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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-Dimethylamino-3-thiapentan-3,3-dioxid 44916-66-7 C6H15NO2S
    1-Dimethylamino-3-thiapentan-3,3-dioxid
    —— 7-acetyl-3-benzylthio-5,6,7,8-tetrahydro-6-hydroxy-1,6-dimethyl-8-(pyridin-3-yl)isoquinoline-4-carbonitrile 1261295-76-4 C26H25N3O2S
    7-acetyl-3-benzylthio-5,6,7,8-tetrahydro-6-hydroxy-1,6-dimethyl-8-(pyridin-3-yl)isoquinoline-4-carbonitrile
    —— 7-acetyl-5,6,7,8-tetrahydro-6-hydroxy-1,6-dimethyl-3-methylthio-8-(fur-2-yl)isoquinoline-4-carbonitrile 1261295-78-6 C19H20N2O3S
    7-acetyl-5,6,7,8-tetrahydro-6-hydroxy-1,6-dimethyl-3-methylthio-8-(fur-2-yl)isoquinoline-4-carbonitrile
    —— Ethanamine, 2-[(3,4-dimethylphenyl)thio]- 192634-83-6 C10H15NS
    Ethanamine, 2-[(3,4-dimethylphenyl)thio]-
    —— (2R,4S,6R)-(4-methoxy-6-phenylsulfanyl-tetrahydro-pyran-2-yl)-ethanol 244781-34-8 C14H20O3S
    (2R,4S,6R)-(4-methoxy-6-phenylsulfanyl-tetrahydro-pyran-2-yl)-ethanol
    —— (2R,4S,6S)-(4-methoxy-6-phenylsulfanyl-tetrahydro-pyran-2-yl)-ethanol 244781-40-6 C14H20O3S
    (2R,4S,6S)-(4-methoxy-6-phenylsulfanyl-tetrahydro-pyran-2-yl)-ethanol
    —— 2-phenylthio-2,7-dimethyl-3-octen-5-yne-2,7-diol 85523-39-3 C16H20O2S
    2-phenylthio-2,7-dimethyl-3-octen-5-yne-2,7-diol
    —— 1,6-bisphenylthiohexa-2,4-diyne 75354-86-8 C18H14S2
    1,6-bisphenylthiohexa-2,4-diyne
    —— 3-(Carbamoylmercapto)-propionsaeureamid 77052-76-7 C4H8N2O2S
    3-(Carbamoylmercapto)-propionsaeureamid
    —— 1-(3,3,3-trifluoropropylthio)-4-bromobenzene 403793-25-9 C9H8BrF3S
    1-(3,3,3-trifluoropropylthio)-4-bromobenzene
    —— 3-(4-chlorophenyl)-5,6-dimethyl-2-(3,3,3-trifluoropropylthio)pyrimidin-4(3H)-one 1093750-03-8 C15H14ClF3N2OS
    3-(4-chlorophenyl)-5,6-dimethyl-2-(3,3,3-trifluoropropylthio)pyrimidin-4(3H)-one
    —— 4,5-Dimethyl-1-(phenylthio)-4-hexen-1-yn-3-one 162292-26-4 C14H14OS
    4,5-Dimethyl-1-(phenylthio)-4-hexen-1-yn-3-one
    —— (4S,5R)-5-Pentadec-1-ynyl-2-thioxo-[1,3]dioxolane-4-carboxylic acid ethyl ester 1027520-50-8 C21H34O4S
    (4S,5R)-5-Pentadec-1-ynyl-2-thioxo-[1,3]dioxolane-4-carboxylic acid ethyl ester
    —— N-[3-[2-(4-fluorophenylthio)phenyl]prop-2-enyl]-O-tetrahydropyranyl hydroxylamine 146372-84-1 C20H22FNO2S
    N-[3-[2-(4-fluorophenylthio)phenyl]prop-2-enyl]-O-tetrahydropyranyl hydroxylamine
    —— 1,8,10,17-tetraazacyclooctadecane-9,18-dithione 62829-34-9 C14H28N4S2
    1,8,10,17-tetraazacyclooctadecane-9,18-dithione
    —— 4,5-Dimethyl-1-phenylsulfanylhex-4-en-1-yn-3-ol 162292-78-6 C14H16OS
    4,5-Dimethyl-1-phenylsulfanylhex-4-en-1-yn-3-ol
    —— Ethyl 3-hydroxy-3-[1'-(phenylsulfanyl)cyclohexyl]propanedithioate 174784-03-3 C17H24OS3
    Ethyl 3-hydroxy-3-[1'-(phenylsulfanyl)cyclohexyl]propanedithioate
    —— [(4R,5R)-5-phenylsulfanyl-1-oxaspiro[5.5]undecan-4-yl]methanol 139747-35-6 C17H24O2S
    [(4R,5R)-5-phenylsulfanyl-1-oxaspiro[5.5]undecan-4-yl]methanol
    —— 1-[[2-Amino-5-[[(2,3-difluorophenyl)methyl]thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-2-methyl-2-propanol 259101-57-0 C16H17F2N5OS2
    1-[[2-Amino-5-[[(2,3-difluorophenyl)methyl]thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-2-methyl-2-propanol
    —— 2-[1'-(Phenylsulfanyl)cyclohexyl]ethane-1,2-diol 165677-48-5 C14H20O2S
    2-[1'-(Phenylsulfanyl)cyclohexyl]ethane-1,2-diol
    —— 2-[(3S,4R)-4-phenylsulfanyl-1-oxaspiro[4.5]decan-3-yl]ethanol 139747-36-7 C17H24O2S
    2-[(3S,4R)-4-phenylsulfanyl-1-oxaspiro[4.5]decan-3-yl]ethanol
    —— 4-[1'-(Phenylsulfanyl)cyclohexyl]butane-1,4-diol 136201-20-2 C16H24O2S
    4-[1'-(Phenylsulfanyl)cyclohexyl]butane-1,4-diol
    —— 3S-(2-chloro-4-fluorophenylthio)-2S-isobutylbutan-1,4-dioic acid 4-tert-butyl ester 198421-96-4 C18H24ClFO4S
    3S-(2-chloro-4-fluorophenylthio)-2S-isobutylbutan-1,4-dioic acid 4-tert-butyl ester
    —— 2S-isobutyl-3S-phenylthiobutan-1,4-dioic acid 4-tert-butyl ester 198421-43-1 C18H26O4S
    2S-isobutyl-3S-phenylthiobutan-1,4-dioic acid 4-tert-butyl ester
    —— 2S-isobutyl-3R-phenylthiobutan-1,4-dioic acid 4-tert-butyl ester 198421-44-2 C18H26O4S
    2S-isobutyl-3R-phenylthiobutan-1,4-dioic acid 4-tert-butyl ester
    —— 1-[(1'-phenylsulfanyl)cyclohexyl]butane-1,4-sulfite 247019-88-1 C16H22O3S2
    1-[(1'-phenylsulfanyl)cyclohexyl]butane-1,4-sulfite
    —— (E)-3-(1-phenylsulfanylcyclohexyl)prop-2-enal 711028-78-3 C15H18OS
    (E)-3-(1-phenylsulfanylcyclohexyl)prop-2-enal
    —— ((2S,3R)-3-Cyclohex-1-enyl-2-methyl-3-phenylsulfanyl-propyl)-carbamic acid ethyl ester 127941-07-5 C19H27NO2S
    ((2S,3R)-3-Cyclohex-1-enyl-2-methyl-3-phenylsulfanyl-propyl)-carbamic acid ethyl ester
    —— 2-[(1'-phenylsulfanyl)cyclohexyl]tetrahydrofuran 165748-28-7 C16H22OS
    2-[(1'-phenylsulfanyl)cyclohexyl]tetrahydrofuran
    —— 3-Benzyl-5,5-dimethyl-6-(1-phenylsulfanylcyclohexyl)-1,3-oxazinan-2-one 627537-13-7 C25H31NO2S
    3-Benzyl-5,5-dimethyl-6-(1-phenylsulfanylcyclohexyl)-1,3-oxazinan-2-one
    —— (S)-3-(o-tolylthio)cycloheptanone 1215843-46-1 C14H18OS
    (S)-3-(o-tolylthio)cycloheptanone
    —— 3,5,5-Trimethyl-6-(1-phenylsulfanylcyclohexyl)-1,3-oxazinan-2-one 627537-11-5 C19H27NO2S
    3,5,5-Trimethyl-6-(1-phenylsulfanylcyclohexyl)-1,3-oxazinan-2-one
    —— 5,5-Dimethyl-6-(1-phenylsulfanylcyclohexyl)-3-propan-2-yl-1,3-oxazinan-2-one 627537-15-9 C21H31NO2S
    5,5-Dimethyl-6-(1-phenylsulfanylcyclohexyl)-3-propan-2-yl-1,3-oxazinan-2-one
    —— 5,5-Dimethyl-6-(1-phenylsulfanylcyclohexyl)-1,3-oxazinan-2-one 627536-66-7 C18H25NO2S
    5,5-Dimethyl-6-(1-phenylsulfanylcyclohexyl)-1,3-oxazinan-2-one
    —— 1-[1-(phenylsulfanyl)cyclohexyl]but-3-en-1-one 311806-88-9 C16H20OS
    1-[1-(phenylsulfanyl)cyclohexyl]but-3-en-1-one
    —— 5-(Phenylsulfanyl)-1-oxaspiro[5.5]undecane 135967-30-5 C16H22OS
    5-(Phenylsulfanyl)-1-oxaspiro[5.5]undecane
    —— (1RS)-1-[1-(phenylsulfanyl)cyclohexyl]but-3-en-1-ol 311806-86-7 C16H22OS
    (1RS)-1-[1-(phenylsulfanyl)cyclohexyl]but-3-en-1-ol
    —— (2RS,3SR)-3-(cyclohex-1-enyl)-2-methyl-3-(phenylthio)propylamine 127940-88-9 C16H23NS
    (2RS,3SR)-3-(cyclohex-1-enyl)-2-methyl-3-(phenylthio)propylamine
    —— 6-(1''-Ethoxyethoxy)-1-[1'-(phenylsulfanyl)cyclohexyl]hexanol 253152-07-7 C22H36O3S
    6-(1''-Ethoxyethoxy)-1-[1'-(phenylsulfanyl)cyclohexyl]hexanol
    —— ethyl (E)-3-(1-phenylsulfanylcyclohexyl)prop-2-enoate 1026603-30-4 C17H22O2S
    ethyl (E)-3-(1-phenylsulfanylcyclohexyl)prop-2-enoate
    —— 2-[1'-(Phenylsulfanyl)cyclohexyl]epoxyethane 165748-29-8 C14H18OS
    2-[1'-(Phenylsulfanyl)cyclohexyl]epoxyethane
    —— 1-<methoxy(phenylthio)methyl>-1-cyclohexanol 75456-59-6 C14H20O2S
    1-<methoxy(phenylthio)methyl>-1-cyclohexanol
    —— 3-[(3-chloropropyl)sulphinyl]-1,1,1-trifluoropropane 1353008-85-1 C6H10ClF3OS
    3-[(3-chloropropyl)sulphinyl]-1,1,1-trifluoropropane
    —— 2-<4-<1-(ethoxycarbonyl)-ethylthio>-benzyl>-pyridine 132382-32-2 C17H19NO2S
    2-<4-<1-(ethoxycarbonyl)-ethylthio>-benzyl>-pyridine
    —— 8-N-(cyclopropylmethyl)-2-(2,6-diazaspiro[3.4]octan-6-yl)-4-N-(2-methylsulfanylphenyl)pyrimido[5,4-d]pyrimidine-4,8-diamine 1392889-12-1 C23H28N8S
    8-N-(cyclopropylmethyl)-2-(2,6-diazaspiro[3.4]octan-6-yl)-4-N-(2-methylsulfanylphenyl)pyrimido[5,4-d]pyrimidine-4,8-diamine
    —— diethyl 2-[3,3-bis(mesitylsulfanyl)propyl]-2-(6-oxocyclohex-1-enyl)malonate 1026695-75-9 C34H44O5S2
    diethyl 2-[3,3-bis(mesitylsulfanyl)propyl]-2-(6-oxocyclohex-1-enyl)malonate
    —— N-Methyl-N-(2-methyl-2-propanthiosulfenyl)-carbamoylfluorid 58684-01-8 C6H12FNOS2
    N-Methyl-N-(2-methyl-2-propanthiosulfenyl)-carbamoylfluorid
    —— 2-Methyl-2-(cis-4-phenylcyclohexyl)-1,3-dithiolan 113035-78-2 C16H22S2
    2-Methyl-2-(cis-4-phenylcyclohexyl)-1,3-dithiolan
    —— 4,6-dichloro-5-fluoro-2-(methylthio)pyrimidine 6693-07-8 C5H3Cl2FN2S
    4,6-dichloro-5-fluoro-2-(methylthio)pyrimidine
    —— (S)-4-Phenyl-3-((4S,5S)-2-phenylsulfanyl-1,6-dioxa-spiro[4.5]dec-4-yl)-oxazolidin-2-one 201680-51-5 C23H25NO4S
    (S)-4-Phenyl-3-((4S,5S)-2-phenylsulfanyl-1,6-dioxa-spiro[4.5]dec-4-yl)-oxazolidin-2-one