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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-2-(3-aminopyridin-2-yl)sulfanylpropanehydrazide —— C8H12N4OS
    (2R)-2-(3-aminopyridin-2-yl)sulfanylpropanehydrazide
    —— (2E)-2-hydroxyimino-1-benzothiophen-3-one —— C8H5NO2S
    (2E)-2-hydroxyimino-1-benzothiophen-3-one
    —— 1-Benzyl-4-[(4-chlorophenyl)sulfanyl]phthalazine —— C21H15ClN2S
    1-Benzyl-4-[(4-chlorophenyl)sulfanyl]phthalazine
    —— 3-Benzyl-2,4,7-tris(ethylsulfanyl)imidazo[4,5-d]pyridazine —— C18H22N4S3
    3-Benzyl-2,4,7-tris(ethylsulfanyl)imidazo[4,5-d]pyridazine
    —— (E)-N-[(4-fluorophenyl)methoxy]-2-(6-methyl-3-prop-2-enylsulfanyl-1,2,4-triazin-5-yl)ethenamine —— C16H17FN4OS
    (E)-N-[(4-fluorophenyl)methoxy]-2-(6-methyl-3-prop-2-enylsulfanyl-1,2,4-triazin-5-yl)ethenamine
    —— 2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-(2,5-dimethyl-1-propylpyrrol-3-yl)ethanone —— C28H30N4OS
    2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-(2,5-dimethyl-1-propylpyrrol-3-yl)ethanone
    —— 2,4-Difluoro-N-(2-(6-methyl-3-(methylsulfanyl)-1,2,4-triazin-5-yl)vinyl)aniline —— C13H12F2N4S
    2,4-Difluoro-N-(2-(6-methyl-3-(methylsulfanyl)-1,2,4-triazin-5-yl)vinyl)aniline
    —— 3-[[(2R)-oxolan-2-yl]methylsulfanyl]-5,6-diphenyl-1,2,4-triazine —— C20H19N3OS
    3-[[(2R)-oxolan-2-yl]methylsulfanyl]-5,6-diphenyl-1,2,4-triazine
    —— 3-(4-Chlorophenyl)-6-(4-fluorophenyl)-5-phenylsulfanyl-1,2,4-triazine —— C21H13ClFN3S
    3-(4-Chlorophenyl)-6-(4-fluorophenyl)-5-phenylsulfanyl-1,2,4-triazine
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide —— C24H28N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide
    —— (3R)-3-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]oxolan-2-one —— C19H15N3O2S
    (3R)-3-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]oxolan-2-one
    —— 1-[2,5-dimethyl-1-[[(2S)-oxolan-2-yl]methyl]pyrrol-3-yl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethanone —— C28H28N4O2S
    1-[2,5-dimethyl-1-[[(2S)-oxolan-2-yl]methyl]pyrrol-3-yl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethanone
    —— 3-(2,4-Dichlorophenyl)-6-phenyl-5-phenylsulfanyl-1,2,4-triazine —— C21H13Cl2N3S
    3-(2,4-Dichlorophenyl)-6-phenyl-5-phenylsulfanyl-1,2,4-triazine
    —— 1-[2-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetyl]pyrrolidin-2-one —— C21H18N4O2S
    1-[2-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetyl]pyrrolidin-2-one
    —— 2-[(3S,5S)-5-methyl-2-oxooxolan-3-yl]sulfanyl-6-thiophen-2-yl-4-(trifluoromethyl)pyridine-3-carbonitrile —— C16H11F3N2O2S2
    2-[(3S,5S)-5-methyl-2-oxooxolan-3-yl]sulfanyl-6-thiophen-2-yl-4-(trifluoromethyl)pyridine-3-carbonitrile
    —— N-cyclopropyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C20H18N4OS
    N-cyclopropyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(2-methoxyethyl)acetamide —— C20H20N4O2S
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(2-methoxyethyl)acetamide
    —— N-[(4-chlorophenyl)methyl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C24H19ClN4OS
    N-[(4-chlorophenyl)methyl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-propan-2-ylacetamide —— C22H24N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-propan-2-ylacetamide
    —— 1,3-Bis[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]propan-2-one —— C33H24N6OS2
    1,3-Bis[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]propan-2-one
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-methyl-N-(thiophen-2-ylmethyl)acetamide —— C23H20N4OS2
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-methyl-N-(thiophen-2-ylmethyl)acetamide
    —— (2S)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]propanamide —— C23H24N4O2S
    (2S)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]propanamide
    —— 2-[(3R,5S)-5-methyl-2-oxooxolan-3-yl]sulfanyl-6-thiophen-2-yl-4-(trifluoromethyl)pyridine-3-carbonitrile —— C16H11F3N2O2S2
    2-[(3R,5S)-5-methyl-2-oxooxolan-3-yl]sulfanyl-6-thiophen-2-yl-4-(trifluoromethyl)pyridine-3-carbonitrile
    —— 2-[2-[(3S,5S)-3,5-dimethylcyclohexyl]ethylsulfonyl]ethanol —— C12H24O3S
    2-[2-[(3S,5S)-3,5-dimethylcyclohexyl]ethylsulfonyl]ethanol
    —— 2-[2-[(3S,5R)-3,5-dimethylcyclohexyl]ethylsulfonyl]ethanol —— C12H24O3S
    2-[2-[(3S,5R)-3,5-dimethylcyclohexyl]ethylsulfonyl]ethanol
    —— 2-[(3S,5R)-5-methyl-2-oxooxolan-3-yl]sulfanyl-6-thiophen-2-yl-4-(trifluoromethyl)pyridine-3-carbonitrile —— C16H11F3N2O2S2
