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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (S)-2-amino-3-methyl-1-thioethylbutane 527680-87-1 C7H17NS
    (S)-2-amino-3-methyl-1-thioethylbutane
    —— 1,2,4-Dithiazine-3(4H)-thione, 5,6-dihydro-4-(cyclohexylbutyl)- 60171-73-5 C13H21NS3
    1,2,4-Dithiazine-3(4H)-thione, 5,6-dihydro-4-(cyclohexylbutyl)-
    —— 2-(ethylthio)-5,7-dihydrofuro[3,4-d]pyrimidin-4-ol 864439-11-2 C8H10N2O2S
    2-(ethylthio)-5,7-dihydrofuro[3,4-d]pyrimidin-4-ol
    —— 4-dimethylamino(thiobutyramide) hydrochloride 80948-02-3 C6H14N2S*ClH
    4-dimethylamino(thiobutyramide) hydrochloride
    —— 5-Amino-3-methylsulfanyl-[1,2,4]triazole-1-carbothioic acid phenylamide 82118-02-3 C10H11N5S2
    5-Amino-3-methylsulfanyl-[1,2,4]triazole-1-carbothioic acid phenylamide
    —— 6-methyl-7-methylthiobicyclo<3.3.0>octa-2,6-diene-2-carbonitrile 89952-01-2 C11H13NS
    6-methyl-7-methylthiobicyclo<3.3.0>octa-2,6-diene-2-carbonitrile
    —— (2-o-Tolylsulfanyl-phenyl)-acetonitrile 132121-22-3 C15H13NS
    (2-o-Tolylsulfanyl-phenyl)-acetonitrile
    —— 2-(2-methylphenylthio)benzyl alcohol 132121-21-2 C14H14OS
    2-(2-methylphenylthio)benzyl alcohol
    —— 2-(3,3-Dimethoxy-propyl)-2-(3-methoxymethoxy-propyl)-[1,3]dithiane 864758-28-1 C14H28O4S2
    2-(3,3-Dimethoxy-propyl)-2-(3-methoxymethoxy-propyl)-[1,3]dithiane
    —— 2-((4-bromophenylthio)methyl)tetrahydro-2H-pyran 1356207-07-2 C12H15BrOS
    2-((4-bromophenylthio)methyl)tetrahydro-2H-pyran
    —— (2R,3S,6R)-2-Methyl-3-methylsulfanyl-6-phenylsulfanyl-3,6-dihydro-2H-pyran 125848-22-8 C13H16OS2
    (2R,3S,6R)-2-Methyl-3-methylsulfanyl-6-phenylsulfanyl-3,6-dihydro-2H-pyran
    —— (2R,3S,4S)-3-Methanesulfinyl-2-methyl-3,4-dihydro-2H-pyran-4-ol 125848-24-0 C7H12O3S
    (2R,3S,4S)-3-Methanesulfinyl-2-methyl-3,4-dihydro-2H-pyran-4-ol
    —— 2-<<(p-bromophenyl)thio>methyl>pyridine 83782-10-9 C12H10BrNS
    2-<<(p-bromophenyl)thio>methyl>pyridine
    —— Aethinyl-methyl-sulfon 20526-31-2 C3H4O2S
    Aethinyl-methyl-sulfon
    —— 1-(4-isopropylthiophenyl)-2-n-octylamino-1-butanol hydrochloride 54789-96-7 C21H37NOS*ClH
    1-(4-isopropylthiophenyl)-2-n-octylamino-1-butanol hydrochloride
    —— alpha-(1-(Butylamino)propyl)-4-((1-methylethyl)thio)benzenemethanol hydrochloride 54789-95-6 C17H30ClNOS
    alpha-(1-(Butylamino)propyl)-4-((1-methylethyl)thio)benzenemethanol hydrochloride
    —— 2,2,2-trifluoro-N-[(E,1S)-3-phenylsulfanyl-1-[(4S,5S)-2,2,5-trimethyl-1,3-dioxolan-4-yl]prop-2-enyl]acetamide 1101169-85-0 C17H20F3NO3S
    2,2,2-trifluoro-N-[(E,1S)-3-phenylsulfanyl-1-[(4S,5S)-2,2,5-trimethyl-1,3-dioxolan-4-yl]prop-2-enyl]acetamide
    —— (Z)-Methyl <1-(Ethylthio)ethylidene>hydrazinocarboxylate 114393-58-7 C6H12N2O2S
    (Z)-Methyl <1-(Ethylthio)ethylidene>hydrazinocarboxylate
    —— 4-Ethylthio-1,2,3-thiadiazole 114393-57-6 C4H6N2S2
    4-Ethylthio-1,2,3-thiadiazole
    —— 2H-Pyrazino(2,3-b)-1,4-thiazin-3(4H)-one, 4-(3-(dimethylamino)propyl)-, monohydrochloride 55879-58-8 C11H17ClN4OS
    2H-Pyrazino(2,3-b)-1,4-thiazin-3(4H)-one, 4-(3-(dimethylamino)propyl)-, monohydrochloride
    —— N-(4-Benzylthiobenzyl)-acetamid 55301-92-3 C16H17NOS
    N-(4-Benzylthiobenzyl)-acetamid
    —— 2-methyl-1-phenylthio-1-trimethylsilylpropane 64732-73-6 C13H22SSi
    2-methyl-1-phenylthio-1-trimethylsilylpropane
    —— 1,1-Bisphenylthiobut-3-ene 54905-16-7 C16H16S2
    1,1-Bisphenylthiobut-3-ene
    —— 3-<(phenylthio)methylene>-1,5,5,-trimethyl-1-cyclohexane 104115-21-1 C16H20S
    3-<(phenylthio)methylene>-1,5,5,-trimethyl-1-cyclohexane
    —— β-mercaptoethanol persulfide 29070-79-9 C2H6OS2
    β-mercaptoethanol persulfide
    —— 2,4-dimethyl-1-(phenylthio)-1,3-pentadiene 104115-16-4 C13H16S
    2,4-dimethyl-1-(phenylthio)-1,3-pentadiene
    —— 3-<(phenylthio)(trimethylsilyl)methyl>cyclohexanone 79409-24-8 C16H24OSSi
    3-<(phenylthio)(trimethylsilyl)methyl>cyclohexanone
    —— 3-<(phenylthio)(trimethylsilyl)methyl>-3,5,5-trimethylcyclohexanone 104115-22-2 C19H30OSSi
    3-<(phenylthio)(trimethylsilyl)methyl>-3,5,5-trimethylcyclohexanone
    —— 3-(thiomethylphenyl)cyclohexan-1-one 163069-14-5 C13H16OS
    3-(thiomethylphenyl)cyclohexan-1-one
    —— 1-methyl-3-<(phenylthio)methylene>-1-cyclohexanone 104115-19-7 C14H16S
    1-methyl-3-<(phenylthio)methylene>-1-cyclohexanone
    —— 3-methyl-3-<(phenylthio)(trimethylsilyl)methyl>cyclohexanone 104115-20-0 C17H26OSSi
    3-methyl-3-<(phenylthio)(trimethylsilyl)methyl>cyclohexanone
    —— 5-Methylsulfanyl-3-pyridin-2-yl-[1,2,4]triazin-6-ylamine 112394-69-1 C9H9N5S
    5-Methylsulfanyl-3-pyridin-2-yl-[1,2,4]triazin-6-ylamine
    —— 1-(phenylthio)-1-(trimethylsilyl)but-3-ene 76200-36-7 C13H20SSi
    1-(phenylthio)-1-(trimethylsilyl)but-3-ene
    —— 1-phenylthio-1-trimethylsilylheptane 62418-58-0 C16H28SSi
    1-phenylthio-1-trimethylsilylheptane
    —— Isobutyric acid phenylsulfanylmethyl ester 112607-89-3 C11H14O2S
    Isobutyric acid phenylsulfanylmethyl ester
    —— 1-Morpholin-4-yl-2-(3-pyridin-2-yl-thiazolo[5,4-e][1,2,4]triazin-6-ylsulfanyl)-ethanone 112394-61-3 C15H14N6O2S2
    1-Morpholin-4-yl-2-(3-pyridin-2-yl-thiazolo[5,4-e][1,2,4]triazin-6-ylsulfanyl)-ethanone
