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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S,3S)-3-(tert-butoxycarbonylamino)-5-methyl-1-phenylthio-2-hexanol 799559-94-7 C18H29NO3S
    (2S,3S)-3-(tert-butoxycarbonylamino)-5-methyl-1-phenylthio-2-hexanol
    —— 2-Amino-4-hydroxy-5-(4-chlor-phenylmercapto)-pyrimidin 90799-83-0 C10H8ClN3OS
    2-Amino-4-hydroxy-5-(4-chlor-phenylmercapto)-pyrimidin
    —— (2S,3S)-3-(tert-butoxycarbonylamino)-5-methyl-1-methylsulfonyl-2-hexanol 799560-36-4 C13H27NO5S
    (2S,3S)-3-(tert-butoxycarbonylamino)-5-methyl-1-methylsulfonyl-2-hexanol
    —— 1H-Pyrido(3,2-b)pyrimido(4,5-e)(1,4)thiazin-4(10H)-one, 2-amino-8-methyl- 63931-12-4 C10H9N5OS
    1H-Pyrido(3,2-b)pyrimido(4,5-e)(1,4)thiazin-4(10H)-one, 2-amino-8-methyl-
    —— 1-tert-butyl-4-methylsulfonylcyclohexane 4943-24-2 C11H22O2S
    1-tert-butyl-4-methylsulfonylcyclohexane
    —— 4-bromo-2-(3-fluoro-phenylsulfanyl)-1-methoxybenzene 905815-86-3 C13H10BrFOS
    4-bromo-2-(3-fluoro-phenylsulfanyl)-1-methoxybenzene
    —— <i>S</i>-ethyl-<i>N</i>,<i>N</i>-dimethyl-isothiourea 90298-19-4 C5H12N2S
    <i>S</i>-ethyl-<i>N</i>,<i>N</i>-dimethyl-isothiourea
    —— 4-(3-bromo-2,2-difluoropropyl)-2,2-bis(trifluoromethyl)-1,3-oxathiolan-5-one 774603-40-6 C8H5BrF8O2S
    4-(3-bromo-2,2-difluoropropyl)-2,2-bis(trifluoromethyl)-1,3-oxathiolan-5-one
    —— 4-(3-diazo-2-oxopropyl)-2,2-bis(trifluoromethyl)-1,3-oxathiolan-5-one 603960-94-7 C8H4F6N2O3S
    4-(3-diazo-2-oxopropyl)-2,2-bis(trifluoromethyl)-1,3-oxathiolan-5-one
    —— 1-(butane-1-sulfonyl)-propan-2-one 91589-37-6 C7H14O3S
    1-(butane-1-sulfonyl)-propan-2-one
    —— 3,4,5,6-tetrachloro-2-trifluoromethylthiopyridine 765915-28-4 C6Cl4F3NS
    3,4,5,6-tetrachloro-2-trifluoromethylthiopyridine
    —— N-(2-chloroethyl)-N-ethyl-2-(2-methylphenyl)sulfanylethanamine;hydron;chloride —— C13H21Cl2NS
    N-(2-chloroethyl)-N-ethyl-2-(2-methylphenyl)sulfanylethanamine;hydron;chloride
    —— 2-Ethylthiomethyl-1,3-dithiacycloheptan 80158-23-2 C8H16S3
    2-Ethylthiomethyl-1,3-dithiacycloheptan
    —— (4-amino-5-methyl-pyrimidin-2-ylmercapto)-acetic acid 83991-19-9 C7H9N3O2S
    (4-amino-5-methyl-pyrimidin-2-ylmercapto)-acetic acid
    —— 2,6-dimethyl-octane-3-thiol 91180-22-2 C10H22S
    2,6-dimethyl-octane-3-thiol
    —— (5-chloro-2-thienylthio)-acetonitrile 60493-06-3 C6H4ClNS2
    (5-chloro-2-thienylthio)-acetonitrile
    —— S-4-O-(ethylxanthic)pentanenitrile 796073-62-6 C8H13NOS2
    S-4-O-(ethylxanthic)pentanenitrile
    —— (3-Phenylsulfanylphenyl)methyl methanesulfonate 898535-17-6 C14H14O3S2
    (3-Phenylsulfanylphenyl)methyl methanesulfonate
    —— R-4-(O-ethylxanthic)pentanenitrile 796073-65-9 C8H13NOS2
    R-4-(O-ethylxanthic)pentanenitrile
    —— 1-(4-bromo-2,2-dimethylbutyl)-2-phenylthio-1H-indole 202346-04-1 C20H22BrNS
    1-(4-bromo-2,2-dimethylbutyl)-2-phenylthio-1H-indole
    —— 1-(4-aminophenyl)-7-phenylthioheptane 257289-15-9 C19H25NS
    1-(4-aminophenyl)-7-phenylthioheptane
    —— [Difluoro-(2-methylsulfanyl-3,6-dihydro-2H-thiopyran-2-yl)-methyl]-phosphonic acid diethyl ester 437713-32-1 C11H19F2O3PS2
    [Difluoro-(2-methylsulfanyl-3,6-dihydro-2H-thiopyran-2-yl)-methyl]-phosphonic acid diethyl ester
    —— 4-(2,5-dimethyl-2H-pyrazol-3-ylamino)-2-methylsulfanyl-pyrimidine-5-carbaldehyde 1001129-05-0 C11H13N5OS
    4-(2,5-dimethyl-2H-pyrazol-3-ylamino)-2-methylsulfanyl-pyrimidine-5-carbaldehyde
    —— 5-(5-chloro-thiophen-2-ylsulfanylmethyl)-1<i>H</i>-tetrazole 60493-05-2 C6H5ClN4S2
    5-(5-chloro-thiophen-2-ylsulfanylmethyl)-1<i>H</i>-tetrazole
    —— Imidazole, 1-methyl-2-(prop-2-ynyl)thio-, hydrobromide 66156-62-5 C7H9BrN2S
    Imidazole, 1-methyl-2-(prop-2-ynyl)thio-, hydrobromide
    —— 2-Phenylsulfanyl-propionic acid (R)-1-formyl-butyl ester 1026584-97-3 C14H18O3S
    2-Phenylsulfanyl-propionic acid (R)-1-formyl-butyl ester
    —— Methyl (2R,3R,4R)-<4-methyl-5-oxo-4-(phenylthio)-2-propyltetrahydrofuran-3-yl>acetate 134829-46-2 C17H22O4S
    Methyl (2R,3R,4R)-<4-methyl-5-oxo-4-(phenylthio)-2-propyltetrahydrofuran-3-yl>acetate
    —— 5-Bromo-2-methylsulfanyl-1H-benzoimidazole-4,7-dione 310461-62-2 C8H5BrN2O2S
    5-Bromo-2-methylsulfanyl-1H-benzoimidazole-4,7-dione
    —— 4,6-Bis(2-glucosylhydrazino)-7H-pyrimido(4,5-b)(1,4)thiazine 65413-41-4 C18H29N7O10S
    4,6-Bis(2-glucosylhydrazino)-7H-pyrimido(4,5-b)(1,4)thiazine
    —— (S)-2-mercapto-1-hexanol 383414-72-0 C6H14OS
    (S)-2-mercapto-1-hexanol
    —— 5,10-dihydro-4H-thieno<3,2-b>benzo<f><1,4>thiazocin-5-one 139308-16-0 C12H9NOS2
    5,10-dihydro-4H-thieno<3,2-b>benzo<f><1,4>thiazocin-5-one
    —— (-)-(R)-3-methyl-thio-1-hexanol 90180-89-5 C7H16OS
    (-)-(R)-3-methyl-thio-1-hexanol
    —— (2S,3R)-2-<(S)-(phenylsulfanyl)methyl>-3-propyloxirane 145841-93-6 C12H16OS
    (2S,3R)-2-<(S)-(phenylsulfanyl)methyl>-3-propyloxirane
    —— 5,10-Dihydro-1,11-dithia-5-aza-benzo[a]cyclopenta[e]cycloocten-4-one 139308-19-3 C12H9NOS2
    5,10-Dihydro-1,11-dithia-5-aza-benzo[a]cyclopenta[e]cycloocten-4-one
    —— 2,2,2-trifluoro-N-[4-(phenylthio)phenyl]acetamide 904115-46-4 C14H10F3NOS
    2,2,2-trifluoro-N-[4-(phenylthio)phenyl]acetamide
    —— (+)-(S)-3-methylthio-1-hexanol 90180-91-9 C7H16OS
    (+)-(S)-3-methylthio-1-hexanol
    —— (2S,3R)-2-((S)-Methanesulfinylmethyl)-3-propyl-oxirane 145842-00-8 C7H14O2S
    (2S,3R)-2-((S)-Methanesulfinylmethyl)-3-propyl-oxirane
    —— (R)-2-mercapto-1-hexanol 383414-71-9 C6H14OS
    (R)-2-mercapto-1-hexanol
    —— Methyl (4R)-4-<2-<(phenylthio)propionyl>oxy>hept-2(E)-enoate 134829-45-1 C17H22O4S
    Methyl (4R)-4-<2-<(phenylthio)propionyl>oxy>hept-2(E)-enoate
    —— 5-azido-4-(phenylthio)spiro<2H-benzimidazole-2,1'-cyclohexane> 130256-97-2 C18H17N5S
    5-azido-4-(phenylthio)spiro<2H-benzimidazole-2,1'-cyclohexane>
    —— 4-[(imino)(methoxy)methyl]phenyl 2,6-anhydro-1,2-thio-β-D-mannopyranoside 208761-69-7 C14H17NO4S2
    4-[(imino)(methoxy)methyl]phenyl 2,6-anhydro-1,2-thio-β-D-mannopyranoside
    —— (2S,3R)-2-hydroxy-3-(phenylsulfanyl)heptanoic acid (tetrahydropyran-2-yloxy)amide 285572-43-2 C18H27NO4S
    (2S,3R)-2-hydroxy-3-(phenylsulfanyl)heptanoic acid (tetrahydropyran-2-yloxy)amide
    —— 4-(aminothiocarbonyl)phenyl 2,6-anhydro-1,2-thio-β-D-mannopyranoside 208761-70-0 C13H15NO3S3
    4-(aminothiocarbonyl)phenyl 2,6-anhydro-1,2-thio-β-D-mannopyranoside
    —— hydron;S-phenyl 3-(1-phenylethyl)imidazole-4-carbothioate;chloride —— C18H17ClN2OS
    hydron;S-phenyl 3-(1-phenylethyl)imidazole-4-carbothioate;chloride
    —— 1-(2,3-dihydro-3,3-dimethylbenzo<b>thien-5-yl)ethanol 132102-35-3 C12H16OS
    1-(2,3-dihydro-3,3-dimethylbenzo<b>thien-5-yl)ethanol
    —— [4-(2-Methylaminomethyl-phenylsulfanyl)-3-nitro-phenyl]-methanol 627488-48-6 C15H16N2O3S
    [4-(2-Methylaminomethyl-phenylsulfanyl)-3-nitro-phenyl]-methanol
    —— 2-(3,3-Dimethyl-2,3-dihydro-benzo[b]thiophen-5-yl)-but-3-en-2-ol 197379-61-6 C14H18OS
    2-(3,3-Dimethyl-2,3-dihydro-benzo[b]thiophen-5-yl)-but-3-en-2-ol
    —— 5-Fluoromethyl-2-(2-methylaminomethyl-phenylsulfanyl)-phenylamine 844699-84-9 C15H17FN2S
    5-Fluoromethyl-2-(2-methylaminomethyl-phenylsulfanyl)-phenylamine
    —— [2-(4-Fluoromethyl-2-nitro-phenylsulfanyl)-benzyl]-methyl-amine 627488-72-6 C15H15FN2O2S
    [2-(4-Fluoromethyl-2-nitro-phenylsulfanyl)-benzyl]-methyl-amine
    —— 5-thiocyanatohept-1-en-6-yne 220435-11-0 C8H9NS
    5-thiocyanatohept-1-en-6-yne