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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(3-methylbutan-2-yl)acetamide —— C17H24N4OS2
    2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(3-methylbutan-2-yl)acetamide
    —— N-(1-cyano-1,2-dimethylpropyl)-2-[(5-hydroxy-4-propyl-4H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C13H21N5O2S
    N-(1-cyano-1,2-dimethylpropyl)-2-[(5-hydroxy-4-propyl-4H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-butan-2-yl-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H22N4OS2
    N-butan-2-yl-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (Z)-hex-1-ene-1,2-dithiol —— C6H12S2
    (Z)-hex-1-ene-1,2-dithiol
    —— 6-[(2-aminoethylamino)methylidene]cyclohexa-2,4-diene-1-thione —— C9H12N2S
    6-[(2-aminoethylamino)methylidene]cyclohexa-2,4-diene-1-thione
    —— 2-(4-bromophenyl)sulfanyl-N-[(1S)-1-(2H-tetrazol-5-yl)butyl]acetamide —— C13H16BrN5OS
    2-(4-bromophenyl)sulfanyl-N-[(1S)-1-(2H-tetrazol-5-yl)butyl]acetamide
    —— methyl (2Z)-3-[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]prop-2-enoate —— C13H11N3O2S
    methyl (2Z)-3-[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]prop-2-enoate
    —— 2-(4-bromophenyl)sulfanyl-N-[(1R)-1-(2H-tetrazol-5-yl)butyl]acetamide —— C13H16BrN5OS
    2-(4-bromophenyl)sulfanyl-N-[(1R)-1-(2H-tetrazol-5-yl)butyl]acetamide
    —— tert-butyl N-[(E)-(4-methylsulfanylphenyl)methylideneamino]carbamate —— C13H18N2O2S
    tert-butyl N-[(E)-(4-methylsulfanylphenyl)methylideneamino]carbamate
    —— methyl (2E)-2-[4-(methylsulfanyl)benzylidene]hydrazinecarboxylate —— C10H12N2O2S
    methyl (2E)-2-[4-(methylsulfanyl)benzylidene]hydrazinecarboxylate
    —— 1-(2-methylprop-2-enyl)-3-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]thiourea —— C15H17N7O2S2
    1-(2-methylprop-2-enyl)-3-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]thiourea
    —— tert-butyl N-[(3S,4R)-3-ethyl-1-(2-phenylsulfanylpyridine-3-carbonyl)piperidin-4-yl]carbamate —— C24H31N3O3S
    tert-butyl N-[(3S,4R)-3-ethyl-1-(2-phenylsulfanylpyridine-3-carbonyl)piperidin-4-yl]carbamate
    —— tert-butyl N-[(3R,4R)-3-ethyl-1-(2-phenylsulfanylpyridine-3-carbonyl)piperidin-4-yl]carbamate —— C24H31N3O3S
    tert-butyl N-[(3R,4R)-3-ethyl-1-(2-phenylsulfanylpyridine-3-carbonyl)piperidin-4-yl]carbamate
    —— 1-(3-chloro-2-methylphenyl)-3-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]thiourea —— C18H16ClN7O2S2
    1-(3-chloro-2-methylphenyl)-3-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]thiourea
    —— tert-butyl N-[(3S,4S)-3-ethyl-1-(2-phenylsulfanylpyridine-3-carbonyl)piperidin-4-yl]carbamate —— C24H31N3O3S
    tert-butyl N-[(3S,4S)-3-ethyl-1-(2-phenylsulfanylpyridine-3-carbonyl)piperidin-4-yl]carbamate
    —— tert-butyl N-[(3R,4S)-3-ethyl-1-(2-phenylsulfanylpyridine-3-carbonyl)piperidin-4-yl]carbamate —— C24H31N3O3S
    tert-butyl N-[(3R,4S)-3-ethyl-1-(2-phenylsulfanylpyridine-3-carbonyl)piperidin-4-yl]carbamate
    —— 3-butyl-1-methyl-1-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]thiourea —— C16H21N7O2S2
    3-butyl-1-methyl-1-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]thiourea
    —— N-[(E)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]cyclopropanecarboxamide —— C15H13N5O3S
    N-[(E)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]cyclopropanecarboxamide
    —— (E)-N-(4-methylpiperazin-1-yl)-1-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methanimine —— C15H19N7O2S
    (E)-N-(4-methylpiperazin-1-yl)-1-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methanimine
    —— (E)-4-(3-bromophenyl)-N-(2-methoxyethyl)-3-[(E)-(4-methylsulfanylphenyl)methylideneamino]-1,3-thiazol-2-imine —— C20H20BrN3OS2
    (E)-4-(3-bromophenyl)-N-(2-methoxyethyl)-3-[(E)-(4-methylsulfanylphenyl)methylideneamino]-1,3-thiazol-2-imine
    —— N-[(2R)-butan-2-yl]-5-[(2-thiophen-2-yl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C14H16N4S4
    N-[(2R)-butan-2-yl]-5-[(2-thiophen-2-yl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-[(2S)-butan-2-yl]-5-[(2-thiophen-2-yl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C14H16N4S4
    N-[(2S)-butan-2-yl]-5-[(2-thiophen-2-yl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 3-nitro-4-(phenylsulfanyl)benzenecarbaldehyde O-(2,6-dichlorobenzyl)oxime —— C20H14Cl2N2O3S
    3-nitro-4-(phenylsulfanyl)benzenecarbaldehyde O-(2,6-dichlorobenzyl)oxime
    —— 2-(2-pyrimidinylthio)-N'-(2-thienylmethylene)acetohydrazide —— C11H10N4OS2
    2-(2-pyrimidinylthio)-N'-(2-thienylmethylene)acetohydrazide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-methyl-N-[(E)-(5-methyl-2-methylsulfanylthiophen-3-yl)methylideneamino]triazole-4-carboxamide —— C13H14N8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-methyl-N-[(E)-(5-methyl-2-methylsulfanylthiophen-3-yl)methylideneamino]triazole-4-carboxamide
    —— 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[(1R,2R)-1-(4-methylphenyl)-1-(1,2,4-triazol-1-yl)butan-2-yl]propanamide —— C23H30N6OS
    3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[(1R,2R)-1-(4-methylphenyl)-1-(1,2,4-triazol-1-yl)butan-2-yl]propanamide
    —— N'-[(E)-(3-chlorophenyl)methylidene]-2-(pyrimidin-2-ylsulfanyl)acetohydrazide —— C13H11ClN4OS
    N'-[(E)-(3-chlorophenyl)methylidene]-2-(pyrimidin-2-ylsulfanyl)acetohydrazide
    —— 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[(1R,2S)-1-(4-methylphenyl)-1-(1,2,4-triazol-1-yl)butan-2-yl]propanamide —— C23H30N6OS
    3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[(1R,2S)-1-(4-methylphenyl)-1-(1,2,4-triazol-1-yl)butan-2-yl]propanamide
    —— (2S)-N-[(E)-(2-chlorophenyl)methylideneamino]-2-pyrimidin-2-ylsulfanylpropanamide —— C14H13ClN4OS
    (2S)-N-[(E)-(2-chlorophenyl)methylideneamino]-2-pyrimidin-2-ylsulfanylpropanamide
    —— 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[(1S,2R)-1-(4-methylphenyl)-1-(1,2,4-triazol-1-yl)butan-2-yl]propanamide —— C23H30N6OS
    3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[(1S,2R)-1-(4-methylphenyl)-1-(1,2,4-triazol-1-yl)butan-2-yl]propanamide
    —— 4,6-dimethyl-1-({(E)-[4-(methylsulfanyl)phenyl]methylidene}amino)pyridin-2(1H)-one —— C15H16N2OS
    4,6-dimethyl-1-({(E)-[4-(methylsulfanyl)phenyl]methylidene}amino)pyridin-2(1H)-one
    —— 1-[4-[(3S)-2,3-dihydro-1-benzothiophene-3-carbonyl]-1,4-diazepan-1-yl]propan-1-one —— C17H22N2O2S
    1-[4-[(3S)-2,3-dihydro-1-benzothiophene-3-carbonyl]-1,4-diazepan-1-yl]propan-1-one
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-1-(2,3,6-trichlorophenyl)methanimine —— C19H16BrCl3N4S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-1-(2,3,6-trichlorophenyl)methanimine
    —— (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-1-(3-methylthiophen-2-yl)methanimine —— C18H19ClN4S2
    (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-1-(3-methylthiophen-2-yl)methanimine
    —— N-[(E)-[2-(4-methylphenyl)sulfanylquinolin-3-yl]methylideneamino]furan-2-carboxamide —— C22H17N3O2S
    N-[(E)-[2-(4-methylphenyl)sulfanylquinolin-3-yl]methylideneamino]furan-2-carboxamide
    —— 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[(1S,2S)-1-(4-methylphenyl)-1-(1,2,4-triazol-1-yl)butan-2-yl]propanamide —— C23H30N6OS
    3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[(1S,2S)-1-(4-methylphenyl)-1-(1,2,4-triazol-1-yl)butan-2-yl]propanamide
    —— 1-[4-[(3S)-2,3-dihydro-1-benzothiophene-3-carbonyl]piperazin-1-yl]propan-1-one —— C16H20N2O2S
    1-[4-[(3S)-2,3-dihydro-1-benzothiophene-3-carbonyl]piperazin-1-yl]propan-1-one
    —— 1-[4-[(3R)-2,3-dihydro-1-benzothiophene-3-carbonyl]piperazin-1-yl]propan-1-one —— C16H20N2O2S
    1-[4-[(3R)-2,3-dihydro-1-benzothiophene-3-carbonyl]piperazin-1-yl]propan-1-one
    —— 2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]-N-[(E)-(4-fluorophenyl)methylideneamino]acetamide —— C12H10FN5O3S
    2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]-N-[(E)-(4-fluorophenyl)methylideneamino]acetamide
    —— 1-[4-[(3R)-2,3-dihydro-1-benzothiophene-3-carbonyl]-1,4-diazepan-1-yl]propan-1-one —— C17H22N2O2S
    1-[4-[(3R)-2,3-dihydro-1-benzothiophene-3-carbonyl]-1,4-diazepan-1-yl]propan-1-one
    —— N'-[(E)-(4-fluorophenyl)methylidene]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetohydrazide —— C11H10FN5OS
    N'-[(E)-(4-fluorophenyl)methylidene]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetohydrazide
    —— 4-chloro-N'-[(E)-{5-[(6-ethoxy-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]benzohydrazide —— C21H16ClN3O3S2
    4-chloro-N'-[(E)-{5-[(6-ethoxy-1,3-benzothiazol-2-yl)sulfanyl]furan-2-yl}methylidene]benzohydrazide
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-thiophen-2-ylmethanimine —— C15H13BrN4S2
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-thiophen-2-ylmethanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propan-2-yl-1,2,4-triazol-4-yl]-1-(2-chloro-6-fluorophenyl)methanimine —— C19H17BrClFN4S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propan-2-yl-1,2,4-triazol-4-yl]-1-(2-chloro-6-fluorophenyl)methanimine
    —— (E,Z)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-2-methyl-3-phenylprop-2-en-1-imine —— C22H23BrN4S
    (E,Z)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-2-methyl-3-phenylprop-2-en-1-imine
    —— (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-1-(4-fluorophenyl)methanimine —— C19H18ClFN4S
    (E)-N-[3-[(4-chlorophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-1-(4-fluorophenyl)methanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propan-2-yl-1,2,4-triazol-4-yl]-1-(2,3,6-trichlorophenyl)methanimine —— C19H16BrCl3N4S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propan-2-yl-1,2,4-triazol-4-yl]-1-(2,3,6-trichlorophenyl)methanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(3-methylthiophen-2-yl)methanimine —— C16H15BrN4S2
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(3-methylthiophen-2-yl)methanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-1-(4-ethylphenyl)methanimine —— C21H23BrN4S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-1-(4-ethylphenyl)methanimine
    —— 4-[(E)-[3-[(4-bromophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]iminomethyl]-N,N-dimethylaniline —— C21H24BrN5S
    4-[(E)-[3-[(4-bromophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]iminomethyl]-N,N-dimethylaniline