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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(bromophenyl-2-thioyl)tetrahydro-2H-pyran 620988-02-5 C11H13BrOS
    2-(bromophenyl-2-thioyl)tetrahydro-2H-pyran
    —— methyl (Z)-2-(N-methyl)aminomethyl-3-phenylthio-2-propenoate 156263-70-6 C12H15NO2S
    methyl (Z)-2-(N-methyl)aminomethyl-3-phenylthio-2-propenoate
    —— (+)-(S)-1-(phenylthio)pentan-2-ol 1073528-75-2 C11H16OS
    (+)-(S)-1-(phenylthio)pentan-2-ol
    —— allyl (phenylthio)ethyl ether 122396-65-0 C11H14OS
    allyl (phenylthio)ethyl ether
    —— (2-bromo-4-chloro-6-(methylthio)pyrimidin-5-yl)(phenyl)methanol 1034619-72-1 C12H10BrClN2OS
    (2-bromo-4-chloro-6-(methylthio)pyrimidin-5-yl)(phenyl)methanol
    —— 4-butylamino-6-chloro-2-methylthiopyrimidine-5-carbonitrile 169473-38-5 C10H13ClN4S
    4-butylamino-6-chloro-2-methylthiopyrimidine-5-carbonitrile
    —— 2-[4-(3-Bromopropylsulfanyl)phenyl]acetic acid 185802-94-2 C11H13BrO2S
    2-[4-(3-Bromopropylsulfanyl)phenyl]acetic acid
    —— 2-(phenylamino)-2-(2-(phenylthio)phenyl)acetonitrile 1529776-75-7 C20H16N2S
    2-(phenylamino)-2-(2-(phenylthio)phenyl)acetonitrile
    —— 2-(Phenylsulfanyl)ethyl 3-methylbut-2-enoate 60359-71-9 C13H16O2S
    2-(Phenylsulfanyl)ethyl 3-methylbut-2-enoate
    —— N-benzyl-N-[2-[4-[(4-methoxyphenyl)thio]-phenyl]ethyl]amine 477256-58-9 C22H23NOS
    N-benzyl-N-[2-[4-[(4-methoxyphenyl)thio]-phenyl]ethyl]amine
    —— tert-butyl N-(5-sec-butyl-6-chloro-2-methylthiopyrimidin-4-yl)-N-(2,2,2-trifluoroethyl)carbamate 944740-22-1 C16H23ClF3N3O2S
    tert-butyl N-(5-sec-butyl-6-chloro-2-methylthiopyrimidin-4-yl)-N-(2,2,2-trifluoroethyl)carbamate
    —— 5-<i>sec</i>-butyl-2-methylsulfanyl-1<i>H</i>-pyrimidine-4,6-dione 42039-72-5 C9H14N2O2S
    5-<i>sec</i>-butyl-2-methylsulfanyl-1<i>H</i>-pyrimidine-4,6-dione
    —— 4-difluoromethylthiophenyl isocyanate 50844-56-9 C8H5F2NOS
    4-difluoromethylthiophenyl isocyanate
    —— Acetic acid, methoxy-, 2-(phenylthio)ethyl ester 60359-69-5 C11H14O3S
    Acetic acid, methoxy-, 2-(phenylthio)ethyl ester
    —— dimethyl 1-[2-(phenylthio)ethyl]-1H-1,2,3-triazole-4,5-dicarboxylate 478626-19-6 C14H15N3O4S
    dimethyl 1-[2-(phenylthio)ethyl]-1H-1,2,3-triazole-4,5-dicarboxylate
    —— 2-(Phenylthio)ethyl formate 91228-20-5 C9H10O2S
    2-(Phenylthio)ethyl formate
    —— dimethyl 2-[2-(phenylthio)ethyl]-2H-1,2,3-triazole-4,5-dicarboxylate 478626-21-0 C14H15N3O4S
    dimethyl 2-[2-(phenylthio)ethyl]-2H-1,2,3-triazole-4,5-dicarboxylate
    —— (6-amino-4-methylsulfanyl-pyridin-2-yl)-methanol 1158787-60-0 C7H10N2OS
    (6-amino-4-methylsulfanyl-pyridin-2-yl)-methanol
    —— 1-(4-pyridyl)-3-(5-(4-thiazolyl)methylthio-2-pyridyloxy)pyrrolidine 194667-88-4 C18H18N4OS2
    1-(4-pyridyl)-3-(5-(4-thiazolyl)methylthio-2-pyridyloxy)pyrrolidine
    —— 5-(2,3-dichlorophenylsulfanyl)-N-methyl-4-nitrothiophene-2-carboxamide 1247820-22-9 C12H8Cl2N2O3S2
    5-(2,3-dichlorophenylsulfanyl)-N-methyl-4-nitrothiophene-2-carboxamide
    —— S-2,3-dichloroallyl di-isopropylthiocarbamate 17708-57-5 C10H17Cl2NOS
    S-2,3-dichloroallyl di-isopropylthiocarbamate
    —— 1-bromo-4-[(3-methylbut-3-en-1-yl)sulfanyl]benzene 1360916-04-6 C11H13BrS
    1-bromo-4-[(3-methylbut-3-en-1-yl)sulfanyl]benzene
    —— 2-chloro-5-(4-thiazolyl)methylthiopyridine 194668-58-1 C9H7ClN2S2
    2-chloro-5-(4-thiazolyl)methylthiopyridine
    —— tert-pentylthioethanol 26901-96-2 C7H16OS
    tert-pentylthioethanol
    —— 1,8-Dithiophenyl-3,6-dioxyoctan 30983-01-8 C18H22O2S2
    1,8-Dithiophenyl-3,6-dioxyoctan
    —— 1,2-bis(2-(pyridin-2-ylthio)ethoxy)ethane 501935-17-7 C16H20N2O2S2
    1,2-bis(2-(pyridin-2-ylthio)ethoxy)ethane
    —— 3-(2-(2-(2-fluoroethoxy)ethoxy)ethylthio)-4-(1-methyl-1,2,5,6-tetrahydropyridin-3-yl)-1,2,5-thiadiazole 1262964-26-0 C14H22FN3O2S2
    3-(2-(2-(2-fluoroethoxy)ethoxy)ethylthio)-4-(1-methyl-1,2,5,6-tetrahydropyridin-3-yl)-1,2,5-thiadiazole
    —— 2-{2-[2-(2-hydroxymethyl-3-methyl-pyridin-4-ylsulfanyl)-ethoxy]-ethoxy}-ethanol 251560-53-9 C13H21NO4S
    2-{2-[2-(2-hydroxymethyl-3-methyl-pyridin-4-ylsulfanyl)-ethoxy]-ethoxy}-ethanol
    —— 2-(2-(2-(4-(1-methyl-1,2,5,6-tetrahydropyridin-3-yl)-1,2,5-thiadiazol-3-ylthio)ethoxy)ethoxy)ethanol 1262964-22-6 C14H23N3O3S2
    2-(2-(2-(4-(1-methyl-1,2,5,6-tetrahydropyridin-3-yl)-1,2,5-thiadiazol-3-ylthio)ethoxy)ethoxy)ethanol
    —— 1,3-Dibenzyl-5-ethylsulfanylpyrimidine-2,4-dione 141075-06-1 C20H20N2O2S
    1,3-Dibenzyl-5-ethylsulfanylpyrimidine-2,4-dione
    —— 2-bromocyclooctyl bromomethyl sulfone 102683-74-9 C9H16Br2O2S
    2-bromocyclooctyl bromomethyl sulfone
    —— 2-methyl-6-methylthiothiazolo<4,5-b>pyrazine 87444-44-8 C7H7N3S2
    2-methyl-6-methylthiothiazolo<4,5-b>pyrazine
    —— 3-(4-fluorophenyl)-6-methyl-4-(4-methylthio)phenyl-pyran-2-one 387866-32-2 C19H15FO2S
    3-(4-fluorophenyl)-6-methyl-4-(4-methylthio)phenyl-pyran-2-one
    —— N-butyl-2-<(2-pyridylthio)methyl>pyrrolidine 128729-92-0 C14H22N2S
    N-butyl-2-<(2-pyridylthio)methyl>pyrrolidine
    —— allyl trifluoromethyl sulfone 73587-48-1 C4H5F3O2S
    allyl trifluoromethyl sulfone
    —— 4,2'-Dinitro-3-methyldiphenylsulfid 53827-86-4 C13H10N2O4S
    4,2'-Dinitro-3-methyldiphenylsulfid
    —— 2-[3-(1,3-dioxan-2-yl)-2-hydroxyphenyl]sulfanyl-N,N-diethylacetamide 731785-58-3 C16H23NO4S
    2-[3-(1,3-dioxan-2-yl)-2-hydroxyphenyl]sulfanyl-N,N-diethylacetamide
    —— 3-(Decane-1-sulfinyl)-propan-1-ol 82811-06-1 C13H28O2S
    3-(Decane-1-sulfinyl)-propan-1-ol
    —— 2-(4'-methyloxycarbonylphenylthio)-6-methylnicotinic acid 889879-79-2 C15H13NO4S
    2-(4'-methyloxycarbonylphenylthio)-6-methylnicotinic acid
    —— 4-(3-indolylthio)nicotinic acid 242491-29-8 C14H10N2O2S
    4-(3-indolylthio)nicotinic acid
    —— 1,3-bis(1-propylthio)benzene 21128-52-9 C12H18S2
    1,3-bis(1-propylthio)benzene
    —— bis-<2,2-bis(methylthio)vinyl> sulphone 89880-21-7 C8H14O2S5
    bis-<2,2-bis(methylthio)vinyl> sulphone
    —— 3-(2-hydroxymethyl-5-isopropyl-3-pyridin-4-ylmethyl-3H-imidazol-4-ylsulfanyl)-phenol 620969-36-0 C19H21N3O2S
    3-(2-hydroxymethyl-5-isopropyl-3-pyridin-4-ylmethyl-3H-imidazol-4-ylsulfanyl)-phenol
    —— 2-[3-(4-bromo-phenylsulfanyl)propenyl]thiophene 1223575-21-0 C13H11BrS2
    2-[3-(4-bromo-phenylsulfanyl)propenyl]thiophene
    —— 5-Anilino-3-methylthio-1,2,4-triazin-6-carbonsaeure 112080-86-1 C11H10N4O2S
    5-Anilino-3-methylthio-1,2,4-triazin-6-carbonsaeure
    —— 3-methylamino-4-phenylthio-2-butenoic acid ethyl ester 827039-37-2 C13H17NO2S
    3-methylamino-4-phenylthio-2-butenoic acid ethyl ester
    —— 5,6-Dimethyl-2-methylsulfanyl-thieno[2,3-d][1,3]oxazin-4-one 207744-06-7 C9H9NO2S2
    5,6-Dimethyl-2-methylsulfanyl-thieno[2,3-d][1,3]oxazin-4-one
    —— 2-Ethylsulfanyl-5,6-dimethyl-thieno[2,3-d][1,3]oxazin-4-one 207744-07-8 C10H11NO2S2
    2-Ethylsulfanyl-5,6-dimethyl-thieno[2,3-d][1,3]oxazin-4-one
    —— 2-Benzylsulfanyl-5,6-dimethyl-thieno[2,3-d][1,3]oxazin-4-one 207744-08-9 C15H13NO2S2
    2-Benzylsulfanyl-5,6-dimethyl-thieno[2,3-d][1,3]oxazin-4-one
    —— 1-(4-chloro-phenylsulfanylmethyl)-3-isopropyl-2,2-dioxo-2,3-dihydro-1<i>H</i>-2λ<sup>6</sup>-benzo[1,2,6]thiadiazin-4-one 61225-08-9 C17H17ClN2O3S2
    1-(4-chloro-phenylsulfanylmethyl)-3-isopropyl-2,2-dioxo-2,3-dihydro-1<i>H</i>-2λ<sup>6</sup>-benzo[1,2,6]thiadiazin-4-one