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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N'-propan-2-ylethanedithioamide 78553-95-4 C5H10N2S2
    N'-propan-2-ylethanedithioamide
    —— 2,3-bis(thiosulfanyl)but-2-enedinitrile 7373-03-7 C6H6N2S2
    2,3-bis(thiosulfanyl)but-2-enedinitrile
    —— N'-cyclohexylethanedithioamide 78554-01-5 C8H14N2S2
    N'-cyclohexylethanedithioamide
    —— 1-cyano-N-propylmethanethioamide 78554-05-9 C5H8N2S
    1-cyano-N-propylmethanethioamide
    —— 4-methylsulfanyl-6-tributylstannanyl-pyrimidine 1002719-56-3 C17H32N2SSn
    4-methylsulfanyl-6-tributylstannanyl-pyrimidine
    —— 2-[(Cyanocarbothioyl)amino]propane 78554-06-0 C5H8N2S
    2-[(Cyanocarbothioyl)amino]propane
    —— Dithiooxalsaeure-(1-methyl-hydrazid)-amid 104313-80-6 C3H7N3S2
    Dithiooxalsaeure-(1-methyl-hydrazid)-amid
    —— 1-cyano-N-(2-methylpropyl)methanethioamide 78554-08-2 C6H10N2S
    1-cyano-N-(2-methylpropyl)methanethioamide
    —— (1R)-1-[2-(p-tolylsulfanyl)phenyl]ethan-1-ol 705255-54-5 C15H16OS
    (1R)-1-[2-(p-tolylsulfanyl)phenyl]ethan-1-ol
    —— 4-chloro-2-(5-methyl[1,2,4]triazol-3-ylsulfanyl)-thiazole-5-carbaldehyde 1213236-12-4 C7H5ClN4OS2
    4-chloro-2-(5-methyl[1,2,4]triazol-3-ylsulfanyl)-thiazole-5-carbaldehyde
    —— tributylstannyl-(13)C-methyl-phenylsulfide 918149-16-3 C19H34SSn
    tributylstannyl-(13)C-methyl-phenylsulfide
    —— N-phenylmethoxy-3-phenylsulfanylbutanamide 851228-23-4 C17H19NO2S
    N-phenylmethoxy-3-phenylsulfanylbutanamide
    —— 1-azido-3-(phenylthio)propan-2-ol 175718-41-9 C9H11N3OS
    1-azido-3-(phenylthio)propan-2-ol
    —— <i>p</i>-tolylsulfanylmethyl-oxirane 5373-01-3 C10H12OS
    <i>p</i>-tolylsulfanylmethyl-oxirane
    —— 2-chloro-5-(2-chloropyrimidin-4-ylsulfanyl)benzoic acid 1394349-12-2 C11H6Cl2N2O2S
    2-chloro-5-(2-chloropyrimidin-4-ylsulfanyl)benzoic acid
    —— 2-chloro-5-[2-(2-trimethylsilanyl-ethoxy)-pyrimidin-4-ylsulfanyl]-benzoic acid 1394349-16-6 C16H19ClN2O3SSi
    2-chloro-5-[2-(2-trimethylsilanyl-ethoxy)-pyrimidin-4-ylsulfanyl]-benzoic acid
    —— 5-[1-(2-bromo-phenylamino)-ethyl]-2-methylsulfanyl-pyrimidin-4-yl-methyl-amine 686758-89-4 C14H17BrN4S
    5-[1-(2-bromo-phenylamino)-ethyl]-2-methylsulfanyl-pyrimidin-4-yl-methyl-amine
    —— 1-(isopropylsulfinyl)-3-isothiocyanatopropane 1414791-60-8 C7H13NOS2
    1-(isopropylsulfinyl)-3-isothiocyanatopropane
    —— 3-Isopropylmercapto-propylamin 67215-22-9 C6H15NS
    3-Isopropylmercapto-propylamin
    —— isopropyl(4-isothiocyanatopropyl)sulfane 1414792-58-7 C7H13NS2
    isopropyl(4-isothiocyanatopropyl)sulfane
    —— 3-aminomethyl-4,6-dimethyl-2-methylthiopyridine 445471-13-6 C9H14N2S
    3-aminomethyl-4,6-dimethyl-2-methylthiopyridine
    —— 3-cyano-4,6-dimethyl-2-methylthiopyridine 72456-86-1 C9H10N2S
    3-cyano-4,6-dimethyl-2-methylthiopyridine
    —— methyl 5-(methylthio)-2-thioxo-1,3-dithiole-4-dithiocarboxylate 120060-17-5 C6H6S6
    methyl 5-(methylthio)-2-thioxo-1,3-dithiole-4-dithiocarboxylate
    —— 3-(methylthio)heptane 57093-86-4 C8H18S
    3-(methylthio)heptane
    —— 3-Methyl-5-benzylthio-1,3,4-thiadiazol-2(3H)-thione 134919-03-2 C10H10N2S3
    3-Methyl-5-benzylthio-1,3,4-thiadiazol-2(3H)-thione
    —— heptane-3-thiol 1639-07-2 C7H16S
    heptane-3-thiol
    —— 5,5'-(o-Xylidenedithio)bis-<3-methyl-1,3,4-thiadiazole-2(3H)-thione> 134919-04-3 C14H14N4S6
    5,5'-(o-Xylidenedithio)bis-<3-methyl-1,3,4-thiadiazole-2(3H)-thione>
    —— 2,2'-Tetramethylenediiminobis-(2,3-dihydro-3-methyl-5-methylthio-1,3,4-thiadiazole) 134897-06-6 C12H20N6S4
    2,2'-Tetramethylenediiminobis-(2,3-dihydro-3-methyl-5-methylthio-1,3,4-thiadiazole)
    —— 2-Methyl-6-methylidene-8-(phenylsulfanyl)oct-1-en-3-ol 87639-58-5 C16H22OS
    2-Methyl-6-methylidene-8-(phenylsulfanyl)oct-1-en-3-ol
    —— 1,5-Dithiaspiro<5.12>octadecan-7-ol 73397-83-8 C16H30OS2
    1,5-Dithiaspiro<5.12>octadecan-7-ol
    —— 7-Isopropenyl-1,5-dithiaspiro[5.12]octadecan-7-ol 68984-57-6 C19H34OS2
    7-Isopropenyl-1,5-dithiaspiro[5.12]octadecan-7-ol
    —— 1,5-Dithiaspiro<5.12>octadecan-7-one 68984-55-4 C16H28OS2
    1,5-Dithiaspiro<5.12>octadecan-7-one
    —— 1,2-bis(butylthio)acetylene 66566-76-5 C10H18S2
    1,2-bis(butylthio)acetylene
    —— 1-[5-(1,3-difluoro-2-methylpropan-2-yl)isoxazol-3-yl]-3-[3-(6,7-dimethoxyquinazolin-4-ylthio)phenyl]urea 1188909-95-6 C24H23F2N5O4S
    1-[5-(1,3-difluoro-2-methylpropan-2-yl)isoxazol-3-yl]-3-[3-(6,7-dimethoxyquinazolin-4-ylthio)phenyl]urea
    —— (S)-2,2-dimethyl-1-(2-methylazetidin-1-yl)propane-1-thione 1228453-05-1 C9H17NS
    (S)-2,2-dimethyl-1-(2-methylazetidin-1-yl)propane-1-thione
    —— tert-butyl-3-sulfanamine 130439-58-6 C4H11NS
    tert-butyl-3-sulfanamine
    —— rac-2,2-dimethyl-1-(2-methylazetidin-1-yl)propane-1-thione 1228452-88-7 C9H17NS
    rac-2,2-dimethyl-1-(2-methylazetidin-1-yl)propane-1-thione
    —— (2R)-2-({2-chloro-5-[(2,3-difluorobenzyl)thio][1,3]thiazolo[4,5-d]pyrimidin-7-yl}amino)-4-methylpentan-1-ol 849943-10-8 C18H19ClF2N4OS2
    (2R)-2-({2-chloro-5-[(2,3-difluorobenzyl)thio][1,3]thiazolo[4,5-d]pyrimidin-7-yl}amino)-4-methylpentan-1-ol
    —— 5-[(2,3-difluorobenzyl)thio]-7-{[(1R)-1-(hydroxymethyl)-3-methylbutyl]amino}[1,3]thiazolo[4,5-d]pyrimidin-2(3H)-one 849943-12-0 C18H20F2N4O2S2
    5-[(2,3-difluorobenzyl)thio]-7-{[(1R)-1-(hydroxymethyl)-3-methylbutyl]amino}[1,3]thiazolo[4,5-d]pyrimidin-2(3H)-one
    —— methyl 3-fluoro-4-(2-(5-(hydroxymethyl)pyridin-2-ylamino)thiazol-5-ylthio)picolinate 1034922-10-5 C16H13FN4O3S2
    methyl 3-fluoro-4-(2-(5-(hydroxymethyl)pyridin-2-ylamino)thiazol-5-ylthio)picolinate
    —— (2R)-2-[[2-Amino-5-[[(2,3-difluorophenyl)methyl]thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-4-methyl-1-pentanol 259101-69-4 C18H21F2N5OS2
    (2R)-2-[[2-Amino-5-[[(2,3-difluorophenyl)methyl]thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-4-methyl-1-pentanol
    —— methyl 3-fluoro-4-(2-(5-(methoxymethyl)pyridin-2-ylamino)thiazol-5-ylthio)picolinate 1034922-28-5 C17H15FN4O3S2
    methyl 3-fluoro-4-(2-(5-(methoxymethyl)pyridin-2-ylamino)thiazol-5-ylthio)picolinate
    —— methyl 4-(2-(5-((tert-butoxycarbonyl(methyl)amino)methyl)pyridin-2-ylamino)thiazol-5-ylthio)-3-fluoropicolinate 1034922-52-5 C22H24FN5O4S2
    methyl 4-(2-(5-((tert-butoxycarbonyl(methyl)amino)methyl)pyridin-2-ylamino)thiazol-5-ylthio)-3-fluoropicolinate
    —— 5-butylsulfanyl-3-phenyl-isoxazole 25755-81-1 C13H15NOS
    5-butylsulfanyl-3-phenyl-isoxazole
    —— methyl 3-fluoro-4-(2-(thieno[3,2-c]pyridin-4-ylamino)thiazol-5-ylthio)picolinate 1034922-56-9 C17H11FN4O2S3
    methyl 3-fluoro-4-(2-(thieno[3,2-c]pyridin-4-ylamino)thiazol-5-ylthio)picolinate
    —— (2R)-2-({5-[(2,3-difluorobenzyl)thio]-2-methoxy[1,3]thiazolo[4,5-d]pyrimidin-7-yl}amino)-4-methylpentan-1-ol 849943-11-9 C19H22F2N4O2S2
    (2R)-2-({5-[(2,3-difluorobenzyl)thio]-2-methoxy[1,3]thiazolo[4,5-d]pyrimidin-7-yl}amino)-4-methylpentan-1-ol
    —— methyl 4-(2-(5-((tert-butoxycarbonylamino)methyl)pyridin-2-ylamino)thiazol-5-ylthio)-3-fluoropicolinate 1034922-18-3 C21H22FN5O4S2
    methyl 4-(2-(5-((tert-butoxycarbonylamino)methyl)pyridin-2-ylamino)thiazol-5-ylthio)-3-fluoropicolinate
    —— (2R)-2-{[5-(benzylsulfanyl)-2-methoxy[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino}-4-methylpentan-1-ol 849943-53-9 C19H24N4O2S2
    (2R)-2-{[5-(benzylsulfanyl)-2-methoxy[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino}-4-methylpentan-1-ol
    —— 3-fluoro-4-(2-(pyridin-2-ylamino)thiazol-5-ylthio)picolinic acid 1034921-09-9 C14H9FN4O2S2
    3-fluoro-4-(2-(pyridin-2-ylamino)thiazol-5-ylthio)picolinic acid
    —— 5-(4,4-difluorobut-3-enylthio)-3-phenylisoxazole 172932-75-1 C13H11F2NOS
    5-(4,4-difluorobut-3-enylthio)-3-phenylisoxazole