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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-phenylsulfanyl-5,6,7,8-tetrahydro-benzo[4,5]thieno[2,3-<i>d</i>]pyrimidine 40277-42-7 C16H14N2S2
    4-phenylsulfanyl-5,6,7,8-tetrahydro-benzo[4,5]thieno[2,3-<i>d</i>]pyrimidine
    —— 3-(1,3-Benzothiazol-2-yl)-4-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]but-3-enoic acid 5487-84-3 C21H16N4O4S2
    3-(1,3-Benzothiazol-2-yl)-4-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]but-3-enoic acid
    —— O-(3-dimethylaminopropyl)-4-(2-propylthio)acetophenone oxime 129602-88-6 C16H26N2OS
    O-(3-dimethylaminopropyl)-4-(2-propylthio)acetophenone oxime
    —— (4-(2-propylthio)phenyl)acetic acid 3583-60-6 C11H14O2S
    (4-(2-propylthio)phenyl)acetic acid
    —— 2-[(5-methylthioimidazol-4-yl)methylthio]ethylamine 83553-61-1 C7H13N3S2
    2-[(5-methylthioimidazol-4-yl)methylthio]ethylamine
    —— 3-diethylamino-5(1,3-dimethyl-5-methylthio-1H-pyrazol-4-yl)-2-propionyl-2-cyclohexen-1-one 132456-74-7 C19H29N3O2S
    3-diethylamino-5(1,3-dimethyl-5-methylthio-1H-pyrazol-4-yl)-2-propionyl-2-cyclohexen-1-one
    —— 2,6-Ditert-butyl-4-thiabicyclo[5.4.1]dodeca-1(11),2,5,7,9-pentaene 7226-05-3 C19H26S
    2,6-Ditert-butyl-4-thiabicyclo[5.4.1]dodeca-1(11),2,5,7,9-pentaene
    —— N-{4-[4-chloro-6-({3-[5-((diethylamino)methyl)-1H-benzo[d]imidazol-2-yl]-1H-pyrazol-4-yl}amino)pyrimidin-2-ylthio]phenyl}cyclopropanecarboxamide 1254229-39-4 C29H30ClN9OS
    N-{4-[4-chloro-6-({3-[5-((diethylamino)methyl)-1H-benzo[d]imidazol-2-yl]-1H-pyrazol-4-yl}amino)pyrimidin-2-ylthio]phenyl}cyclopropanecarboxamide
    —— (E)-3-(4-N,N-dimethylaminobenzylidenyl)-3H-benzo[b]thiophen-2-one 60224-06-8 C17H15NOS
    (E)-3-(4-N,N-dimethylaminobenzylidenyl)-3H-benzo[b]thiophen-2-one
    —— 4,6-Bis[(4-methylphenyl)sulfanyl]pyrimidin-2-amine 7226-50-8 C18H17N3S2
    4,6-Bis[(4-methylphenyl)sulfanyl]pyrimidin-2-amine
    —— Trimethylsiloxy-trimethylsilylmethyl-phenylsulphide 129584-67-4 C13H24OSSi2
    Trimethylsiloxy-trimethylsilylmethyl-phenylsulphide
    —— N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-3-[5-(3-chloro-4-methylphenyl)furan-2-yl]prop-2-enamide 5522-62-3 C24H21ClN4O2S
    N-(3-benzylsulfanyl-5-methyl-1,2,4-triazol-4-yl)-3-[5-(3-chloro-4-methylphenyl)furan-2-yl]prop-2-enamide
    —— O-Methyl-2-(phenylthio)benzohydroxamic acid 89114-60-3 C14H13NO2S
    O-Methyl-2-(phenylthio)benzohydroxamic acid
    —— 2-(phenylthio)benzamidoxime 117596-54-0 C13H12N2OS
    2-(phenylthio)benzamidoxime
    —— 2-(Phenylthio)benzohydroxamic acid 65765-04-0 C13H11NO2S
    2-(Phenylthio)benzohydroxamic acid
    —— Agn-PC-0loysx 7226-53-1 C18H16N6S6+2
    Agn-PC-0loysx
    —— 4-amino-6-chloro-2-(1-(pyridin-2-yl)ethyl)thio-pyrimidine 185219-17-4 C11H11ClN4S
    4-amino-6-chloro-2-(1-(pyridin-2-yl)ethyl)thio-pyrimidine
    —— S-<(methylthio)methyl>-L-cysteinol 88001-48-3 C5H13NOS2
    S-<(methylthio)methyl>-L-cysteinol
    —— 3-[[4-(4-bromophenyl)-1,3-thiazol-2-yl]sulfanyl]-N,N-diethylpropanamide 5387-40-6 C16H19BrN2OS2
    3-[[4-(4-bromophenyl)-1,3-thiazol-2-yl]sulfanyl]-N,N-diethylpropanamide
    —— 5-Morpholinosulfonylspiro[benzo[b]thiophene-2(3H),1'-cyclopropan]-3-one 79002-97-4 C14H15NO4S2
    5-Morpholinosulfonylspiro[benzo[b]thiophene-2(3H),1'-cyclopropan]-3-one
    —— 4',5'-dihydrospiro<benzo<b>furan-2(3H),3'(2'H)-furan>-3,2'-dione 107191-18-4 C11H8O3S
    4',5'-dihydrospiro<benzo<b>furan-2(3H),3'(2'H)-furan>-3,2'-dione
    —— 5-morpholinosulfonyl-4',5'-dihydrospiro<benzo<b>thiophene-2(3H),3'(2'H)-furan>-3,2'-dione 79003-16-0 C15H15NO6S2
    5-morpholinosulfonyl-4',5'-dihydrospiro<benzo<b>thiophene-2(3H),3'(2'H)-furan>-3,2'-dione
    —— 4,6-dichloro-2-(1-(pyridin-2-yl)ethyl)thio-pyrimidine 185220-22-8 C11H9Cl2N3S
    4,6-dichloro-2-(1-(pyridin-2-yl)ethyl)thio-pyrimidine
    —— N-methyl-N-[[4-(trifluoromethylsulfanyl)phenyl]methyl]carbamoyl chloride 211619-45-3 C10H9ClF3NOS
    N-methyl-N-[[4-(trifluoromethylsulfanyl)phenyl]methyl]carbamoyl chloride
    —— ((1R,2S)-1-(3,5-dimethylphenylthio)-3-methoxy-1-phenylpropan-2-yloxy)diphenylphosphine 1221576-58-4 C30H31O2PS
    ((1R,2S)-1-(3,5-dimethylphenylthio)-3-methoxy-1-phenylpropan-2-yloxy)diphenylphosphine
    —— ((1R,2S)-1-(4-bromophenylthio)-3-methoxy-1-phenylpropan-2-yloxy)diphenylphosphine 1221576-61-9 C28H26BrO2PS
    ((1R,2S)-1-(4-bromophenylthio)-3-methoxy-1-phenylpropan-2-yloxy)diphenylphosphine
    —— (1R,2S)-1-(3,5-dimethylphenylthio)-3-methoxy-1-phenylpropan-2-ol 1221576-20-0 C18H22O2S
    (1R,2S)-1-(3,5-dimethylphenylthio)-3-methoxy-1-phenylpropan-2-ol
    —— 3-Ethylthio-5,5-dimethyl-2-cyclohexen-1-thion 69060-43-1 C10H16S2
    3-Ethylthio-5,5-dimethyl-2-cyclohexen-1-thion
    —— (1R,2S)-1-(4-bromophenylthio)-3-methoxy-1-phenylpropan-2-ol 1221576-23-3 C16H17BrO2S
    (1R,2S)-1-(4-bromophenylthio)-3-methoxy-1-phenylpropan-2-ol
    —— 2-({5-(1,5-Dimethyl-1H-pyrazol-3-yl)-4-[(furan-2-yl)methyl]-4H-1,2,4-triazol-3-yl}sulfanyl)-N-(prop-2-en-1-yl)acetamide 7168-12-9 C17H20N6O2S
    2-({5-(1,5-Dimethyl-1H-pyrazol-3-yl)-4-[(furan-2-yl)methyl]-4H-1,2,4-triazol-3-yl}sulfanyl)-N-(prop-2-en-1-yl)acetamide
    —— N-[3-(difluoromethyl)-5-(ethylsulfanyl)-4H-1,2,4-triazol-4-yl]-3-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]propanamide 7168-10-7 C13H15F5N6OS
    N-[3-(difluoromethyl)-5-(ethylsulfanyl)-4H-1,2,4-triazol-4-yl]-3-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]propanamide
    —— 2,3-Bis(phenylsulfanyl)prop-2-enyl-dimethylazanium 7229-72-3 C17H20NS2+
    2,3-Bis(phenylsulfanyl)prop-2-enyl-dimethylazanium
    —— 3-chloro-N,N-diethyl-4-{[(4-hydroxy-6-methylpyrimidin-2-yl)sulfanyl]methyl}benzene-1-carboximidamide 1256559-21-3 C17H21ClN4OS
    3-chloro-N,N-diethyl-4-{[(4-hydroxy-6-methylpyrimidin-2-yl)sulfanyl]methyl}benzene-1-carboximidamide
    —— 2-{[3-Cyano-6-methyl-4-(trifluoromethyl)pyridin-2-yl]sulfanyl}-N,N-diethylacetamide 6926-93-8 C14H16F3N3OS
    2-{[3-Cyano-6-methyl-4-(trifluoromethyl)pyridin-2-yl]sulfanyl}-N,N-diethylacetamide
    —— 2-propyl-2-(13,15-dioxahexadec-4-ynyl)-1,3-dithiane 928030-59-5 C21H38O2S2
    2-propyl-2-(13,15-dioxahexadec-4-ynyl)-1,3-dithiane
    —— Propan-2-yl 7-methyl-5-[4-(methylsulfanyl)phenyl]-2-{[4-(methylsulfanyl)phenyl]methylidene}-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate 6998-31-8 C26H26N2O3S3
    Propan-2-yl 7-methyl-5-[4-(methylsulfanyl)phenyl]-2-{[4-(methylsulfanyl)phenyl]methylidene}-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— methyl 2,2-dimethoxy-4-phenylsulfanylpentanoate 556051-18-4 C14H20O4S
    methyl 2,2-dimethoxy-4-phenylsulfanylpentanoate
    —— Methyl 2-oxo-4-phenylsulfanylpentanoate 556051-17-3 C12H14O3S
    Methyl 2-oxo-4-phenylsulfanylpentanoate
    —— 4-amino-2-benzylthiopyrimidine-5-methanol 100193-64-4 C12H13N3OS
    4-amino-2-benzylthiopyrimidine-5-methanol
    —— 1H-Indole, 2,2'-(1,2-ethenediyl)bis[1-(phenylsulfonyl)-3-(phenylthio)- 226947-49-5 C42H30N2O4S4
    1H-Indole, 2,2'-(1,2-ethenediyl)bis[1-(phenylsulfonyl)-3-(phenylthio)-
    —— (2-methoxy-2-methylpropanesulfonyl)acetonitrile 1232400-76-8 C7H13NO3S
    (2-methoxy-2-methylpropanesulfonyl)acetonitrile
    —— 2,2'-[1,4-phenylenebis(methylenethio)]bisthiazole 501676-71-7 C14H12N2S4
    2,2'-[1,4-phenylenebis(methylenethio)]bisthiazole
    —— 2-[(4-Bromophenyl)sulfanyl]-5-(3,5-dimethylpiperidine-1-sulfonyl)benzoate 6770-11-2 C20H21BrNO4S2-
    2-[(4-Bromophenyl)sulfanyl]-5-(3,5-dimethylpiperidine-1-sulfonyl)benzoate
    —— Zinc 3-ethyl-5-{[4-({5-[(4-ethyl-3,5-dimethyl-2H-pyrrol-2-ylidene)methyl]-2,4-dimethylpyrrol-1-id-3-yl}sulfanyl)-3,5-dimethyl-2H-pyrrol-2-ylidene]methyl}-2,4-dimethylpyrrol-1-ide (1/1) 7236-04-6 C60H72N8S2Zn2
    Zinc 3-ethyl-5-{[4-({5-[(4-ethyl-3,5-dimethyl-2H-pyrrol-2-ylidene)methyl]-2,4-dimethylpyrrol-1-id-3-yl}sulfanyl)-3,5-dimethyl-2H-pyrrol-2-ylidene]methyl}-2,4-dimethylpyrrol-1-ide (1/1)
    —— 5,5,6,6,6-pentafluoro-2-(3-methoxypropanesulfonyl)hexanenitrile 1232400-60-0 C10H14F5NO3S
    5,5,6,6,6-pentafluoro-2-(3-methoxypropanesulfonyl)hexanenitrile
    —— (3,3,4,4,5,5,5-heptafluoropentylsulfonyl)acetonitrile 939049-26-0 C7H6F7NO2S
    (3,3,4,4,5,5,5-heptafluoropentylsulfonyl)acetonitrile
    —— perfluorooctylpropylsulfonylethanol 1154463-63-4 C13H11F17O3S
    perfluorooctylpropylsulfonylethanol
    —— 5,5,6,6,6-pentafluoro-2-(2-methoxy-2-methylpropanesulfonyl)hexanenitrile 1232400-62-2 C11H16F5NO3S
    5,5,6,6,6-pentafluoro-2-(2-methoxy-2-methylpropanesulfonyl)hexanenitrile
    —— 5,5,6,6,6-pentafluoro-2-(2-hydroxyethanesulfonyl)hexanenitrile 1232400-63-3 C8H10F5NO3S
    5,5,6,6,6-pentafluoro-2-(2-hydroxyethanesulfonyl)hexanenitrile
    —— 5,5,6,6,6-pentafluoro-2-(2-isopropoxyethanesulfonyl)hexanenitrile 1232400-61-1 C11H16F5NO3S
    5,5,6,6,6-pentafluoro-2-(2-isopropoxyethanesulfonyl)hexanenitrile