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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— ethyl 2-benzyl-4-phenylthiobut-2-enoate 86895-85-4 C19H20O2S
    ethyl 2-benzyl-4-phenylthiobut-2-enoate
    —— rac.-Adamantyl-(1)-methylsulfoxid 34895-43-7 C11H18OS
    rac.-Adamantyl-(1)-methylsulfoxid
    —— Methyl (R,S)-2-(isopropylsulfinyl)ethanedithioate 188847-56-5 C6H12OS3
    Methyl (R,S)-2-(isopropylsulfinyl)ethanedithioate
    —— Methyl (R,S)-2-(cyclohexylsulfinyl)ethanedithioate 188847-57-6 C9H16OS3
    Methyl (R,S)-2-(cyclohexylsulfinyl)ethanedithioate
    —— 1-(2-Methyl-1,3-dithian-2-yl)-1-phenyl-2-propen-1-ol 68984-53-2 C14H18OS2
    1-(2-Methyl-1,3-dithian-2-yl)-1-phenyl-2-propen-1-ol
    —— 1-<2-(4-fluorophenylthio)ethyl>piperazine 70931-42-9 C12H17FN2S
    1-<2-(4-fluorophenylthio)ethyl>piperazine
    —— 2-(4a-hydroxybenzyl)-2-methyl-1,3-dithiane 78349-00-5 C12H16OS2
    2-(4a-hydroxybenzyl)-2-methyl-1,3-dithiane
    —— 1-(2-phenylthioethyl)piperazine 73446-34-1 C12H18N2S
    1-(2-phenylthioethyl)piperazine
    —— 3-[2-(2-methyl-1,3-dithianyl)]-cyclohexanone 68984-52-1 C11H18OS2
    3-[2-(2-methyl-1,3-dithianyl)]-cyclohexanone
    —— (3-Carboxyphenyl)[2-nitro-4-(E-((4-acetylpiperazin-1-yl)carbonyl)ethenyl)phenyl]sulfide 1055911-51-7 C22H21N3O6S
    (3-Carboxyphenyl)[2-nitro-4-(E-((4-acetylpiperazin-1-yl)carbonyl)ethenyl)phenyl]sulfide
    —— 1-[2-(2-methyl-1,3-dithianyl)]-2-cyclohexen-1-ol 15040-92-3 C11H18OS2
    1-[2-(2-methyl-1,3-dithianyl)]-2-cyclohexen-1-ol
    —— 2-Methyl-2-vinyl-1,3-dithian 64087-39-4 C7H12S2
    2-Methyl-2-vinyl-1,3-dithian
    —— [(2R)-1-(2-methyl-1,3-dithian-2-yl)-4-(trimethylsilylmethyl)pent-4-en-2-yl] 2,2-dimethylpropanoate 233750-54-4 C19H36O2S2Si
    [(2R)-1-(2-methyl-1,3-dithian-2-yl)-4-(trimethylsilylmethyl)pent-4-en-2-yl] 2,2-dimethylpropanoate
    —— (4R,5S)-(-)-4-Ethyl-2,2-dimethyl-5-<3-(2-methyl-1,3-dithian-2-yl)propyl>-1,3-dioxolane 149818-50-8 C15H28O2S2
    (4R,5S)-(-)-4-Ethyl-2,2-dimethyl-5-<3-(2-methyl-1,3-dithian-2-yl)propyl>-1,3-dioxolane
    —— 3-(2-methyl-[1,3]dithian-2-yl)-5-oxo-cyclohex-3-enecarboxylic acid isobutyl ester 60891-21-6 C16H24O3S2
    3-(2-methyl-[1,3]dithian-2-yl)-5-oxo-cyclohex-3-enecarboxylic acid isobutyl ester
    —— 2-(phenylthio)-1H-imidazole 173416-54-1 C9H8N2S
    2-(phenylthio)-1H-imidazole
    —— 1,3-bis(ethoxycarbonyldithio)propane 202270-73-3 C9H16O4S4
    1,3-bis(ethoxycarbonyldithio)propane
    —— 6-fluorobenzo<b>thiophen-2<3H>-one 70931-82-7 C8H5FOS