    2-[(3S,5R)-5-methyl-2-oxooxolan-3-yl]sulfanyl-6-thiophen-2-yl-4-(trifluoromethyl)pyridine-3-carbonitrile
    —— 2-[2-[(3R,5R)-3,5-dimethylcyclohexyl]ethylsulfonyl]ethanol —— C12H24O3S
    2-[2-[(3R,5R)-3,5-dimethylcyclohexyl]ethylsulfonyl]ethanol
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[(2R)-2-cyano-3-methylbutan-2-yl]acetamide —— C25H27N5OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[(2R)-2-cyano-3-methylbutan-2-yl]acetamide
    —— 3-(4-fluorobenzylthio)-5,6-diphenyl-1,2,4-triazine —— C22H16FN3S
    3-(4-fluorobenzylthio)-5,6-diphenyl-1,2,4-triazine
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C24H26N4O2S
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— 2-[(5,6-diethyl-1,2,4-triazin-3-yl)sulfanyl]-N-(2-phenylethyl)acetamide —— C17H22N4OS
    2-[(5,6-diethyl-1,2,4-triazin-3-yl)sulfanyl]-N-(2-phenylethyl)acetamide
    —— 1-[3-(methylsulfanyl)-1,2,4-triazin-5-yl]ethanone O-methyloxime —— C7H10N4OS
    1-[3-(methylsulfanyl)-1,2,4-triazin-5-yl]ethanone O-methyloxime
    —— (3S)-3-[5-[(1R)-cyclohex-2-en-1-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C15H21N3O2S2
    (3S)-3-[5-[(1R)-cyclohex-2-en-1-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— Ethyl 5-[(4-methoxyphenyl)sulfanyl]-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazine-6-carboxylate —— C20H16F3N3O3S
    Ethyl 5-[(4-methoxyphenyl)sulfanyl]-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazine-6-carboxylate
    —— (3R)-3-[5-[(1S)-cyclohex-2-en-1-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C15H21N3O2S2
    (3R)-3-[5-[(1S)-cyclohex-2-en-1-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— Ethyl 5-[(6-phenyl-1,2,4-triazin-3-yl)sulfanyl]thiadiazole-4-carboxylate —— C14H11N5O2S2
    Ethyl 5-[(6-phenyl-1,2,4-triazin-3-yl)sulfanyl]thiadiazole-4-carboxylate
    —— Propan-2-yl 2-[[5,6-bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]acetate —— C16H15N3O4S
    Propan-2-yl 2-[[5,6-bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]acetate
    —— (2S)-2-(4-chlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetamide —— C18H14ClN3OS
    (2S)-2-(4-chlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetamide
    —— (2R)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]propanoic acid —— C18H15N3O2S
    (2R)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]propanoic acid
    —— ethyl 2-[[(1R,8S)-8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-trien-5-yl]sulfanyl]acetate —— C15H21N3O2S
    ethyl 2-[[(1R,8S)-8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-trien-5-yl]sulfanyl]acetate
    —— ethyl (2R)-2-[[5,6-bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]propanoate —— C16H15N3O4S
    ethyl (2R)-2-[[5,6-bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]propanoate
    —— (1R)-2,2-dichloro-N-[5-chloro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-1-methylcyclopropane-1-carboxamide —— C15H14Cl3N3OS
    (1R)-2,2-dichloro-N-[5-chloro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-1-methylcyclopropane-1-carboxamide
    —— (1S)-2,2-dichloro-N-[5-chloro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-1-methylcyclopropane-1-carboxamide —— C15H14Cl3N3OS
    (1S)-2,2-dichloro-N-[5-chloro-2-(1-methylimidazol-2-yl)sulfanylphenyl]-1-methylcyclopropane-1-carboxamide
    —— N-(2-(3-(Benzylsulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)-4-fluoroaniline —— C19H17FN4S
    N-(2-(3-(Benzylsulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)-4-fluoroaniline
    —— (3S)-3-[5-[(1S)-cyclohex-2-en-1-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C15H21N3O2S2
    (3S)-3-[5-[(1S)-cyclohex-2-en-1-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— (3R)-3-[5-[(1R)-cyclohex-2-en-1-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C15H21N3O2S2
    (3R)-3-[5-[(1R)-cyclohex-2-en-1-yl]sulfanyl-4-prop-2-enyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— 2-[(5,6-diethyl-1,2,4-triazin-3-yl)sulfanyl]-N-methylacetamide —— C10H16N4OS
    2-[(5,6-diethyl-1,2,4-triazin-3-yl)sulfanyl]-N-methylacetamide
    —— 3-[[5,6-Bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]propanoic acid —— C14H11N3O4S
    3-[[5,6-Bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]propanoic acid
    —— 1,9-dimethyl-2H-triazolo[4,5-c]phenothiazine —— C14H12N4S
    1,9-dimethyl-2H-triazolo[4,5-c]phenothiazine
    —— [amino-(4,5-dimethoxypyridazin-3-yl)sulfanylmethylidene]azanium —— C7H11N4O2S+
    [amino-(4,5-dimethoxypyridazin-3-yl)sulfanylmethylidene]azanium