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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 7-(Furan-2-yl)-1,3-dimethyl-5-(pyridin-3-ylmethylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4-dione —— C18H15N5O3S
    7-(Furan-2-yl)-1,3-dimethyl-5-(pyridin-3-ylmethylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4-dione
    —— 1-[(6S)-4-(6-amino-2-methylsulfanylpyrimidin-4-yl)-6-hydroxy-1,4-diazepan-1-yl]ethanone —— C12H19N5O2S
    1-[(6S)-4-(6-amino-2-methylsulfanylpyrimidin-4-yl)-6-hydroxy-1,4-diazepan-1-yl]ethanone
    —— 1-[(6R)-4-(6-amino-2-methylsulfanylpyrimidin-4-yl)-6-hydroxy-1,4-diazepan-1-yl]ethanone —— C12H19N5O2S
    1-[(6R)-4-(6-amino-2-methylsulfanylpyrimidin-4-yl)-6-hydroxy-1,4-diazepan-1-yl]ethanone
    —— 2-ethylsulfanyl-5-[1-[[(3R)-1-methylsulfonylpiperidin-3-yl]methyl]triazol-4-yl]pyrimidine —— C15H22N6O2S2
    2-ethylsulfanyl-5-[1-[[(3R)-1-methylsulfonylpiperidin-3-yl]methyl]triazol-4-yl]pyrimidine
    —— 2-ethylsulfanyl-5-[1-[[(3S)-1-methylsulfonylpiperidin-3-yl]methyl]triazol-4-yl]pyrimidine —— C15H22N6O2S2
    2-ethylsulfanyl-5-[1-[[(3S)-1-methylsulfonylpiperidin-3-yl]methyl]triazol-4-yl]pyrimidine
    —— (5R)-5-methyl-N-(3-phenylsulfanylpropyl)-1,4-oxazepane-4-carboxamide —— C16H24N2O2S
    (5R)-5-methyl-N-(3-phenylsulfanylpropyl)-1,4-oxazepane-4-carboxamide
    —— (5S)-5-methyl-N-(3-phenylsulfanylpropyl)-1,4-oxazepane-4-carboxamide —— C16H24N2O2S
    (5S)-5-methyl-N-(3-phenylsulfanylpropyl)-1,4-oxazepane-4-carboxamide
    —— 4-methyl-3-[(1R)-1-[4-[5-(4-methylphenyl)sulfanylfuran-2-yl]triazol-1-yl]ethyl]-1,2,4-triazole —— C18H18N6OS
    4-methyl-3-[(1R)-1-[4-[5-(4-methylphenyl)sulfanylfuran-2-yl]triazol-1-yl]ethyl]-1,2,4-triazole
    —— 4-methyl-3-[(1S)-1-[4-[5-(4-methylphenyl)sulfanylfuran-2-yl]triazol-1-yl]ethyl]-1,2,4-triazole —— C18H18N6OS
    4-methyl-3-[(1S)-1-[4-[5-(4-methylphenyl)sulfanylfuran-2-yl]triazol-1-yl]ethyl]-1,2,4-triazole
    —— (2R)-2-(4-chlorophenyl)sulfanylpropanoate —— C9H8ClO2S-
    (2R)-2-(4-chlorophenyl)sulfanylpropanoate
    —— 4-[(1S)-cyclohex-3-en-1-yl]-2-prop-2-enylsulfanyl-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile —— C18H20N2S
    4-[(1S)-cyclohex-3-en-1-yl]-2-prop-2-enylsulfanyl-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile
    —— 2-[[4-Ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C10H10N3O3S-
    2-[[4-Ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[(1S)-1-chloro-2,2,2-trifluoroethyl]sulfanylpyridine —— C7H5ClF3NS
    2-[(1S)-1-chloro-2,2,2-trifluoroethyl]sulfanylpyridine
    —— 2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]ethylazanium —— C5H9N4O2S+
    2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]ethylazanium
    —— 2-methylsulfanyl-4-[(3S)-3-[1-(pyridin-4-ylmethyl)imidazol-2-yl]piperidin-1-yl]pyrimidine —— C19H22N6S
    2-methylsulfanyl-4-[(3S)-3-[1-(pyridin-4-ylmethyl)imidazol-2-yl]piperidin-1-yl]pyrimidine
    —— 2-methylsulfanyl-4-[(3R)-3-[1-(pyridin-4-ylmethyl)imidazol-2-yl]piperidin-1-yl]pyrimidine —— C19H22N6S
    2-methylsulfanyl-4-[(3R)-3-[1-(pyridin-4-ylmethyl)imidazol-2-yl]piperidin-1-yl]pyrimidine
    —— {[5-(4-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetate 49809-28-1 C10H6ClN2O3S-
