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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1,3,5-triethylsulfanyl-benzene 91638-76-5 C12H18S3
    1,3,5-triethylsulfanyl-benzene
    —— 2-[(2-(methylselenyl)phenyl)ethynyl]thioanisole 1094615-13-0 C16H14SSe
    2-[(2-(methylselenyl)phenyl)ethynyl]thioanisole
    —— 1,3-bis(1-imidazolyl-2-thione)-2,4,6-trimethylbenzene 1258931-95-1 C17H20N4S2
    1,3-bis(1-imidazolyl-2-thione)-2,4,6-trimethylbenzene
    —— 4-phenyl-1-(p-tolylthio)butan-2-ol 141036-65-9 C17H20OS
    4-phenyl-1-(p-tolylthio)butan-2-ol
    —— (2R)-2-[[6-chloro-2-[[(2,3-difluorophenyl)methyl]thio]-4-pyrimidinyl]oxy]-propanoic acid ethyl ester 878385-07-0 C16H15ClF2N2O3S
    (2R)-2-[[6-chloro-2-[[(2,3-difluorophenyl)methyl]thio]-4-pyrimidinyl]oxy]-propanoic acid ethyl ester
    —— 6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carboxylic acid diethylamide 37071-59-3 C19H22N2OS
    6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carboxylic acid diethylamide
    —— N-{9-[2-(1-acetylpiperidin-4-yl)ethyl]-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-6-yl}acetamide 1156469-50-9 C24H27BrN6O4S
    N-{9-[2-(1-acetylpiperidin-4-yl)ethyl]-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-6-yl}acetamide
    —— dibenzazocine 37075-05-1 C16H15NOS
    dibenzazocine
    —— 12-(3-Chlor-propionyl)-11,12-dihydro-6H-dibenzo<b,f><1.4>thiazozin 37075-11-9 C17H16ClNOS
    12-(3-Chlor-propionyl)-11,12-dihydro-6H-dibenzo<b,f><1.4>thiazozin
    —— 6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carboxylic acid amide 24084-36-4 C15H14N2OS
    6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carboxylic acid amide
    —— 6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carbothioyl chloride 37075-17-5 C15H12ClNS2
    6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carbothioyl chloride
    —— 6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carboxylic acid 4-dimethylamino-butyl ester 47488-55-1 C21H26N2O2S
    6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carboxylic acid 4-dimethylamino-butyl ester
    —— 6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carbothioic acid amide 37071-58-2 C15H14N2S2
    6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carbothioic acid amide
    —— 6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carboxylic acid 2-dimethylamino-ethylamide 37071-60-6 C19H23N3OS
    6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carboxylic acid 2-dimethylamino-ethylamide
    —— 12-(3-Dimethylamino-propyl)-11,12-dihydro-6H-dibenzo<b,f><1.4>thiazozin 6800-65-3 C19H24N2S
    12-(3-Dimethylamino-propyl)-11,12-dihydro-6H-dibenzo<b,f><1.4>thiazozin
    —— 6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carboxylic acid 2-(2-piperidin-1-yl-ethoxy)-ethyl ester 37071-63-9 C24H30N2O3S
    6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carboxylic acid 2-(2-piperidin-1-yl-ethoxy)-ethyl ester
    —— 6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carboxylic acid 3-dimethylamino-propylamide 37071-61-7 C20H25N3OS
    6,11-dihydro-dibenzo[<i>b</i>,<i>f</i>][1,4]thiazocine-12-carboxylic acid 3-dimethylamino-propylamide
    —— 9-[2-(1-acetylpiperidin-4-yl)ethyl]-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-6-amine 1156466-74-8 C22H25BrN6O3S
    9-[2-(1-acetylpiperidin-4-yl)ethyl]-8-[(7-bromo-2,3-dihydro-1,4-benzodioxin-6-yl)thio]-9H-purin-6-amine
    —— 4-isopentylsulfanyl-phenol 91967-99-6 C11H16OS
    4-isopentylsulfanyl-phenol
    —— S-(2-Pyridyl) (S)-2-(tert-butyldiphenylsilyloxy)thiopropanoate 125941-76-6 C24H27NO2SSi
    S-(2-Pyridyl) (S)-2-(tert-butyldiphenylsilyloxy)thiopropanoate
    —— 1-[2-[(2S)-4-[tert-butyl(dimethyl)silyl]oxy-2-methylbutyl]-1,3-dithian-2-yl]propan-2-one 1351446-08-6 C18H36O2S2Si
    1-[2-[(2S)-4-[tert-butyl(dimethyl)silyl]oxy-2-methylbutyl]-1,3-dithian-2-yl]propan-2-one
    —— 2-amino-4-methanesulfinyl-6-methylsulfanyl-pyrimidine-5-carbonitrile 851335-82-5 C7H8N4OS2
    2-amino-4-methanesulfinyl-6-methylsulfanyl-pyrimidine-5-carbonitrile
    —— 1-Phenyl-4-(phenylthio)buttersaeure 41932-61-0 C16H16O2S
    1-Phenyl-4-(phenylthio)buttersaeure
    —— 2-[2-(Dimethylamino)ethyl]-2-phenyl-4-phenylsulfanylbutanenitrile 41932-63-2 C20H24N2S
    2-[2-(Dimethylamino)ethyl]-2-phenyl-4-phenylsulfanylbutanenitrile
    —— 5-[3-(2-chloromethyl-3-methyl-pyridin-4-ylsulfanyl)propylsulfanylmethyl]-3-methyloxazolidin-2-one hydrochloride 251344-88-4 C15H21ClN2O2S2*ClH
    5-[3-(2-chloromethyl-3-methyl-pyridin-4-ylsulfanyl)propylsulfanylmethyl]-3-methyloxazolidin-2-one hydrochloride
    —— 1-Phenyl-4-(4-tolylthio)butyronitril 41932-59-6 C17H17NS
    1-Phenyl-4-(4-tolylthio)butyronitril
    —— N-[2-(2-Bromo-phenylsulfanyl)-5-(2-bromo-phenylsulfanylmethoxy)-4-methoxy-phenyl]-2-chloro-acetamide 1026456-92-7 C22H18Br2ClNO3S2
    N-[2-(2-Bromo-phenylsulfanyl)-5-(2-bromo-phenylsulfanylmethoxy)-4-methoxy-phenyl]-2-chloro-acetamide
    —— 4-Isobutylmercapto-phenol 90925-34-1 C10H14OS
    4-Isobutylmercapto-phenol
    —— 3,5-Dichloro-4-quinolin-3-ylsulfanylaniline 315227-80-6 C15H10Cl2N2S
    3,5-Dichloro-4-quinolin-3-ylsulfanylaniline
    —— 2-(4-aminophenylthio)-4-ethoxycarbonylquinoline 190331-32-9 C18H16N2O2S
    2-(4-aminophenylthio)-4-ethoxycarbonylquinoline
    —— 6-methyl-3-phenylthiohept-5-en-2-ol 108362-41-0 C14H20OS
    6-methyl-3-phenylthiohept-5-en-2-ol
    —— 3,4-Dimethyl-3-(phenylthio)-pentan-2-on 63996-52-1 C13H18OS
    3,4-Dimethyl-3-(phenylthio)-pentan-2-on
    —— 1-Acetyl-1-phenylthiocyclohexan 62292-04-0 C14H18OS
    1-Acetyl-1-phenylthiocyclohexan
    —— 4-oxo-3-phenylthiopentanenitrile 108378-40-1 C11H11NOS
    4-oxo-3-phenylthiopentanenitrile
    —— 4,4-dimethyl-3-phenylthiohex-5-en-2-ol 108362-42-1 C14H20OS
    4,4-dimethyl-3-phenylthiohex-5-en-2-ol
    —— 3-Phenylsulfanyl-4-(2,3,3-trimethylcyclohexen-1-yl)butan-2-one 300543-60-6 C19H26OS
    3-Phenylsulfanyl-4-(2,3,3-trimethylcyclohexen-1-yl)butan-2-one
    —— 5-(2-bromophenylthio)-2-(2-bromophenylthiomethoxy)-4-nitrophenol 158719-77-8 C19H13Br2NO4S2
    5-(2-bromophenylthio)-2-(2-bromophenylthiomethoxy)-4-nitrophenol
    —— 2-(2-Bromo-phenylsulfanyl)-5-(2-bromo-phenylsulfanylmethoxy)-4-methoxy-phenylamine 158719-81-4 C20H17Br2NO2S2
    2-(2-Bromo-phenylsulfanyl)-5-(2-bromo-phenylsulfanylmethoxy)-4-methoxy-phenylamine
    —— tert-butyl (Z)-4-oxo-3-phenylsulfanylpent-2-enoate 117052-72-9 C15H18O3S
    tert-butyl (Z)-4-oxo-3-phenylsulfanylpent-2-enoate
    —— phenylmercaptopropanone oxime 27872-74-8 C9H11NOS
    phenylmercaptopropanone oxime
    —— 4-hydroxy-3-phenylthiopentanenitrile 108378-42-3 C11H13NOS
    4-hydroxy-3-phenylthiopentanenitrile
    —— [Cyclohexane-1,3-diylbis(methylene)]dicarbamodithioic acid 67377-63-3 C10H18N2S4
    [Cyclohexane-1,3-diylbis(methylene)]dicarbamodithioic acid
    —— t-butyl 3-phenylthio-4-oxo-2-pentenoate 114711-01-2 C15H18O3S
    t-butyl 3-phenylthio-4-oxo-2-pentenoate
    —— 2,4-Dimethyl-5-(phenylthio)pyrimidine 91157-94-7 C12H12N2S
    2,4-Dimethyl-5-(phenylthio)pyrimidine
    —— 2-chloro-5-(methylsulfanyl)pyrazine 1177421-28-1 C5H5ClN2S
    2-chloro-5-(methylsulfanyl)pyrazine
    —— 4-Dimethylamino-3-phenylthio-3-buten-2-on 76511-78-9 C12H15NOS
    4-Dimethylamino-3-phenylthio-3-buten-2-on
    —— 2-Cyclopropylidenepropylsulfanylbenzene 155397-51-6 C12H14S
    2-Cyclopropylidenepropylsulfanylbenzene
    —— <2,7-Dimethyl-indolyl-(3)>-thiophenylether 92964-37-9 C16H15NS
    <2,7-Dimethyl-indolyl-(3)>-thiophenylether
    —— 1-(1-methyl-4-piperidinyl)-2-methyl-3-phenylthio-1H-indole hydrochloride 137641-59-9 C21H24N2S*ClH
    1-(1-methyl-4-piperidinyl)-2-methyl-3-phenylthio-1H-indole hydrochloride
    —— 4-(Dimethylamino)-3-(phenylthio)-3-buten-2-one 76511-78-9 C12H15NOS
    4-(Dimethylamino)-3-(phenylthio)-3-buten-2-one