    6-fluorobenzo<b>thiophen-2<3H>-one
    —— 1,2-bis(ethoxycarbonyldithio)ethane 42777-12-8 C8H14O4S4
    1,2-bis(ethoxycarbonyldithio)ethane
    —— 3,6-Dibrom-2,5-N,N'-dicyanodiimin-2,5-dihydrothieno<3,2-b>thiophen 125594-18-5 C8Br2N4S2
    3,6-Dibrom-2,5-N,N'-dicyanodiimin-2,5-dihydrothieno<3,2-b>thiophen
    —— 6-chloro-3-{2-[(2-methyl-5-nitrophenyl)thio]-1,3-thiazol-4-yl}imidazo[1,2-a]pyridine 372198-16-8 C17H11ClN4O2S2
    6-chloro-3-{2-[(2-methyl-5-nitrophenyl)thio]-1,3-thiazol-4-yl}imidazo[1,2-a]pyridine
    —— 1,3-dimethyl-1,3-diaza-6,9,12,15-tetraoxa-2-cycloheptadecanethione 100890-91-3 C13H26N2O4S
    1,3-dimethyl-1,3-diaza-6,9,12,15-tetraoxa-2-cycloheptadecanethione
    —— 6,9,12,15-tetraoxa-1,3-diazacycloheptadecane-2-thione 82718-54-5 C11H22N2O4S
    6,9,12,15-tetraoxa-1,3-diazacycloheptadecane-2-thione
    —— (6-thioxo-2,4-cyclohexadien-1-ylidene)methanone 75126-75-9 C7H4OS
    (6-thioxo-2,4-cyclohexadien-1-ylidene)methanone
    —— 4-(4-methoxy-7<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-yl)-aniline 21576-25-0 C13H12N4OS
    4-(4-methoxy-7<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-yl)-aniline
    —— 1,9,17-trithia-[2.2.2]orthocyclophane-2,10,18-trione 39264-06-7 C21H12O3S3
    1,9,17-trithia-[2.2.2]orthocyclophane-2,10,18-trione
    —— 4H-1,3-benzodithiin-4-one 1034249-74-5 C8H6OS2
    4H-1,3-benzodithiin-4-one
    —— 5,5'-disulfanediyldipentan-1-amine 15919-44-5 C10H24N2S2
    5,5'-disulfanediyldipentan-1-amine
    —— 6-(4-amino-phenyl)-4-methyl-7<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-2-ylamine 21576-23-8 C13H13N5S
    6-(4-amino-phenyl)-4-methyl-7<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-2-ylamine
    —— 3-(phenylthio)-2-methylenepropanal 86531-03-5 C10H10OS
    3-(phenylthio)-2-methylenepropanal
    —— 2,3-Dihydro-9-phenylthio-1H-pyrrolo[1,2-a]indol-1-one 143612-31-1 C17H13NOS
    2,3-Dihydro-9-phenylthio-1H-pyrrolo[1,2-a]indol-1-one
    —— 3-(phenylthio)-2-methylenepropionaldehyde diethyl acetal 401893-44-5 C14H20O2S
    3-(phenylthio)-2-methylenepropionaldehyde diethyl acetal
    —— 4-hydroxymethyl-2-(3,4,4-trifluoro-3-butenylthio)oxazole 359631-10-0 C8H8F3NO2S
    4-hydroxymethyl-2-(3,4,4-trifluoro-3-butenylthio)oxazole
    —— β-phenylthio-2,3-O-isopropylidene-D-ribofuranose 153362-34-6 C14H18O4S
    β-phenylthio-2,3-O-isopropylidene-D-ribofuranose
    —— 3-<4-(1-(methoxymethyl)-1H-2-(phenylthio)imidazol-5-yl)-2,5-dioxo-2,5-dihydro-1H-pyrrol-3-yl>indole 219817-92-2 C23H18N4O3S
