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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(tert-Butylsulfonyl)-N'-hydroxyacetimidamide —— C6H14N2O3S
    2-(tert-Butylsulfonyl)-N'-hydroxyacetimidamide
    —— (S)-2-mesyloxy-6-(phenylthio)hexane 1416148-55-4 C13H20O3S2
    (S)-2-mesyloxy-6-(phenylthio)hexane
    —— 2-Methylcyclopentanethiol 57067-19-3 C6H12S
    2-Methylcyclopentanethiol
    —— 3-Ethyl-hexan-2-thiol ('1,1-Diethyl-butan-1-thiol') 55956-00-8 C8H18S
    3-Ethyl-hexan-2-thiol ('1,1-Diethyl-butan-1-thiol')
    —— 2,2'-thiobis(6-t-octyl-4-methylphenol) 13816-08-5 C30H46O2S
    2,2'-thiobis(6-t-octyl-4-methylphenol)
    —— 2-(1'-pivaloylamino-2',2'-dichlorovinyl)thiouracil 147298-53-1 C11H13Cl2N3O2S
    2-(1'-pivaloylamino-2',2'-dichlorovinyl)thiouracil
    —— (R)-6-phenylthio-2-hexanol 1416148-46-3 C12H18OS
    (R)-6-phenylthio-2-hexanol
    —— 4,4-bis(methylthio)-2-methyl-2-butenal 84735-59-1 C7H12OS2
    4,4-bis(methylthio)-2-methyl-2-butenal
    —— 3-cyano-4-(methylthio)-2,6-dimethylpyridine 130445-76-0 C9H10N2S
    3-cyano-4-(methylthio)-2,6-dimethylpyridine
    —— 4-cyano-3-(phenylthio)benzo[b][1,6]naphthyridine 370844-73-8 C19H11N3S
    4-cyano-3-(phenylthio)benzo[b][1,6]naphthyridine
    —— 5-(4-methylsulphanylphenylsulphanyl)indoline 329794-78-7 C15H15NS2
    5-(4-methylsulphanylphenylsulphanyl)indoline
    —— 2-Phenyl-6-methylthio-4H-pyran-4-one 117683-53-1 C12H10O2S
    2-Phenyl-6-methylthio-4H-pyran-4-one
    —— methyl 4-methyl-2-(methylsulfanyl)-6-(p-tolylsulfanyl)benzoate 1195804-25-1 C17H18O2S2
    methyl 4-methyl-2-(methylsulfanyl)-6-(p-tolylsulfanyl)benzoate
    —— methyl 3,4-dimethyl-6-(methylsulfanyl)-2-(phenylsulfanyl)benzoate 1195804-31-9 C17H18O2S2
    methyl 3,4-dimethyl-6-(methylsulfanyl)-2-(phenylsulfanyl)benzoate
    —— 4,4,5,5-Tetra(methylthio)-octane-2,3,6,7-tetraone 140611-78-5 C12H18O4S4
    4,4,5,5-Tetra(methylthio)-octane-2,3,6,7-tetraone
    —— methyl 3,4-dimethyl-6-(methylsulfanyl)-2-(p-tolylsulfanyl)benzoate 1195804-33-1 C18H20O2S2
    methyl 3,4-dimethyl-6-(methylsulfanyl)-2-(p-tolylsulfanyl)benzoate
    —— {2-[3-(4-morpholin-4-ylmethylphenyl)-[1,2,4]triazolo[4,3-a]pyridin-6-ylsulfanyl]phenyl}methanol 946050-92-6 C24H24N4O2S
    {2-[3-(4-morpholin-4-ylmethylphenyl)-[1,2,4]triazolo[4,3-a]pyridin-6-ylsulfanyl]phenyl}methanol
