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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Dithiocarbonic acid O-cyclohex-2-enylmethyl ester S-methyl ester 126384-17-6 C9H14OS2
    Dithiocarbonic acid O-cyclohex-2-enylmethyl ester S-methyl ester
    —— 1-(3-naphthylsulfanyl)-2-vinylbenzene 1181645-55-5 C18H14S
    1-(3-naphthylsulfanyl)-2-vinylbenzene
    —— 2-(4-chlorobutylthio)pyridine 155967-80-9 C9H12ClNS
    2-(4-chlorobutylthio)pyridine
    —— Dithiocarbonic acid S-methyl ester O-(1-methyl-cyclopent-2-enylmethyl) ester 134889-53-5 C9H14OS2
    Dithiocarbonic acid S-methyl ester O-(1-methyl-cyclopent-2-enylmethyl) ester
    —— [(4-chlorobutyl)sulfanyl]-4-methyl-5-(4-methyl-1,3-oxazol-5-yl)-4H-1,2,4-triazole 1016977-06-2 C11H15ClN4OS
    [(4-chlorobutyl)sulfanyl]-4-methyl-5-(4-methyl-1,3-oxazol-5-yl)-4H-1,2,4-triazole
    —— N-{[6-(imidazo[1,2-a]pyridin-3-yl)sulphanyl]-1,3-benzothiazol-2-yl}cyclopropanecarboxamide 1205744-28-0 C18H14N4OS2
    N-{[6-(imidazo[1,2-a]pyridin-3-yl)sulphanyl]-1,3-benzothiazol-2-yl}cyclopropanecarboxamide
    —— 5-Methylspiro[1-benzothiophene-2,3'-oxolane]-2',3-dione 79003-40-0 C12H10O3S
    5-Methylspiro[1-benzothiophene-2,3'-oxolane]-2',3-dione
    —— 5-Nitrospiro[1-benzothiophene-2,1'-cyclopropane]-3-one 79003-11-5 C10H7NO3S
    5-Nitrospiro[1-benzothiophene-2,1'-cyclopropane]-3-one
    —— 2-benzyl-5-ethylsulfanyl-[1,3,4]thiadiazole 64837-43-0 C11H12N2S2
    2-benzyl-5-ethylsulfanyl-[1,3,4]thiadiazole
    —— (E)-2-Methyl-8-phenyl-5-phenylsulfanyl-5-trimethylsilanyl-non-3-en-2-ol 79409-75-9 C25H36OSSi
    (E)-2-Methyl-8-phenyl-5-phenylsulfanyl-5-trimethylsilanyl-non-3-en-2-ol
    —— 5-phenyl-3,4-dihydro-2H-1,6-benzothiazocine 76293-51-1 C16H15NS
    5-phenyl-3,4-dihydro-2H-1,6-benzothiazocine
    —— (Bicyclo[2.2.1]hept-5-en-2-yl)methanethiol 632325-23-6 C8H12S
    (Bicyclo[2.2.1]hept-5-en-2-yl)methanethiol
    —— n-butyl dithioacetate 69380-59-2 C6H12S2
    n-butyl dithioacetate
    —— 4-[((E)-2-Non-4-enyl)-[1,3]dithian-2-yl]-butyraldehyde 918343-96-1 C17H30OS2
    4-[((E)-2-Non-4-enyl)-[1,3]dithian-2-yl]-butyraldehyde
    —— 5-(Trifluoromethylthio)-2-(2,5-difluorophenylthio)benzaldehyde 83975-71-7 C14H7F5OS2
    5-(Trifluoromethylthio)-2-(2,5-difluorophenylthio)benzaldehyde
    —— [5-Chloro-2-(2,5-difluoro-phenylsulfanyl)-phenyl]-(1-methyl-piperidin-4-yl)-methanol 83986-23-6 C19H20ClF2NOS
    [5-Chloro-2-(2,5-difluoro-phenylsulfanyl)-phenyl]-(1-methyl-piperidin-4-yl)-methanol
    —— methyl R-(5',6'-dihydro-2'-oxo-1,3-dithiolo[4,5-b]-1,4-dithiin-5'-yl)ethanoate 859911-65-2 C8H8O3S4
    methyl R-(5',6'-dihydro-2'-oxo-1,3-dithiolo[4,5-b]-1,4-dithiin-5'-yl)ethanoate
    —— methyl (R)-(5',6'-dihydro-2'-thioxo-1,3-dithiolo[4,5-b]-1,4-dithiin-5'-yl)ethanoate 859911-64-1 C8H8O2S5
    methyl (R)-(5',6'-dihydro-2'-thioxo-1,3-dithiolo[4,5-b]-1,4-dithiin-5'-yl)ethanoate
    —— 2-Phenylsulfanylpent-4-enoic acid 84363-42-8 C11H12O2S
    2-Phenylsulfanylpent-4-enoic acid
    —— 8-Chloro-6-<1-(2-decanoyloxyethyl)-4-piperidyl>-2-fluoro-6H-dibenz<b,e>-1,4-oxathiepin 83975-88-6 C30H39ClFNO3S
    8-Chloro-6-<1-(2-decanoyloxyethyl)-4-piperidyl>-2-fluoro-6H-dibenz<b,e>-1,4-oxathiepin
    —— 2-(2,5-Difluorophenylthio)-5-methoxy-α-(1-methyl-4-piperidyl)benzyl Alcohol 83975-61-5 C20H23F2NO2S
    2-(2,5-Difluorophenylthio)-5-methoxy-α-(1-methyl-4-piperidyl)benzyl Alcohol
    —— 2-fluoro-8-methoxy-6H-dibenz<b,e>-1,4-oxathiepin 83975-60-4 C20H22FNO2S
    2-fluoro-8-methoxy-6H-dibenz<b,e>-1,4-oxathiepin
    —— 8-chloro-2-fluoro-6H-dibenz<b,e>-1,4-oxathiepin 84884-57-1 C13H8ClFOS
    8-chloro-2-fluoro-6H-dibenz<b,e>-1,4-oxathiepin
    —— [2-(2,5-Difluoro-phenylsulfanyl)-5-trifluoromethylsulfanyl-phenyl]-(1-methyl-piperidin-4-yl)-methanol 83975-66-0 C20H20F5NOS2
    [2-(2,5-Difluoro-phenylsulfanyl)-5-trifluoromethylsulfanyl-phenyl]-(1-methyl-piperidin-4-yl)-methanol
    —— 2-Fluoro-8-(trifluoromethylthio)-6-(1-methyl-4-piperidyl)-6H-dibenz<b,e>-1,4-oxathiepin 83975-65-9 C20H19F4NOS2
    2-Fluoro-8-(trifluoromethylthio)-6-(1-methyl-4-piperidyl)-6H-dibenz<b,e>-1,4-oxathiepin
    —— 5-Chloro-2-(2,5-difluorophenylthio)benzaldehyde 83975-59-1 C13H7ClF2OS
    5-Chloro-2-(2,5-difluorophenylthio)benzaldehyde
    —— 8-Chloro-2-fluoro-6-(1-methyl-4-piperidyl)-6H-dibenz<b,e>-1,4-oxathiepin 83986-22-5 C19H19ClFNOS
    8-Chloro-2-fluoro-6-(1-methyl-4-piperidyl)-6H-dibenz<b,e>-1,4-oxathiepin
    —— 5-cyclohexylmethyl-2-methylthio-4-pyrimidone 72717-03-4 C12H18N2OS
    5-cyclohexylmethyl-2-methylthio-4-pyrimidone
    —— 1,3-dichloro-2-methylthiopropane 85366-03-6 C4H8Cl2S
    1,3-dichloro-2-methylthiopropane
    —— 3,6-bis-methylsulfanyl-[1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazole 55770-77-9 C5H6N4S3
    3,6-bis-methylsulfanyl-[1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazole
    —— 2-(ethynylsulfonyl)propane 20526-34-5 C5H8O2S
    2-(ethynylsulfonyl)propane
    —— S-isopropyl O-(propan-2-yl-1,1,1,3,3,3-d6) carbonodithioate 38379-92-9 C7H14OS2
    S-isopropyl O-(propan-2-yl-1,1,1,3,3,3-d6) carbonodithioate
    —— ethyl 3-bromo-4-[4-(methylthio)phenyl]-2-oxobutanoate 737824-48-5 C13H15BrO3S
    ethyl 3-bromo-4-[4-(methylthio)phenyl]-2-oxobutanoate
    —— 2-(4-chloro-2-methoxyphenylthio)benzoic acid 68350-97-0 C14H11ClO3S
    2-(4-chloro-2-methoxyphenylthio)benzoic acid
    —— 5-Benzylsulfanyl-1-methyl-1H-pyrazole-4-carbonitrile 111493-53-9 C12H11N3S
    5-Benzylsulfanyl-1-methyl-1H-pyrazole-4-carbonitrile
    —— 4-(3-fluoropyrazin-2-yl)-2-methyl-6-(methylthio)-pyrimidine 1253570-43-2 C10H9FN4S
    4-(3-fluoropyrazin-2-yl)-2-methyl-6-(methylthio)-pyrimidine
    —— 6-Azido-4-phenylsulfanyl-hexan-2-one 84702-78-3 C12H15N3OS
    6-Azido-4-phenylsulfanyl-hexan-2-one
    —— N-<2-(4-methylphenylthio)-2-methylpropylidene>-2-methyl-2-propylamine 110466-23-4 C15H23NS
    N-<2-(4-methylphenylthio)-2-methylpropylidene>-2-methyl-2-propylamine
    —— 1-Methyl-5-phenylsulfanyl-1H-pyrazole-4-carbonitrile 839732-04-6 C11H9N3S
    1-Methyl-5-phenylsulfanyl-1H-pyrazole-4-carbonitrile
    —— 7-(3-chloro-4-fluoro-phenylamino)-2-methylsulfanyl-thiazolo[4,5-b]pyridine-6-carbonitrile 879222-36-3 C14H8ClFN4S2
    7-(3-chloro-4-fluoro-phenylamino)-2-methylsulfanyl-thiazolo[4,5-b]pyridine-6-carbonitrile
    —— 4-(p-methoxyphenylthio)-6-phenyl-8-methoxypyrimido[4,5-b][1,4]benzothiazepine 873106-52-6 C25H19N3O2S2
    4-(p-methoxyphenylthio)-6-phenyl-8-methoxypyrimido[4,5-b][1,4]benzothiazepine
    —— N-(6-methoxypyridin-3-yl)-3-(2-methyl-6-(methylthio)pyrimidin-4-yl)pyrazin-2-amine 1253570-45-4 C16H16N6OS
    N-(6-methoxypyridin-3-yl)-3-(2-methyl-6-(methylthio)pyrimidin-4-yl)pyrazin-2-amine
    —— 2-{[5-Methoxy-5-(phenylsulfanyl)pentyl]oxy}oxane 89037-02-5 C17H26O3S
    2-{[5-Methoxy-5-(phenylsulfanyl)pentyl]oxy}oxane
    —— 4,6-bis((4-methoxyphenyl)thio)pyrimidin-5-amine 873106-31-1 C18H17N3O2S2
    4,6-bis((4-methoxyphenyl)thio)pyrimidin-5-amine
    —— 1-ethynyl-4-(3,3,3-trifluoropropyl-1-sulfonylmethyl)cyclohexene 1097630-13-1 C12H15F3O2S
    1-ethynyl-4-(3,3,3-trifluoropropyl-1-sulfonylmethyl)cyclohexene
    —— 2,3,9,10,16,17,23,24-octakis(2,6-dimethylphenylsulfanyl)-1,4,8,11,15,18,22,25-(octaaza)phthalocyanine 1569939-72-5 C88H74N16S8
    2,3,9,10,16,17,23,24-octakis(2,6-dimethylphenylsulfanyl)-1,4,8,11,15,18,22,25-(octaaza)phthalocyanine
    —— 4-(1,1-dimethoxy-ethyl)-2-methylsulfanyl-pyrimidine 521092-35-3 C9H14N2O2S
    4-(1,1-dimethoxy-ethyl)-2-methylsulfanyl-pyrimidine
    —— 4,6-bismethylthio-5-nitropyrimidine 88317-72-0 C6H7N3O2S2
    4,6-bismethylthio-5-nitropyrimidine
    —— 5-benzylsulfanyl-3-phenyl-3<i>H</i>-[1,3,4]thiadiazole-2-thione 41126-42-5 C15H12N2S3
    5-benzylsulfanyl-3-phenyl-3<i>H</i>-[1,3,4]thiadiazole-2-thione
    —— 6-methylthio-4-methoxy-5-nitropyrimidine 90860-54-1 C6H7N3O3S
    6-methylthio-4-methoxy-5-nitropyrimidine