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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (E)-methyl 3-methylthio-2-phenylthio-2-heptenoate 96899-42-2 C15H20O2S2
    (E)-methyl 3-methylthio-2-phenylthio-2-heptenoate
    —— 1-(methylsulfonyl)pinacolone 61524-35-4 C7H14O3S
    1-(methylsulfonyl)pinacolone
    —— 1-bromo-1-(methylsulfonyl)pinacolone 77006-35-0 C7H13BrO3S
    1-bromo-1-(methylsulfonyl)pinacolone
    —— 1,3-Diphenyl-2-oxa-6,10-dithiaspiro[4.5]decan-1-ol 141523-80-0 C19H20O2S2
    1,3-Diphenyl-2-oxa-6,10-dithiaspiro[4.5]decan-1-ol
    —— 3-bromo-4-[2-(1-methoxymethyl-2-phenylthio-1H-imidazol-5-yl)-1H-indol-3-yl]-1-methyl-pyrrole-2,5-dione 569643-32-9 C24H19BrN4O3S
    3-bromo-4-[2-(1-methoxymethyl-2-phenylthio-1H-imidazol-5-yl)-1H-indol-3-yl]-1-methyl-pyrrole-2,5-dione
    —— 5-(1-methoxy-1H-indol-2-yl)-1-methyl-2-phenylthio-1H-imidazole 569643-22-7 C19H17N3OS
    5-(1-methoxy-1H-indol-2-yl)-1-methyl-2-phenylthio-1H-imidazole
    —— 4-(2-(1H-indol-2-yl)pyrimidin-4-ylthio)aniline 1207681-75-1 C18H14N4S
    4-(2-(1H-indol-2-yl)pyrimidin-4-ylthio)aniline
    —— 5-(1H-indol-2-yl)-1-(methoxymethyl)-2-phenylthio-1H-imidazole 569643-31-8 C19H17N3OS
    5-(1H-indol-2-yl)-1-(methoxymethyl)-2-phenylthio-1H-imidazole
    —— 3-bromo-4-[2-(2-phenylthio-1H-imidazol-5-yl)-1H-indol-3-yl]-1-methyl-pyrrole-2,5-dione 569643-33-0 C22H15BrN4O2S
    3-bromo-4-[2-(2-phenylthio-1H-imidazol-5-yl)-1H-indol-3-yl]-1-methyl-pyrrole-2,5-dione
    —— 3-bromo-4-[2-(1-methyl-2-phenylthio-1H-imidazol-5-yl)-1H-indol-3-yl]-1-methyl-pyrrole-2,5-dione 569643-24-9 C23H17BrN4O2S
    3-bromo-4-[2-(1-methyl-2-phenylthio-1H-imidazol-5-yl)-1H-indol-3-yl]-1-methyl-pyrrole-2,5-dione
    —— (S)-2-amino-3,3-dimethylbutane-1-thiol hydrochloride 259257-82-4 C6H15NS*ClH
    (S)-2-amino-3,3-dimethylbutane-1-thiol hydrochloride
    —— 5-(1-methoxy-1H-indol-2-yl)-1-(methoxymethyl)-2-phenylthio-1H-imidazole 569643-30-7 C20H19N3O2S
    5-(1-methoxy-1H-indol-2-yl)-1-(methoxymethyl)-2-phenylthio-1H-imidazole
    —— 2-(3-amino-pyrazin-2-yl)-5-methylthio-1,3,4-thiadiazole 1402083-90-2 C7H7N5S2
    2-(3-amino-pyrazin-2-yl)-5-methylthio-1,3,4-thiadiazole
    —— ethyl 2-(5-(3-amino-pyrazin-2-yl)-1,3,4-thiadiazol-2-ylthio)acetate 1402083-91-3 C10H11N5O2S2
    ethyl 2-(5-(3-amino-pyrazin-2-yl)-1,3,4-thiadiazol-2-ylthio)acetate
    —— [2-methyl-4-(1H-1,2,4-triazol-5-ylsulfanyl)quinolin-3-yl]methyl acetate 198017-71-9 C15H14N4O2S
    [2-methyl-4-(1H-1,2,4-triazol-5-ylsulfanyl)quinolin-3-yl]methyl acetate
    —— 2,2'-Sulfonylbis<3-(dimethylamino)-(E,E)-2-propenenitrile> 111037-47-9 C10H14N4O2S
    2,2'-Sulfonylbis<3-(dimethylamino)-(E,E)-2-propenenitrile>
    —— 3-Methoxy-4-(2-pyridin-2-ylsulfanylethyl)cyclobut-3-ene-1,2-dione 134863-04-0 C12H11NO3S
    3-Methoxy-4-(2-pyridin-2-ylsulfanylethyl)cyclobut-3-ene-1,2-dione
    —— 3-Methoxy-4-(2-phenylsulfanylethyl)cyclobut-3-ene-1,2-dione 134863-03-9 C13H12O3S
    3-Methoxy-4-(2-phenylsulfanylethyl)cyclobut-3-ene-1,2-dione
    —— [2-methyl-4-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]quinolin-3-yl]methanol 198017-75-3 C14H14N4OS
    [2-methyl-4-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]quinolin-3-yl]methanol
    —— [2-methyl-4-(1H-1,2,4-triazol-5-ylsulfanyl)quinolin-3-yl]methanol 198017-72-0 C13H12N4OS
    [2-methyl-4-(1H-1,2,4-triazol-5-ylsulfanyl)quinolin-3-yl]methanol
    —— 9-Methyl-17-thia-8,12,14,15-tetrazatetracyclo[8.7.0.02,7.012,16]heptadeca-1(10),2,4,6,8,13,15-heptaene 145623-32-1 C13H10N4S
    9-Methyl-17-thia-8,12,14,15-tetrazatetracyclo[8.7.0.02,7.012,16]heptadeca-1(10),2,4,6,8,13,15-heptaene
    —— 9,14-Dimethyl-17-thia-8,12,13,15-tetrazatetracyclo[8.7.0.02,7.012,16]heptadeca-1(10),2,4,6,8,13,15-heptaene 145623-35-4 C14H12N4S
    9,14-Dimethyl-17-thia-8,12,13,15-tetrazatetracyclo[8.7.0.02,7.012,16]heptadeca-1(10),2,4,6,8,13,15-heptaene
    —— Aethyl-tert.-butyl-trithiocarbonat 89975-80-4 C7H14S3
    Aethyl-tert.-butyl-trithiocarbonat
    —— 6-methyl-7H-[1,2,4]triazolo[5',1':2,3][1,3]thiazino[5,6-c]quinoline 145623-34-3 C13H10N4S
    6-methyl-7H-[1,2,4]triazolo[5',1':2,3][1,3]thiazino[5,6-c]quinoline
    —— 9,13-Dimethyl-17-thia-8,12,14,15-tetrazatetracyclo[8.7.0.02,7.012,16]heptadeca-1(10),2,4,6,8,13,15-heptaene 145623-33-2 C14H12N4S
    9,13-Dimethyl-17-thia-8,12,14,15-tetrazatetracyclo[8.7.0.02,7.012,16]heptadeca-1(10),2,4,6,8,13,15-heptaene
    —— 2,2'-Sulfonylbis<3-(diethylamino)-(E,E)-2-propenenitrile> 121078-49-7 C14H22N4O2S
    2,2'-Sulfonylbis<3-(diethylamino)-(E,E)-2-propenenitrile>
    —— 2-Amino-6-(2-chlor-5-methyl-pyrimidinyl-(4)-mercapto)-purin 90800-00-3 C10H8ClN7S
    2-Amino-6-(2-chlor-5-methyl-pyrimidinyl-(4)-mercapto)-purin
    —— N-(4-methylthiophenyl)-N'-[2-(2-trimethylsilylethynyl)phenyl]carbodiimide 450380-96-8 C19H20N2SSi
    N-(4-methylthiophenyl)-N'-[2-(2-trimethylsilylethynyl)phenyl]carbodiimide
    —— N-<2-<(4-methylphenyl)thio>ethyl>propanamide 82772-76-7 C12H17NOS
    N-<2-<(4-methylphenyl)thio>ethyl>propanamide
    —— (diisopropylthiocarbamoylsulfanyl)methyl diisopropyldithiocarbamate 90276-57-6 C15H30N2S4
    (diisopropylthiocarbamoylsulfanyl)methyl diisopropyldithiocarbamate
    —— 1,3-dimethyl-6-sulfanylidene-8-thiophen-2-ylsulfanyl-7H-purin-2-one 6492-89-3 C11H10N4OS3
    1,3-dimethyl-6-sulfanylidene-8-thiophen-2-ylsulfanyl-7H-purin-2-one
    —— 4-(o-Hydroxybenzylidene)-4'-nitrodiphenylsulfid 20162-20-3 C19H14N2O3S
    4-(o-Hydroxybenzylidene)-4'-nitrodiphenylsulfid
    —— 1-(cyclohexylamino)-3-[(5-pyrazin-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propan-2-ol 134744-89-1 C15H22N6OS
    1-(cyclohexylamino)-3-[(5-pyrazin-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propan-2-ol
    —— 13,19,36,37-tetraaza-6,16,26-trioxa-3,9,11,21,23,29-hexathiotetracyclo-[29,3,1,1(10,13),1(19,22)]-heptatriaconta-1(35),10(36),22(37),31(32),33(34)-pentaene-12,20-dione 1041201-00-6 C24H32N4O5S6
    13,19,36,37-tetraaza-6,16,26-trioxa-3,9,11,21,23,29-hexathiotetracyclo-[29,3,1,1(10,13),1(19,22)]-heptatriaconta-1(35),10(36),22(37),31(32),33(34)-pentaene-12,20-dione
    —— 11-thiamethylundecylisothiocyanate 144027-76-9 C13H25NS2
    11-thiamethylundecylisothiocyanate
    —— DL-2-Amino-butyl-isothioharnstoff 63679-68-5 C5H13N3S
    DL-2-Amino-butyl-isothioharnstoff
    —— 6-(2-ethyl-5-nitro-3-propyl-3<i>H</i>-imidazol-4-ylsulfanyl)-7(9)<i>H</i>-purine 4526-64-1 C13H15N7O2S
    6-(2-ethyl-5-nitro-3-propyl-3<i>H</i>-imidazol-4-ylsulfanyl)-7(9)<i>H</i>-purine
    —— 2-{[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetamide 886510-60-7 C10H8ClN3O2S
    2-{[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetamide
    —— 9-amino-1,4,6,8-tetraazabenzo<b>phenothiazine 81562-25-6 C12H8N6S
    9-amino-1,4,6,8-tetraazabenzo<b>phenothiazine
    —— 5-methylthio-[1,2,5]thiadiazolo[3,4-d]pyrimidin-7(6H)-one 62700-64-5 C5H4N4OS2
    5-methylthio-[1,2,5]thiadiazolo[3,4-d]pyrimidin-7(6H)-one
    —— 4-Amino-2-(methylamino)-6-(methylsulfanyl)pyrimidine-5-carbonitrile 112637-52-2 C7H9N5S
    4-Amino-2-(methylamino)-6-(methylsulfanyl)pyrimidine-5-carbonitrile
    —— 2-[[5-(1-Benzyl-5-oxopyrrolidin-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetic acid 129913-26-4 C16H18N4O3S
    2-[[5-(1-Benzyl-5-oxopyrrolidin-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-methyl-4-phenylthio-5,7-dihydrothieno<3,4-d>pyrimidine 6,6-dioxide 154697-87-7 C13H12N2O2S2
    2-methyl-4-phenylthio-5,7-dihydrothieno<3,4-d>pyrimidine 6,6-dioxide
    —— Acetic acid, ((4-(dibutylamino)-6-methyl-2-pyrimidinyl)thio)-, hydrazide 77940-24-0 C15H27N5OS
    Acetic acid, ((4-(dibutylamino)-6-methyl-2-pyrimidinyl)thio)-, hydrazide
    —— Methyl 2-(4-methyl-6-piperidin-1-ylpyrimidin-2-yl)sulfanylacetate 77940-21-7 C13H19N3O2S
    Methyl 2-(4-methyl-6-piperidin-1-ylpyrimidin-2-yl)sulfanylacetate
    —— Methyl 2-{[4-methyl-6-(morpholin-4-YL)pyrimidin-2-YL]sulfanyl}acetate 77940-22-8 C12H17N3O3S
    Methyl 2-{[4-methyl-6-(morpholin-4-YL)pyrimidin-2-YL]sulfanyl}acetate
    —— Acetic acid, ((6-methyl-4-piperidino-2-pyrimidinyl)thio)-, hydrazide 77940-25-1 C12H19N5OS
    Acetic acid, ((6-methyl-4-piperidino-2-pyrimidinyl)thio)-, hydrazide
    —— Acetic acid, ((6-methyl-4-morpholino-2-pyrimidinyl)thio)-, hydrazide 77965-40-3 C11H17N5O2S
    Acetic acid, ((6-methyl-4-morpholino-2-pyrimidinyl)thio)-, hydrazide
    —— ethyl <4-(4'-methylphenyl)thiazol-2-ylthio>acetate 112779-70-1 C14H15NO2S2
    ethyl <4-(4'-methylphenyl)thiazol-2-ylthio>acetate
    —— 1-Methylsulfonylsulfanyltriacontane 887407-63-8 C31H64O2S2
    1-Methylsulfonylsulfanyltriacontane