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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-[(5-Pyridin-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-2-one 81555-92-2 C10H9N3O2S
    1-[(5-Pyridin-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-2-one
    —— 2-{5-[(5-Phenylpentyl)sulfanyl]-1,3,4-oxadiazol-2-YL}pyridine 832077-71-1 C18H19N3OS
    2-{5-[(5-Phenylpentyl)sulfanyl]-1,3,4-oxadiazol-2-YL}pyridine
    —— (2-methoxy-ethyl)-methyl-disulfane 69177-67-9 C4H10OS2
    (2-methoxy-ethyl)-methyl-disulfane
    —— N-ethenylsulfanylcyclohexanimine 132065-70-4 C8H13NS
    N-ethenylsulfanylcyclohexanimine
    —— 5,6-dimethyl-2,7a-bis(methylsulfonyl)-3a,4,7,7a-tetrahydro-1-benzothiophene 1,1-dioxide 870773-00-5 C12H18O6S3
    5,6-dimethyl-2,7a-bis(methylsulfonyl)-3a,4,7,7a-tetrahydro-1-benzothiophene 1,1-dioxide
    —— 1-Benzyl-2-chloro-3-phenylthioindole 98508-72-6 C21H16ClNS
    1-Benzyl-2-chloro-3-phenylthioindole
    —— methyl 2-(3-cyano-4,6-dimethylpyridin-2-yl)mercapto-2-methylacetate 718597-71-8 C12H14N2O2S
    methyl 2-(3-cyano-4,6-dimethylpyridin-2-yl)mercapto-2-methylacetate
    —— (3S)-4,4,4-trifluoro-3-(phenylsulfanylmethyl)butan-1-ol 109685-46-3 C11H13F3OS
    (3S)-4,4,4-trifluoro-3-(phenylsulfanylmethyl)butan-1-ol
    —— 2-benzylthio-4-amino-6-(N-benzylcyanamino)pyrimidine 98322-50-0 C19H17N5S
    2-benzylthio-4-amino-6-(N-benzylcyanamino)pyrimidine
    —— 5-allylmercapto-3-methyl-1,2,4-triazole 229486-47-9 C6H9N3S
    5-allylmercapto-3-methyl-1,2,4-triazole
    —— (RS)-10-<2'-hydroxy-5'-methyl-3'-(phenylthio)phenyl>-2-decanol 112999-63-0 C23H32O2S
    (RS)-10-<2'-hydroxy-5'-methyl-3'-(phenylthio)phenyl>-2-decanol
    —— Ethyl 2-[1-(2-ethoxy-2-oxoethyl)sulfanyl-1-phenylethyl]sulfanylacetate 61713-26-6 C16H22O4S2
    Ethyl 2-[1-(2-ethoxy-2-oxoethyl)sulfanyl-1-phenylethyl]sulfanylacetate
    —— 2-hexylmercapto-ethylamine 53056-85-2 C8H19NS
    2-hexylmercapto-ethylamine
    —— 11-octyldisulfanyl-undecan-1-ol 909401-68-9 C19H40OS2
    11-octyldisulfanyl-undecan-1-ol
    —— Acetic acid, 2,2'-[(1-phenylethylidene)bis(sulfonyl)]bis-, diethyl ester 61713-31-3 C16H22O8S2
    Acetic acid, 2,2'-[(1-phenylethylidene)bis(sulfonyl)]bis-, diethyl ester
    —— Methyl 4-methyl-3-phenylsulfanylpentanoate 84837-78-5 C13H18O2S
    Methyl 4-methyl-3-phenylsulfanylpentanoate
    —— cyclopropyl ethyl sulfone 575454-45-4 C5H10O2S
    cyclopropyl ethyl sulfone
    —— ethyl 1-adamantanecarbodithionate 1228576-19-9 C13H20S2
    ethyl 1-adamantanecarbodithionate
    —— 3-(2,4-Dinitrophenyl)sulfanyl-5-[8-[5-(2,4-dinitrophenyl)sulfanyl-4-phenyl-1,2,4-triazol-3-yl]octyl]-4-phenyl-1,2,4-triazole 54188-83-9 C36H32N10O8S2
    3-(2,4-Dinitrophenyl)sulfanyl-5-[8-[5-(2,4-dinitrophenyl)sulfanyl-4-phenyl-1,2,4-triazol-3-yl]octyl]-4-phenyl-1,2,4-triazole
    —— thiacyclohexadeca-3,14-diyne-1,1-dioxide 514853-66-8 C15H22O2S
    thiacyclohexadeca-3,14-diyne-1,1-dioxide
    —— (1'S,3'S,4'R)-1-(3',4'-epoxy-4'-methylcyclohexyl)-5-methyl-2-phenylthio-4-hexen-1-one 203632-84-2 C20H26O2S
    (1'S,3'S,4'R)-1-(3',4'-epoxy-4'-methylcyclohexyl)-5-methyl-2-phenylthio-4-hexen-1-one
    —— (1-(Bis(phenylthio)methylene)-2,3,3-trichloro-2-propenyl)(hydroxy)azane oxide 151052-73-2 C16H10Cl3NO2S2
    (1-(Bis(phenylthio)methylene)-2,3,3-trichloro-2-propenyl)(hydroxy)azane oxide
    —— Methyl 4-phenyl-4-phenylsulfanylbut-2-enoate 88087-93-8 C17H16O2S
    Methyl 4-phenyl-4-phenylsulfanylbut-2-enoate
    —— 3-(2-oxo-5-phenylthio-2,5-dihydrofuran-3-yl)propionic acid methyl ester 475091-21-5 C14H14O4S
    3-(2-oxo-5-phenylthio-2,5-dihydrofuran-3-yl)propionic acid methyl ester
    —— 1-Acetylmercapto-2-phenylmercapto-aethan 14476-42-7 C10H12OS2
    1-Acetylmercapto-2-phenylmercapto-aethan
    —— 2-Phenylthioethansulfonsaeure 749795-11-7 C8H10O3S2
    2-Phenylthioethansulfonsaeure
    —— 5-(difluoro(phenylsulfanyl)methyl)-5-hydroxy-1-(3-methylbut-2-enyl)pyrrolidin-2-one 1152033-02-7 C16H19F2NO2S
    5-(difluoro(phenylsulfanyl)methyl)-5-hydroxy-1-(3-methylbut-2-enyl)pyrrolidin-2-one
    —— S-404 38058-82-1 C7H17O5PS2
    S-404
    —— [2-(2-methylsulfanyl-imidazol-1-yl)-ethyl]-carbamic acid tert-butyl ester 1202690-33-2 C11H19N3O2S
    [2-(2-methylsulfanyl-imidazol-1-yl)-ethyl]-carbamic acid tert-butyl ester
    —— 8-(6-(furan-3-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(2-(neopentylamino)ethyl)-9H-purin-6-amine 1289544-12-2 C23H26N6O3S
    8-(6-(furan-3-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(2-(neopentylamino)ethyl)-9H-purin-6-amine
    —— Ethyl-(2-cyanopyridine-4-ylthio)acetate 256657-61-1 C10H10N2O2S
    Ethyl-(2-cyanopyridine-4-ylthio)acetate
    —— 1-adamantyl tert-butyl thioketone 185817-24-7 C15H24S
    1-adamantyl tert-butyl thioketone
    —— (E)-3-benzylidene-5-(4-(methylthio)benzyl)furan-2(3H)-one 1350721-00-4 C19H16O2S
    (E)-3-benzylidene-5-(4-(methylthio)benzyl)furan-2(3H)-one
    —— (S)-2-(2-hydroxypropyl)-2-nonyl-1,3-dithiane 173266-65-4 C16H32OS2
    (S)-2-(2-hydroxypropyl)-2-nonyl-1,3-dithiane
    —— (Z)-4-phenylsulfinyl-3-buten-2-one 33944-97-7 C10H10OS
    (Z)-4-phenylsulfinyl-3-buten-2-one
    —— benzyldimethyl(1-thiophenyl)cyclopropylsilane 166672-24-8 C18H22SSi
    benzyldimethyl(1-thiophenyl)cyclopropylsilane
    —— 2-Amino-5,6-dihydrothiazolo<3,2-b>-1,2,4-triazole 116544-90-2 C4H6N4S
    2-Amino-5,6-dihydrothiazolo<3,2-b>-1,2,4-triazole
    —— N,N-diisopropyl-bis<2-(methylsulfonyl)ethyl> phosphoramidite 157728-69-3 C12H28NO6PS2
    N,N-diisopropyl-bis<2-(methylsulfonyl)ethyl> phosphoramidite
    —— 2-methylthio-5-(3-phenylpropyn-1-yl)-6-methylaminopyrimidine 598298-06-7 C15H15N3S
    2-methylthio-5-(3-phenylpropyn-1-yl)-6-methylaminopyrimidine
    —— 6-(2-oxopropyl)-2,3-dihydrothiazolo<3,2-c>pyrimidine-5,7-dione 149221-51-2 C9H10N2O3S
    6-(2-oxopropyl)-2,3-dihydrothiazolo<3,2-c>pyrimidine-5,7-dione
    —— (4S,5S)-1-[4-(3,5-difluoro-benzyl)-2-phenyl-5-phenylsulfanylmethyl-oxazolidin-3-yl]-ethanone 951401-50-6 C25H23F2NO2S
    (4S,5S)-1-[4-(3,5-difluoro-benzyl)-2-phenyl-5-phenylsulfanylmethyl-oxazolidin-3-yl]-ethanone
    —— [(R)-8-fluoro-6-(3-fluoro-phenylsulfanyl)-1,2,3,4-tetrahydro-naphthalen-1-ylmethyl]-urea 1231765-22-2 C18H18F2N2OS
    [(R)-8-fluoro-6-(3-fluoro-phenylsulfanyl)-1,2,3,4-tetrahydro-naphthalen-1-ylmethyl]-urea
    —— 4-(2-(methylthio)pyrimidin-4-yl)pyrimidin-2(1H)-one 1453852-78-2 C9H8N4OS
    4-(2-(methylthio)pyrimidin-4-yl)pyrimidin-2(1H)-one
    —— 2-[(3-Cyano-6-methylpyridin-2-yl)sulfanyl]-2-methylpropanoic acid 681840-66-4 C11H12N2O2S
    2-[(3-Cyano-6-methylpyridin-2-yl)sulfanyl]-2-methylpropanoic acid
    —— 2-Cyclohex-2-en-1-ylsulfanyl-6-methylpyridine-3-carbonitrile 121567-79-1 C13H14N2S
    2-Cyclohex-2-en-1-ylsulfanyl-6-methylpyridine-3-carbonitrile
    —— (1Z,3R)-3-hydroxy-1-(4'-methylphenylthio)-1-nitro-3-phenylprop-1-ene 228716-87-8 C16H15NO3S
    (1Z,3R)-3-hydroxy-1-(4'-methylphenylthio)-1-nitro-3-phenylprop-1-ene
    —— (E)-3-(dimethylamino)-1-(2-(methylthio)pyrimidin-4-yl)prop-2-en-1-one 496863-49-1 C10H13N3OS
    (E)-3-(dimethylamino)-1-(2-(methylthio)pyrimidin-4-yl)prop-2-en-1-one
    —— 3-acetyl-6-methyl-2-(methylthio)pyridine 1191923-85-9 C9H11NOS
    3-acetyl-6-methyl-2-(methylthio)pyridine
    —— 1-(2-(tert-butyldimethylsilyloxy)-1-(4-chloro-3-fluorophenyl)ethyl)-4-(2-(methylthio)pyrimidin-4-yl)pyrimidin-2(1H)-one 1453852-80-6 C23H28ClFN4O2SSi
    1-(2-(tert-butyldimethylsilyloxy)-1-(4-chloro-3-fluorophenyl)ethyl)-4-(2-(methylthio)pyrimidin-4-yl)pyrimidin-2(1H)-one
    —— (1'S,2R,3R)-3-(1'-hydroxy-1'-phenylmethyl)-2-(4''-methylphenylthio)-2-nitrooxirane 228716-89-0 C16H15NO4S
    (1'S,2R,3R)-3-(1'-hydroxy-1'-phenylmethyl)-2-(4''-methylphenylthio)-2-nitrooxirane