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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(4-Acetamido-phenyl-mercapto)-benzylalkohol 20904-47-6 C15H15NO2S
    2-(4-Acetamido-phenyl-mercapto)-benzylalkohol
    —— 2-(5-oxofuran-2(5H)-yliden)-1-benzothienyl-3(2H)-one 1260173-97-4 C12H6O3S
    2-(5-oxofuran-2(5H)-yliden)-1-benzothienyl-3(2H)-one
    —— (S,E)-1-(phenylthio)pent-3-en-2-ol 1257427-94-3 C11H14OS
    (S,E)-1-(phenylthio)pent-3-en-2-ol
    —— 4-Thiazolamine, 2-(methylthio)- 1264033-89-7 C4H6N2S2
    4-Thiazolamine, 2-(methylthio)-
    —— 1-[(1-Aminopropan-2-yl)sulfanyl]-4-bromobenzene hydrochloride 1269152-10-4 C9H13BrClNS
    1-[(1-Aminopropan-2-yl)sulfanyl]-4-bromobenzene hydrochloride
    —— 2-(Isopropylsulfonyl)ethanol hydrate 1242339-21-4 C5H14O4S
    2-(Isopropylsulfonyl)ethanol hydrate
    —— 2-(6-Chloro-4-(trifluoromethyl)pyridin-2-ylsulfanyl)acetic acid 1053656-44-2 C8H5ClF3NO2S
    2-(6-Chloro-4-(trifluoromethyl)pyridin-2-ylsulfanyl)acetic acid
    —— 2-(Propylthio)ethanamine hydrochloride 1242339-84-9 C5H14ClNS
    2-(Propylthio)ethanamine hydrochloride
    —— [2-(Methylsulfinyl)ethyl]amine hydrobromide 1242339-83-8 C3H10BrNOS
    [2-(Methylsulfinyl)ethyl]amine hydrobromide
    —— 6-bromo-7-(phenylthio)-1,2,3,5-tetrahydro-5-indolizinone 1261062-63-8 C14H12BrNOS
    6-bromo-7-(phenylthio)-1,2,3,5-tetrahydro-5-indolizinone
    —— 1-Amino-3-methoxythiourea;hydrochloride 1265622-67-0 C2H7N3OS*ClH
    1-Amino-3-methoxythiourea;hydrochloride
    —— 6-bromo-7-(phenylthio)-1,2,3,5,8,8a-hexahydro-5-indolizinone 1261062-60-5 C14H14BrNOS
    6-bromo-7-(phenylthio)-1,2,3,5,8,8a-hexahydro-5-indolizinone
    —— 6-phenyl-7-(phenylthio)-1,2,3,5,8,8a-hexahydro-5-indolizinone 1261062-62-7 C20H19NOS
    6-phenyl-7-(phenylthio)-1,2,3,5,8,8a-hexahydro-5-indolizinone
    —— 7-(phenylthio)-1,2,3,5-tetrahydro-5-indolizinone 1261062-61-6 C14H13NOS
    7-(phenylthio)-1,2,3,5-tetrahydro-5-indolizinone
    —— 2-(phenylthio)-6,7,8,9-tetrahydro-4-quinolizinone 1261062-66-1 C15H15NOS
    2-(phenylthio)-6,7,8,9-tetrahydro-4-quinolizinone
    —— (9S)-7-methyl-9-propyl-1,4-dithiaspiro[4.5]dec-6-ene 1266679-09-7 C12H20S2
    (9S)-7-methyl-9-propyl-1,4-dithiaspiro[4.5]dec-6-ene
    —— 1-[3-(Methylsulfanyl)phenyl]-4-oxo-1,4-dihydropyridazine-3-carboxylic acid 1291486-54-8 C12H10N2O3S
    1-[3-(Methylsulfanyl)phenyl]-4-oxo-1,4-dihydropyridazine-3-carboxylic acid
    —— (+/-)-ethyl 2-[4-[(2-chlorophenylthio)methyl]phenyl]-2-hydroxyacetate 1268473-45-5 C17H17ClO3S
    (+/-)-ethyl 2-[4-[(2-chlorophenylthio)methyl]phenyl]-2-hydroxyacetate
    —— Acetamide, N-[1-(4-fluorophenyl)ethyl]-2-[[4-methyl-5-(2-thienyl)-4H-1,2,4-triazol-3-yl]thio]- 1300254-52-7 C17H17FN4OS2
    Acetamide, N-[1-(4-fluorophenyl)ethyl]-2-[[4-methyl-5-(2-thienyl)-4H-1,2,4-triazol-3-yl]thio]-
    —— 1-(2-amino-6-methylpyrimidin-4-yl)-3-(1,3,5-trimethyl-1H-pyrazol-4-ylsulfanyl)-[1,2,4]triazole 1295576-30-5 C13H16N8S
    1-(2-amino-6-methylpyrimidin-4-yl)-3-(1,3,5-trimethyl-1H-pyrazol-4-ylsulfanyl)-[1,2,4]triazole
    —— (E)-6'-(4-hydroxybenzylidene)-4a'-methyl-4',4a',7',8'-tetrahydro-3'H-spiro[[1,3]dithiolane-2,2'-naphthalen]-5'(6'H)-one 1289642-67-6 C20H22O2S2
    (E)-6'-(4-hydroxybenzylidene)-4a'-methyl-4',4a',7',8'-tetrahydro-3'H-spiro[[1,3]dithiolane-2,2'-naphthalen]-5'(6'H)-one
    —— 2-Tert-butyl-5-methylsulfanyl-1,3,4-oxadiazole 83430-53-9 C7H12N2OS
    2-Tert-butyl-5-methylsulfanyl-1,3,4-oxadiazole
    —— Alyssin, (S)- 167963-04-4 C7H13NOS2
    Alyssin, (S)-
    —— 4-ethyl-3-methyl-5-methylsulfanyl-4<i>H</i>-[1,2,4]triazole 102170-30-9 C6H11N3S
    4-ethyl-3-methyl-5-methylsulfanyl-4<i>H</i>-[1,2,4]triazole
    —— 2-Pyrimidinamine, 4-chloro-6-[[5-(2-fluorophenyl)-4-(phenylmethyl)-4H-1,2,4-triazol-3-yl]thio]- 1376320-30-7 C19H14ClFN6S
    2-Pyrimidinamine, 4-chloro-6-[[5-(2-fluorophenyl)-4-(phenylmethyl)-4H-1,2,4-triazol-3-yl]thio]-
    —— 6-Benzylthio-tetrazolo<1.5-b>pyridazin 62645-24-3 C11H9N5S
    6-Benzylthio-tetrazolo<1.5-b>pyridazin
    —— 2-(2,4-Difluorophenylsulfanyl)-1-nitrobenzene 187845-74-5 C12H7F2NO2S
    2-(2,4-Difluorophenylsulfanyl)-1-nitrobenzene
    —— 2-(4-bromophenyl)-2-(phenylthio)penta-3,4-dienyl-2,2,2-trichloroacetimidate 1262633-73-7 C19H15BrCl3NOS
    2-(4-bromophenyl)-2-(phenylthio)penta-3,4-dienyl-2,2,2-trichloroacetimidate
    —— (R)-7-(4-(3-aminopyrrolidin-1-yl)-5-chloro-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-ylthio)-1,5-naphthyridine-1-oxide 1275606-61-5 C20H20ClN7OS
    (R)-7-(4-(3-aminopyrrolidin-1-yl)-5-chloro-6-ethyl-7H-pyrrolo[2,3-d]pyrimidin-2-ylthio)-1,5-naphthyridine-1-oxide
    —— 3-(5-hydroxymethyl-2-methylsulfanylpyrimidin-4-ylamino)propan-1-ol 1280218-29-2 C9H15N3O2S
    3-(5-hydroxymethyl-2-methylsulfanylpyrimidin-4-ylamino)propan-1-ol
    —— methyl 2-amino-5-hydroxy-6,7-dimethyl-4-(phenylthio)-benzofuran-3-carboxylate 1257240-01-9 C18H17NO4S
    methyl 2-amino-5-hydroxy-6,7-dimethyl-4-(phenylthio)-benzofuran-3-carboxylate
    —— 3-butylthio-5-(3-butylthio-1,2,4-triazin-5-yl)-1,2,4-triazine 1255789-65-1 C14H20N6S2
    3-butylthio-5-(3-butylthio-1,2,4-triazin-5-yl)-1,2,4-triazine
    —— Methyl 2-amino-4-(3-fluorophenyl)sulfanyl-5-hydroxy-6,7-dimethyl-benzofuran-3-carboxylate 1257240-04-2 C18H16FNO4S
    Methyl 2-amino-4-(3-fluorophenyl)sulfanyl-5-hydroxy-6,7-dimethyl-benzofuran-3-carboxylate
    —— Methyl 2-amino-5-hydroxy-6,7-dimethyl-4-(m-tolylsulfanyl)benzofuran-3-carboxylate 1257240-05-3 C19H19NO4S
    Methyl 2-amino-5-hydroxy-6,7-dimethyl-4-(m-tolylsulfanyl)benzofuran-3-carboxylate
    —— 4-[(4-chlorophenyl)sulfanyl]-1-[(E)-2-[(4-chlorophenyl)sulfanyl]-1-(2-naphthyl)ethenyl]-3-(2-naphthyl)-1H-pyrazole 1260255-06-8 C37H24Cl2N2S2
    4-[(4-chlorophenyl)sulfanyl]-1-[(E)-2-[(4-chlorophenyl)sulfanyl]-1-(2-naphthyl)ethenyl]-3-(2-naphthyl)-1H-pyrazole
    —— 4-[(4-chlorophenyl)sulfanyl]-1-[(Z)-2-[(4-chlorophenyl)sulfanyl]-1-(2-naphthyl)ethenyl]-3-(2-naphthyl)-1H-pyrazole 1260255-14-8 C37H24Cl2N2S2
    4-[(4-chlorophenyl)sulfanyl]-1-[(Z)-2-[(4-chlorophenyl)sulfanyl]-1-(2-naphthyl)ethenyl]-3-(2-naphthyl)-1H-pyrazole
    —— 2-[[5-[3-(2-diethylaminoethylsulfanyl)-1,2,4-triazin-5-yl]-1,2,4-triazin-3-yl]sulfanyl]-N,N-diethyl-ethanamine 1255789-73-1 C18H30N8S2
    2-[[5-[3-(2-diethylaminoethylsulfanyl)-1,2,4-triazin-5-yl]-1,2,4-triazin-3-yl]sulfanyl]-N,N-diethyl-ethanamine
    —— Methyl 2-amino-5-hydroxy-6,7-dimethyl-4-(p-tolylsulfanyl)benzofuran-3-carboxylate 1257240-02-0 C19H19NO4S
    Methyl 2-amino-5-hydroxy-6,7-dimethyl-4-(p-tolylsulfanyl)benzofuran-3-carboxylate
    —— 1-{4-[(5-methyl-5H-pyrrolo[3,2-d]pyrimidin-4-yl)sulfanyl]-phenyl}-3-phenylurea 1255948-56-1 C20H17N5OS
    1-{4-[(5-methyl-5H-pyrrolo[3,2-d]pyrimidin-4-yl)sulfanyl]-phenyl}-3-phenylurea
    —— (2S)-2-amino-4-methylpentanethiol hydrochloride 522607-42-7 C6H15NS*ClH
    (2S)-2-amino-4-methylpentanethiol hydrochloride
    —— 3,3′-bis(propylthio)-5,5′-bi(1,2,4-triazine) 1255789-64-0 C12H16N6S2
    3,3′-bis(propylthio)-5,5′-bi(1,2,4-triazine)
    —— 3-(2-trifluoromethylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-00-0 C27H31F3NS*I
    3-(2-trifluoromethylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(3-trifluoromethylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-02-2 C27H31F3NS*I
    3-(3-trifluoromethylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(4-trifluoromethylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-04-4 C27H31F3NS*I
    3-(4-trifluoromethylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 4-Nitro-1,3-oxathiol-2-amine 1233025-60-9 C3H4N2O3S
    4-Nitro-1,3-oxathiol-2-amine
    —— 1-bromo-3-cyclobutylsulfanylbenzene 1199773-05-1 C10H11BrS
    1-bromo-3-cyclobutylsulfanylbenzene
    —— (2,4,6-Tribromophenyl)(trifluoromethyl)sulfane 1215205-79-0 C7H2Br3F3S
    (2,4,6-Tribromophenyl)(trifluoromethyl)sulfane
    —— 1-Bromo-3-isobutylthiobenzene 1199773-06-2 C10H13BrS
    1-Bromo-3-isobutylthiobenzene
    —— 5-Bromo-2-isobutylthiopyrimidine 1242336-74-8 C8H11BrN2S
    5-Bromo-2-isobutylthiopyrimidine
    —— 3-(2-bromophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299398-97-2 C26H31BrNS*I
    3-(2-bromophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide