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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-[5-(4-bromophenylthio)thien-2-yl]-4-methoxytetrahydropyran 140667-14-7 C16H17BrO2S2
    4-[5-(4-bromophenylthio)thien-2-yl]-4-methoxytetrahydropyran
    —— 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one 1448012-87-0 C18H17Br2NOS2
    3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one
    —— 3-(4-bromophenylthio)-2,4-pentanedione 314769-46-5 C11H11BrO2S
    3-(4-bromophenylthio)-2,4-pentanedione
    —— 2-[(4-Bromophenyl)sulfanyl]cyclohexan-1-one 636602-77-2 C12H13BrOS
    2-[(4-Bromophenyl)sulfanyl]cyclohexan-1-one
    —— (2-(phenylthio)phenyl)acetamidoxime 117596-50-6 C14H14N2OS
    (2-(phenylthio)phenyl)acetamidoxime
    —— N,N-pentamethylene-(2-(phenylthio)phenyl)acetamidine hydrochloride 117596-37-9 C19H22N2S*ClH
    N,N-pentamethylene-(2-(phenylthio)phenyl)acetamidine hydrochloride
    —— (2-(phenylthio)phenyl)acetamidine 117596-35-7 C14H14N2S
    (2-(phenylthio)phenyl)acetamidine
    —— N,N-(3-oxapentane-1,5-diyl)-(2-(phenylthio)phenyl)acetamidine hydrochloride 117596-39-1 C18H20N2OS*ClH
    N,N-(3-oxapentane-1,5-diyl)-(2-(phenylthio)phenyl)acetamidine hydrochloride
    —— N-methyl-1-(2-(phenylthio)phenyl)-2-propylamine 127876-68-0 C16H19NS
    N-methyl-1-(2-(phenylthio)phenyl)-2-propylamine
    —— 1-(2-(phenylthio)phenyl)-2-propylamine 127876-67-9 C15H17NS
    1-(2-(phenylthio)phenyl)-2-propylamine
    —— 2-cyano-3-(2-hydroxy-2-methylpropanethio)pyridine 342816-15-3 C10H12N2OS
    2-cyano-3-(2-hydroxy-2-methylpropanethio)pyridine
    —— 3-(4-bromophenyl)-2-(phenylthio)-2H-pyrido[3,2-b][1,4]oxazine 1255647-86-9 C19H13BrN2OS
    3-(4-bromophenyl)-2-(phenylthio)-2H-pyrido[3,2-b][1,4]oxazine
    —— 3-phenyl-2-(phenylthio)-2H-pyrido[3,2-b][1,4]oxazine 1255647-85-8 C19H14N2OS
    3-phenyl-2-(phenylthio)-2H-pyrido[3,2-b][1,4]oxazine
    —— Butin-1-butin-2-sulfid 52422-98-7 C8H10S
    Butin-1-butin-2-sulfid
    —— 3-(benzyloxy)-N-(4-methylthiazol-2-yl)-5-(phenylthio)pyridin-2-amine 936245-34-0 C22H19N3OS2*ClH
    3-(benzyloxy)-N-(4-methylthiazol-2-yl)-5-(phenylthio)pyridin-2-amine
    —— 5-(propargylthio)uracil 73236-44-9 C7H6N2O2S
    5-(propargylthio)uracil
    —— 2-benzylthiopyrazine 4-oxide 136742-98-8 C11H10N2OS
    2-benzylthiopyrazine 4-oxide
    —— ethyl 5-bromo-2,3-dihydrobenzo<b>thiophene-3-carboxylate 93670-21-4 C11H11BrO2S
    ethyl 5-bromo-2,3-dihydrobenzo<b>thiophene-3-carboxylate
    —— methyl 2,3-dihydrobenzo<b>thiophene-3-carboxylate 39891-63-9 C10H10O2S
    methyl 2,3-dihydrobenzo<b>thiophene-3-carboxylate
    —— 4-methoxy-7,7-dimethyl-N-propan-2-yl-6,8-dihydropyrimido[4,5-b][1,4]benzothiazin-9-amine 102689-07-6 C16H22N4OS
    4-methoxy-7,7-dimethyl-N-propan-2-yl-6,8-dihydropyrimido[4,5-b][1,4]benzothiazin-9-amine
    —— 4-phenyl-2-(6,6,5-trifluorohex-5-enylthio)-1,3-thiazole 390410-89-6 C15H14F3NS2
    4-phenyl-2-(6,6,5-trifluorohex-5-enylthio)-1,3-thiazole
    —— 2-(4-phenylthiazolyl) propargyl sulfide 493046-72-3 C12H9NS2
    2-(4-phenylthiazolyl) propargyl sulfide
    —— 4-Methoxy-6-aminopyrimido<4,5-b>(1,4)thiazine 37497-00-0 C7H8N4OS
    4-Methoxy-6-aminopyrimido<4,5-b>(1,4)thiazine
    —— 3-chloro-4-(4-phenylthiazol-2-ylsulfanyl)phenylamine 848133-12-0 C15H11ClN2S2
    3-chloro-4-(4-phenylthiazol-2-ylsulfanyl)phenylamine
    —— (4-phenyl-thiazol-2-ylsulfanyl)-acetic acid ethyl ester 10002-33-2 C13H13NO2S2
    (4-phenyl-thiazol-2-ylsulfanyl)-acetic acid ethyl ester
    —— acetonyl 2-(4-phenylthiazolyl) sulfide 22997-33-7 C12H11NOS2
    acetonyl 2-(4-phenylthiazolyl) sulfide
    —— 2-cyanomethylmercapto-4-phenylthiazole 103483-15-4 C11H8N2S2
    2-cyanomethylmercapto-4-phenylthiazole
    —— 4-<(4-methylbenzylidene)amino>-2,4-dihydro-2-methyl-5-(methylthio)-3H-1,2,4-triazole-3-thione 102423-44-9 C12H14N4S2
    4-<(4-methylbenzylidene)amino>-2,4-dihydro-2-methyl-5-(methylthio)-3H-1,2,4-triazole-3-thione
    —— 5-amino-1-butyl-2-(4-phenyl-thiazol-2-ylsulfanyl)-1H-imidazole-4-carboxamide 1102466-65-8 C17H19N5OS2
    5-amino-1-butyl-2-(4-phenyl-thiazol-2-ylsulfanyl)-1H-imidazole-4-carboxamide
    —— N-hexyl-4-methoxy-7,7-dimethyl-6,8-dihydropyrimido[4,5-b][1,4]benzothiazin-9-amine 102688-87-9 C19H28N4OS
    N-hexyl-4-methoxy-7,7-dimethyl-6,8-dihydropyrimido[4,5-b][1,4]benzothiazin-9-amine
    —— 4-methoxypyrimido[4,5-b][1,4]thiazin-6-one-7-acetic acid hydrazine 252556-52-8 C9H11N5O3S
    4-methoxypyrimido[4,5-b][1,4]thiazin-6-one-7-acetic acid hydrazine
    —— 4-Methoxy-7-ethylpyrimido<4,5-b><1,4>-6-thiazinon 16025-13-1 C9H11N3O2S
    4-Methoxy-7-ethylpyrimido<4,5-b><1,4>-6-thiazinon
    —— 4-methoxy-7,8-dihydro-5<i>H</i>,6<i>H</i>-benzo[<i>b</i>]pyrimido[5,4-<i>e</i>][1,4]thiazin-9-one 72031-32-4 C11H11N3O2S
    4-methoxy-7,8-dihydro-5<i>H</i>,6<i>H</i>-benzo[<i>b</i>]pyrimido[5,4-<i>e</i>][1,4]thiazin-9-one
    —— N-butyl-4-methoxy-7,7-dimethyl-6,8-dihydropyrimido[4,5-b][1,4]benzothiazin-9-amine 102689-04-3 C17H24N4OS
    N-butyl-4-methoxy-7,7-dimethyl-6,8-dihydropyrimido[4,5-b][1,4]benzothiazin-9-amine
    —— N-heptyl-4-methoxy-7,7-dimethyl-6,8-dihydropyrimido[4,5-b][1,4]benzothiazin-9-amine 102688-88-0 C20H30N4OS
    N-heptyl-4-methoxy-7,7-dimethyl-6,8-dihydropyrimido[4,5-b][1,4]benzothiazin-9-amine
    —— 4-Methoxy-6-phenylpyrimido<4,5-b>-1,4-thiazine 1981-06-2 C13H11N3OS
    4-Methoxy-6-phenylpyrimido<4,5-b>-1,4-thiazine
    —— 4-methoxy-7,7-dimethyl-N-pentyl-6,8-dihydropyrimido[4,5-b][1,4]benzothiazin-9-amine 102688-86-8 C18H26N4OS
    4-methoxy-7,7-dimethyl-N-pentyl-6,8-dihydropyrimido[4,5-b][1,4]benzothiazin-9-amine
    —— 4-Methoxy-6-(3-methyl-5-nitroimidazol-4-yl)sulfanylpyrimidin-5-amine 130623-79-9 C9H10N6O3S
    4-Methoxy-6-(3-methyl-5-nitroimidazol-4-yl)sulfanylpyrimidin-5-amine
    —— 4-methoxy-7,7-dimethyl-7,8-dihydro-5<i>H</i>,6<i>H</i>-benzo[<i>b</i>]pyrimido[5,4-<i>e</i>][1,4]thiazin-9-one 72031-31-3 C13H15N3O2S
    4-methoxy-7,7-dimethyl-7,8-dihydro-5<i>H</i>,6<i>H</i>-benzo[<i>b</i>]pyrimido[5,4-<i>e</i>][1,4]thiazin-9-one
    —— 5-benzylthio-2-(trimethylsilyloxy)pyrazine 136743-08-3 C14H18N2OSSi
    5-benzylthio-2-(trimethylsilyloxy)pyrazine
    —— 1-methyl-3-methylthio-6-phenyl-7H-1,2,4-triazolo<3,4-b><1,3,4>thiadiazinium chloride 113385-49-2 C12H13N4S2*Cl
    1-methyl-3-methylthio-6-phenyl-7H-1,2,4-triazolo<3,4-b><1,3,4>thiadiazinium chloride
    —— 3-fluoro-N-(6-(phenylthio)-9-(tetrahydro-2H-pyran-2-yl)-9H-purin-8-yl)benzamide 1380333-96-9 C23H20FN5O2S
    3-fluoro-N-(6-(phenylthio)-9-(tetrahydro-2H-pyran-2-yl)-9H-purin-8-yl)benzamide
    —— n-octadecyldimethylsulfonium iodide 84040-81-3 C20H43S*I
    n-octadecyldimethylsulfonium iodide
    —— 2-(4-Phenylsulfanylbut-3-yn-2-yloxy)oxane 1027995-67-0 C15H18O2S
    2-(4-Phenylsulfanylbut-3-yn-2-yloxy)oxane
    —— (E)-1,2-bis[(chloromethyl)sulfonyl]ethene 664306-72-3 C4H6Cl2O4S2
    (E)-1,2-bis[(chloromethyl)sulfonyl]ethene
    —— 1,5,5-trimethyl-2-thia-4-aza-bicyclo[4.2.2]dec-3-en-3-ylamine 5330-92-7 C11H20N2S
    1,5,5-trimethyl-2-thia-4-aza-bicyclo[4.2.2]dec-3-en-3-ylamine
    —— 2-Aethylmercapto-6-phenyl-1,3,4-thiadiazol-s-triazin-5,7-dion 69378-08-1 C12H10N4O2S2
    2-Aethylmercapto-6-phenyl-1,3,4-thiadiazol-s-triazin-5,7-dion
    —— 2-bromo-5-(ethylthio)-1,3,4-thiadiazole 848499-16-1 C4H5BrN2S2
    2-bromo-5-(ethylthio)-1,3,4-thiadiazole
    —— 2-ethylsulfanyl-[1,3,4]thiadiazolo[3,2-<i>a</i>]pyrimidine-5,7-dione 69395-57-9 C7H7N3O2S2
    2-ethylsulfanyl-[1,3,4]thiadiazolo[3,2-<i>a</i>]pyrimidine-5,7-dione
    —— 1-((2R,4S,5R)-4-hydroxy-5-(hydroxymethyl)-5-(4-((phenylthio)methyl)-1H-1,2,3-triazol-1-yl)tetrahydrofuran-2-yl)-5-methylpyrimidine-2,4(1H,3H)-dione 1612885-80-9 C19H21N5O5S
    1-((2R,4S,5R)-4-hydroxy-5-(hydroxymethyl)-5-(4-((phenylthio)methyl)-1H-1,2,3-triazol-1-yl)tetrahydrofuran-2-yl)-5-methylpyrimidine-2,4(1H,3H)-dione