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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-[(3S)-3-(4-methylphenyl)-5-thiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-pyrimidin-2-ylsulfanylethanone —— C20H18N4OS2
    1-[(3S)-3-(4-methylphenyl)-5-thiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-pyrimidin-2-ylsulfanylethanone
    —— 1-[(3S)-3-(4-fluorophenyl)-5-thiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-(4-methylphenyl)sulfanylethanone —— C22H19FN2OS2
    1-[(3S)-3-(4-fluorophenyl)-5-thiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-(4-methylphenyl)sulfanylethanone
    —— (3S)-3-[1-(2-methoxyethyl)imidazol-2-yl]-1-(2-phenylsulfanylethyl)piperidine —— C19H27N3OS
    (3S)-3-[1-(2-methoxyethyl)imidazol-2-yl]-1-(2-phenylsulfanylethyl)piperidine
    —— (3R)-3-[1-(2-methoxyethyl)imidazol-2-yl]-1-(2-phenylsulfanylethyl)piperidine —— C19H27N3OS
    (3R)-3-[1-(2-methoxyethyl)imidazol-2-yl]-1-(2-phenylsulfanylethyl)piperidine
    —— 2-methylsulfanyl-6-[(3S)-3-[1-(pyridin-3-ylmethyl)imidazol-2-yl]piperidin-1-yl]pyrimidin-4-amine —— C19H23N7S
    2-methylsulfanyl-6-[(3S)-3-[1-(pyridin-3-ylmethyl)imidazol-2-yl]piperidin-1-yl]pyrimidin-4-amine
    —— N-(4-fluorobenzyl)-2-((6-methyl-5-oxo-4,5-dihydro-1,2,4-triazin-3-yl)thio)acetamide —— C13H13FN4O2S
    N-(4-fluorobenzyl)-2-((6-methyl-5-oxo-4,5-dihydro-1,2,4-triazin-3-yl)thio)acetamide
    —— 2-((1-(4-chlorobenzyl)-1H-imidazol-2-yl)thio)-N-phenethylacetamide —— C20H20ClN3OS
    2-((1-(4-chlorobenzyl)-1H-imidazol-2-yl)thio)-N-phenethylacetamide
    —— N-[(2-Chlorophenyl)methyl]-2-({1-[(furan-2-YL)methyl]-1H-imidazol-2-YL}sulfanyl)acetamide —— C17H16ClN3O2S
    N-[(2-Chlorophenyl)methyl]-2-({1-[(furan-2-YL)methyl]-1H-imidazol-2-YL}sulfanyl)acetamide
    —— 2-[1-(furan-2-ylmethyl)imidazol-2-yl]sulfanyl-N-propylacetamide —— C13H17N3O2S
    2-[1-(furan-2-ylmethyl)imidazol-2-yl]sulfanyl-N-propylacetamide
    —— N-[(2-Chlorophenyl)methyl]-2-({1-[(4-methylphenyl)methyl]-1H-imidazol-2-YL}sulfanyl)acetamide —— C20H20ClN3OS
    N-[(2-Chlorophenyl)methyl]-2-({1-[(4-methylphenyl)methyl]-1H-imidazol-2-YL}sulfanyl)acetamide
    —— 2-({1-[(4-Chlorophenyl)methyl]-1H-imidazol-2-YL}sulfanyl)-N-propylacetamide —— C15H18ClN3OS
    2-({1-[(4-Chlorophenyl)methyl]-1H-imidazol-2-YL}sulfanyl)-N-propylacetamide
    —— 3-((4-bromobenzyl)thio)-1,2,4-triazin-5(4H)-one —— C10H8BrN3OS
    3-((4-bromobenzyl)thio)-1,2,4-triazin-5(4H)-one
    —— 7-[(E)-2-hydroxy-4-oxopent-2-en-3-yl]sulfanyl-3-methyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one —— C10H10N4O3S2
    7-[(E)-2-hydroxy-4-oxopent-2-en-3-yl]sulfanyl-3-methyl-[1,3,4]thiadiazolo[2,3-c][1,2,4]triazin-4-one
    —— N-(3-methylsulfanylphenyl)piperidin-1-ium-4-amine —— C12H19N2S+
    N-(3-methylsulfanylphenyl)piperidin-1-ium-4-amine
    —— 2-({1-[(furan-2-yl)methyl]-1H-imidazol-2-yl}sulfanyl)-N-methylacetamide —— C11H13N3O2S
    2-({1-[(furan-2-yl)methyl]-1H-imidazol-2-yl}sulfanyl)-N-methylacetamide
    —— 2-(1-benzylimidazol-2-yl)sulfanyl-N-[(2-chlorophenyl)methyl]acetamide —— C19H18ClN3OS
    2-(1-benzylimidazol-2-yl)sulfanyl-N-[(2-chlorophenyl)methyl]acetamide
    —— 2-methylsulfanyl-6-[(3R)-3-[1-(pyridin-3-ylmethyl)imidazol-2-yl]piperidin-1-yl]pyrimidin-4-amine —— C19H23N7S
    2-methylsulfanyl-6-[(3R)-3-[1-(pyridin-3-ylmethyl)imidazol-2-yl]piperidin-1-yl]pyrimidin-4-amine
    —— N-(3-(Methylthio)phenyl)piperidin-4-amine —— C12H18N2S
    N-(3-(Methylthio)phenyl)piperidin-4-amine
    —— (9R)-7-amino-2-phenyl-9H-[1,2,4]triazolo[5,1-b][1,3]benzothiazin-9-ol —— C15H12N4OS
    (9R)-7-amino-2-phenyl-9H-[1,2,4]triazolo[5,1-b][1,3]benzothiazin-9-ol
    —— 2-[(4,6-Dimethylpyrimidin-2-yl)sulfanylmethylsulfanyl]acetate —— C9H11N2O2S2-
    2-[(4,6-Dimethylpyrimidin-2-yl)sulfanylmethylsulfanyl]acetate
    —— 2-(Pyrimidin-2-ylsulfanylmethylsulfanyl)acetate —— C7H7N2O2S2-
    2-(Pyrimidin-2-ylsulfanylmethylsulfanyl)acetate
    —— 6-[[4-[(3S)-oxolan-3-yl]triazol-1-yl]methyl]-2,3-dihydroimidazo[2,1-b][1,3]thiazole —— C12H15N5OS
    6-[[4-[(3S)-oxolan-3-yl]triazol-1-yl]methyl]-2,3-dihydroimidazo[2,1-b][1,3]thiazole
    —— 6-[[4-[(3R)-oxolan-3-yl]triazol-1-yl]methyl]-2,3-dihydroimidazo[2,1-b][1,3]thiazole —— C12H15N5OS
    6-[[4-[(3R)-oxolan-3-yl]triazol-1-yl]methyl]-2,3-dihydroimidazo[2,1-b][1,3]thiazole
    —— 2-[[[(2S)-2,3-dihydro-1-benzothiophene-2-carbonyl]amino]methyl]-N,N-dimethyl-6,7-dihydro-4H-pyrazolo[1,5-a]pyrazine-5-carboxamide —— C19H23N5O2S
    2-[[[(2S)-2,3-dihydro-1-benzothiophene-2-carbonyl]amino]methyl]-N,N-dimethyl-6,7-dihydro-4H-pyrazolo[1,5-a]pyrazine-5-carboxamide
    —— 2-[(2,4-Dimethyl-3,5-dioxo-2,3,4,5-tetrahydro-1,2,4-triazin-6-yl)sulfanyl]acetohydrazide —— C7H11N5O3S
    2-[(2,4-Dimethyl-3,5-dioxo-2,3,4,5-tetrahydro-1,2,4-triazin-6-yl)sulfanyl]acetohydrazide
    —— 3-[2-(2-Amino-2-oxoethyl)sulfanyl-4,6-dimethylpyrimidin-5-yl]propanoate —— C11H14N3O3S-
    3-[2-(2-Amino-2-oxoethyl)sulfanyl-4,6-dimethylpyrimidin-5-yl]propanoate
    —— 2-[[[(2R)-2,3-dihydro-1-benzothiophene-2-carbonyl]amino]methyl]-N,N-dimethyl-6,7-dihydro-4H-pyrazolo[1,5-a]pyrazine-5-carboxamide —— C19H23N5O2S
    2-[[[(2R)-2,3-dihydro-1-benzothiophene-2-carbonyl]amino]methyl]-N,N-dimethyl-6,7-dihydro-4H-pyrazolo[1,5-a]pyrazine-5-carboxamide
    —— 2-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)pyridine-3-carboxylate —— C14H10NO4S-
    2-(2,3-Dihydro-1,4-benzodioxin-6-ylsulfanyl)pyridine-3-carboxylate
    —— 2-(2,4-Difluorophenyl)sulfanylacetate —— C8H5F2O2S-
    2-(2,4-Difluorophenyl)sulfanylacetate
    —— 3-(3,4-Difluorophenyl)sulfanylpropanoate —— C9H7F2O2S-
    3-(3,4-Difluorophenyl)sulfanylpropanoate
    —— 2-(4-Chlorophenyl)sulfanylcyclohexene-1-carboxylate —— C13H12ClO2S-
    2-(4-Chlorophenyl)sulfanylcyclohexene-1-carboxylate
    —— 1-[(1S)-1-chloro-2,2,2-trifluoroethyl]sulfanyl-4-methylbenzene —— C9H8ClF3S
    1-[(1S)-1-chloro-2,2,2-trifluoroethyl]sulfanyl-4-methylbenzene
    —— 3-(4,6-Dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate —— C10H13N2O2S-
    3-(4,6-Dimethyl-2-methylsulfanylpyrimidin-5-yl)propanoate
    —— 2-(4-Methylphenyl)sulfanylcyclohexene-1-carboxylate —— C14H15O2S-
    2-(4-Methylphenyl)sulfanylcyclohexene-1-carboxylate
    —— 2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C21H31N5O2S
    2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— 2-[(2S)-2,3-dibromopropyl]sulfanyl-4,6-dimethylpyridine-3-carbonitrile —— C11H12Br2N2S
    2-[(2S)-2,3-dibromopropyl]sulfanyl-4,6-dimethylpyridine-3-carbonitrile
    —— 1-[(6S)-6-hydroxy-4-(2-phenylsulfanylethyl)-1,4-diazepan-1-yl]ethanone —— C15H22N2O2S
    1-[(6S)-6-hydroxy-4-(2-phenylsulfanylethyl)-1,4-diazepan-1-yl]ethanone
    —— 1-[(6R)-6-hydroxy-4-(2-phenylsulfanylethyl)-1,4-diazepan-1-yl]ethanone —— C15H22N2O2S
    1-[(6R)-6-hydroxy-4-(2-phenylsulfanylethyl)-1,4-diazepan-1-yl]ethanone
    —— N-(furan-2-ylmethyl)-2-((3-phenyl-1,2,4-thiadiazol-5-yl)thio)acetamide —— C15H13N3O2S2
    N-(furan-2-ylmethyl)-2-((3-phenyl-1,2,4-thiadiazol-5-yl)thio)acetamide
    —— N-benzyl-2-((3-(o-tolyl)-1,2,4-thiadiazol-5-yl)thio)acetamide —— C18H17N3OS2
    N-benzyl-2-((3-(o-tolyl)-1,2,4-thiadiazol-5-yl)thio)acetamide
    —— N-(furan-2-ylmethyl)-2-[[3-(2-methylphenyl)-1,2,4-thiadiazol-5-yl]sulfanyl]acetamide —— C16H15N3O2S2
    N-(furan-2-ylmethyl)-2-[[3-(2-methylphenyl)-1,2,4-thiadiazol-5-yl]sulfanyl]acetamide
    —— [(1R)-1-[5-[2-(2-hydroxyethylazaniumyl)ethylsulfanyl]-4-(2-morpholin-4-ium-4-ylethyl)-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C17H37N6O2S+3
    [(1R)-1-[5-[2-(2-hydroxyethylazaniumyl)ethylsulfanyl]-4-(2-morpholin-4-ium-4-ylethyl)-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— (5-Bromoimidazo[2,1-b][1,3]thiazol-6-yl)methyl (5-phenyl-1,3,4-oxadiazol-2-yl) sulfide —— C14H9BrN4OS2
    (5-Bromoimidazo[2,1-b][1,3]thiazol-6-yl)methyl (5-phenyl-1,3,4-oxadiazol-2-yl) sulfide
    —— (3-Methylimidazo[2,1-B][1,3]thiazol-6-YL)methyl (5-phenyl-1,3,4-oxadiazol-2-YL) sulfide —— C15H12N4OS2
    (3-Methylimidazo[2,1-B][1,3]thiazol-6-YL)methyl (5-phenyl-1,3,4-oxadiazol-2-YL) sulfide
    —— (2S)-N-[2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-2-pyrazol-1-ylbutanamide —— C12H17N5OS2
    (2S)-N-[2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-2-pyrazol-1-ylbutanamide
    —— (2R)-N-[2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-2-pyrazol-1-ylbutanamide —— C12H17N5OS2
    (2R)-N-[2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-2-pyrazol-1-ylbutanamide
    —— 2-[4-[[(2R)-oxan-2-yl]methyl]phenyl]sulfanylacetamide —— C14H19NO2S
    2-[4-[[(2R)-oxan-2-yl]methyl]phenyl]sulfanylacetamide
    —— 2-[4-[[(2S)-oxan-2-yl]methyl]phenyl]sulfanylacetamide —— C14H19NO2S
    2-[4-[[(2S)-oxan-2-yl]methyl]phenyl]sulfanylacetamide
    —— (3R)-1-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-3-prop-2-enylpiperidine-3-carboxylic acid —— C17H22N4O3S
    (3R)-1-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-3-prop-2-enylpiperidine-3-carboxylic acid
    —— (3S)-1-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-3-prop-2-enylpiperidine-3-carboxylic acid —— C17H22N4O3S
    (3S)-1-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-3-prop-2-enylpiperidine-3-carboxylic acid