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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-nitro-2-[[(3S)-piperidin-3-yl]methylsulfanyl]pyridine —— C11H15N3O2S
    3-nitro-2-[[(3S)-piperidin-3-yl]methylsulfanyl]pyridine
    —— 3-nitro-2-[[(2R)-pyrrolidin-2-yl]methylsulfanyl]pyridine —— C10H13N3O2S
    3-nitro-2-[[(2R)-pyrrolidin-2-yl]methylsulfanyl]pyridine
    —— 3-nitro-2-[(3S)-piperidin-3-yl]sulfanylpyridine —— C10H13N3O2S
    3-nitro-2-[(3S)-piperidin-3-yl]sulfanylpyridine
    —— 3-nitro-2-[[(2S)-piperidin-2-yl]methylsulfanyl]pyridine —— C11H15N3O2S
    3-nitro-2-[[(2S)-piperidin-2-yl]methylsulfanyl]pyridine
    —— 3-nitro-2-[(3R)-piperidin-3-yl]sulfanylpyridine —— C10H13N3O2S
    3-nitro-2-[(3R)-piperidin-3-yl]sulfanylpyridine
    —— 3-nitro-2-[[(2R)-piperidin-2-yl]methylsulfanyl]pyridine —— C11H15N3O2S
    3-nitro-2-[[(2R)-piperidin-2-yl]methylsulfanyl]pyridine
    —— 5-nitro-2-[[(2S)-piperidin-2-yl]methylsulfanyl]pyridine —— C11H15N3O2S
    5-nitro-2-[[(2S)-piperidin-2-yl]methylsulfanyl]pyridine
    —— ethyl (6S,7R)-6-(4-hydroxyphenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate —— C14H16N4O3S
    ethyl (6S,7R)-6-(4-hydroxyphenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate
    —— ethyl (6S,7S)-6-(4-chlorophenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate —— C14H15ClN4O2S
    ethyl (6S,7S)-6-(4-chlorophenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate
    —— ethyl (6R,7R)-6-(4-chlorophenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate —— C14H15ClN4O2S
    ethyl (6R,7R)-6-(4-chlorophenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate
    —— ethyl (6S,7R)-6-(4-fluorophenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate —— C14H15FN4O2S
    ethyl (6S,7R)-6-(4-fluorophenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate
    —— (6R)-6-(4-chlorophenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C11H11ClN4S
    (6R)-6-(4-chlorophenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (6S)-6-(4-chlorophenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C11H11ClN4S
    (6S)-6-(4-chlorophenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— ethyl (6R,7S)-6-(4-fluorophenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate —— C14H15FN4O2S
    ethyl (6R,7S)-6-(4-fluorophenyl)-3-methyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate
    —— 2-[(3-Fluorophenyl)methylsulfanyl]-3-methyl-6-propan-2-ylpyrimidin-4-one —— C15H17FN2OS
    2-[(3-Fluorophenyl)methylsulfanyl]-3-methyl-6-propan-2-ylpyrimidin-4-one
    —— (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]butanoate —— C7H10N3O2S-
    (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]butanoate
    —— 2-Amino-4,6-dimethyl-5-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]cyclopenta[b]pyridin-1-ium-3,7-dicarbonitrile —— C24H19N4OS+
    2-Amino-4,6-dimethyl-5-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]cyclopenta[b]pyridin-1-ium-3,7-dicarbonitrile
    —— 1-[(3R)-3-phenyl-3,4-dihydropyrazol-2-yl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone —— C19H16N4OS3
    1-[(3R)-3-phenyl-3,4-dihydropyrazol-2-yl]-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone
    —— 2-(3-Cyano-6-propylpyridin-2-yl)sulfanyl-2-methylpropanoate —— C13H15N2O2S-
    2-(3-Cyano-6-propylpyridin-2-yl)sulfanyl-2-methylpropanoate
    —— 2-[(5E)-5-[[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetate —— C17H10N3O5S2-
    2-[(5E)-5-[[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetate
    —— 2-[3-(1H-benzimidazol-2-ylsulfanyl)-4-nitroanilino]ethylazanium —— C15H16N5O2S+
    2-[3-(1H-benzimidazol-2-ylsulfanyl)-4-nitroanilino]ethylazanium
    —— N-[(3S)-3-cyano-3,3a,4,5,6,7-hexahydro-1-benzothiophen-2-yl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C17H20N4OS2
    N-[(3S)-3-cyano-3,3a,4,5,6,7-hexahydro-1-benzothiophen-2-yl]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— (4S)-4-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]-2-phenyl-5-propyl-4H-pyrazol-3-one —— C22H21N3OS2
    (4S)-4-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]-2-phenyl-5-propyl-4H-pyrazol-3-one
    —— (4R)-2-phenyl-4-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]-5-propyl-4H-pyrazol-3-one —— C21H19N3OS2
    (4R)-2-phenyl-4-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]-5-propyl-4H-pyrazol-3-one
    —— 3-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]propanoate —— C10H13N2O3S-
    3-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]propanoate
    —— N-[4-[6-[(4-methoxyphenyl)methylamino]pyrimidin-4-yl]sulfanylphenyl]acetamide —— C20H20N4O2S
