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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-benzyl-1-methyl-2-phenylthio-1-H-imidazole 146744-54-9 C17H16N2S
    5-benzyl-1-methyl-2-phenylthio-1-H-imidazole
    —— 4-Benzo[1,3]dioxol-5-ylmethyl-1-methyl-5-phenylsulfanyl-1H-imidazole 181879-93-6 C18H16N2O2S
    4-Benzo[1,3]dioxol-5-ylmethyl-1-methyl-5-phenylsulfanyl-1H-imidazole
    —— 2,6-dimethyl-3-methylthiopyridine 116651-87-7 C8H11NS
    2,6-dimethyl-3-methylthiopyridine
    —— Benzo[1,3]dioxol-5-yl-(1-methyl-2,5-bis-phenylsulfanyl-1H-imidazol-4-yl)-methanol 181879-89-0 C24H20N2O3S2
    Benzo[1,3]dioxol-5-yl-(1-methyl-2,5-bis-phenylsulfanyl-1H-imidazol-4-yl)-methanol
    —— (E)-3-(2-(phenylthio)-1-((2-(trimethylsilyl)ethoxy)methyl)-1H-imidazol-5-yl)acrylamide 1309961-60-1 C18H25N3O2SSi
    (E)-3-(2-(phenylthio)-1-((2-(trimethylsilyl)ethoxy)methyl)-1H-imidazol-5-yl)acrylamide
    —— 2,2-Dimethyl-1-(1-methyl-2,5-bis-phenylsulfanyl-1H-imidazol-4-yl)-propan-1-ol 157331-18-5 C21H24N2OS2
    2,2-Dimethyl-1-(1-methyl-2,5-bis-phenylsulfanyl-1H-imidazol-4-yl)-propan-1-ol
    —— methyl dithioformate 59065-19-9 C2H4S2
    methyl dithioformate
    —— [5-(4-bromo-anilino)-[1,3,4]thiadiazol-2-ylsulfanyl]-acetic acid 68161-38-6 C10H8BrN3O2S2
    [5-(4-bromo-anilino)-[1,3,4]thiadiazol-2-ylsulfanyl]-acetic acid
    —— 1-methyl-4-methylthio-5-fluoropyrimidin-2-one 63331-47-5 C6H7FN2OS
    1-methyl-4-methylthio-5-fluoropyrimidin-2-one
    —— 2-(phenylthio)-1-((2-(trimethylsilyl)ethoxy)methyl)-1H-imidazole 153172-35-1 C15H22N2OSSi
    2-(phenylthio)-1-((2-(trimethylsilyl)ethoxy)methyl)-1H-imidazole
    —— 3-([1,2,4]Triazolo[4,3-c][1,2,3]benzotriazin-3-ylsulfanyl)chromen-2-imine 339314-99-7 C17H10N6OS
    3-([1,2,4]Triazolo[4,3-c][1,2,3]benzotriazin-3-ylsulfanyl)chromen-2-imine
    —— N-Methyl-2-(pyrid-2-yl)-1,3-oxathiane-2-carbothioamide 82081-50-3 C11H14N2OS2
    N-Methyl-2-(pyrid-2-yl)-1,3-oxathiane-2-carbothioamide
    —— 2,2-dimethylpropionic acid 6-cyano-4-ethoxythiocarbonylsulfanyl-7,7-dimethoxyheptyl ester 870106-36-8 C18H31NO5S2
    2,2-dimethylpropionic acid 6-cyano-4-ethoxythiocarbonylsulfanyl-7,7-dimethoxyheptyl ester
    —— Methyl 2-methyl-1-propenyl Trithiocarbonat 73552-41-7 C6H10S3
    Methyl 2-methyl-1-propenyl Trithiocarbonat
    —— 1-ethoxymethyl-6-(3-aminophenylthio)thymine 1393847-33-0 C14H17N3O3S
    1-ethoxymethyl-6-(3-aminophenylthio)thymine
    —— 1-((2-trimethylsilylethoxy)methyl)-6-(phenylthio)thymine 144410-24-2 C17H24N2O3SSi
    1-((2-trimethylsilylethoxy)methyl)-6-(phenylthio)thymine
    —— 1-(2,5-dimethylbenzyl)-6-(3-aminophenylthio)thymine 1393847-37-4 C20H21N3O2S
    1-(2,5-dimethylbenzyl)-6-(3-aminophenylthio)thymine
    —— 1-((2-trimethylsilylethoxy)methyl)-6-(3-aminophenylthio)thymine 1393847-30-7 C17H25N3O3SSi
    1-((2-trimethylsilylethoxy)methyl)-6-(3-aminophenylthio)thymine
    —— 1-ethoxymethyl-3,4-dihydro-5-methyl-6-(phenylthio)-4-thioxopyrimidin-2(1H)-one 1393847-40-9 C14H16N2O2S2
    1-ethoxymethyl-3,4-dihydro-5-methyl-6-(phenylthio)-4-thioxopyrimidin-2(1H)-one
    —— 1-cyano-2,7-bis(methylthio)pyrazolo<1,5-c><1,3,5>thiadiazine-5(5H)-thione 130224-60-1 C8H6N4S4
    1-cyano-2,7-bis(methylthio)pyrazolo<1,5-c><1,3,5>thiadiazine-5(5H)-thione
    —— methyl 2-ethoxythiocarbonylsulfanyl-3,3-dimethoxypropionate 462099-91-8 C9H16O5S2
    methyl 2-ethoxythiocarbonylsulfanyl-3,3-dimethoxypropionate
    —— 9-Butyl-8-(3,4,5-trimethoxy-phenylsulfanyl)-9H-purin-6-ylamine 852030-53-6 C18H23N5O3S
    9-Butyl-8-(3,4,5-trimethoxy-phenylsulfanyl)-9H-purin-6-ylamine
    —— (2-chloroethenyl)sulfanylbenzene 98554-14-4 C8H7ClS
    (2-chloroethenyl)sulfanylbenzene
    —— 3-(Benzylsulfanyl)-5-hydrazinyl-1H-1,2,4-triazole 88141-21-3 C9H11N5S
    3-(Benzylsulfanyl)-5-hydrazinyl-1H-1,2,4-triazole
    —— <tert-Butylthio(thiocarbonyloxy)>essigsaeure 82979-46-2 C7H12O3S2
    <tert-Butylthio(thiocarbonyloxy)>essigsaeure
    —— 9-(2-Isopropoxy-ethyl)-8-(3-methoxy-phenylsulfanyl)-9H-purin-6-ylamine 852030-51-4 C17H21N5O2S
    9-(2-Isopropoxy-ethyl)-8-(3-methoxy-phenylsulfanyl)-9H-purin-6-ylamine
    —— 4-Ethoxy-2-ethylmercapto-5-methyl-pyrimidin 99516-33-3 C9H14N2OS
    4-Ethoxy-2-ethylmercapto-5-methyl-pyrimidin
    —— 9-butyl-8-(3-methoxy-phenylsulfanyl)adenine 521308-36-1 C16H19N5OS
    9-butyl-8-(3-methoxy-phenylsulfanyl)adenine
    —— 9-Pent-4-ynyl-8-(3,4,5-trimethoxy-phenylsulfanyl)-9H-purin-6-ylamine 852030-48-9 C19H21N5O3S
    9-Pent-4-ynyl-8-(3,4,5-trimethoxy-phenylsulfanyl)-9H-purin-6-ylamine
    —— 9-(2-Isopropoxy-ethyl)-8-(3,4,5-trimethoxy-phenylsulfanyl)-9H-purin-6-ylamine 852030-54-7 C19H25N5O4S
    9-(2-Isopropoxy-ethyl)-8-(3,4,5-trimethoxy-phenylsulfanyl)-9H-purin-6-ylamine
    —— 8-(3,4,5-trimethoxy-phenylsulfanyl)adenine 827302-37-4 C14H15N5O3S
    8-(3,4,5-trimethoxy-phenylsulfanyl)adenine
    —— 9-butyl-8-(2,5-dimethoxy-phenylsulfanyl)-9H-purin-6-ylamine 521308-37-2 C17H21N5O2S
    9-butyl-8-(2,5-dimethoxy-phenylsulfanyl)-9H-purin-6-ylamine
    —— 2-methylthio-3-phenylthiophene 72946-77-1 C11H10S2
    2-methylthio-3-phenylthiophene
    —— 8-(phenylthio)-9H-purin-6-amine 908117-27-1 C11H9N5S
    8-(phenylthio)-9H-purin-6-amine
    —— cis-3-(phenylthio)prop-2-en-1-ol —— C9H10OS
    cis-3-(phenylthio)prop-2-en-1-ol
    —— tert-butyl 3-(4-bromophenylthio)azetidine-1-carboxylate 1002355-69-2 C14H18BrNO2S
    tert-butyl 3-(4-bromophenylthio)azetidine-1-carboxylate
    —— (E)-3-chloro-1-phenylthioprop-1-ene 52072-01-2 C9H9ClS
    (E)-3-chloro-1-phenylthioprop-1-ene
    —— 4-Methyl-3-(phenylthio)-pentan-2-on 27872-69-1 C12H16OS
    4-Methyl-3-(phenylthio)-pentan-2-on
    —— S-Methyl-S-(n-propyl) dithiocarbonate 10596-54-0 C5H10OS2
    S-Methyl-S-(n-propyl) dithiocarbonate
    —— 4-methylthio-5-heptyl-1,3-oxathiolene 129206-06-0 C11H20OS2
    4-methylthio-5-heptyl-1,3-oxathiolene
    —— 3-methyl-4-methylsulfanyl-buta-1,2-diene 23451-61-8 C6H10S
    3-methyl-4-methylsulfanyl-buta-1,2-diene
    —— 2-<<(p-bromophenyl)thio>methyl>-5-methylpyridine 83782-45-0 C13H12BrNS
    2-<<(p-bromophenyl)thio>methyl>-5-methylpyridine
    —— 6-methylthio-2-phenyl-1,3-diazin-4-one 87905-18-8 C11H10N2OS
    6-methylthio-2-phenyl-1,3-diazin-4-one
    —— 4-amino-1,6-dihydro-1-methyl-2-methylthio-5-nitroso-6-oxo-pyrimidine 42026-60-8 C6H8N4O2S
    4-amino-1,6-dihydro-1-methyl-2-methylthio-5-nitroso-6-oxo-pyrimidine
    —— [(2,2-Dichloro-1-phenylethenyl)sulfanyl]benzene 88649-72-3 C14H10Cl2S
    [(2,2-Dichloro-1-phenylethenyl)sulfanyl]benzene
    —— (1,4-Diphenyl-4-phenylsulfanylbuta-1,2,3-trienyl)sulfanylbenzene 88649-77-8 C28H20S2
    (1,4-Diphenyl-4-phenylsulfanylbuta-1,2,3-trienyl)sulfanylbenzene
    —— 3-Methyl-1-methylsulfanylcyclohexene 70871-34-0 C8H14S
    3-Methyl-1-methylsulfanylcyclohexene
    —— 2-methoxy-3-phenylsulfanyl-toluene 107774-39-0 C14H14OS
    2-methoxy-3-phenylsulfanyl-toluene
    —— N-[(1S)-2,2-difluoro-1-phenyl-2-phenylsulfanylethyl]prop-2-en-1-amine 938463-88-8 C17H17F2NS
    N-[(1S)-2,2-difluoro-1-phenyl-2-phenylsulfanylethyl]prop-2-en-1-amine
    —— phenyl(phenylthiomethylene)cyclohexane 107014-86-8 C19H20S
    phenyl(phenylthiomethylene)cyclohexane