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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-chloro-4-<i>p</i>-tolylsulfanyl-benzonitrile 873378-23-5 C14H10ClNS
    2-chloro-4-<i>p</i>-tolylsulfanyl-benzonitrile
    —— 4-(2,2-diethoxy-ethyl)-3-(4-methyl-benzyl)-5-methylsulfanyl-4<i>H</i>-[1,2,4]triazole 66205-66-1 C17H25N3O2S
    4-(2,2-diethoxy-ethyl)-3-(4-methyl-benzyl)-5-methylsulfanyl-4<i>H</i>-[1,2,4]triazole
    —— (3S,4R)-3-tert-Butyl-2-((S)-1-phenyl-ethyl)-4-phenylsulfanyl-[1,2]thiazetidine 1,1-dioxide 218460-72-1 C20H25NO2S2
    (3S,4R)-3-tert-Butyl-2-((S)-1-phenyl-ethyl)-4-phenylsulfanyl-[1,2]thiazetidine 1,1-dioxide
    —— 5-(4-hydroxyphenylsulphanyl)-2-amino-1H-indole-3-carbonitrile 378236-71-6 C15H11N3OS
    5-(4-hydroxyphenylsulphanyl)-2-amino-1H-indole-3-carbonitrile
    —— 2-(acetylamino)thiopropionamide 91188-51-1 C5H10N2OS
    2-(acetylamino)thiopropionamide
    —— (2R,3R)-2-Phenylsulfanylmethyl-3-vinyl-cyclopentanone 143008-57-5 C14H16OS
    (2R,3R)-2-Phenylsulfanylmethyl-3-vinyl-cyclopentanone
    —— 1-(but-2-ynoyl)-6,6-dimethyl-3-(methylsulfanyl)-4-oxo-4,5,6,7-tetrahydro-2-benzothiophen-4(5H)-one 1395919-74-0 C15H16O2S2
    1-(but-2-ynoyl)-6,6-dimethyl-3-(methylsulfanyl)-4-oxo-4,5,6,7-tetrahydro-2-benzothiophen-4(5H)-one
    —— (1-methoxy-3-phenylpropyl)phenylsulfide 67975-86-4 C16H18OS
    (1-methoxy-3-phenylpropyl)phenylsulfide
    —— 6,6-dimethyl-3-(methylsulfanyl)-4-oxo-4,5,6,7-tetrahydro-2-benzothiophene-1-carbaldehyde 1395919-77-3 C12H14O2S2
    6,6-dimethyl-3-(methylsulfanyl)-4-oxo-4,5,6,7-tetrahydro-2-benzothiophene-1-carbaldehyde
    —— 1-acetamido-3-acetoxy-1-phenyl-2-phenylthiopropane 98289-67-9 C19H21NO3S
    1-acetamido-3-acetoxy-1-phenyl-2-phenylthiopropane
    —— 3-isothiocyanato-cyclopentene 52566-12-8 C6H7NS
    3-isothiocyanato-cyclopentene
    —— (5-Ethyl-4-phenylsulfanyl-6-trimethylsilyloxypyrimidin-2-yl)oxy-trimethylsilane 1026490-47-0 C18H28N2O2SSi2
    (5-Ethyl-4-phenylsulfanyl-6-trimethylsilyloxypyrimidin-2-yl)oxy-trimethylsilane
    —— 1,1,3,3-tetrakis-butylsulfanyl-propane 53480-98-1 C19H40S4
    1,1,3,3-tetrakis-butylsulfanyl-propane
    —— methyl 2-(2-((2-(methylthio)pyrimidin-4-yl)ethynyl)phenyl)acetate 1566584-29-9 C16H14N2O2S
    methyl 2-(2-((2-(methylthio)pyrimidin-4-yl)ethynyl)phenyl)acetate
    —— 8-isobutoxy-1,4-dithiaspiro<4.5>dec-7-en-6-one 155996-44-4 C12H18O2S2
    8-isobutoxy-1,4-dithiaspiro<4.5>dec-7-en-6-one
    —— 1-allyl-2-isopropyldisulfane 67421-85-6 C6H12S2
    1-allyl-2-isopropyldisulfane
    —— methyl 2-(2-(2-(2-(methylthio)pyrimidin-4-yl)ethyl)phenyl)acetate 1566584-30-2 C16H18N2O2S
    methyl 2-(2-(2-(2-(methylthio)pyrimidin-4-yl)ethyl)phenyl)acetate
    —— 3-(6-Nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane]-5-yl)sulfanylpyridine 1025847-07-7 C16H14N2O4S
    3-(6-Nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane]-5-yl)sulfanylpyridine
    —— 1,1,1-Tris(methylsulfanyl)pentane 99029-99-9 C8H18S3
    1,1,1-Tris(methylsulfanyl)pentane
    —— 3,4'-thiobispyridine 72890-90-5 C10H8N2S
    3,4'-thiobispyridine
    —— (E)-1-Cinnamyl-6-(phenylthio)thymine 157401-04-2 C20H18N2O2S
    (E)-1-Cinnamyl-6-(phenylthio)thymine
    —— 2-Isopropylthio-2-methylpropanal 89812-33-9 C7H14OS
    2-Isopropylthio-2-methylpropanal
    —— 2-(2-Isocyanatoethyl)-2-(isocyanatomethyl)-1,3-dithiolane 72331-47-6 C8H10N2O2S2
    2-(2-Isocyanatoethyl)-2-(isocyanatomethyl)-1,3-dithiolane
    —— α-isopropylthiobutyraldehyde 89812-38-4 C7H14OS
    α-isopropylthiobutyraldehyde
    —— trans-2,2-dimethyl-6-phenyl-5-phenylthio-1,3-dioxolane 119061-73-3 C18H20O2S
    trans-2,2-dimethyl-6-phenyl-5-phenylthio-1,3-dioxolane
    —— 2-isopropylthio,6-bromopyridine 98626-90-5 C8H10BrNS
    2-isopropylthio,6-bromopyridine
    —— 2-isopropylthio,5-chloropyridine 98626-99-4 C8H10ClNS
    2-isopropylthio,5-chloropyridine
    —— 2-Isopropylsulfanyl-2-methyl-butyraldehyde 89812-37-3 C8H16OS
    2-Isopropylsulfanyl-2-methyl-butyraldehyde
    —— 2,6-bis(isopropylthio)pyridine 98627-03-3 C11H17NS2
    2,6-bis(isopropylthio)pyridine
    —— 3-chloro-6-(isopropylthio)pyridazine 66089-81-4 C7H9ClN2S
    3-chloro-6-(isopropylthio)pyridazine
    —— 2-Chloro-3-propan-2-ylsulfanylpyridine 871099-86-4 C8H10ClNS
    2-Chloro-3-propan-2-ylsulfanylpyridine
    —— (RS)-1-(3-pyridylthio)propan-2-ol 464934-46-1 C8H11NOS
    (RS)-1-(3-pyridylthio)propan-2-ol
    —— α-Methyl-α-amino-thioisovaleriansaeureamid 16256-19-2 C6H14N2S
    α-Methyl-α-amino-thioisovaleriansaeureamid
    —— 1-(phenylthio)-5-isoquinolinol 144242-88-6 C15H11NOS
    1-(phenylthio)-5-isoquinolinol
    —— 2-Nitro-3-phenethyl-2-p-tolylsulfanyl-oxirane 168135-87-3 C17H17NO3S
    2-Nitro-3-phenethyl-2-p-tolylsulfanyl-oxirane
    —— 5,6-dihydrothieno<2,3-d>-1,3-dithiol-2-one 67188-89-0 C5H4OS3
    5,6-dihydrothieno<2,3-d>-1,3-dithiol-2-one
    —— 2,4-Bis-(2-pentyl-benzo[1,3]dithiol-2-yl)-1H-pyrrole 147089-59-6 C28H33NS4
    2,4-Bis-(2-pentyl-benzo[1,3]dithiol-2-yl)-1H-pyrrole
    —— N-(diisopropoxyphosphorothioyl)-N',N'-dimethylthiourea 1211031-03-6 C9H21N2O2PS2
    N-(diisopropoxyphosphorothioyl)-N',N'-dimethylthiourea
    —— (E)-tert-butyl 1-propenyl sulfone 69113-46-8 C7H14O2S
    (E)-tert-butyl 1-propenyl sulfone
    —— 2-cyano-N,N-dimethylethanethioamide 146561-43-5 C5H8N2S
    2-cyano-N,N-dimethylethanethioamide
    —— 3-Ethyl-2-methylthio-4-phenylthiophene 72814-46-1 C13H14S2
    3-Ethyl-2-methylthio-4-phenylthiophene
    —— (2R,3S,4R)-1-[2-[(2S,3S,6R)-3-[tert-butyl(dimethyl)silyl]oxy-6-[(2S,3S,6R,8S,9R)-3,9-dimethyl-8-[(3S)-3-(2-methyl-1,3-dithian-2-yl)butyl]-1,7-dioxaspiro[5.5]undecan-2-yl]heptan-2-yl]-1,3-dithian-2-yl]-3-methoxy-5-methylhexane-2,4-diol 642442-80-6 C45H86O6S4Si
    (2R,3S,4R)-1-[2-[(2S,3S,6R)-3-[tert-butyl(dimethyl)silyl]oxy-6-[(2S,3S,6R,8S,9R)-3,9-dimethyl-8-[(3S)-3-(2-methyl-1,3-dithian-2-yl)butyl]-1,7-dioxaspiro[5.5]undecan-2-yl]heptan-2-yl]-1,3-dithian-2-yl]-3-methoxy-5-methylhexane-2,4-diol
    —— 2-Methylthio-4-phenyl-3-propylthiophene 125150-84-7 C14H16S2
    2-Methylthio-4-phenyl-3-propylthiophene
    —— 2-benzylthio-3-methyl-4,5-diphenylthiophene 89003-21-4 C24H20S2
    2-benzylthio-3-methyl-4,5-diphenylthiophene
    —— tert-butyl-[(2S,3S,6R)-6-[(2S,3S,6R,8S,9R)-3,9-dimethyl-8-[(3S)-3-(2-methyl-1,3-dithian-2-yl)butyl]-1,7-dioxaspiro[5.5]undecan-2-yl]-2-(1,3-dithian-2-yl)heptan-3-yl]oxy-dimethylsilane 642442-77-1 C37H70O3S4Si
    tert-butyl-[(2S,3S,6R)-6-[(2S,3S,6R,8S,9R)-3,9-dimethyl-8-[(3S)-3-(2-methyl-1,3-dithian-2-yl)butyl]-1,7-dioxaspiro[5.5]undecan-2-yl]-2-(1,3-dithian-2-yl)heptan-3-yl]oxy-dimethylsilane
    —— 3-methyl-6-methylsulfanyl-3<i>H</i>-pyrimido[5,4-<i>d</i>]pyrimidin-4-one 99584-35-7 C8H8N4OS
    3-methyl-6-methylsulfanyl-3<i>H</i>-pyrimido[5,4-<i>d</i>]pyrimidin-4-one
    —— <3R,4R,5R,8S,9S,12R,12<2S,3S,6R,8S,8(3S),9R>>-5,9-bis(tert-butyldimethylsilyl)oxy-12-<3,9-dimethyl-8-<3-(2-methyl-1,3-dithian-2-yl)butyl>-1,7-dioxaspiro<5,5>undecan-2-yl>-4-methoxy-2,8-dimethyl-7-(1,3-dithian-2-yl)-3-tridecanol 170708-58-4 C51H100O6S4Si2
    <3R,4R,5R,8S,9S,12R,12<2S,3S,6R,8S,8(3S),9R>>-5,9-bis(tert-butyldimethylsilyl)oxy-12-<3,9-dimethyl-8-<3-(2-methyl-1,3-dithian-2-yl)butyl>-1,7-dioxaspiro<5,5>undecan-2-yl>-4-methoxy-2,8-dimethyl-7-(1,3-dithian-2-yl)-3-tridecanol
    —— 4,5,6,7-tetrakis(methylthio)-1,3-benzodithiole-2-thione 133148-79-5 C11H12S7
    4,5,6,7-tetrakis(methylthio)-1,3-benzodithiole-2-thione
    —— (4R,5S,6S)-<<5-(Methoxymethoxy)-4,6-dimethyl-8-(phenylthio)-1-octyl>oxy>(1,1-dimethylethyl)diphenylsilane 165961-51-3 C34H48O3SSi
    (4R,5S,6S)-<<5-(Methoxymethoxy)-4,6-dimethyl-8-(phenylthio)-1-octyl>oxy>(1,1-dimethylethyl)diphenylsilane
    —— per(methylthio)dibenzotetrathiafulvalene 129137-82-2 C22H24S12
    per(methylthio)dibenzotetrathiafulvalene