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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-Vinyl-[1,3]oxathiole 3-oxide 114274-81-6 C5H6O2S
    5-Vinyl-[1,3]oxathiole 3-oxide
    —— 5-methylsulfanyl-3,6-dihydro-2H-pyrazine-1-carboxylic acid tert-butyl ester 1182359-41-6 C10H18N2O2S
    5-methylsulfanyl-3,6-dihydro-2H-pyrazine-1-carboxylic acid tert-butyl ester
    —— 2,2-dimethyl-1-(1'-methyl-5'-nitro-1'H-pyrrol-2'-yl)propyl p-tolyl sulfide 115975-81-0 C17H22N2O2S
    2,2-dimethyl-1-(1'-methyl-5'-nitro-1'H-pyrrol-2'-yl)propyl p-tolyl sulfide
    —— {3-[5-(3,5-dichloro-phenylsulfanyl)-4-isopropyl-1-pyridin-4-ylmethyl-1H-imidazol-2-ylmethoxycarbonylamino]-propyl}-phosphonic acid 620969-29-1 C23H27Cl2N4O5PS
    {3-[5-(3,5-dichloro-phenylsulfanyl)-4-isopropyl-1-pyridin-4-ylmethyl-1H-imidazol-2-ylmethoxycarbonylamino]-propyl}-phosphonic acid
    —— 14,14-dimethyl-7-methylsulfanyl-3-phenyl-2,13,15-trioxa-8-azatricyclo[9.4.0.04,8]pentadeca-1(11),4,6-trien-12-one 225502-94-3 C20H21NO4S
    14,14-dimethyl-7-methylsulfanyl-3-phenyl-2,13,15-trioxa-8-azatricyclo[9.4.0.04,8]pentadeca-1(11),4,6-trien-12-one
    —— 5-Isopropenyl-[1,3]oxathiole 3-oxide 114274-84-9 C6H8O2S
    5-Isopropenyl-[1,3]oxathiole 3-oxide
    —— Phenyl-2.3-xylyl-sulfid 105336-67-2 C14H14S
    Phenyl-2.3-xylyl-sulfid
    —— 3,4-Dimethylphenyl ethyl sulfide 105336-64-9 C10H14S
    3,4-Dimethylphenyl ethyl sulfide
    —— 2,2'thiobis(6-t-butyl-4-bromophenol) 39769-79-4 C20H24Br2O2S
    2,2'thiobis(6-t-butyl-4-bromophenol)
    —— Di-tert-butyl vic-disulfone 98248-42-1 C8H18O4S2
    Di-tert-butyl vic-disulfone
    —— di-tert-butylsulfonyl dithioanhydride 163362-42-3 C8H18O4S4
    di-tert-butylsulfonyl dithioanhydride
    —— Di-tert-butyl vic-disulfoxide 79599-55-6 C8H18O2S2
    Di-tert-butyl vic-disulfoxide
    —— tert-butylsulfonic tert-butylsulfinic thioanhydride 161151-73-1 C8H18O3S3
    tert-butylsulfonic tert-butylsulfinic thioanhydride
    —— 2,2'thiobis(6-t-butyl-4-chlorophenol) 6012-78-8 C20H24Cl2O2S
    2,2'thiobis(6-t-butyl-4-chlorophenol)
    —— S-Methyl-N-butyl-isothioharnstoff 100319-25-3 C6H14N2S
    S-Methyl-N-butyl-isothioharnstoff
    —— 5-(2-fluorophenyl)-4-(phenylthio)furan-2-carbaldehyde 1138035-95-6 C17H11FO2S
    5-(2-fluorophenyl)-4-(phenylthio)furan-2-carbaldehyde
    —— 2-methyl-4-phenyl-1-(phenylthiol)-3-butyn-2-ol 150587-38-5 C17H16OS
    2-methyl-4-phenyl-1-(phenylthiol)-3-butyn-2-ol
    —— 2-(1-dihydroxyboranyl-1-methyl-ethyl)-isothiourea; hydrobromide 5271-88-5 BrH*C4H11BN2O2S
    2-(1-dihydroxyboranyl-1-methyl-ethyl)-isothiourea; hydrobromide
    —— Methylen-bis-thioharnstoff 20939-13-3 C3H8N4S2
    Methylen-bis-thioharnstoff
    —— [(3,7-Dimethylocta-1,2,6-trien-1-YL)sulfanyl]benzene 69358-72-1 C16H20S
    [(3,7-Dimethylocta-1,2,6-trien-1-YL)sulfanyl]benzene
    —— 3,6-dihydro-3,6-diphenyl-5-phenylthio-1,2,3-triazolo[4,5-d]pyrimidine-7-one 1364422-19-4 C22H15N5OS
    3,6-dihydro-3,6-diphenyl-5-phenylthio-1,2,3-triazolo[4,5-d]pyrimidine-7-one
    —— 6-isothiocyanatohexyl isocyanate 118685-44-2 C8H12N2OS
    6-isothiocyanatohexyl isocyanate
    —— 5-[(4-chlorophenyl)thio]-3,6-dihydro-3,6-diphenyl-1,2,3-triazolo[4,5-d]pyrimidine-7-one 1364422-22-9 C22H14ClN5OS
    5-[(4-chlorophenyl)thio]-3,6-dihydro-3,6-diphenyl-1,2,3-triazolo[4,5-d]pyrimidine-7-one
    —— bis[3-(cyclohept-1-enyl)propargyl] sulfoxide 432546-16-2 C20H26OS
    bis[3-(cyclohept-1-enyl)propargyl] sulfoxide
    —— bis[3-(cyclohept-1-enyl)propargyl] sulfide 432546-11-7 C20H26S
    bis[3-(cyclohept-1-enyl)propargyl] sulfide
    —— 2,2-dimethyl-[1,3]dithiane-1,1,3,3-tetraoxide 69489-99-2 C6H12O4S2
    2,2-dimethyl-[1,3]dithiane-1,1,3,3-tetraoxide
    —— 3,6-dihydro-3,6-diphenyl-5-[(4-methylphenyl)thio]-1,2,3-triazolo[4,5-d]pyrimidine-7-one 1364422-28-5 C23H17N5OS
    3,6-dihydro-3,6-diphenyl-5-[(4-methylphenyl)thio]-1,2,3-triazolo[4,5-d]pyrimidine-7-one
    —— 6-Butyl-2,2-dimethyl-1lambda~4~,3-dithian-1-one 114113-91-6 C10H20OS2
    6-Butyl-2,2-dimethyl-1lambda~4~,3-dithian-1-one
    —— 2-(5-Amino-4-chloro-2-nitro-phenylthio)-N,N-dimethyl-benzamide 474432-18-3 C15H14ClN3O3S
    2-(5-Amino-4-chloro-2-nitro-phenylthio)-N,N-dimethyl-benzamide
    —— (2R)-2-[(5-{[(1S)-1-(2-fluorophenyl)ethyl]thio}-2-methoxy[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]pentan-1-ol 911716-15-9 C19H23FN4O2S2
    (2R)-2-[(5-{[(1S)-1-(2-fluorophenyl)ethyl]thio}-2-methoxy[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]pentan-1-ol
    —— (2R)-2-[(2-chloro-5-{[(1S)-1-(2-fluorophenyl)ethyl]thio}[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]pentan-1-ol 911716-14-8 C18H20ClFN4OS2
    (2R)-2-[(2-chloro-5-{[(1S)-1-(2-fluorophenyl)ethyl]thio}[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]pentan-1-ol
    —— 2-ethylmercapto-5-benzyl-6-methyl-3<i>H</i>-pyrimidin-4-one 452350-50-4 C14H16N2OS
    2-ethylmercapto-5-benzyl-6-methyl-3<i>H</i>-pyrimidin-4-one
    —— 2-Dimethylaminoethyl 4-phenyl-4-(phenylthio)butyrate hydrogen maleate 37014-89-4 C24H29NO6S
    2-Dimethylaminoethyl 4-phenyl-4-(phenylthio)butyrate hydrogen maleate
    —— 2-ethylmercapto-1-benzyl-1<i>H</i>-pyrimidin-4-one 62652-40-8 C13H14N2OS
    2-ethylmercapto-1-benzyl-1<i>H</i>-pyrimidin-4-one
    —— 1-Benzyl-4-(methylthio)-2-(1H)-pyrimidone 25855-35-0 C12H12N2OS
    1-Benzyl-4-(methylthio)-2-(1H)-pyrimidone
    —— 1-Methyl-4-(2-(phenylthio)-1-(2-thienyl)ethyl)piperazine dimaleate 40028-18-0 C25H30N2O8S2
    1-Methyl-4-(2-(phenylthio)-1-(2-thienyl)ethyl)piperazine dimaleate
    —— (2R)-2-[(2-chloro-5-{[(1S)-1-(2-fluorophenyl)ethyl]thio}[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]-4-fluoro-4-methylpentan-1-ol 911716-11-5 C19H21ClF2N4OS2
    (2R)-2-[(2-chloro-5-{[(1S)-1-(2-fluorophenyl)ethyl]thio}[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]-4-fluoro-4-methylpentan-1-ol
    —— N,2-dimethyl-2-(methylsulfonyl)propan-1-amine 1249167-64-3 C6H15NO2S
    N,2-dimethyl-2-(methylsulfonyl)propan-1-amine
    —— (2R)-4-fluoro-2-[(5-{[(1S)-1-(2-fluorophenyl)ethyl]thio}-2-methoxy[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]-4-methylpentan-1-ol 911716-12-6 C20H24F2N4O2S2
    (2R)-4-fluoro-2-[(5-{[(1S)-1-(2-fluorophenyl)ethyl]thio}-2-methoxy[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]-4-methylpentan-1-ol
    —— 1-Hydroxymethyl-1-phenylthiocyclopropan 63048-66-8 C10H12OS
    1-Hydroxymethyl-1-phenylthiocyclopropan
    —— 2-amino-1-mercapto-2,3-dimethylbut-3-ene 116065-19-1 C6H13NS
    2-amino-1-mercapto-2,3-dimethylbut-3-ene
    —— tert-butyl-[(3S,4S)-7,7-dibromo-4-methoxy-1-phenylsulfanylhept-6-en-3-yl]oxy-dimethylsilane 945036-98-6 C20H32Br2O2SSi
    tert-butyl-[(3S,4S)-7,7-dibromo-4-methoxy-1-phenylsulfanylhept-6-en-3-yl]oxy-dimethylsilane
    —— methyl 2-[(2R,3S,4S,5R)-4-[tert-butyl(dimethyl)silyl]oxy-6-[(4S,5S)-5-[tert-butyl(dimethyl)silyl]oxy-4-methoxy-7-phenylsulfanylhept-1-ynyl]-6-hydroxy-3,5-dimethyloxan-2-yl]acetate 945037-01-4 C36H62O7SSi2
    methyl 2-[(2R,3S,4S,5R)-4-[tert-butyl(dimethyl)silyl]oxy-6-[(4S,5S)-5-[tert-butyl(dimethyl)silyl]oxy-4-methoxy-7-phenylsulfanylhept-1-ynyl]-6-hydroxy-3,5-dimethyloxan-2-yl]acetate
    —— 2-(phenylthio)-3-[(phenylthio)(trimethylsilyl)-methyl]-1H-indole 247222-88-4 C24H25NS2Si
    2-(phenylthio)-3-[(phenylthio)(trimethylsilyl)-methyl]-1H-indole
    —— 4-dimethylamino-2-methylthio-6-phenylethynylpyrimidine-5-carbaldehyde 1104638-78-9 C16H15N3OS
    4-dimethylamino-2-methylthio-6-phenylethynylpyrimidine-5-carbaldehyde
    —— 6-[bis(ethyloxy)methyl]-2-[(phenylmethyl)thio]-4-pyrimidinamine 1246034-55-8 C16H21N3O2S
    6-[bis(ethyloxy)methyl]-2-[(phenylmethyl)thio]-4-pyrimidinamine
    —— 6-[(methyloxy)methyl]-2-(methylthio)-4-pyrimidinamine 1246034-70-7 C7H11N3OS
    6-[(methyloxy)methyl]-2-(methylthio)-4-pyrimidinamine
    —— N,N-dimethyl-4-(3-methoxyphenylthio)-3-thenylamine 134478-50-5 C14H17NOS2
    N,N-dimethyl-4-(3-methoxyphenylthio)-3-thenylamine
    —— (2S)-1-(4-fluorophenyl)sulfanylpentan-2-amine 377083-60-8 C11H16FNS
    (2S)-1-(4-fluorophenyl)sulfanylpentan-2-amine
    —— 4-nitro-N-(6-(phenylthio)-9-(tetrahydro-2H-pyran-2-yl)-9H-purin-8-yl)benzamide 1380333-92-5 C23H20N6O4S
    4-nitro-N-(6-(phenylthio)-9-(tetrahydro-2H-pyran-2-yl)-9H-purin-8-yl)benzamide