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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(6-chloro-2,3-dihydroimidazo[2,1-b][1,3]thiazol-5-yl)methylidene]hydroxylamine 83253-31-0 C6H6ClN3OS
    N-[(6-chloro-2,3-dihydroimidazo[2,1-b][1,3]thiazol-5-yl)methylidene]hydroxylamine
    —— (6-chloro-2,3-dihydroimidazo[2,1-b][1,3]thiazol-5-yl)methyl N-methylcarbamate 76919-53-4 C8H10ClN3O2S
    (6-chloro-2,3-dihydroimidazo[2,1-b][1,3]thiazol-5-yl)methyl N-methylcarbamate
    —— (6-Chloro-2,3-dihydroimidazo[2,1-b][1,3]thiazol-5-yl)methyl ethylcarbamate 76932-63-3 C9H12ClN3O2S
    (6-Chloro-2,3-dihydroimidazo[2,1-b][1,3]thiazol-5-yl)methyl ethylcarbamate
    —— (6-Methyl-2,3-dihydroimidazo[2,1-b][1,3]thiazol-5-yl)methyl ethylcarbamate 76919-59-0 C10H15N3O2S
    (6-Methyl-2,3-dihydroimidazo[2,1-b][1,3]thiazol-5-yl)methyl ethylcarbamate
    —— 2-N-(n-butylamino)cyclopentene-1-dithiocarboxylic acid S-methyl ester 91334-26-8 C11H19NS2
    2-N-(n-butylamino)cyclopentene-1-dithiocarboxylic acid S-methyl ester
    —— (6-Methyl-2,3-dihydroimidazo[2,1-b][1,3]thiazol-5-yl)methyl methylcarbamate 76919-54-5 C9H13N3O2S
    (6-Methyl-2,3-dihydroimidazo[2,1-b][1,3]thiazol-5-yl)methyl methylcarbamate
    —— N-[(6-methyl-2,3-dihydroimidazo[2,1-b][1,3]thiazol-5-yl)methylidene]hydroxylamine 83253-32-1 C7H9N3OS
    N-[(6-methyl-2,3-dihydroimidazo[2,1-b][1,3]thiazol-5-yl)methylidene]hydroxylamine
    —— 3-Methyl-2-butenyl 4-methylphenyl sulfide 123359-07-9 C12H16S
    3-Methyl-2-butenyl 4-methylphenyl sulfide
    —— β-Propylamino-cyclopenten-dithiocarbonsaeure-methylester 91140-51-1 C10H17NS2
    β-Propylamino-cyclopenten-dithiocarbonsaeure-methylester
    —— 1-ethylsulfanyl-pent-1-en-3-yne 2807-28-5 C7H10S
    1-ethylsulfanyl-pent-1-en-3-yne
    —— 2,4-bis-(hydroxymethyl)diphenyl sulfide 67666-83-5 C14H14O2S
    2,4-bis-(hydroxymethyl)diphenyl sulfide
    —— 6-hydroxy-5,7,8-trimethyl-1,4-benzoxathiin-2(3H)-one 115048-26-5 C11H12O3S
    6-hydroxy-5,7,8-trimethyl-1,4-benzoxathiin-2(3H)-one
    —— 2,4-Bis(chloromethyl)diphenylsulfid 67666-86-8 C14H12Cl2S
    2,4-Bis(chloromethyl)diphenylsulfid
    —— 2,4-bis-(carboxymethyl)diphenylsulfide 67666-89-1 C16H14O4S
    2,4-bis-(carboxymethyl)diphenylsulfide
    —— (2,2-difluoroethyl)(phenyl)sulfane 134024-36-5 C8H8F2S
    (2,2-difluoroethyl)(phenyl)sulfane
    —— 4-benzyloxy-6-ethyl-8,8-dimethyl-2-methylsulfanyl-7,8-dihydro-6H-9-oxa-1,3,6-triazabenzocyclohepten-5-one 1448987-79-8 C19H23N3O3S
    4-benzyloxy-6-ethyl-8,8-dimethyl-2-methylsulfanyl-7,8-dihydro-6H-9-oxa-1,3,6-triazabenzocyclohepten-5-one
    —— 4-chloro-6-ethyl-8,8-dimethyl-2-methylsulfanyl-7,8-dihydro-6H-9-oxa-1,3,6-triazabenzocyclohepten-5-one 1448987-72-1 C12H16ClN3O2S
    4-chloro-6-ethyl-8,8-dimethyl-2-methylsulfanyl-7,8-dihydro-6H-9-oxa-1,3,6-triazabenzocyclohepten-5-one
    —— (E,2R)-1-[2-[(2R,4E)-2-[tert-butyl(dimethyl)silyl]oxy-4-methylocta-4,7-dienyl]-1,3-dithian-2-yl]-5-methyl-7-phenylhept-5-en-2-ol 1375412-52-4 C33H54O2S2Si
    (E,2R)-1-[2-[(2R,4E)-2-[tert-butyl(dimethyl)silyl]oxy-4-methylocta-4,7-dienyl]-1,3-dithian-2-yl]-5-methyl-7-phenylhept-5-en-2-ol
    —— 3,3-Bis(ethylthio)-2-(phenylthio)acrylonitril 139427-28-4 C13H15NS3
    3,3-Bis(ethylthio)-2-(phenylthio)acrylonitril
    —— 4-chloro-6-ethyl-8,8-dimethyl-2-methylsulfanyl-6,7,8,9-tetrahydro-10-oxa-1,3,6-triazabenzocycloocten-5-one 1448987-99-2 C13H18ClN3O2S
    4-chloro-6-ethyl-8,8-dimethyl-2-methylsulfanyl-6,7,8,9-tetrahydro-10-oxa-1,3,6-triazabenzocycloocten-5-one
    —— 4,5-bis<<2-(methylthio)ethyl>thio>-1,3-dithiole-2-thione 75949-39-2 C9H14S7
    4,5-bis<<2-(methylthio)ethyl>thio>-1,3-dithiole-2-thione
    —— 2-(Ethylthio)bicyclo<2.2.1>hepta-2,5-dien 86661-00-9 C9H12S
    2-(Ethylthio)bicyclo<2.2.1>hepta-2,5-dien
    —— p-Chlorphenyl-thioisobuttersaeurechlorid 18518-82-6 C10H10Cl2OS
    p-Chlorphenyl-thioisobuttersaeurechlorid
    —— 2-Methyl-7-phenylsulfanylundec-2-en-5-yn-4-one 532390-39-9 C18H22OS
    2-Methyl-7-phenylsulfanylundec-2-en-5-yn-4-one
    —— 5-bromo-4-chloro-6-methyl-2-ethylsulfanylpyrimidine 897030-98-7 C7H8BrClN2S
    5-bromo-4-chloro-6-methyl-2-ethylsulfanylpyrimidine
    —— 5-Methyl-4-(1-methyl-prop-2-ynylsulfanyl)-1H-pyrimidin-2-one 105245-99-6 C9H10N2OS
    5-Methyl-4-(1-methyl-prop-2-ynylsulfanyl)-1H-pyrimidin-2-one
    —— 4-allylthio-5-methylpyrimidin-2(1H)-one 105173-89-5 C8H10N2OS
    4-allylthio-5-methylpyrimidin-2(1H)-one
    —— 2-Dimethylamino-3-methylthiothiohene 114143-32-7 C7H11NS2
    2-Dimethylamino-3-methylthiothiohene
    —— 5-Methyl-4-prop-2-ynylsulfanyl-1H-pyrimidin-2-one 105245-95-2 C8H8N2OS
    5-Methyl-4-prop-2-ynylsulfanyl-1H-pyrimidin-2-one
    —— 2,8-Dimethyl-3-methylene-2,3-dihydro-thiazolo[3,2-c]pyrimidin-5-one 105246-08-0 C9H10N2OS
    2,8-Dimethyl-3-methylene-2,3-dihydro-thiazolo[3,2-c]pyrimidin-5-one
    —— 4-Benzylsulfanyl-5-methyl-1H-pyrimidin-2-one 78932-27-1 C12H12N2OS
    4-Benzylsulfanyl-5-methyl-1H-pyrimidin-2-one
    —— 3-bromo-2,4,5-tris(methylthio)thiophene 152570-38-2 C7H9BrS4
    3-bromo-2,4,5-tris(methylthio)thiophene
    —— 1-amino-3-(4-chloro-phenylsulfanyl)-propan-2-ol 35550-44-8 C9H12ClNOS
    1-amino-3-(4-chloro-phenylsulfanyl)-propan-2-ol
    —— 5-bromo-2,5-bis(methylthio)thiophene 152570-32-6 C6H7BrS3
    5-bromo-2,5-bis(methylthio)thiophene
    —— 2,3-bis(methylsulfanyl)thiophene 84034-31-1 C6H8S3
    2,3-bis(methylsulfanyl)thiophene
    —— 2-bromo-3-(methylthio)thiophene 94781-39-2 C5H5BrS2
    2-bromo-3-(methylthio)thiophene
    —— 2,3-bis(methylsulfanyl)-5-(trimethylsilyl)thiophene 1031685-71-8 C9H16S3Si
    2,3-bis(methylsulfanyl)-5-(trimethylsilyl)thiophene
    —— (1-Methyl-2,5-bis-phenylsulfanyl-1H-imidazol-4-yl)-phenyl-methanol 157331-17-4 C23H20N2OS2
    (1-Methyl-2,5-bis-phenylsulfanyl-1H-imidazol-4-yl)-phenyl-methanol
    —— 5-Benzyl-4-bromo-1-methyl-2-phenylsulfanyl-1H-imidazole 157331-15-2 C17H15BrN2S
    5-Benzyl-4-bromo-1-methyl-2-phenylsulfanyl-1H-imidazole
    —— 1-amino-3-<i>p</i>-tolylsulfanyl-propan-2-ol 35550-47-1 C10H15NOS
    1-amino-3-<i>p</i>-tolylsulfanyl-propan-2-ol
    —— (E)-2-[2-(phenylthio)vinyl]thiophene 123432-00-8 C12H10S2
    (E)-2-[2-(phenylthio)vinyl]thiophene
    —— N,N'-bis(6-aminohexyl)cystamine 68536-04-9 C16H38N4S2
    N,N'-bis(6-aminohexyl)cystamine
    —— 2-Azido-4-benzo[1,3]dioxol-5-ylmethyl-1-methyl-5-phenylsulfanyl-1H-imidazole 181880-09-1 C18H15N5O2S
    2-Azido-4-benzo[1,3]dioxol-5-ylmethyl-1-methyl-5-phenylsulfanyl-1H-imidazole
    —— 4-bromo-1-methyl-2,5-bis(phenylthio)-1H-imidazole 157331-14-1 C16H13BrN2S2
    4-bromo-1-methyl-2,5-bis(phenylthio)-1H-imidazole
    —— (4-dimethylamino-but-2-ynyl)-thiourea 59961-50-1 C7H13N3S
    (4-dimethylamino-but-2-ynyl)-thiourea
    —— N,N'-bis(ω-aminoheptyl)cystamine 77799-83-8 C18H42N4S2
    N,N'-bis(ω-aminoheptyl)cystamine
    —— 2-[2-(4-Methylphenyl)sulfanylethynyl]thiophene 1384843-87-1 C13H10S2
    2-[2-(4-Methylphenyl)sulfanylethynyl]thiophene
    —— 2,6-dimethyl-3-methylthiopyridine 1-oxide 116651-86-6 C8H11NOS
    2,6-dimethyl-3-methylthiopyridine 1-oxide
    —— 1-methyl-2,5-diphenylthio-1H-imidazole 146744-53-8 C16H14N2S2
    1-methyl-2,5-diphenylthio-1H-imidazole
    —— 1,3-dihydro-3-p-methylthiophenyl-6-methyl-7-hydroxy-furo-[3,4-c]-pyridine 96908-97-3 C15H15NO2S
    1,3-dihydro-3-p-methylthiophenyl-6-methyl-7-hydroxy-furo-[3,4-c]-pyridine