    {[5-(4-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetate
    —— (1'S,5'R)-spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxylate —— C12H17O2S2-
    (1'S,5'R)-spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxylate
    —— (1R,5S)-spiro[bicyclo[3.3.1]nonane-9,2'-[1,3]dithiolane]-3-carboxylic acid —— C12H18O2S2
    (1R,5S)-spiro[bicyclo[3.3.1]nonane-9,2'-[1,3]dithiolane]-3-carboxylic acid
    —— 2-(2,3-Dihydroimidazo[2,1-b][1,3]thiazol-6-yl)ethylazanium —— C7H12N3S+
    2-(2,3-Dihydroimidazo[2,1-b][1,3]thiazol-6-yl)ethylazanium
    —— 2-[4-[[(2R)-oxolan-2-yl]methyl]phenyl]sulfanylacetamide —— C13H17NO2S
    2-[4-[[(2R)-oxolan-2-yl]methyl]phenyl]sulfanylacetamide
    —— 2-[4-[[(2S)-oxolan-2-yl]methyl]phenyl]sulfanylacetamide —— C13H17NO2S
    2-[4-[[(2S)-oxolan-2-yl]methyl]phenyl]sulfanylacetamide
    —— methyl (1S,6R)-3-(4-chlorophenyl)sulfanyl-2-hydroxy-4-oxo-6-phenylcyclohex-2-ene-1-carboxylate —— C20H17ClO4S
    methyl (1S,6R)-3-(4-chlorophenyl)sulfanyl-2-hydroxy-4-oxo-6-phenylcyclohex-2-ene-1-carboxylate
    —— 2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S)-2-(3-pyridin-2-yl-1,2,4-oxadiazol-5-yl)pyrrolidin-1-yl]ethanone —— C16H17N7O2S
    2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S)-2-(3-pyridin-2-yl-1,2,4-oxadiazol-5-yl)pyrrolidin-1-yl]ethanone
    —— 2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(2R)-2-(3-pyridin-2-yl-1,2,4-oxadiazol-5-yl)pyrrolidin-1-yl]ethanone —— C16H17N7O2S
    2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-1-[(2R)-2-(3-pyridin-2-yl-1,2,4-oxadiazol-5-yl)pyrrolidin-1-yl]ethanone
    —— (2R)-2,3,3,3-tetrafluoro-2-methoxy-N-(3-nitro-5-phenylsulfanylphenyl)propanamide —— C16H12F4N2O4S
    (2R)-2,3,3,3-tetrafluoro-2-methoxy-N-(3-nitro-5-phenylsulfanylphenyl)propanamide
    —— 4-(4-Morpholin-4-ium-4-ylbutylsulfanyl)phenol —— C14H22NO2S+
    4-(4-Morpholin-4-ium-4-ylbutylsulfanyl)phenol
    —— (2R)-2-[[5-[(2R)-1-amino-1-oxobutan-2-yl]sulfanyl-1,2,4-thiadiazol-3-yl]sulfanyl]butanamide —— C10H16N4O2S3
    (2R)-2-[[5-[(2R)-1-amino-1-oxobutan-2-yl]sulfanyl-1,2,4-thiadiazol-3-yl]sulfanyl]butanamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-(4-methylphenyl)sulfanylacetamide —— C14H19NO3S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-(4-methylphenyl)sulfanylacetamide
    —— (2R)-1-[4-(3-methylpyridin-4-yl)-1,4-diazepan-1-yl]-2-pyridin-2-ylsulfanylpropan-1-one —— C19H24N4OS
    (2R)-1-[4-(3-methylpyridin-4-yl)-1,4-diazepan-1-yl]-2-pyridin-2-ylsulfanylpropan-1-one
    —— (2S)-1-[4-(3-methylpyridin-4-yl)-1,4-diazepan-1-yl]-2-pyridin-2-ylsulfanylpropan-1-one —— C19H24N4OS
    (2S)-1-[4-(3-methylpyridin-4-yl)-1,4-diazepan-1-yl]-2-pyridin-2-ylsulfanylpropan-1-one
    —— [(1R)-1-[4-benzyl-5-[(2R)-1-(cyclohexylamino)-1-oxopropan-2-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C23H36N5OS+
    [(1R)-1-[4-benzyl-5-[(2R)-1-(cyclohexylamino)-1-oxopropan-2-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexyl-N-ethylacetamide —— C23H28N4O2S
    2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexyl-N-ethylacetamide
    —— 3-[[5-[2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid —— C11H15N3O5S4
    3-[[5-[2-[[(3S)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid
    —— (2E)-2-cyano-N-cyclopropyl-2-[(5E)-5-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]-4-oxo-3-prop-2-enyl-1,3-thiazolidin-2-ylidene]acetamide —— C23H20N6O4S2
    (2E)-2-cyano-N-cyclopropyl-2-[(5E)-5-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]-4-oxo-3-prop-2-enyl-1,3-thiazolidin-2-ylidene]acetamide
    —— N-[(1R,2S,3S)-2,3-dimethylcyclohexyl]-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C19H26N4OS2
    N-[(1R,2S,3S)-2,3-dimethylcyclohexyl]-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-(6-Amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanylacetamide —— C9H8N5OS+
    2-(6-Amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanylacetamide
    —— 7-methylsulfanyl-4-oxo-6H-[1,2,4]triazolo[5,1-c][1,2,4]triazine-3-carboxylate —— C6H4N5O3S-
    7-methylsulfanyl-4-oxo-6H-[1,2,4]triazolo[5,1-c][1,2,4]triazine-3-carboxylate
    —— 1-(2-hydroxyethyl)-3-[(1S,5S)-3,3,5-trimethylcyclohexyl]thiourea —— C12H24N2OS
    1-(2-hydroxyethyl)-3-[(1S,5S)-3,3,5-trimethylcyclohexyl]thiourea
    —— 3-Ethylsulfanyl-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile —— C16H22N3OS+
    3-Ethylsulfanyl-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile
    —— 3-Methylsulfanyl-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile —— C15H20N3OS+
    3-Methylsulfanyl-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile
    —— 2-(6-Amino-3,5-dicyano-4-methylpyridin-1-ium-2-yl)sulfanylacetamide —— C10H10N5OS+
    2-(6-Amino-3,5-dicyano-4-methylpyridin-1-ium-2-yl)sulfanylacetamide
    —— 3-(2-Methylpropylsulfanyl)-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile —— C18H26N3OS+
    3-(2-Methylpropylsulfanyl)-1-morpholin-4-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-4-carbonitrile
    —— methyl (5S)-5-bromo-4-(4-chlorophenyl)sulfanyl-2,5-dihydrothiophene-3-carboxylate —— C12H10BrClO2S2
    methyl (5S)-5-bromo-4-(4-chlorophenyl)sulfanyl-2,5-dihydrothiophene-3-carboxylate
    —— methyl 2,2-dicyano-N-prop-2-enylethanimidothioate —— C8H9N3S
    methyl 2,2-dicyano-N-prop-2-enylethanimidothioate
    —— (6S)-2-butylsulfanyl-4,4,6-trimethyl-5,6-dihydro-1,3-oxazine —— C11H21NOS
    (6S)-2-butylsulfanyl-4,4,6-trimethyl-5,6-dihydro-1,3-oxazine
    —— 2,2-dimethyl-N-[(1R)-2,2,2-trichloro-1-[2-[2,2-dichloro-1-(2,2-dimethylpropanoylamino)ethenyl]sulfanyl-6-methylpyrimidin-4-yl]oxyethyl]propanamide —— C19H25Cl5N4O3S
    2,2-dimethyl-N-[(1R)-2,2,2-trichloro-1-[2-[2,2-dichloro-1-(2,2-dimethylpropanoylamino)ethenyl]sulfanyl-6-methylpyrimidin-4-yl]oxyethyl]propanamide
    —— (6R)-2-butylsulfanyl-4,4,6-trimethyl-5,6-dihydro-1,3-oxazine —— C11H21NOS
    (6R)-2-butylsulfanyl-4,4,6-trimethyl-5,6-dihydro-1,3-oxazine
    —— 4-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]-2-methoxycyclohexa-2,5-dien-1-one —— C19H19N3O2S
    4-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]-2-methoxycyclohexa-2,5-dien-1-one
    —— Diethyl 2-(6-amino-3,5-dicyano-4-methylsulfanylpyridin-1-ium-2-yl)sulfanyl-2-methylpropanedioate —— C16H19N4O4S2+
    Diethyl 2-(6-amino-3,5-dicyano-4-methylsulfanylpyridin-1-ium-2-yl)sulfanyl-2-methylpropanedioate