroxylamine —— C17H15ClN6O2S
    N-[(E)-2-[[3-[(3-chlorophenyl)methylsulfanyl]-1H-1,2,4-triazol-5-yl]amino]-2-nitroso-1-phenylethenyl]hydroxylamine
    —— 2-Methyl-5-[6-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]pyridazin-3-yl]sulfanyl-1,3,4-thiadiazole —— C10H8N6S4
    2-Methyl-5-[6-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]pyridazin-3-yl]sulfanyl-1,3,4-thiadiazole
    —— 2-{[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-butylbutanamide —— C25H30N4OS
    2-{[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-butylbutanamide
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-pentan-3-ylacetamide —— C24H28N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-pentan-3-ylacetamide
    —— 2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]propanamide —— C20H20N4OS
    2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]propanamide
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(furan-2-ylmethyl)acetamide —— C24H22N4O2S
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(furan-2-ylmethyl)acetamide
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(2-phenylpropyl)acetamide —— C26H24N4OS
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(2-phenylpropyl)acetamide
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(3-methylbutan-2-yl)acetamide —— C24H28N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(3-methylbutan-2-yl)acetamide
    —— Ethyl 5-[(4-bromophenyl)sulfanyl]-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazine-6-carboxylate —— C19H13BrF3N3O2S
    Ethyl 5-[(4-bromophenyl)sulfanyl]-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazine-6-carboxylate
    —— 2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]propanenitrile —— C20H18N4S
    2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]propanenitrile
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(1-phenylethyl)acetamide —— C25H22N4OS
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(1-phenylethyl)acetamide
    —— 5-[(2,6-Dichlorophenyl)sulfanyl]-3,6-diphenyl-1,2,4-triazine —— C21H13Cl2N3S
    5-[(2,6-Dichlorophenyl)sulfanyl]-3,6-diphenyl-1,2,4-triazine
    —— 4-Nitro-5-{[5-(2-phenylethyl)-5H-[1,2,4]triazino[5,6-B]indol-3-YL]sulfanyl}-2,1,3-benzothiadiazole —— C23H15N7O2S2
    4-Nitro-5-{[5-(2-phenylethyl)-5H-[1,2,4]triazino[5,6-B]indol-3-YL]sulfanyl}-2,1,3-benzothiadiazole
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-pentan-2-ylacetamide —— C24H28N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-pentan-2-ylacetamide
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(4-phenylbutan-2-yl)acetamide —— C29H30N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(4-phenylbutan-2-yl)acetamide
    —— 5-[(E)-4-(4-chlorophenyl)sulfanylpent-2-enyl]-6-methyl-1,2,4-triazin-3-amine —— C15H17ClN4S
    5-[(E)-4-(4-chlorophenyl)sulfanylpent-2-enyl]-6-methyl-1,2,4-triazin-3-amine
    —— 10-Bromo-3-pentylsulfanyl-[1,2,4]triazino[5,6-d][3,1]benzoxazepine —— C15H15BrN4OS
    10-Bromo-3-pentylsulfanyl-[1,2,4]triazino[5,6-d][3,1]benzoxazepine
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[2-(4-fluorophenyl)ethyl]acetamide —— C27H25FN4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[2-(4-fluorophenyl)ethyl]acetamide