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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [2-[[(2R)-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C17H24N4O4S
    [2-[[(2R)-3-methylbutan-2-yl]amino]-2-oxoethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— Cyanomethyl 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C12H12N4O3S
    Cyanomethyl 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— [2-Oxo-2-(propan-2-ylamino)ethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C15H20N4O4S
    [2-Oxo-2-(propan-2-ylamino)ethyl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— [(2R)-1-amino-1-oxopropan-2-yl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C13H16N4O4S
    [(2R)-1-amino-1-oxopropan-2-yl] 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— Methyl 2-[(4-cyano-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]acetate —— C17H22N3O3S+
    Methyl 2-[(4-cyano-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]acetate
    —— (2R)-2-(4-methylphenyl)sulfanyl-N-(2-morpholin-4-ylethyl)propanamide —— C16H24N2O2S
    (2R)-2-(4-methylphenyl)sulfanyl-N-(2-morpholin-4-ylethyl)propanamide
    —— 5-Benzyl-2-[(3-fluorophenyl)methylsulfanyl]-3,6-dimethylpyrimidin-4-one —— C20H19FN2OS
    5-Benzyl-2-[(3-fluorophenyl)methylsulfanyl]-3,6-dimethylpyrimidin-4-one
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-(3-morpholin-4-ium-4-ylpropyl)propanamide —— C16H24ClN2O2S+
    (2S)-2-(4-chlorophenyl)sulfanyl-N-(3-morpholin-4-ium-4-ylpropyl)propanamide
    —— (2S)-2-(4-methylphenyl)sulfanyl-N-(2-morpholin-4-ylethyl)propanamide —— C16H24N2O2S
    (2S)-2-(4-methylphenyl)sulfanyl-N-(2-morpholin-4-ylethyl)propanamide
    —— 2-[4-Chloro-6-[methyl(propyl)amino]pyrimidin-2-yl]sulfanyl-1-(4-ethylpiperazin-4-ium-1-yl)ethanone —— C16H27ClN5OS+
    2-[4-Chloro-6-[methyl(propyl)amino]pyrimidin-2-yl]sulfanyl-1-(4-ethylpiperazin-4-ium-1-yl)ethanone
    —— [2-[[(3S)-1,1-dioxothiolan-3-yl]-ethylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C18H25NO5S2
    [2-[[(3S)-1,1-dioxothiolan-3-yl]-ethylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [2-[[(3S)-1,1-dioxothiolan-3-yl]-(2-methylpropyl)amino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C20H29NO5S2
    [2-[[(3S)-1,1-dioxothiolan-3-yl]-(2-methylpropyl)amino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] 2-(2-fluorophenyl)sulfanylacetate —— C18H18FNO3S
    [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [2-(1-Benzyl-2,5-dimethylpyrrol-3-yl)-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate —— C23H22FNO3S
    [2-(1-Benzyl-2,5-dimethylpyrrol-3-yl)-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [2-[[(1R)-1-(2-chlorophenyl)ethyl]amino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate —— C18H17ClFNO3S
    [2-[[(1R)-1-(2-chlorophenyl)ethyl]amino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [2-[(1-Cyanocyclohexyl)-methylamino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate —— C18H21FN2O3S
    [2-[(1-Cyanocyclohexyl)-methylamino]-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [2-(Ethoxycarbonylamino)-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate —— C13H14FNO5S
    [2-(Ethoxycarbonylamino)-2-oxoethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— [(2S)-1-oxo-1-[[(2R)-4-phenylbutan-2-yl]amino]propan-2-yl] 2-(2-fluorophenyl)sulfanylacetate —— C21H24FNO3S
    [(2S)-1-oxo-1-[[(2R)-4-phenylbutan-2-yl]amino]propan-2-yl] 2-(2-fluorophenyl)sulfanylacetate
    —— [(2S)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C18H25NO3S
    [(2S)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [(2R)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-(2-fluorophenyl)sulfanylacetate —— C16H20FNO3S
    [(2R)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-(2-fluorophenyl)sulfanylacetate
    —— [2-[[(3R)-1,1-dioxothiolan-3-yl]-ethylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C18H25NO5S2
    [2-[[(3R)-1,1-dioxothiolan-3-yl]-ethylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [2-[(2-Chlorophenyl)methylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C19H20ClNO3S
    [2-[(2-Chlorophenyl)methylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— ethyl (2R)-2-phenyl-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetate —— C18H16N2O3S