    —— 6-Methylsulfanyl-3-pyridin-2-yl-thiazolo[5,4-e][1,2,4]triazine 112394-29-3 C10H7N5S2
    6-Methylsulfanyl-3-pyridin-2-yl-thiazolo[5,4-e][1,2,4]triazine
    —— 1-phenylthio-1-trimethylsilyltridecane 76200-40-3 C22H40SSi
    1-phenylthio-1-trimethylsilyltridecane
    —— Ethanesulfonylmethyl-cyclopentane 52075-26-0 C8H16O2S
    Ethanesulfonylmethyl-cyclopentane
    —— p-tolyl phenylcarbamodithioate 38750-73-1 C14H13NS2
    p-tolyl phenylcarbamodithioate
    —— <i>N</i><sup>2</sup>-benzyl-6-chloro-<i>N</i><sup>4</sup>-(2-diisopropylamino-ethyl)-<i>N</i><sup>2</sup>-methyl-5-methylsulfanyl-pyrimidine-2,4-diamine 55417-00-0 C21H32ClN5S
    <i>N</i><sup>2</sup>-benzyl-6-chloro-<i>N</i><sup>4</sup>-(2-diisopropylamino-ethyl)-<i>N</i><sup>2</sup>-methyl-5-methylsulfanyl-pyrimidine-2,4-diamine
    —— 6-Amino-4-dimethylaminopyrimido<4,5-b>(1,4)thiazine 55383-60-3 C8H11N5S
    6-Amino-4-dimethylaminopyrimido<4,5-b>(1,4)thiazine
    —— 1-Chloro-4-(1,1-dimethyl-propylsulfanyl)-benzene 73239-38-0 C11H15ClS
    1-Chloro-4-(1,1-dimethyl-propylsulfanyl)-benzene
    —— <i>N</i><sup>2</sup>-benzyl-<i>N</i><sup>4</sup>-(2-diisopropylamino-ethyl)-6-methoxy-<i>N</i><sup>2</sup>-methyl-5-methylsulfanyl-pyrimidine-2,4-diamine 55417-14-6 C22H35N5OS
    <i>N</i><sup>2</sup>-benzyl-<i>N</i><sup>4</sup>-(2-diisopropylamino-ethyl)-6-methoxy-<i>N</i><sup>2</sup>-methyl-5-methylsulfanyl-pyrimidine-2,4-diamine
    —— 2,4-Pyrimidinediamine, 6-chloro-N(sup 4)-(2-(diethylamino)ethyl)-5-(methylthio)-N(sup 2), N(sup 2)-dipropyl-, dihydrobromide 55474-01-6 C17H34Br2ClN5S
    2,4-Pyrimidinediamine, 6-chloro-N(sup 4)-(2-(diethylamino)ethyl)-5-(methylthio)-N(sup 2), N(sup 2)-dipropyl-, dihydrobromide
    —— N,N-Dimethylthio-2-nitroacetamid 67730-69-2 C4H8N2O2S
    N,N-Dimethylthio-2-nitroacetamid
    —— 3-Chloro-4-allylthioanilin 19284-86-7 C9H10ClNS
    3-Chloro-4-allylthioanilin
    —— 4-methylsulfanyl-5<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-one hydrazone 55383-67-0 C7H9N5S2
    4-methylsulfanyl-5<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazin-6-one hydrazone
    —— 9-fluoro-2-(1-isopropyl-3-methyl-1H-1,2,4-triazol-5-yl)-10-(1-isopropylpiperidin-4-ylthio)-5,6-dihydrobenzo[f]imidazo[1,2-d][1,4]oxazepine 1401301-75-4 C25H33FN6OS
    9-fluoro-2-(1-isopropyl-3-methyl-1H-1,2,4-triazol-5-yl)-10-(1-isopropylpiperidin-4-ylthio)-5,6-dihydrobenzo[f]imidazo[1,2-d][1,4]oxazepine
    —— (E)-1-Isothiocyanato-3,3-dimethyl-but-1-ene 87656-62-0 C7H11NS
    (E)-1-Isothiocyanato-3,3-dimethyl-but-1-ene