    —— 2,4,6,8-Tetrathiaadamantane, 1,3,5,7,9-pentamethyl- 17749-59-6 C11H18S4
    2,4,6,8-Tetrathiaadamantane, 1,3,5,7,9-pentamethyl-
    —— (R)-[5-(4-methylsulphanylphenylsulphanyl)-1-(3,3,3-trifluoro-2-hydroxy-2-methylpropionyl)indoline] 329794-58-3 C19H18F3NO2S2
    (R)-[5-(4-methylsulphanylphenylsulphanyl)-1-(3,3,3-trifluoro-2-hydroxy-2-methylpropionyl)indoline]
    —— S-t-Butyl phenylthiothioacetate 63006-70-2 C12H16OS2
    S-t-Butyl phenylthiothioacetate
    —— 1-Chloro-1-(dichloro-methanesulfonyl-methanesulfonyl)-ethane 68483-82-9 C4H7Cl3O4S2
    1-Chloro-1-(dichloro-methanesulfonyl-methanesulfonyl)-ethane
    —— 1-(4-(4,6-dimethylpyrimidin-2-ylthio)phenyl)-3-(4-(trifluoromethoxy)phenyl)urea 1263499-67-7 C20H17F3N4O2S
    1-(4-(4,6-dimethylpyrimidin-2-ylthio)phenyl)-3-(4-(trifluoromethoxy)phenyl)urea
    —— 1,1-bis(methylthio)-n-pentane 52317-55-2 C7H16S2
    1,1-bis(methylthio)-n-pentane
    —— 2,4,6,8-Tetrathiaadamantane-1-carboxylic acid, 3,5,7-trimethyl- 21404-62-6 C10H14O2S4
    2,4,6,8-Tetrathiaadamantane-1-carboxylic acid, 3,5,7-trimethyl-
    —— 2,4,6,8-Tetrathiaadamantane, 1,3,5,7,9,9,10,10-octamethyl- 17749-62-1 C14H24S4
    2,4,6,8-Tetrathiaadamantane, 1,3,5,7,9,9,10,10-octamethyl-
    —— 2,4,6,8,9-Pentathiaadamantane, 1,3,5,7,10-pentamethyl- 17443-93-5 C10H16S5
    2,4,6,8,9-Pentathiaadamantane, 1,3,5,7,10-pentamethyl-
    —— 16-bromo-1-hexadecanethiol 1362855-77-3 C16H33BrS
    16-bromo-1-hexadecanethiol
    —— 5-ethylamino-3-methylsulfanyl-1,2,4-triazine-6-carbaldehyde 406920-81-8 C7H10N4OS
    5-ethylamino-3-methylsulfanyl-1,2,4-triazine-6-carbaldehyde
    —— 2-(octylthio)-4,6(1H,5H)-pyrimidinedione 86627-13-6 C12H20N2O2S
    2-(octylthio)-4,6(1H,5H)-pyrimidinedione
    —— Thiosulfuric acid S-{N-[3-(4-methylsulfanyl-phenyl)-adamantan-1-ylmethyl]-carbamimidoylmethyl} ester 117077-52-8 C20H28N2O3S3
    Thiosulfuric acid S-{N-[3-(4-methylsulfanyl-phenyl)-adamantan-1-ylmethyl]-carbamimidoylmethyl} ester
    —— {4-[4-(1,5-Diphenyl-4,5-dihydro-1H-pyrazol-3-yl)-phenylsulfanyl]-phenyl}-[1-phenyl-meth-(E)-ylidene]-amine 154599-66-3 C34H27N3S
    {4-[4-(1,5-Diphenyl-4,5-dihydro-1H-pyrazol-3-yl)-phenylsulfanyl]-phenyl}-[1-phenyl-meth-(E)-ylidene]-amine
    —— 2,2-dichlorocyclopropylmethyl 1H-1,2,4-triazol-5-yl sulfide 118124-76-8 C6H7Cl2N3S
    2,2-dichlorocyclopropylmethyl 1H-1,2,4-triazol-5-yl sulfide