    ethyl (2R)-2-phenyl-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetate
    —— ethyl (2R)-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-2-phenylacetate —— C19H18N2O3S
    ethyl (2R)-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-2-phenylacetate
    —— [2-oxo-2-[[(2R)-2-phenylpropyl]amino]ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C21H25NO3S
    [2-oxo-2-[[(2R)-2-phenylpropyl]amino]ethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [2-[(3-Chlorophenyl)methylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C19H20ClNO3S
    [2-[(3-Chlorophenyl)methylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [2-[[(1R)-1-(3,4-dimethylphenyl)ethyl]amino]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C22H27NO3S
    [2-[[(1R)-1-(3,4-dimethylphenyl)ethyl]amino]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— [(2R)-1-(furan-2-ylmethylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C18H21NO4S
    [(2R)-1-(furan-2-ylmethylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— ethyl (3S,4S)-3-cyano-6-methyl-4-(4-methylsulfanylphenyl)-2-oxo-3,4-dihydro-1H-pyridine-5-carboxylate —— C17H18N2O3S
    ethyl (3S,4S)-3-cyano-6-methyl-4-(4-methylsulfanylphenyl)-2-oxo-3,4-dihydro-1H-pyridine-5-carboxylate
    —— [(2R)-1-(benzylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C20H23NO3S
    [(2R)-1-(benzylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— [2-[2-(4-Fluorophenyl)ethylamino]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C20H22FNO3S
    [2-[2-(4-Fluorophenyl)ethylamino]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— [2-[2-(2,4-Dioxo-1,3-thiazolidin-3-yl)ethylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C17H20N2O5S2
    [2-[2-(2,4-Dioxo-1,3-thiazolidin-3-yl)ethylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C16H21NO3S
    [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— [2-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C20H23NO4S
    [2-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [2-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C22H24N2O4S
    [2-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— [2-[2-(4-Chlorophenyl)ethylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate —— C20H22ClNO3S
    [2-[2-(4-Chlorophenyl)ethylamino]-2-oxoethyl] 2-(2,4-dimethylphenyl)sulfanylacetate
    —— [2-[2,5-dimethyl-1-[[(2S)-oxolan-2-yl]methyl]pyrrol-3-yl]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C23H29NO4S
    [2-[2,5-dimethyl-1-[[(2S)-oxolan-2-yl]methyl]pyrrol-3-yl]-2-oxoethyl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— [(2R)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C18H25NO3S
    [(2R)-1-(cyclopentylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— [(2S)-1-(benzylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate —— C20H23NO3S
    [(2S)-1-(benzylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylacetate
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C11H18N4O3S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2R)-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C8H14N4OS
    (2R)-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— N-[2-(4-chlorophenyl)ethyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C15H19ClN4OS
    N-[2-(4-chlorophenyl)ethyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-(1-cyanocyclopentyl)-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C13H19N5OS
    N-(1-cyanocyclopentyl)-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[(5-Cyano-2-pyridinyl)thio]acetamide, AldrichCPR —— C8H7N3OS
    2-[(5-Cyano-2-pyridinyl)thio]acetamide, AldrichCPR
    —— 2-(Allylthio)-5-chloropyridine, AldrichCPR —— C8H8ClNS
    2-(Allylthio)-5-chloropyridine, AldrichCPR
    —— 2-[(4-Cyano-2-pyridinyl)thio]acetamide, AldrichCPR —— C8H7N3OS
    2-[(4-Cyano-2-pyridinyl)thio]acetamide, AldrichCPR
    —— 5-Chloro-2-(ethylthio)pyrimidine —— C6H7ClN2S
    5-Chloro-2-(ethylthio)pyrimidine
    —— 2-[(5-Chloro-2-pyrimidinyl)thio]acetamide, AldrichCPR —— C6H6ClN3OS
    2-[(5-Chloro-2-pyrimidinyl)thio]acetamide, AldrichCPR
    —— 2-(Allylthio)-5-bromopyridine, AldrichCPR —— C8H8BrNS
    2-(Allylthio)-5-bromopyridine, AldrichCPR
    —— 2-(Allylthio)pyridine-5-carbonitrile, AldrichCPR —— C9H8N2S
    2-(Allylthio)pyridine-5-carbonitrile, AldrichCPR