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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-chloro-5-methyl-2-[(3S)-piperidin-3-yl]sulfanylpyrimidine —— C10H14ClN3S
    4-chloro-5-methyl-2-[(3S)-piperidin-3-yl]sulfanylpyrimidine
    —— 4-chloro-5-methyl-2-[[(2R)-piperidin-2-yl]methylsulfanyl]pyrimidine —— C11H16ClN3S
    4-chloro-5-methyl-2-[[(2R)-piperidin-2-yl]methylsulfanyl]pyrimidine
    —— N-[2-(4-chlorophenyl)sulfanylphenyl]-2-[(2-methylphenyl)methylsulfanyl]acetamide —— C22H20ClNOS2
    N-[2-(4-chlorophenyl)sulfanylphenyl]-2-[(2-methylphenyl)methylsulfanyl]acetamide
    —— 2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-tert-butylacetamide —— C20H31N5OS
    2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-tert-butylacetamide
    —— [(1R)-1-[4-butyl-5-[(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C17H32N5OS+
    [(1R)-1-[4-butyl-5-[(2R)-1-(cyclopropylamino)-1-oxopropan-2-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1R)-1-[4-benzyl-5-[(3R)-2-oxooxolan-3-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C18H25N4O2S+
    [(1R)-1-[4-benzyl-5-[(3R)-2-oxooxolan-3-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1S)-1-[4-benzyl-5-[(1S)-1-cyanoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C17H24N5S+
    [(1S)-1-[4-benzyl-5-[(1S)-1-cyanoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1S)-1-[4-benzyl-5-[2-oxo-2-(2-oxopyrrolidin-1-yl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C20H28N5O2S+
    [(1S)-1-[4-benzyl-5-[2-oxo-2-(2-oxopyrrolidin-1-yl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— (1R)-1-[4-benzyl-5-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine —— C22H27ClN4S
    (1R)-1-[4-benzyl-5-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine
    —— (2S)-2-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopropylpropanamide —— C17H31N5OS
    (2S)-2-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopropylpropanamide
    —— [(1R)-1-[4-benzyl-5-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C20H31N4O2S+
    [(1R)-1-[4-benzyl-5-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1R)-1-[4-benzyl-5-[2-(cyclopropylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C19H28N5OS+
    [(1R)-1-[4-benzyl-5-[2-(cyclopropylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1R)-1-[4-benzyl-5-[(2,5-dimethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C23H31N4S+
    [(1R)-1-[4-benzyl-5-[(2,5-dimethylphenyl)methylsulfanyl]-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— 2-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-chlorophenyl)methyl]acetamide —— C20H30ClN5OS
    2-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-chlorophenyl)methyl]acetamide
    —— [(1R)-1-[4-butyl-5-[2-(tert-butylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C17H34N5OS+
    [(1R)-1-[4-butyl-5-[2-(tert-butylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— 2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-3-methylbutan-2-yl]acetamide —— C21H33N5OS
    2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-3-methylbutan-2-yl]acetamide
    —— [(1R)-1-[4-benzyl-5-[2-oxo-2-(1H-pyrrol-2-yl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C20H26N5OS+
    [(1R)-1-[4-benzyl-5-[2-oxo-2-(1H-pyrrol-2-yl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— 2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-1-(1H-pyrrol-2-yl)ethanone —— C20H25N5OS
    2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-1-(1H-pyrrol-2-yl)ethanone
    —— N-tert-butyl-2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H33N5OS
    N-tert-butyl-2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— [(1R)-1-[4-benzyl-5-[(3S)-2-oxooxolan-3-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C18H25N4O2S+
    [(1R)-1-[4-benzyl-5-[(3S)-2-oxooxolan-3-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1S)-1-[5-(2-amino-2-oxoethyl)sulfanyl-4-butyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C13H26N5OS+
    [(1S)-1-[5-(2-amino-2-oxoethyl)sulfanyl-4-butyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1S)-1-[4-benzyl-5-[2-(cyclopentylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C21H32N5OS+
    [(1S)-1-[4-benzyl-5-[2-(cyclopentylamino)-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1R)-1-[4-butyl-5-[2-[(1-cyanocyclohexyl)amino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C20H35N6OS+
    [(1R)-1-[4-butyl-5-[2-[(1-cyanocyclohexyl)amino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— 2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide —— C17H31N5O3S2
    2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide
    —— [(1R)-1-[4-benzyl-5-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C22H28FN4S+
    [(1R)-1-[4-benzyl-5-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1S)-1-[4-benzyl-5-[(2R)-1-(furan-2-ylmethylamino)-1-oxopropan-2-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C22H30N5O2S+
    [(1S)-1-[4-benzyl-5-[(2R)-1-(furan-2-ylmethylamino)-1-oxopropan-2-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1R)-1-[4-butyl-5-[2-[2-(4-fluorophenyl)ethylamino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C21H33FN5OS+
    [(1R)-1-[4-butyl-5-[2-[2-(4-fluorophenyl)ethylamino]-2-oxoethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1S)-1-[4-benzyl-5-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C22H28FN4S+
    [(1S)-1-[4-benzyl-5-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1R)-1-[4-benzyl-5-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C22H28FN4S+
    [(1R)-1-[4-benzyl-5-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— (2S)-2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-carbamoyl-3-methylbutanamide —— C17H32N6O2S
    (2S)-2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-carbamoyl-3-methylbutanamide
    —— 2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(3-methylbutyl)acetamide —— C21H33N5OS
    2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(3-methylbutyl)acetamide
    —— 2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopentylacetamide —— C21H31N5OS
    2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopentylacetamide
    —— 2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methoxyethyl)acetamide —— C19H29N5O2S
    2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methoxyethyl)acetamide
    —— (1R,2R)-1,2-bis(methylsulfonyl)ethane-1,2-diol —— C4H10O6S2
    (1R,2R)-1,2-bis(methylsulfonyl)ethane-1,2-diol
    —— (1S,2R)-1,2-bis(methylsulfonyl)ethane-1,2-diol —— C4H10O6S2
    (1S,2R)-1,2-bis(methylsulfonyl)ethane-1,2-diol
    —— (2R)-N-[(E)-3,3-dimethylbutan-2-ylideneamino]-2-pyrimidin-2-ylsulfanylpropanamide —— C13H20N4OS
    (2R)-N-[(E)-3,3-dimethylbutan-2-ylideneamino]-2-pyrimidin-2-ylsulfanylpropanamide
    —— (1S,2S)-1,2-bis(methylsulfonyl)ethane-1,2-diol —— C4H10O6S2
    (1S,2S)-1,2-bis(methylsulfonyl)ethane-1,2-diol
    —— (2R)-2-ethanimidoyl-4-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-oxobutanenitrile —— C15H14N4O2S
    (2R)-2-ethanimidoyl-4-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-oxobutanenitrile
    —— 2-(2-methylphenyl)sulfanyl-N-[[(3R)-1-pyrimidin-2-ylpiperidin-3-yl]methyl]acetamide —— C19H24N4OS
    2-(2-methylphenyl)sulfanyl-N-[[(3R)-1-pyrimidin-2-ylpiperidin-3-yl]methyl]acetamide
    —— 2-[(2,4-Difluorophenyl)methylsulfanyl]-3,6-dimethyl-5-[(2-methylphenyl)methyl]pyrimidin-4-one —— C21H20F2N2OS
    2-[(2,4-Difluorophenyl)methylsulfanyl]-3,6-dimethyl-5-[(2-methylphenyl)methyl]pyrimidin-4-one
    —— 2-(2-methylphenyl)sulfanyl-N-[[(3S)-1-pyrimidin-2-ylpiperidin-3-yl]methyl]acetamide —— C19H24N4OS
    2-(2-methylphenyl)sulfanyl-N-[[(3S)-1-pyrimidin-2-ylpiperidin-3-yl]methyl]acetamide
    —— 3-[(1S)-1-(2-fluorophenyl)ethyl]sulfanyl-1-(2-methylpropyl)pyrazin-2-one —— C16H19FN2OS
    3-[(1S)-1-(2-fluorophenyl)ethyl]sulfanyl-1-(2-methylpropyl)pyrazin-2-one
    —— [5-(3-Chloro-2-methylphenyl)furan-2-yl]methyl-[2-(1-methyltetrazol-5-yl)sulfanylethyl]azanium —— C16H19ClN5OS+
    [5-(3-Chloro-2-methylphenyl)furan-2-yl]methyl-[2-(1-methyltetrazol-5-yl)sulfanylethyl]azanium
    —— 3-[(1R)-1-(2-fluorophenyl)ethyl]sulfanyl-1-(2-methylpropyl)pyrazin-2-one —— C16H19FN2OS
    3-[(1R)-1-(2-fluorophenyl)ethyl]sulfanyl-1-(2-methylpropyl)pyrazin-2-one
    —— 3-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-1-(2-methylpropyl)pyrazin-2-one —— C16H19FN2OS
    3-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-1-(2-methylpropyl)pyrazin-2-one
    —— 3-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-1-(2-methylpropyl)pyrazin-2-one —— C16H19FN2OS
    3-[(1S)-1-(4-fluorophenyl)ethyl]sulfanyl-1-(2-methylpropyl)pyrazin-2-one
    —— (4-methylsulfanylphenyl)methyl-(2H-tetrazol-5-yl)azanide —— C9H10N5S-
    (4-methylsulfanylphenyl)methyl-(2H-tetrazol-5-yl)azanide
    —— 4-[2-[(6-Phenyl-1,2,4-triazin-3-yl)sulfanyl]ethyl]morpholin-4-ium —— C15H19N4OS+
    4-[2-[(6-Phenyl-1,2,4-triazin-3-yl)sulfanyl]ethyl]morpholin-4-ium
    —— (2R,6S)-N,2,6-trimethyl-N-[(4-methylsulfanylphenyl)methyl]oxane-4-carboxamide —— C17H25NO2S
    (2R,6S)-N,2,6-trimethyl-N-[(4-methylsulfanylphenyl)methyl]oxane-4-carboxamide
    —— (2S,6S)-N,2,6-trimethyl-N-[(4-methylsulfanylphenyl)methyl]oxane-4-carboxamide —— C17H25NO2S
    (2S,6S)-N,2,6-trimethyl-N-[(4-methylsulfanylphenyl)methyl]oxane-4-carboxamide