    —— 6-<(4-chlorophenyl)thio>-N,N-dimethyl-1,2,4,5-tetrazin-3-amine 75328-95-9 C10H10ClN5S
    6-<(4-chlorophenyl)thio>-N,N-dimethyl-1,2,4,5-tetrazin-3-amine
    —— 2,2-dichlorocyclopropylmethyl pentyl sulfide 892219-89-5 C9H16Cl2S
    2,2-dichlorocyclopropylmethyl pentyl sulfide
    —— 1-butylthio-2-phenylthio-ethane 29654-72-6 C12H18S2
    1-butylthio-2-phenylthio-ethane
    —— 2,2-dichlorocyclopropylmethyl phenyl sulfide 86476-99-5 C10H10Cl2S
    2,2-dichlorocyclopropylmethyl phenyl sulfide
    —— Cyclohexane, (pentylthio)- 7133-42-8 C11H22S
    Cyclohexane, (pentylthio)-
    —— (1S,3aS,4S,7aR)-7a-Methyl-5-oxo-6-phenylsulfanyl-4-[(R)-2-(4,6,7,8-tetrahydro-benzo[1,3]dioxin-8a-yl)-ethyl]-3a-trimethylsilanyloxy-octahydro-indene-1-carbonitrile 1026450-31-6 C30H41NO4SSi
    (1S,3aS,4S,7aR)-7a-Methyl-5-oxo-6-phenylsulfanyl-4-[(R)-2-(4,6,7,8-tetrahydro-benzo[1,3]dioxin-8a-yl)-ethyl]-3a-trimethylsilanyloxy-octahydro-indene-1-carbonitrile
    —— (E)-1-Butylsulfanyl-buta-1,3-diene 109921-64-4 C8H14S
    (E)-1-Butylsulfanyl-buta-1,3-diene
    —— 2-o-Tolylmercapto-butanon-(3) 17078-35-2 C11H14OS
    2-o-Tolylmercapto-butanon-(3)
    —— 2,2-dimethylpropyl 2,2-dimethylpropanesulfinyl sulfone 82360-14-3 C10H22O3S2
    2,2-dimethylpropyl 2,2-dimethylpropanesulfinyl sulfone
    —— bis(benzo[4,5]thieno)[2,3-b: 2'3'-e][1,4]dithiin 42057-21-6 C16H8S4
    bis(benzo[4,5]thieno)[2,3-b: 2'3'-e][1,4]dithiin
    —— 1-(3-(furfurylthio)-2-pyrazinyl)-2-methyl-1-propanone 118043-62-2 C13H14N2O2S
    1-(3-(furfurylthio)-2-pyrazinyl)-2-methyl-1-propanone
    —— 2-(2,5-Dimethyl-phenylmercapto)-butanon-(3) 1204-94-0 C12H16OS
    2-(2,5-Dimethyl-phenylmercapto)-butanon-(3)
    —— (3-hydroxy-6-methyl-pyridin-2-ylsulfanyl)-phenyl-acetic acid 32002-83-8 C14H13NO3S
    (3-hydroxy-6-methyl-pyridin-2-ylsulfanyl)-phenyl-acetic acid
    —— α-(2-pyridylthio)benzyllithium 38711-74-9 C12H10LiNS
    α-(2-pyridylthio)benzyllithium
    —— tributyl[2-(phenylthio)-3,6-(MeO)2-phenyl]tin 780820-51-1 C26H40O2SSn
    tributyl[2-(phenylthio)-3,6-(MeO)2-phenyl]tin
    —— 3-<3-Methyl-phenylmercapto>-butan-2-on 93351-10-1 C11H14OS
    3-<3-Methyl-phenylmercapto>-butan-2-on
    —— 1-ethoxy-1-phenylthiononane 99054-49-6 C17H28OS
    1-ethoxy-1-phenylthiononane
    —— 2-(4-Phenylsulfanyl-butylidene)-malonic acid diethyl ester 130247-52-8 C17H22O4S
    2-(4-Phenylsulfanyl-butylidene)-malonic acid diethyl ester