    N-[4-[6-[(4-methoxyphenyl)methylamino]pyrimidin-4-yl]sulfanylphenyl]acetamide
    —— 3-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl-N-[(2S)-1-methoxypropan-2-yl]propanamide —— C16H18F3N3O3S
    3-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanyl-N-[(2S)-1-methoxypropan-2-yl]propanamide
    —— 4-Benzylsulfanyl-2,6-dimethylpyridine-3-carbonitrile —— C15H14N2S
    4-Benzylsulfanyl-2,6-dimethylpyridine-3-carbonitrile
    —— N-[(2S)-butan-2-yl]-3-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanylpropanamide —— C16H18F3N3O2S
    N-[(2S)-butan-2-yl]-3-[4-(furan-2-yl)-6-(trifluoromethyl)pyrimidin-2-yl]sulfanylpropanamide
    —— (3E,5E)-1-methyl-3,5-bis[(4-methylsulfanylphenyl)methylidene]piperidin-1-ium-4-one —— C22H24NOS2+
    (3E,5E)-1-methyl-3,5-bis[(4-methylsulfanylphenyl)methylidene]piperidin-1-ium-4-one
    —— 2-Ethylsulfanyl-9-oxo-4-thiophen-2-ylindeno[2,1-b]pyridine-3-carbonitrile —— C19H12N2OS2
    2-Ethylsulfanyl-9-oxo-4-thiophen-2-ylindeno[2,1-b]pyridine-3-carbonitrile
    —— 2-Benzylsulfanyl-9-oxo-4-thiophen-2-ylindeno[2,1-b]pyridine-3-carbonitrile —— C24H14N2OS2
    2-Benzylsulfanyl-9-oxo-4-thiophen-2-ylindeno[2,1-b]pyridine-3-carbonitrile
    —— 2-(3-Cyano-9-oxo-4-thiophen-2-ylindeno[2,1-b]pyridin-2-yl)sulfanylacetamide —— C19H11N3O2S2
    2-(3-Cyano-9-oxo-4-thiophen-2-ylindeno[2,1-b]pyridin-2-yl)sulfanylacetamide
    —— 4-[(2S,5S)-5-[(4,6-dimethylpyrimidin-2-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]-N,N-dimethylaniline —— C18H25N4OS+
    4-[(2S,5S)-5-[(4,6-dimethylpyrimidin-2-yl)sulfanylmethyl]-1,3-oxazolidin-3-ium-2-yl]-N,N-dimethylaniline
    —— (2R)-2-[(4-methoxy-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1R)-1-phenylethyl]butanamide —— C17H21N3O3S
    (2R)-2-[(4-methoxy-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1R)-1-phenylethyl]butanamide
    —— (2S)-2-[(4-methoxy-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1R)-1-phenylethyl]butanamide —— C17H21N3O3S
    (2S)-2-[(4-methoxy-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1R)-1-phenylethyl]butanamide
    —— 2-(2-piperidin-1-ium-1-ylethylsulfanyl)-4-(trifluoromethyl)-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridine-3-carbonitrile —— C19H25F3N3S+
    2-(2-piperidin-1-ium-1-ylethylsulfanyl)-4-(trifluoromethyl)-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridine-3-carbonitrile
    —— 3-pentyl-6-(4-methylphenyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C16H20N4S
    3-pentyl-6-(4-methylphenyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 2-[(2-Chloro-6-fluorophenyl)methylsulfanyl]-3,6-dimethyl-5-[(2-methylphenyl)methyl]pyrimidin-4-one —— C21H20ClFN2OS
    2-[(2-Chloro-6-fluorophenyl)methylsulfanyl]-3,6-dimethyl-5-[(2-methylphenyl)methyl]pyrimidin-4-one
    —— 2-Amino-4-methyl-6-methylsulfanylpyridin-1-ium-3,5-dicarbonitrile —— C9H9N4S+
    2-Amino-4-methyl-6-methylsulfanylpyridin-1-ium-3,5-dicarbonitrile
    —— 2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)acetamide —— C14H16FN3O2S
    2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)acetamide
    —— 3-[[2-(4-Methylphenyl)-1,3-thiazol-4-yl]methylsulfanyl]-5-thiophen-2-yl-1,2,4-triazol-4-amine —— C17H15N5S3
    3-[[2-(4-Methylphenyl)-1,3-thiazol-4-yl]methylsulfanyl]-5-thiophen-2-yl-1,2,4-triazol-4-amine
    —— 2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-methylbutyl)acetamide —— C15H18FN3O2S
    2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-methylbutyl)acetamide
    —— 2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(1H-pyrrol-2-yl)ethanone —— C14H10FN3O2S
    2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(1H-pyrrol-2-yl)ethanone
    —— 2-[[5-(4-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[1-(2-methoxyethyl)-2,5-dimethylpyrrol-3-yl]ethanone —— C19H20FN3O3S
    2-[[5-(4-Fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[1-(2-methoxyethyl)-2,5-dimethylpyrrol-3-yl]ethanone
    —— (2S)-N-cyclopropyl-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C14H14FN3O2S
    (2S)-N-cyclopropyl-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-3-methylbutan-2-yl]acetamide —— C15H18FN3O2S
    2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-3-methylbutan-2-yl]acetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C14H14FN3O4S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C16H15FN4O2S
    N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-N-cyclopropyl-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C14H14FN3O2S
    (2R)-N-cyclopropyl-2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide