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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-(2-Phenylsulfanylethyl)piperazine-1,4-diium —— C12H20N2S+2
    1-(2-Phenylsulfanylethyl)piperazine-1,4-diium
    —— 2-[[(2S)-2-methyl-3H-thiophen-2-yl]oxy]acetonitrile —— C7H9NOS
    2-[[(2S)-2-methyl-3H-thiophen-2-yl]oxy]acetonitrile
    —— Dimethyl-[2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethyl]azanium —— C12H16N3OS+
    Dimethyl-[2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethyl]azanium
    —— 4-[(6R)-8-chloro-6H-benzo[c][1,5]benzoxathiepin-6-yl]-1-methylpiperidin-1-ium —— C19H21ClNOS+
    4-[(6R)-8-chloro-6H-benzo[c][1,5]benzoxathiepin-6-yl]-1-methylpiperidin-1-ium
    —— [(2S)-1-[2-(2-hydroxyphenyl)sulfanylphenyl]propan-2-yl]-dimethylazanium —— C17H22NOS+
    [(2S)-1-[2-(2-hydroxyphenyl)sulfanylphenyl]propan-2-yl]-dimethylazanium
    —— (5S,9S)-N-[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-6-oxa-2-thiaspiro[4.5]decan-9-amine —— C16H23NOS3
    (5S,9S)-N-[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-6-oxa-2-thiaspiro[4.5]decan-9-amine
    —— (5S,9R)-N-[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-6-oxa-2-thiaspiro[4.5]decan-9-amine —— C16H23NOS3
    (5S,9R)-N-[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-6-oxa-2-thiaspiro[4.5]decan-9-amine
    —— (5S,9S)-N-[(4S,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-6-oxa-2-thiaspiro[4.5]decan-9-amine —— C16H23NOS3
    (5S,9S)-N-[(4S,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-6-oxa-2-thiaspiro[4.5]decan-9-amine
    —— (5S,9R)-N-[(4S,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-6-oxa-2-thiaspiro[4.5]decan-9-amine —— C16H23NOS3
    (5S,9R)-N-[(4S,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-6-oxa-2-thiaspiro[4.5]decan-9-amine
    —— [(2R)-1-[2-(4-hydroxyphenyl)sulfanylphenyl]propan-2-yl]-methylazanium —— C16H20NOS+
    [(2R)-1-[2-(4-hydroxyphenyl)sulfanylphenyl]propan-2-yl]-methylazanium
    —— 1-[3-[(6R)-6H-benzo[c][1,5]benzoxathiepin-6-yl]propyl]piperidin-1-ium —— C21H26NOS+
    1-[3-[(6R)-6H-benzo[c][1,5]benzoxathiepin-6-yl]propyl]piperidin-1-ium
    —— [(2R)-1-[2-(4-hydroxyphenyl)sulfanylphenyl]propan-2-yl]azanium —— C15H18NOS+
    [(2R)-1-[2-(4-hydroxyphenyl)sulfanylphenyl]propan-2-yl]azanium
    —— (1R)-2,2-dimethyl-N-[(3R)-3-[(S)-methylsulfinyl]butyl]cyclopentan-1-amine —— C12H25NOS
    (1R)-2,2-dimethyl-N-[(3R)-3-[(S)-methylsulfinyl]butyl]cyclopentan-1-amine
    —— (1S)-2,2-dimethyl-N-[(3S)-3-[(S)-methylsulfinyl]butyl]cyclopentan-1-amine —— C12H25NOS
    (1S)-2,2-dimethyl-N-[(3S)-3-[(S)-methylsulfinyl]butyl]cyclopentan-1-amine
    —— (1R)-2,2-dimethyl-N-[(3S)-3-[(S)-methylsulfinyl]butyl]cyclopentan-1-amine —— C12H25NOS
    (1R)-2,2-dimethyl-N-[(3S)-3-[(S)-methylsulfinyl]butyl]cyclopentan-1-amine
    —— (5R)-2-(4-chlorophenyl)sulfanyl-3-hydroxy-5-phenylcyclohex-2-en-1-one —— C18H15ClO2S
    (5R)-2-(4-chlorophenyl)sulfanyl-3-hydroxy-5-phenylcyclohex-2-en-1-one
