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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— p-tolyl 3-C-acetoxymethyl-2,3-di-O-acetyl-1-thio-β-D-erythrofuranoside 1334532-96-5 C18H22O7S
    p-tolyl 3-C-acetoxymethyl-2,3-di-O-acetyl-1-thio-β-D-erythrofuranoside
    —— {3-[2-(6-fluoro-1H-indol-3-ylsulfanyl)-phenyl]-propyl}-methyl-carbamic acid tert-butyl ester 1187478-84-7 C23H27FN2O2S
    {3-[2-(6-fluoro-1H-indol-3-ylsulfanyl)-phenyl]-propyl}-methyl-carbamic acid tert-butyl ester
    —— 3-Hydroxy-1-(β-methoxy-isopropyl)-5-methylmercapto-<1,2,4>-triazol 63881-68-5 C7H13N3O2S
    3-Hydroxy-1-(β-methoxy-isopropyl)-5-methylmercapto-<1,2,4>-triazol
    —— 5-N-(4-tolyl)aminomethyl-2-(β-D-xylopyranosyl)sulfanyl-1,3,4-oxadiazole 1064194-58-6 C15H19N3O5S
    5-N-(4-tolyl)aminomethyl-2-(β-D-xylopyranosyl)sulfanyl-1,3,4-oxadiazole
    —— K{(bromo)3(dimethylsulfoxide)platinum} 28681-13-2 C2H6Br3OPtS*K
    K{(bromo)3(dimethylsulfoxide)platinum}
    —— (1R,3aS,7aS)-1-Methyl-5-phenylsulfanyl-7a-vinyl-octahydro-inden-4-one 73537-35-6 C18H22OS
    (1R,3aS,7aS)-1-Methyl-5-phenylsulfanyl-7a-vinyl-octahydro-inden-4-one
    —— N-(2-butyl-1-methyl-2-cyclopenten-1-yl)-2-methyl-2-propanesulfonamide 1067231-24-6 C14H27NO2S
    N-(2-butyl-1-methyl-2-cyclopenten-1-yl)-2-methyl-2-propanesulfonamide
    —— (E)-4'-[2-amino-6-(4-methoxytetrahydropyran-4-yl)pyrimidin-4-yl-thio]acetophenone oxime 161385-05-3 C18H22N4O3S
    (E)-4'-[2-amino-6-(4-methoxytetrahydropyran-4-yl)pyrimidin-4-yl-thio]acetophenone oxime
    —— (2-Diisopropylamino-aethyl)-(2-amino-phenyl)-sulfid 93896-81-2 C14H24N2S
    (2-Diisopropylamino-aethyl)-(2-amino-phenyl)-sulfid
    —— S-[3-(1,1-dicyano-3-cyclohepta-2,4,6-trien-1-ylideneprop-1-en-2-yl)phenyl] ethanethioate 1448895-55-3 C20H14N2OS
    S-[3-(1,1-dicyano-3-cyclohepta-2,4,6-trien-1-ylideneprop-1-en-2-yl)phenyl] ethanethioate
    —— 5-acetylsulfanyl-4-methyl-2-phenyl-thiazole 24053-34-7 C12H11NOS2
    5-acetylsulfanyl-4-methyl-2-phenyl-thiazole
    —— 315222-57-2 C23H19Cl3N2O2S3
    —— 6-bromo-3-[4-[5-[[5-[4-(6-bromo-2-methyl-4-oxoquinazolin-3-yl)phenyl]-4-(4-methylphenyl)-1,2,4-triazol-3-yl]sulfanyl]-4-(4-methylphenyl)-1,2,4-triazol-3-yl]phenyl]-2-methylquinazolin-4-one 139447-68-0 C48H34Br2N10O2S
    6-bromo-3-[4-[5-[[5-[4-(6-bromo-2-methyl-4-oxoquinazolin-3-yl)phenyl]-4-(4-methylphenyl)-1,2,4-triazol-3-yl]sulfanyl]-4-(4-methylphenyl)-1,2,4-triazol-3-yl]phenyl]-2-methylquinazolin-4-one
    —— 4-[4-(4-methyl-anilino)-6-phenylsulfanyl-[1,3,5]triazin-2-ylamino]-benzoic acid 62692-98-2 C23H19N5O2S
    4-[4-(4-methyl-anilino)-6-phenylsulfanyl-[1,3,5]triazin-2-ylamino]-benzoic acid
    —— 5-chloro-6-methylsulfanyl-3-phenyl-3<i>H</i>-pyrimidin-4-one 59750-47-9 C11H9ClN2OS
    5-chloro-6-methylsulfanyl-3-phenyl-3<i>H</i>-pyrimidin-4-one
    —— 1,3,5-tris(3-methoxyphenylthio)benzene 1609653-60-2 C27H24O3S3
    1,3,5-tris(3-methoxyphenylthio)benzene
    —— (R,Z)-4-phenylthiopent-2-en-1-yl acetate 1384834-22-3 C13H16O2S
    (R,Z)-4-phenylthiopent-2-en-1-yl acetate
    —— 1416465-62-7 C16H23BF2O2S
    —— 4-methyl-2-nonylsulfanyl-1(3)<i>H</i>-imidazole 50968-34-8 C13H24N2S
    4-methyl-2-nonylsulfanyl-1(3)<i>H</i>-imidazole
    —— Pyridin-3-carbaldehyd-(2-methylmercapto-phenylimin) 31183-74-1 C13H12N2S
    Pyridin-3-carbaldehyd-(2-methylmercapto-phenylimin)
    —— 16,31,50-Trimethyl-2,28-dithia-13,17,30,34,47,51,52,53-octazatetracyclo[46.3.1.113,17.129,33]tetrapentaconta-1(51),15,29,31,33(53),48(52),49-heptaene-14,54-dione 1336915-77-5 C47H78N8O2S2
    16,31,50-Trimethyl-2,28-dithia-13,17,30,34,47,51,52,53-octazatetracyclo[46.3.1.113,17.129,33]tetrapentaconta-1(51),15,29,31,33(53),48(52),49-heptaene-14,54-dione
    —— 3-(3-(cyclopentylmethylthio)phenyl)prop-2-yn-1-amine 1215075-23-2 C15H19NS
    3-(3-(cyclopentylmethylthio)phenyl)prop-2-yn-1-amine
    —— 2-((2S,3S)-5-Oxo-2-p-tolylsulfanyl-tetrahydro-furan-3-yl)-2-(3-trimethylsilanyl-prop-2-ynyl)-malonic acid diethyl ester 112373-68-9 C24H32O6SSi
    2-((2S,3S)-5-Oxo-2-p-tolylsulfanyl-tetrahydro-furan-3-yl)-2-(3-trimethylsilanyl-prop-2-ynyl)-malonic acid diethyl ester
    —— 4a-Methoxy-4a,5,6,7,8,8a-hexahydro-benzo[b][1,3]dithiolo[4,5-e][1,4]dithiine-2-thione 119406-79-0 C10H12OS5
    4a-Methoxy-4a,5,6,7,8,8a-hexahydro-benzo[b][1,3]dithiolo[4,5-e][1,4]dithiine-2-thione
    —— 1,3-bis(p-bromophenylthio)adamantane 1373329-73-7 C22H22Br2S2
    1,3-bis(p-bromophenylthio)adamantane
    —— 8-(ethylthio)-1-octen-6-yne 149083-32-9 C10H16S
    8-(ethylthio)-1-octen-6-yne
    —— 1-(1-Undecyl)-2-(4-fluorobenzylthio)-5-(2-ethoxypyrimid-5-ylmethyl)pyrimidin-4-one 224773-33-5 C29H39FN4O2S
    1-(1-Undecyl)-2-(4-fluorobenzylthio)-5-(2-ethoxypyrimid-5-ylmethyl)pyrimidin-4-one
    —— N,N''-<dithiobis(3,1-propanediyl)>bis-1,5-pentanediamine tetrahydrochloride 80685-95-6 C16H38N4S2*4ClH
    N,N''-<dithiobis(3,1-propanediyl)>bis-1,5-pentanediamine tetrahydrochloride
    —— 2,6-bis(propylthio)-1,4-dioxane 81712-68-7 C10H20O2S2
    2,6-bis(propylthio)-1,4-dioxane
    —— 4-bromo-3,5,6-trimethyl-2H-thiopyran-2-one 78592-38-8 C8H9BrOS
    4-bromo-3,5,6-trimethyl-2H-thiopyran-2-one
    —— [Pd(S2CNMe2)(μ-P(o-tolyl)2C6H4CH2)(μ-O2CCH3)Hg(O2CCH3)]*H2O 263412-93-7 C28H32HgNO4PPdS2*H2O
    [Pd(S2CNMe2)(μ-P(o-tolyl)2C6H4CH2)(μ-O2CCH3)Hg(O2CCH3)]*H2O
    —— N-(4-(2-((dimethylamino)methyl)-5-(5-methyl-1H-pyrazol-3-ylamino)imidazo[1,2-c]pyrimidin-7-ylthio)phenyl)cyclopropanecarboxamide 883737-21-1 C23H26N8OS
    N-(4-(2-((dimethylamino)methyl)-5-(5-methyl-1H-pyrazol-3-ylamino)imidazo[1,2-c]pyrimidin-7-ylthio)phenyl)cyclopropanecarboxamide
    —— 7-Thiomethoxy-thiochromanon 13735-15-4 C10H10OS2
    7-Thiomethoxy-thiochromanon
    —— 3-(5,6-dimethyl-2-pyrido[2,3-b]pyrazin-7-ylsulfanyl-7H-pyrrolo[2,3-d]pyrimidin-4-yl)-3-azabicyclo[3.1.0]hexan-6-amine 1275598-85-0 C20H20N8S
    3-(5,6-dimethyl-2-pyrido[2,3-b]pyrazin-7-ylsulfanyl-7H-pyrrolo[2,3-d]pyrimidin-4-yl)-3-azabicyclo[3.1.0]hexan-6-amine
    —— 1-((E)-4-Phenyl-1-phenylsulfanyl-but-1-enyl)-cyclohexanol 104367-25-1 C22H26OS
    1-((E)-4-Phenyl-1-phenylsulfanyl-but-1-enyl)-cyclohexanol
    —— 1,2-Dimethyl-3-methylmercapto-4-cyan-pyrazolon-(5) 89853-59-8 C7H9N3OS
    1,2-Dimethyl-3-methylmercapto-4-cyan-pyrazolon-(5)
    —— (E)-3-Prop-2-ynylsulfanyl-hept-2-enenitrile 41727-27-9 C10H13NS
    (E)-3-Prop-2-ynylsulfanyl-hept-2-enenitrile
    —— 2-[2-chloro-4-(methylthio)phenyl]-3,7-dimethyl-5-(1-methylbutyl)pyrrolo[2,1-f][1,2,4]triazin-4(3H)-one 1079352-31-0 C20H24ClN3OS
    2-[2-chloro-4-(methylthio)phenyl]-3,7-dimethyl-5-(1-methylbutyl)pyrrolo[2,1-f][1,2,4]triazin-4(3H)-one
    —— (2S)-3-(methoxymethoxy)-1,1-bis[(4-methylphenyl)sulfanyl]propan-2-ol 102712-79-8 C19H24O3S2
    (2S)-3-(methoxymethoxy)-1,1-bis[(4-methylphenyl)sulfanyl]propan-2-ol
    —— methyl (Z)-3-phenylthio-1-cyclobutanecarboxylate 89945-45-9 C12H14O2S
    methyl (Z)-3-phenylthio-1-cyclobutanecarboxylate
    —— dimethyl 3,5-trans-diphenylcyclohexanespiro-2'-thidane-4,4-dicarboxylate 81794-24-3 C24H26O4S2
    dimethyl 3,5-trans-diphenylcyclohexanespiro-2'-thidane-4,4-dicarboxylate
    —— cis-3-Acetoxy-4-methyl-1-(phenylthio)cyclohexene 90083-93-5 C15H18O2S
    cis-3-Acetoxy-4-methyl-1-(phenylthio)cyclohexene
    —— 4-cyclopentylamino-6-methyl-2-methylsulfanyl-pyrimidine-5-carbaldehyde 1013101-76-2 C12H17N3OS
    4-cyclopentylamino-6-methyl-2-methylsulfanyl-pyrimidine-5-carbaldehyde
    —— 1,3-Dimethyl-5-carboxymethylthio-6-aminouracil 90091-31-9 C8H11N3O4S
    1,3-Dimethyl-5-carboxymethylthio-6-aminouracil
    —— (3,4,5-trifluorophenyl)-2,3-dichlorophenylsulfide 1229514-37-7 C12H5Cl2F3S
    (3,4,5-trifluorophenyl)-2,3-dichlorophenylsulfide
    —— 3,9-di(tetrahydropyranyl)oxy-7-oxotetradecanal-7-propylenedithioketal 108400-91-5 C27H48O5S2
    3,9-di(tetrahydropyranyl)oxy-7-oxotetradecanal-7-propylenedithioketal
    —— 5-methylsulfanyl-thiophene-2-carbaldehyde thiosemicarbazone 100524-22-9 C7H9N3S3
    5-methylsulfanyl-thiophene-2-carbaldehyde thiosemicarbazone
    —— S-pyridin-2-yl 11-azidoundecanethioate 118162-54-2 C16H24N4OS
    S-pyridin-2-yl 11-azidoundecanethioate
    —— 16066-83-4 C16H32N2O2S
    —— 5-[2-(3-Chlorophenyl)sulfanylethyl]-2-(2,6-diethyl-4-methylphenyl)-3-hydroxycyclohex-2-en-1-one 1415577-20-6 C25H29ClO2S
    5-[2-(3-Chlorophenyl)sulfanylethyl]-2-(2,6-diethyl-4-methylphenyl)-3-hydroxycyclohex-2-en-1-one