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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-chloro-4-aminophenyl phenethyl sulfide hydrochloride 80019-85-8 C14H14ClNS*ClH
    2-chloro-4-aminophenyl phenethyl sulfide hydrochloride
    —— 1-(2-Methyl-1,3-dithian-2-yl)butan-1-one 121829-97-8 C9H16OS2
    1-(2-Methyl-1,3-dithian-2-yl)butan-1-one
    —— 2-chloro-3-(2-methyl-1,3-dithian-2-yl)pyrazine 1131041-56-9 C9H11ClN2S2
    2-chloro-3-(2-methyl-1,3-dithian-2-yl)pyrazine
    —— 2-methyl-2-(3'-methacrylate of propyl-1')-1,3-dithiane 211873-56-2 C12H20O2S2
    2-methyl-2-(3'-methacrylate of propyl-1')-1,3-dithiane
    —— syn-2-methyl-2-crotyl-1,3-dithiane 1-oxide 128062-26-0 C9H14O2S2
    syn-2-methyl-2-crotyl-1,3-dithiane 1-oxide
    —— (+/-)-2-(S)-propanoyl-2-methyl-1,3-dithiane 1-(R)-oxide 124004-42-8 C8H14O2S2
    (+/-)-2-(S)-propanoyl-2-methyl-1,3-dithiane 1-(R)-oxide
    —— 1-(2-Methyl-1,3-dithian-2-yl)-1-pyridin-4-ylethanol 936231-51-5 C12H17NOS2
    1-(2-Methyl-1,3-dithian-2-yl)-1-pyridin-4-ylethanol
    —— (2R)-1-[2-[(2S)-2-[tert-butyl(dimethyl)silyl]oxy-3-(2-methyl-1,3-dithian-2-yl)propyl]-1,3-dithian-2-yl]pent-4-en-2-ol 1431375-84-6 C23H44O2S4Si
    (2R)-1-[2-[(2S)-2-[tert-butyl(dimethyl)silyl]oxy-3-(2-methyl-1,3-dithian-2-yl)propyl]-1,3-dithian-2-yl]pent-4-en-2-ol
    —— trimethyl-[(1S,2R)-2-[(2S)-oxiran-2-yl]-1-phenylsulfanylpropyl]silane 1217293-22-5 C14H22OSSi
    trimethyl-[(1S,2R)-2-[(2S)-oxiran-2-yl]-1-phenylsulfanylpropyl]silane
    —— 6,6-Dimethyl-8-phenyl-7-oxa-1,4-dithia-spiro[4.4]non-8-ene 82448-31-5 C14H16OS2
    6,6-Dimethyl-8-phenyl-7-oxa-1,4-dithia-spiro[4.4]non-8-ene
    —— (2S)-1-[2-[tert-butyl(dimethyl)silyl]-1,3-dithian-2-yl]-3-(2-methyl-1,3-dithian-2-yl)propan-2-ol 875208-34-7 C18H36OS4Si
    (2S)-1-[2-[tert-butyl(dimethyl)silyl]-1,3-dithian-2-yl]-3-(2-methyl-1,3-dithian-2-yl)propan-2-ol
    —— 2-(((4-chlorophenyl)thio)methyl)pyridine, hydrochloride 81851-02-7 C12H10ClNS*ClH
    2-(((4-chlorophenyl)thio)methyl)pyridine, hydrochloride
    —— trimethyl-[(1R,2R)-2-[(2S)-oxiran-2-yl]-1-phenylsulfanylpropyl]silane 1217293-21-4 C14H22OSSi
    trimethyl-[(1R,2R)-2-[(2S)-oxiran-2-yl]-1-phenylsulfanylpropyl]silane
    —— 1-(3-Ethylphenyl)-1-(2-methyl-1,3-dithian-2-yl)ethanol 936231-65-1 C15H22OS2
    1-(3-Ethylphenyl)-1-(2-methyl-1,3-dithian-2-yl)ethanol
    —— 1-(2-Methyl-1,3-dithian-2-yl)-1-pyridin-3-ylethanol 936231-50-4 C12H17NOS2
    1-(2-Methyl-1,3-dithian-2-yl)-1-pyridin-3-ylethanol
    —— trimethyl-[(1S)-2-[(2S)-oxiran-2-yl]-1-phenylsulfanylethyl]silane 1217293-20-3 C13H20OSSi
    trimethyl-[(1S)-2-[(2S)-oxiran-2-yl]-1-phenylsulfanylethyl]silane
    —— 2-(2-Methyl-1,3-dithian-2-yl)butan-2-ol 936231-46-8 C9H18OS2
    2-(2-Methyl-1,3-dithian-2-yl)butan-2-ol
    —— trimethyl-[(1R)-2-[(2S)-oxiran-2-yl]-1-phenylsulfanylethyl]silane 1217293-19-0 C13H20OSSi
    trimethyl-[(1R)-2-[(2S)-oxiran-2-yl]-1-phenylsulfanylethyl]silane
    —— (Z)-methyl 2-phenylthiohex-2-enoate 86895-74-1 C13H16O2S
    (Z)-methyl 2-phenylthiohex-2-enoate
    —— 2-[(5-Phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]cyclohexan-1-one 81556-01-6 C14H14N2O2S
    2-[(5-Phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]cyclohexan-1-one
    —— 1-(Cyclopenten-1-yl)-1-(2-methyl-1,3-dithian-2-yl)ethanol 936231-49-1 C12H20OS2
    1-(Cyclopenten-1-yl)-1-(2-methyl-1,3-dithian-2-yl)ethanol
    —— tert-butyl-dimethyl-[(2R)-1-(2-methyl-1,3-dithian-2-yl)-3-[2-[(R)-(2-prop-2-enylphenyl)-trimethylsilyloxymethyl]-1,3-dithian-2-yl]propan-2-yl]oxysilane 1073174-90-9 C31H54O2S4Si2
    tert-butyl-dimethyl-[(2R)-1-(2-methyl-1,3-dithian-2-yl)-3-[2-[(R)-(2-prop-2-enylphenyl)-trimethylsilyloxymethyl]-1,3-dithian-2-yl]propan-2-yl]oxysilane
    —— 2-(1-hydroxybutyl)-2-methyl-1,3-dithiane 74637-04-0 C9H18OS2
    2-(1-hydroxybutyl)-2-methyl-1,3-dithiane
    —— (3aR,7aR)-N-[(R)-(2-methyl-1,3-dithian-2-yl)-phenylmethyl]-2-oxo-1,3-di(propan-2-yl)-3a,4,5,6,7,7a-hexahydrobenzo[d][1,3,2]diazaphosphol-2-amine 1281867-98-8 C24H40N3OPS2
    (3aR,7aR)-N-[(R)-(2-methyl-1,3-dithian-2-yl)-phenylmethyl]-2-oxo-1,3-di(propan-2-yl)-3a,4,5,6,7,7a-hexahydrobenzo[d][1,3,2]diazaphosphol-2-amine
    —— 1-hexanedithioic acid 39157-91-0 C6H12S2
    1-hexanedithioic acid
    —— 2-[2-(1-adamantyl)ethyl]-2-methyl-1,3-dithiane 827584-95-2 C17H28S2
    2-[2-(1-adamantyl)ethyl]-2-methyl-1,3-dithiane
    —— 5-Methyl-benzo[1,4,2]dithiazine 82946-23-4 C8H7NS2
    5-Methyl-benzo[1,4,2]dithiazine
    —— 1,1-bis-ethylsulfanyl-3,3-dimethyl-butan-2-one 51718-48-0 C10H20OS2
    1,1-bis-ethylsulfanyl-3,3-dimethyl-butan-2-one
    —— 3-Amino-5-<(carbamoyl)methylthio>-4-(phenylthio)-2-thiophencarbonsaeureamid 139427-39-7 C13H13N3O2S3
    3-Amino-5-<(carbamoyl)methylthio>-4-(phenylthio)-2-thiophencarbonsaeureamid
    —— 8-Methyl-benzo[1,4,2]dithiazine 82946-22-3 C8H7NS2
    8-Methyl-benzo[1,4,2]dithiazine
    —— 7-Methyl-benzo[1,4,2]dithiazine 82946-24-5 C8H7NS2
    7-Methyl-benzo[1,4,2]dithiazine
    —— N-(phenylthiomethyl)succinimide 68716-57-4 C11H11NO2S
    N-(phenylthiomethyl)succinimide
    —— 5-hydroxy-1-(phenylthiomethyl)pyrrolidin-2-one 863393-78-6 C11H13NO2S
    5-hydroxy-1-(phenylthiomethyl)pyrrolidin-2-one
    —— 6-Chloro-benzo[1,4,2]dithiazine 82946-27-8 C7H4ClNS2
    6-Chloro-benzo[1,4,2]dithiazine
    —— 6-Methyl-benzo[1,4,2]dithiazine 82946-25-6 C8H7NS2
    6-Methyl-benzo[1,4,2]dithiazine
    —— 1-[5-(4-Chloro-phenyl)-[1,3,4]oxadiazol-2-ylsulfanyl]-propan-2-one 81555-89-7 C11H9ClN2O2S
    1-[5-(4-Chloro-phenyl)-[1,3,4]oxadiazol-2-ylsulfanyl]-propan-2-one
    —— fluorotris(trifluoromethylsulfonyl)methane 565470-23-7 C4F10O6S3
    fluorotris(trifluoromethylsulfonyl)methane
    —— 1-(2-Phenylethyl)-3-(phenylsulfanyl)-3-(trimethylsilyl)cyclobutan-1-ol 86573-85-5 C21H28OSSi
    1-(2-Phenylethyl)-3-(phenylsulfanyl)-3-(trimethylsilyl)cyclobutan-1-ol
    —— amyl (3-methylthio-1,2,4-triazol-5-yl)aminodithiocarbonate 131049-44-0 C9H16N4S3
    amyl (3-methylthio-1,2,4-triazol-5-yl)aminodithiocarbonate
    —— tributyl[2-phenylthio-6-MeO-phenyl]tin 780820-64-6 C25H38OSSn
    tributyl[2-phenylthio-6-MeO-phenyl]tin
    —— 1-Ethyl-3-(phenylsulfanyl)-3-(trimethylsilyl)cyclobutan-1-ol 86573-83-3 C15H24OSSi
    1-Ethyl-3-(phenylsulfanyl)-3-(trimethylsilyl)cyclobutan-1-ol
    —— methyl 2,3-dimethyl-4-phenylthiobut-2-enoate 86895-87-6 C13H16O2S
    methyl 2,3-dimethyl-4-phenylthiobut-2-enoate
    —— Cyclohexyl methyl (R)-sulfoxide 93183-66-5 C7H14OS
    Cyclohexyl methyl (R)-sulfoxide
    —— (S)-4-(1-fluoro-2-phenylethyl)-1-(phenylthiometh-yl)-1H-1,2,3-triazole 1159097-38-7 C17H16FN3S
    (S)-4-(1-fluoro-2-phenylethyl)-1-(phenylthiometh-yl)-1H-1,2,3-triazole
    —— Lithium;3-methylbut-1-ynylsulfanylbenzene —— C11H11LiS
    Lithium;3-methylbut-1-ynylsulfanylbenzene
    —— 2-(2,3-difluorobenzylsulfanyl)-4-hydroxy-6-isopropyl-pyrimidine-5-carbonitrile 1029521-33-2 C15H13F2N3OS
    2-(2,3-difluorobenzylsulfanyl)-4-hydroxy-6-isopropyl-pyrimidine-5-carbonitrile
    —— Methyl (R,S)-2-(tert-butylsulfinyl)ethanedithioate 188847-55-4 C7H14OS3
    Methyl (R,S)-2-(tert-butylsulfinyl)ethanedithioate
    —— 1-Butyl-3-(phenylsulfanyl)-3-(trimethylsilyl)cyclobutan-1-ol 86573-84-4 C17H28OSSi
    1-Butyl-3-(phenylsulfanyl)-3-(trimethylsilyl)cyclobutan-1-ol
    —— methyl (methylsulfinyl)dithioacetate 83483-44-7 C4H8OS3
    methyl (methylsulfinyl)dithioacetate
    —— methyl 2-ethyl-4-phenylthiohex-2-enoate 86895-91-2 C15H20O2S
    methyl 2-ethyl-4-phenylthiohex-2-enoate