    3-<4-(1-(methoxymethyl)-1H-2-(phenylthio)imidazol-5-yl)-2,5-dioxo-2,5-dihydro-1H-pyrrol-3-yl>indole
    —— (2RS,3SR)-ethyl N-<3-hydroxy-2-methyl-3-<1-(phenylthio)cyclohexyl>propyl>carbamate 127940-94-7 C19H29NO3S
    (2RS,3SR)-ethyl N-<3-hydroxy-2-methyl-3-<1-(phenylthio)cyclohexyl>propyl>carbamate
    —— 4-methoxymethyl-2-(3,4,4-trifluoro-3-butenylthio)oxazole 359631-11-1 C9H10F3NO2S
    4-methoxymethyl-2-(3,4,4-trifluoro-3-butenylthio)oxazole
    —— 2-Propan-2-ylsulfanyl-3-(2,2,2-trifluoroethoxy)pyridine 256473-05-9 C10H12F3NOS
    2-Propan-2-ylsulfanyl-3-(2,2,2-trifluoroethoxy)pyridine
    —— 1-<(benzyloxy)methyl>-6-(phenylthio)thymine 132774-43-7 C19H18N2O3S
    1-<(benzyloxy)methyl>-6-(phenylthio)thymine
    —— 5-({[4-(Butylsulfanyl)phenyl]sulfanyl}methyl)pyrimidine-2,4(1H,3H)-dione 89000-14-6 C15H18N2O2S2
    5-({[4-(Butylsulfanyl)phenyl]sulfanyl}methyl)pyrimidine-2,4(1H,3H)-dione
    —— 1,3-diaza-2-oxophenothiazine —— C10H7N3OS
    1,3-diaza-2-oxophenothiazine
    —— 4-methylthiomethyl-2-(3,4,4-trifluoro-3-butenylthio)oxazole 359631-13-3 C9H10F3NOS2
    4-methylthiomethyl-2-(3,4,4-trifluoro-3-butenylthio)oxazole
    —— 4,4'-bis(chloromethyl)diphenyl sulfide 1216-02-0 C14H12Cl2S
    4,4'-bis(chloromethyl)diphenyl sulfide
    —— 5-{[(Pyridin-2-yl)sulfanyl]methyl}pyrimidine-2,4(1H,3H)-dione 89000-16-8 C10H9N3O2S
    5-{[(Pyridin-2-yl)sulfanyl]methyl}pyrimidine-2,4(1H,3H)-dione
    —— 6-{[(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-5-yl)methyl]thio}-1,2,4-triazine-3,5(2H,4H)-dione 301208-18-4 C8H7N5O4S
    6-{[(2,4-dioxo-1,2,3,4-tetrahydropyrimidin-5-yl)methyl]thio}-1,2,4-triazine-3,5(2H,4H)-dione
    —— 5-(4-bromophenylthiomethyl)uracil 89000-17-9 C11H9BrN2O2S
    5-(4-bromophenylthiomethyl)uracil
    —— 5-({[4-(Dimethylamino)phenyl]sulfanyl}methyl)pyrimidine-2,4(1H,3H)-dione 89000-15-7 C13H15N3O2S
    5-({[4-(Dimethylamino)phenyl]sulfanyl}methyl)pyrimidine-2,4(1H,3H)-dione
    —— 5-({[4-(Methylsulfanyl)phenyl]sulfanyl}methyl)pyrimidine-2,4(1H,3H)-dione 89000-13-5 C12H12N2O2S2
    5-({[4-(Methylsulfanyl)phenyl]sulfanyl}methyl)pyrimidine-2,4(1H,3H)-dione
    —— 5-{[(4-Fluorophenyl)sulfanyl]methyl}pyrimidine-2,4(1H,3H)-dione 89000-10-2 C11H9FN2O2S
    5-{[(4-Fluorophenyl)sulfanyl]methyl}pyrimidine-2,4(1H,3H)-dione
    —— 2-[2-(4-chlorophenylsulfanyl)prop-2-enyl]-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide 1000809-06-2 C14H18ClO3PS
    2-[2-(4-chlorophenylsulfanyl)prop-2-enyl]-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide