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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— <2S,2<2R,3S,6R,8S,8(3S),9R>>-2-<3,9-dimethyl-8-<3-(2-methyl-1,3-dithian-2-yl)butyl>-1,7-dioxaspiro<5.5>undecane-2-yl>-1-propanal 160238-59-5 C23H40O3S2
    <2S,2<2R,3S,6R,8S,8(3S),9R>>-2-<3,9-dimethyl-8-<3-(2-methyl-1,3-dithian-2-yl)butyl>-1,7-dioxaspiro<5.5>undecane-2-yl>-1-propanal
    —— 1-Vinyl-trans-2-butenylmethyl-dithiolcarbonat 40486-69-9 C8H12OS2
    1-Vinyl-trans-2-butenylmethyl-dithiolcarbonat
    —— 6-methylsulfanyl-2-thioxo-2,3-dihydro-1<i>H</i>-pyrimido[5,4-<i>d</i>]pyrimidin-4-one 98550-20-0 C7H6N4OS2
    6-methylsulfanyl-2-thioxo-2,3-dihydro-1<i>H</i>-pyrimido[5,4-<i>d</i>]pyrimidin-4-one
    —— 2-methyl-6-(methylthio)pyrimido[5,4-d]pyrimidin-4(3H)-one 99584-34-6 C8H8N4OS
    2-methyl-6-(methylthio)pyrimido[5,4-d]pyrimidin-4(3H)-one
    —— 6-methylsulfanyl-1<i>H</i>-pyrimido[5,4-<i>d</i>]pyrimidine-2,4-dione 98550-25-5 C7H6N4O2S
    6-methylsulfanyl-1<i>H</i>-pyrimido[5,4-<i>d</i>]pyrimidine-2,4-dione
    —— 1-chloro-3-phenyl-2-propynyl phenyl sulfide 153940-38-6 C15H11ClS
    1-chloro-3-phenyl-2-propynyl phenyl sulfide
    —— 5-(2-fluoro-phenyl)-3-methylsulfanyl-[1,2,4]triazine 71347-51-8 C10H8FN3S
    5-(2-fluoro-phenyl)-3-methylsulfanyl-[1,2,4]triazine
    —— 4-[1,3-Bis[(1-butylpyridin-1-ium-4-yl)sulfanyl]propan-2-ylsulfanyl]-1-butylpyridin-1-ium;triiodide 446242-10-0 C30H44I3N3S3
    4-[1,3-Bis[(1-butylpyridin-1-ium-4-yl)sulfanyl]propan-2-ylsulfanyl]-1-butylpyridin-1-ium;triiodide
    —— 2-phenylethynyl-1,3-benzdithiole 131549-16-1 C15H10S2
    2-phenylethynyl-1,3-benzdithiole
    —— 1,1,2-tris(methylthio)-2-(ethylthio)ethylene 87373-96-4 C7H14S4
    1,1,2-tris(methylthio)-2-(ethylthio)ethylene
    —— (E)-1-(methylthio)-2-(ethylthio)ethylene 87373-94-2 C5H10S2
    (E)-1-(methylthio)-2-(ethylthio)ethylene
    —— 3-heptanamido-5-methyl-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one 172470-01-8 C21H28N2O2S
    3-heptanamido-5-methyl-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one
    —— 3-formamido-5-methyl-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one 172469-98-6 C15H16N2O2S
    3-formamido-5-methyl-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one
    —— Carbamic acid, (4-((3,5-dimethylphenyl)thio)-1,2-dihydro-5-methyl-2-oxo-3-pyridinyl)-, ethyl ester 172469-69-1 C17H20N2O3S
    Carbamic acid, (4-((3,5-dimethylphenyl)thio)-1,2-dihydro-5-methyl-2-oxo-3-pyridinyl)-, ethyl ester
    —— 2-(4-chlorophenylthio)-3-phenylpropanal 1383467-76-2 C15H13ClOS
    2-(4-chlorophenylthio)-3-phenylpropanal
    —— 3-acetamido-5-methyl-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one 172469-99-7 C16H18N2O2S
    3-acetamido-5-methyl-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one
    —— 3-amino-5-ethyl-4-(3', 5'-dimethylphenyl) thio-pyridin-2(1H)-one 172469-93-1 C15H18N2OS
    3-amino-5-ethyl-4-(3', 5'-dimethylphenyl) thio-pyridin-2(1H)-one
    —— 2-(4-bromophenylthio)-3-phenylpropanal 1383467-75-1 C15H13BrOS
    2-(4-bromophenylthio)-3-phenylpropanal
    —— 5-methyl-3-phenylacetamido-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one 172470-02-9 C22H22N2O2S
    5-methyl-3-phenylacetamido-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one
    —— 5-ethyl-3-nitro-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one 172469-77-1 C15H16N2O3S
    5-ethyl-3-nitro-4-(3', 5'-dimethylphenyl)thio-pyridin-2(1H)-one
    —— 6-[(4-methylphenyl)sulfanyl]-2,4-diaminopyrimidine 606964-84-5 C11H12N4S
    6-[(4-methylphenyl)sulfanyl]-2,4-diaminopyrimidine
    —— 6-(phenylsulfanyl)pyrimidine-2,4-diamine 73119-72-9 C10H10N4S
    6-(phenylsulfanyl)pyrimidine-2,4-diamine
    —— 6-(benzylsulfanyl)-2,4-diaminopyrimidine 99864-74-1 C11H12N4S
    6-(benzylsulfanyl)-2,4-diaminopyrimidine
    —— 3-phenyl-2-phenylthio-propionaldehyde 55064-98-7 C15H14OS
    3-phenyl-2-phenylthio-propionaldehyde
    —— 6-(benzylthio)pyridin-3-amine 52024-32-5 C12H12N2S
    6-(benzylthio)pyridin-3-amine
    —— 2,2,5,5-Tetramethyl-3,4-dithiahexane-1,6-diamine 58262-78-5 C8H20N2S2
    2,2,5,5-Tetramethyl-3,4-dithiahexane-1,6-diamine
    —— 1,3-di-s-octyl-2-thiourea 62549-34-2 C17H36N2S
    1,3-di-s-octyl-2-thiourea
    —— methyl (1-benzyl-3-methylthio-1H-1,2,4-triazole-5-yl)-N-benzyliminodithiocarbonate 131023-17-1 C19H20N4S3
    methyl (1-benzyl-3-methylthio-1H-1,2,4-triazole-5-yl)-N-benzyliminodithiocarbonate
    —— 5-(N-acetyl-N-benzylamino)-4-benzyl-3-methylthio-4H-1,2,4-triazole 110984-83-3 C19H20N4OS
    5-(N-acetyl-N-benzylamino)-4-benzyl-3-methylthio-4H-1,2,4-triazole
    —— N,N-Bis-(2-phenylmercapto-aethyl)-propionamid 2173-31-1 C19H23NOS2
    N,N-Bis-(2-phenylmercapto-aethyl)-propionamid
    —— (2R)-2-isothiocyanatooctane 737761-97-6 C9H17NS
    (2R)-2-isothiocyanatooctane
    —— 2,2'-sulfinylbis[1,2-<sup>13</sup>C<sub>2</sub>]ethanol 672310-51-9 C4H10O3S
    2,2'-sulfinylbis[1,2-<sup>13</sup>C<sub>2</sub>]ethanol
    —— 5-bromo-3-(2,4-dimethoxyphenylthio)-1H-indole 1448175-36-7 C16H14BrNO2S
    5-bromo-3-(2,4-dimethoxyphenylthio)-1H-indole
    —— 6,7-dihydro-5H-7-oxothieno[3,2-b]thiopyran-2-sulfonamide 105951-32-4 C7H7NO3S3
    6,7-dihydro-5H-7-oxothieno[3,2-b]thiopyran-2-sulfonamide
    —— tert-Butyl-(2,3-dimethyl-5,8-dithia-spiro[3.4]oct-2-en-1-yloxy)-dimethylsilane 361523-19-5 C14H26OS2Si
    tert-Butyl-(2,3-dimethyl-5,8-dithia-spiro[3.4]oct-2-en-1-yloxy)-dimethylsilane
    —— 2,3-Dimethyl-5,8-dithiaspiro[3.4]oct-2-ene-1-ol 361523-17-3 C8H12OS2
    2,3-Dimethyl-5,8-dithiaspiro[3.4]oct-2-ene-1-ol
    —— 2,3-Dimethyl-5,8-dithiaspiro[3.4]oct-2-en-1-one 361523-07-1 C8H10OS2
    2,3-Dimethyl-5,8-dithiaspiro[3.4]oct-2-en-1-one
    —— 5-(N-acetyl-N-benzylamino)-2-benzyl-3-methylthio-2H-1,2,4-triazole 110984-82-2 C19H20N4OS
    5-(N-acetyl-N-benzylamino)-2-benzyl-3-methylthio-2H-1,2,4-triazole
    —— 4-benzyl-5-benzylamino-3-methylthio-4H-1,2,4-triazole 110984-80-0 C17H18N4S
    4-benzyl-5-benzylamino-3-methylthio-4H-1,2,4-triazole
    —— 1-benzyl-5-benzylamino-3-methylthio-1H-1,2,4-triazole 110984-78-6 C17H18N4S
    1-benzyl-5-benzylamino-3-methylthio-1H-1,2,4-triazole
    —— methyl (4-benzyl-3-methylthio-4H-1,2,4-triazole-5-yl)-N-benzyliminodithiocarbonate 131023-19-3 C19H20N4S3
    methyl (4-benzyl-3-methylthio-4H-1,2,4-triazole-5-yl)-N-benzyliminodithiocarbonate
    —— 2,2-Dichloro-3,4-dimethyl-3-(phenylsulfanyl)cyclobutan-1-one 91359-03-4 C12H12Cl2OS
    2,2-Dichloro-3,4-dimethyl-3-(phenylsulfanyl)cyclobutan-1-one
    —— 9-methylene-1,5-dithiacyclononane 144227-21-4 C8H14S2
    9-methylene-1,5-dithiacyclononane
    —— 1-(Phenylsulfinyl)-9-(phenylthio)dibenzoselenophene 142371-52-6 C24H16OS2Se
    1-(Phenylsulfinyl)-9-(phenylthio)dibenzoselenophene
    —— 5-(N-acetyl-N-benzylamino)-1-benzyl-3-methylthio-1H-1,2,4-triazole 110984-81-1 C19H20N4OS
    5-(N-acetyl-N-benzylamino)-1-benzyl-3-methylthio-1H-1,2,4-triazole
    —— 6-(3-bromophenyl)-2-ethylsulfanyl-4H-thiopyran-4-one 500169-94-8 C13H11BrOS2
    6-(3-bromophenyl)-2-ethylsulfanyl-4H-thiopyran-4-one
    —— 2-[3-(1,3-Dioxan-2-yl)-1-phenylsulfanylpropyl]-3-hydroxy-5,5-dimethylcyclohex-2-en-1-one 154876-43-4 C21H28O4S
    2-[3-(1,3-Dioxan-2-yl)-1-phenylsulfanylpropyl]-3-hydroxy-5,5-dimethylcyclohex-2-en-1-one
    —— methyl (2-benzyl-3-methylthio-2H-1,2,4-triazole-5-yl)-N-benzyliminodithiocarbonate 131023-18-2 C19H20N4S3
    methyl (2-benzyl-3-methylthio-2H-1,2,4-triazole-5-yl)-N-benzyliminodithiocarbonate
    —— 2-benzyl-5-benzylamino-3-methylthio-2H-1,2,4-triazole 110984-79-7 C17H18N4S
    2-benzyl-5-benzylamino-3-methylthio-2H-1,2,4-triazole
    —— bis(5-bromo-indole-3-yl) sulfide 1449520-49-3 C16H10Br2N2S
    bis(5-bromo-indole-3-yl) sulfide