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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (3R)-3-t-butyldimethylsilyloxy-1-(phenylthio)-1-butene 120787-38-4 C16H26OSSi
    (3R)-3-t-butyldimethylsilyloxy-1-(phenylthio)-1-butene
    —— 1,6-Dibutylmercaptohexan 13344-04-2 C14H30S2
    1,6-Dibutylmercaptohexan
    —— O-ethyl S-1-methoxyhexane-3-yl carbonothioate 1241905-19-0 C10H20O3S
    O-ethyl S-1-methoxyhexane-3-yl carbonothioate
    —— Benzene, 1-methyl-4-[[2-phenyl-1-(phenylthio)ethenyl]thio]-, (E)- 104411-47-4 C21H18S2
    Benzene, 1-methyl-4-[[2-phenyl-1-(phenylthio)ethenyl]thio]-, (E)-
    —— 11-(2-hexyl-[1,3]dithian-2-yl)-1-(tert-butyldimethylsiloxy)undec-4-yne 386742-86-5 C27H52OS2Si
    11-(2-hexyl-[1,3]dithian-2-yl)-1-(tert-butyldimethylsiloxy)undec-4-yne
    —— 2-(1-pyrrolidinyl)-3-phenylthiopropionitrile 111248-41-0 C13H16N2S
    2-(1-pyrrolidinyl)-3-phenylthiopropionitrile
    —— (6-isopropylsulfanylpyridin-2-yl)methanol 1609289-20-4 C9H13NOS
    (6-isopropylsulfanylpyridin-2-yl)methanol
    —— 1,11-bis[3-(pyrid-3-yl)-1,2,5-thiadiazol-4-ylthio]undecane 390800-00-7 C25H30N6S4
    1,11-bis[3-(pyrid-3-yl)-1,2,5-thiadiazol-4-ylthio]undecane
    —— 3-hydroxy-2'-nitrodiphenyl sulphide 76039-59-3 C12H9NO3S
    3-hydroxy-2'-nitrodiphenyl sulphide
    —— Tetraethyl sulfanediyldibenzene-4,1-diyl bis(phosphate) 19875-86-6 C20H28O8P2S
    Tetraethyl sulfanediyldibenzene-4,1-diyl bis(phosphate)
    —— 2,5,2',5'-tetra(dimethylaminemethylene)bis(4-hydroxyphenyl)sulfide 912474-60-3 C24H38N4O2S
    2,5,2',5'-tetra(dimethylaminemethylene)bis(4-hydroxyphenyl)sulfide
    —— Tert-butyl [4-[4-[(2-methylpropan-2-yl)oxycarbonyloxy]phenyl]sulfanylphenyl] carbonate 138888-97-8 C22H26O6S
    Tert-butyl [4-[4-[(2-methylpropan-2-yl)oxycarbonyloxy]phenyl]sulfanylphenyl] carbonate
    —— 4,4'-thiodiphenyl dipropiolate 117583-42-3 C18H10O4S
    4,4'-thiodiphenyl dipropiolate
    —— 1,1,3,3-tetramethyl-2-(thiocarbonyl)cyclohexane S-oxide 63702-87-4 C11H18OS
    1,1,3,3-tetramethyl-2-(thiocarbonyl)cyclohexane S-oxide
    —— 2-hydroxy-3-[4-({4-[2-hydroxy-3-(prop-2-enoyloxy)propoxy]phenyl}sulfanyl)phenoxy]propyl prop-2-enoate 1238889-15-0 C24H26O8S
    2-hydroxy-3-[4-({4-[2-hydroxy-3-(prop-2-enoyloxy)propoxy]phenyl}sulfanyl)phenoxy]propyl prop-2-enoate
    —— 2,2'-dimethylaminemethylenebis(4-hydroxyphenyl)sulfide 912474-40-9 C18H24N2O2S
    2,2'-dimethylaminemethylenebis(4-hydroxyphenyl)sulfide
    —— thiobis(4,1-phenylene) diacetate 63449-96-7 C16H14O4S
    thiobis(4,1-phenylene) diacetate
    —— 2,3,5,6,8,10-Hexathiaundecane 423765-80-4 C5H12S6
    2,3,5,6,8,10-Hexathiaundecane
    —— 2,6,2',6'-tetrabromo-4,4'-sulfanediyl-di-phenol 40654-51-1 C12H6Br4O2S
    2,6,2',6'-tetrabromo-4,4'-sulfanediyl-di-phenol
    —— 4,4'-bis-(Tributylstannoxy)-diphenylsulfide 68963-84-8 C36H62O2SSn2
    4,4'-bis-(Tributylstannoxy)-diphenylsulfide
    —— 8-Isothiocyanatooctan-1-ol 1037167-37-5 C9H17NOS
    8-Isothiocyanatooctan-1-ol
    —— 4,4'-thiodiphenol diallyl ether 99873-56-0 C18H18O2S
    4,4'-thiodiphenol diallyl ether
    —— (3Z,7Z,9Z)-7,10-Bis-(2-trimethylsilanyl-ethylsulfanyl)-trideca-1,3,7,9-tetraene-5,11-diyne 218444-55-4 C23H36S2Si2
    (3Z,7Z,9Z)-7,10-Bis-(2-trimethylsilanyl-ethylsulfanyl)-trideca-1,3,7,9-tetraene-5,11-diyne
    —— tetrakis(2,6-di-t-butyl-4-methylphenyl) 4,4'-thiobisphenyl diphosphite 104082-83-9 C72H100O6P2S
    tetrakis(2,6-di-t-butyl-4-methylphenyl) 4,4'-thiobisphenyl diphosphite
    —— bis(4-(benzyloxy)phenyl)sulfane 98985-98-9 C26H22O2S
    bis(4-(benzyloxy)phenyl)sulfane
    —— 3-(1-Ethyl-1-methyl-pentyl)-6-methylsulfanyl-[1,2,4,5]tetrazine 159801-94-2 C11H20N4S
    3-(1-Ethyl-1-methyl-pentyl)-6-methylsulfanyl-[1,2,4,5]tetrazine
    —— (heptane-1-sulfinyl)-ethene 21961-09-1 C9H18OS
    (heptane-1-sulfinyl)-ethene
    —— 2-methylthio-6-[(1'-carboxyethyl)methan-1'-yl]-4(3H)-pyrimidinone 251347-70-3 C9H12N2O3S
    2-methylthio-6-[(1'-carboxyethyl)methan-1'-yl]-4(3H)-pyrimidinone
    —— 2,6,2',6'-tetrachloro-4,4'-sulfanediyl-di-phenol 51543-47-6 C12H6Cl4O2S
    2,6,2',6'-tetrachloro-4,4'-sulfanediyl-di-phenol
    —— Propenyldithioacetat 67230-78-8 C5H8S2
    Propenyldithioacetat
    —— dithiopropionic acid prop-2-ynyl ester 41830-44-8 C6H8S2
    dithiopropionic acid prop-2-ynyl ester
    —— tributyl-[3-(4-methylphenyl)sulfanylprop-1-enyl]stannane 155197-76-5 C22H38SSn
    tributyl-[3-(4-methylphenyl)sulfanylprop-1-enyl]stannane
    —— 2-methylthio-6-[(2'-hydroxy)ethan-1'-yl]-4(3H)-pyrimidinone 251347-72-5 C7H10N2O2S
    2-methylthio-6-[(2'-hydroxy)ethan-1'-yl]-4(3H)-pyrimidinone
    —— N-(2,5-Dimethyl-2H-pyrazol-3-yl)-2-{3-[1-hydroxy-meth-(Z)-ylidene]-2-oxo-2,3-dihydro-1H-indol-6-ylsulfanyl}-benzamide 919103-52-9 C21H18N4O3S
    N-(2,5-Dimethyl-2H-pyrazol-3-yl)-2-{3-[1-hydroxy-meth-(Z)-ylidene]-2-oxo-2,3-dihydro-1H-indol-6-ylsulfanyl}-benzamide
    —— 4-allylsulfanyl-3-methyl-4-methylsulfanyl-pent-1-ene 62418-91-1 C10H18S2
    4-allylsulfanyl-3-methyl-4-methylsulfanyl-pent-1-ene
    —— 4-but-2-enylsulfanyl-4-methylsulfanyl-pent-1-ene 62418-92-2 C10H18S2
    4-but-2-enylsulfanyl-4-methylsulfanyl-pent-1-ene
    —— 4-allylsulfanyl-3,3-dimethyl-4-methylsulfanyl-pent-1-ene 66312-52-5 C11H20S2
    4-allylsulfanyl-3,3-dimethyl-4-methylsulfanyl-pent-1-ene
    —— (2Z,4Z)-2,5-bis(tert-butylsulfanyl)hexa-2,4-diene-1,6-diol 186499-98-9 C14H26O2S2
    (2Z,4Z)-2,5-bis(tert-butylsulfanyl)hexa-2,4-diene-1,6-diol
    —— allyl 2-methylpropanedithioate 63881-54-9 C7H12S2
    allyl 2-methylpropanedithioate
    —— allylsulfanyl isopropyl thioketone oxide 162336-77-8 C7H12OS2
    allylsulfanyl isopropyl thioketone oxide
    —— 1-(5-amino-pyridin-2-yl)-2-[2-(dimethylamino)benzylthio]imidazole 117296-28-3 C17H19N5S
    1-(5-amino-pyridin-2-yl)-2-[2-(dimethylamino)benzylthio]imidazole
    —— ((S)-8-Azido-1,4-dithia-spiro[4.4]non-6-en-6-ylmethoxy)-tert-butyl-dimethyl-silane 154375-19-6 C14H25N3OS2Si
    ((S)-8-Azido-1,4-dithia-spiro[4.4]non-6-en-6-ylmethoxy)-tert-butyl-dimethyl-silane
    —— 4-isopropylthio-7-methyl-4-methylthio-5-(1-propen-2-yl)-1,7-octadiene —— C16H28S2
    4-isopropylthio-7-methyl-4-methylthio-5-(1-propen-2-yl)-1,7-octadiene
    —— 2,3-dibutylthiobutyraldehyde 108431-30-7 C12H24OS2
    2,3-dibutylthiobutyraldehyde
    —— 4-(4-methylsulfanylphenyl)-2H-1,2-oxazol-5-one 259543-69-6 C10H9NO2S
    4-(4-methylsulfanylphenyl)-2H-1,2-oxazol-5-one
    —— 2-n-Propyloxy-1,3-benzodithiolan 55315-54-3 C10H12OS2
    2-n-Propyloxy-1,3-benzodithiolan
    —— N-{[4-(4-methylthiophenyl)-5-oxo-2-hydroisoxazol-2-yl]methyl}acetamide 259542-29-5 C13H14N2O3S
    N-{[4-(4-methylthiophenyl)-5-oxo-2-hydroisoxazol-2-yl]methyl}acetamide
    —— {2,6-dichloro-4-[(phenylthio)methyl]pyridin-3-yl}(4-methylphenyl)methanol 607708-13-4 C20H17Cl2NOS
    {2,6-dichloro-4-[(phenylthio)methyl]pyridin-3-yl}(4-methylphenyl)methanol
    —— 9,14-diphenyl-6,7,8,9,14,15,16,17-octahydro-5,18-dithia-9,14-diphospha-dibenzo[<i>a</i>,<i>h</i>]cyclotetradecene 78339-70-5 C30H30P2S2
    9,14-diphenyl-6,7,8,9,14,15,16,17-octahydro-5,18-dithia-9,14-diphospha-dibenzo[<i>a</i>,<i>h</i>]cyclotetradecene
    —— isothiocyanic acid 1-cyclopentanecarbonyl ester 1154366-71-8 C7H9NOS
    isothiocyanic acid 1-cyclopentanecarbonyl ester