    —— (4-Methylpiperazin-4-ium-1-yl)-(2-phenylsulfanylphenyl)methanone —— C18H21N2OS+
    (4-Methylpiperazin-4-ium-1-yl)-(2-phenylsulfanylphenyl)methanone
    —— (1R,2S,7S,8S)-4-(4,6-dimethylpyridin-2-yl)sulfanyl-5-hydroxytricyclo[6.2.1.02,7]undeca-4,9-diene-3,6-dione —— C18H17NO3S
    (1R,2S,7S,8S)-4-(4,6-dimethylpyridin-2-yl)sulfanyl-5-hydroxytricyclo[6.2.1.02,7]undeca-4,9-diene-3,6-dione
    —— 2-[2-(4-Aminophenyl)sulfanylphenyl]acetate —— C14H12NO2S-
    2-[2-(4-Aminophenyl)sulfanylphenyl]acetate
    —— [3-(4-Chlorophenyl)sulfanylphenyl]methyl-dimethylazanium —— C15H17ClNS+
    [3-(4-Chlorophenyl)sulfanylphenyl]methyl-dimethylazanium
    —— [2-(4-Bromophenyl)sulfanylphenyl]methyl-dimethylazanium —— C15H17BrNS+
    [2-(4-Bromophenyl)sulfanylphenyl]methyl-dimethylazanium
    —— dimethyl-[2-[(2-sulfanylidene-3H-1,3,4-thiadiazol-5-yl)sulfanyl]ethyl]azanium —— C6H12N3S3+
    dimethyl-[2-[(2-sulfanylidene-3H-1,3,4-thiadiazol-5-yl)sulfanyl]ethyl]azanium
    —— [2-[2-Amino-4-(trifluoromethyl)phenyl]sulfanyl-5-fluorophenyl]methyl-dimethylazanium —— C16H17F4N2S+
    [2-[2-Amino-4-(trifluoromethyl)phenyl]sulfanyl-5-fluorophenyl]methyl-dimethylazanium
    —— 2-Phenylsulfanylcarbonylsulfanylacetate —— C9H7O3S2-
    2-Phenylsulfanylcarbonylsulfanylacetate
    —— (2S)-2-(3-bromothiophen-2-yl)sulfanylpropanoate —— C7H6BrO2S2-
    (2S)-2-(3-bromothiophen-2-yl)sulfanylpropanoate
    —— 1-[2-(4-Chlorophenyl)sulfanylethyl]-4-methylpiperazine-1,4-diium —— C13H21ClN2S+2
    1-[2-(4-Chlorophenyl)sulfanylethyl]-4-methylpiperazine-1,4-diium
    —— (2S)-2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate —— C8H9N2O3S-
    (2S)-2-[(4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoate
    —— (5R)-N-[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-4,5,6,7-tetrahydro-1H-indazol-5-amine —— C15H19N3S2
    (5R)-N-[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-4,5,6,7-tetrahydro-1H-indazol-5-amine
    —— (5S)-N-[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-4,5,6,7-tetrahydro-1H-indazol-5-amine —— C15H19N3S2
    (5S)-N-[(4R,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-4,5,6,7-tetrahydro-1H-indazol-5-amine
    —— (2R)-2-(4-bromothiophen-3-yl)sulfanylpropanoate —— C7H6BrO2S2-
    (2R)-2-(4-bromothiophen-3-yl)sulfanylpropanoate
    —— (1S)-2,2-dimethyl-N-[(3R)-3-[(S)-methylsulfinyl]butyl]cyclopentan-1-amine —— C12H25NOS
    (1S)-2,2-dimethyl-N-[(3R)-3-[(S)-methylsulfinyl]butyl]cyclopentan-1-amine
    —— (5S)-N-[(4S,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-4,5,6,7-tetrahydro-1H-indazol-5-amine —— C15H19N3S2
    (5S)-N-[(4S,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-4,5,6,7-tetrahydro-1H-indazol-5-amine
    —— 3-Phenylsulfanylbenzoate —— C13H9O2S-
    3-Phenylsulfanylbenzoate
    —— (5R)-N-[(4S,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-4,5,6,7-tetrahydro-1H-indazol-5-amine —— C15H19N3S2
    (5R)-N-[(4S,6S)-6-methyl-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-yl]-4,5,6,7-tetrahydro-1H-indazol-5-amine
    —— 2-Amino-6-benzylsulfanyl-4-thiophen-2-ylpyridin-1-ium-3,5-dicarbonitrile —— C18H13N4S2+
    2-Amino-6-benzylsulfanyl-4-thiophen-2-ylpyridin-1-ium-3,5-dicarbonitrile
    —— N-[(1S)-1-(3-fluoro-4-methylsulfanylphenyl)ethyl]hex-5-yn-1-amine —— C15H20FNS
    N-[(1S)-1-(3-fluoro-4-methylsulfanylphenyl)ethyl]hex-5-yn-1-amine
    —— N-[(1R)-1-(3-fluoro-4-methylsulfanylphenyl)ethyl]hex-5-yn-1-amine —— C15H20FNS
    N-[(1R)-1-(3-fluoro-4-methylsulfanylphenyl)ethyl]hex-5-yn-1-amine
    —— 2-[[4-Cyclohexyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C14H16N3O3S-
    2-[[4-Cyclohexyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— (1R,8R,9S)-8-(4-methylphenyl)-2,6-dithia-4,11-diazatricyclo[7.3.0.03,7]dodec-3(7)-ene-5,10,12-trione —— C15H12N2O3S2
    (1R,8R,9S)-8-(4-methylphenyl)-2,6-dithia-4,11-diazatricyclo[7.3.0.03,7]dodec-3(7)-ene-5,10,12-trione
    —— (1S)-2,2-dimethyl-N-[[1-(methylsulfonylmethyl)cyclopropyl]methyl]cyclopentan-1-amine —— C13H25NO2S
    (1S)-2,2-dimethyl-N-[[1-(methylsulfonylmethyl)cyclopropyl]methyl]cyclopentan-1-amine
    —— (1R)-2,2-dimethyl-N-[[1-(methylsulfonylmethyl)cyclopropyl]methyl]cyclopentan-1-amine —— C13H25NO2S
    (1R)-2,2-dimethyl-N-[[1-(methylsulfonylmethyl)cyclopropyl]methyl]cyclopentan-1-amine
    —— (7S,8R)-7-bromo-2-methyl-8-phenyl-4,6,7,8-tetrahydro-[1,3]thiazino[3,2-b][1,2,4]triazin-9-ium-3-one —— C13H13BrN3OS+
    (7S,8R)-7-bromo-2-methyl-8-phenyl-4,6,7,8-tetrahydro-[1,3]thiazino[3,2-b][1,2,4]triazin-9-ium-3-one
    —— (7S,8S)-7-bromo-2-methyl-8-phenyl-4,6,7,8-tetrahydro-[1,3]thiazino[3,2-b][1,2,4]triazin-9-ium-3-one —— C13H13BrN3OS+
    (7S,8S)-7-bromo-2-methyl-8-phenyl-4,6,7,8-tetrahydro-[1,3]thiazino[3,2-b][1,2,4]triazin-9-ium-3-one
    —— 4-(Dimethylamino)-2-phenylsulfanylpyridin-1-ium-3-carbonitrile —— C14H14N3S+
    4-(Dimethylamino)-2-phenylsulfanylpyridin-1-ium-3-carbonitrile
    —— 2-(N-cyclohexyl-C-methylcarbonimidoyl)-1-benzothiophen-3-one —— C16H19NOS
    2-(N-cyclohexyl-C-methylcarbonimidoyl)-1-benzothiophen-3-one
    —— 3-[(Z)-but-2-enyl]sulfanyl-5-tert-butyl-1H-1,2,4-triazole —— C10H17N3S
    3-[(Z)-but-2-enyl]sulfanyl-5-tert-butyl-1H-1,2,4-triazole
    —— (4S,6S)-6-methyl-N-[(4-propan-2-yl-1,2,4-triazol-3-yl)methyl]-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-amine —— C14H20N4S2
    (4S,6S)-6-methyl-N-[(4-propan-2-yl-1,2,4-triazol-3-yl)methyl]-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-amine
    —— (3S)-3-phenylsulfanyl-2,3-dihydro-1-benzothiophene 1,1-dioxide —— C14H12O2S2
    (3S)-3-phenylsulfanyl-2,3-dihydro-1-benzothiophene 1,1-dioxide
    —— (4R,6S)-6-methyl-N-[(4-propan-2-yl-1,2,4-triazol-3-yl)methyl]-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-amine —— C14H20N4S2
    (4R,6S)-6-methyl-N-[(4-propan-2-yl-1,2,4-triazol-3-yl)methyl]-5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-amine
    —— (3R)-1-(2-chloropyridin-3-yl)-3-(4-methylphenyl)sulfanylpyrrolidine-2,5-dione —— C16H13ClN2O2S
    (3R)-1-(2-chloropyridin-3-yl)-3-(4-methylphenyl)sulfanylpyrrolidine-2,5-dione