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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(3-methoxyphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299398-99-4 C27H34NOS*I
    3-(3-methoxyphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(4-hydroxyphenylthio)quinoline 1299398-60-9 C15H11NOS
    3-(4-hydroxyphenylthio)quinoline
    —— 3-(3-cyanophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-13-5 C27H31N2S*I
    3-(3-cyanophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(4-hydroxyphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-20-4 C26H32NOS*I
    3-(4-hydroxyphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(2-hydroxyphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-17-9 C26H32NOS*I
    3-(2-hydroxyphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(3-hydroxyphenylthio)quinoline 1299398-58-5 C15H11NOS
    3-(3-hydroxyphenylthio)quinoline
    —— 5-(cyclopent-1-en-1-yl)-2-(2-hydroxyethyl)-2-(phenylthio)pentanenitrile 1276114-82-9 C18H23NOS
    5-(cyclopent-1-en-1-yl)-2-(2-hydroxyethyl)-2-(phenylthio)pentanenitrile
    —— 3-(3-fluorophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299398-95-0 C26H31FNS*I
    3-(3-fluorophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(4-cyanophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-15-7 C27H31N2S*I
    3-(4-cyanophenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(2-methylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-05-5 C27H34NS*I
    3-(2-methylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(3-hydroxyphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-18-0 C26H32NOS*I
    3-(3-hydroxyphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— 3-(2-hydroxyphenylthio)quinoline 1299398-56-3 C15H11NOS
    3-(2-hydroxyphenylthio)quinoline
    —— 5-(cyclopent-1-en-1-yl)-2-(phenylthio)pentanenitrile 1276114-81-8 C16H19NS
    5-(cyclopent-1-en-1-yl)-2-(phenylthio)pentanenitrile
    —— 3-(quinolin-3-ylsulfanyl)benzonitrile 1299398-64-3 C16H10N2S
    3-(quinolin-3-ylsulfanyl)benzonitrile
    —— 3-(phenylthio)-1-(5-cyclohexylpentyl)quinolinium iodide 1265087-27-1 C26H32NS*I
    3-(phenylthio)-1-(5-cyclohexylpentyl)quinolinium iodide
    —— 3-(4-methylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide 1299399-09-9 C27H34NS*I
    3-(4-methylphenylsulfanyl)-1-(5-cyclohexylpentyl)quinolin-1-ium iodide
    —— (4R,6S)-6-[(E)-2-[2-cyclopropyl-6-methoxy-4-(3-methoxyphenyl)sulfanylquinolin-3-yl]ethenyl]-4-hydroxyoxan-2-one 1202383-08-1 C27H27NO5S
    (4R,6S)-6-[(E)-2-[2-cyclopropyl-6-methoxy-4-(3-methoxyphenyl)sulfanylquinolin-3-yl]ethenyl]-4-hydroxyoxan-2-one
    —— 5-(2-bromoethylthio)selenophene-2-carbaldehyde 1297906-70-7 C7H7BrOSSe
    5-(2-bromoethylthio)selenophene-2-carbaldehyde
    —— (Z)-2-(1-bromodec-1-en-2-ylthio)aniline 1279713-37-9 C16H24BrNS
    (Z)-2-(1-bromodec-1-en-2-ylthio)aniline
    —— Fluhexafon 1097630-26-6 C12H17F3N2O3S
    Fluhexafon
    —— 4-fluoro-2-pentyl-3-(phenylthio)-1H-indole 1287792-06-6 C19H20FNS
    4-fluoro-2-pentyl-3-(phenylthio)-1H-indole
    —— tert-butyl-dimethyl-[(3S,4R)-4-[2-[(2R,4S,6S)-2,4,6,7-tetrakis[[tert-butyl(dimethyl)silyl]oxy]heptyl]-1,3-dithian-2-yl]pent-1-en-3-yl]oxysilane 1306603-25-7 C46H100O5S2Si5
    tert-butyl-dimethyl-[(3S,4R)-4-[2-[(2R,4S,6S)-2,4,6,7-tetrakis[[tert-butyl(dimethyl)silyl]oxy]heptyl]-1,3-dithian-2-yl]pent-1-en-3-yl]oxysilane
    —— 7-methyl-6-[2-(3-thienyl)ethyl]-1,4-dithiaspiro[4.5]dec-6-ene 1292848-63-5 C15H20S3
    7-methyl-6-[2-(3-thienyl)ethyl]-1,4-dithiaspiro[4.5]dec-6-ene
    —— N-(4-methylsulfanyl-3-propan-2-yloxadiazol-3-ium-5-yl)benzenecarboximidate 1217516-00-1 C13H15N3O2S
    N-(4-methylsulfanyl-3-propan-2-yloxadiazol-3-ium-5-yl)benzenecarboximidate
    —— 2-Methylmercapto-5-m-tolyl-1,3,4-oxadiazol 71134-60-6 C10H10N2OS
    2-Methylmercapto-5-m-tolyl-1,3,4-oxadiazol
    —— N-[4-(cyclopropylmethylsulfanyl)-3-propan-2-yloxadiazol-3-ium-5-yl]benzenecarboximidate 1217516-03-4 C16H19N3O2S
    N-[4-(cyclopropylmethylsulfanyl)-3-propan-2-yloxadiazol-3-ium-5-yl]benzenecarboximidate
    —— 2-(3-Methylphenyl)-5-prop-2-ynylsulfanyl-1,3,4-oxadiazole 892446-26-3 C12H10N2OS
    2-(3-Methylphenyl)-5-prop-2-ynylsulfanyl-1,3,4-oxadiazole
    —— N-(4-methylsulfanyl-3-propan-2-yloxadiazol-3-ium-5-yl)ethanimidate 1217515-98-4 C8H13N3O2S
    N-(4-methylsulfanyl-3-propan-2-yloxadiazol-3-ium-5-yl)ethanimidate
    —— N-[3-(dimethylamino)-4-methylsulfanyloxadiazol-3-ium-5-yl]benzenecarboximidate 1217515-96-2 C12H14N4O2S
    N-[3-(dimethylamino)-4-methylsulfanyloxadiazol-3-ium-5-yl]benzenecarboximidate
    —— N-(4-benzylsulfanyl-3-propan-2-yloxadiazol-3-ium-5-yl)benzenecarboximidate 1217516-02-3 C19H19N3O2S
    N-(4-benzylsulfanyl-3-propan-2-yloxadiazol-3-ium-5-yl)benzenecarboximidate
    —— methyl 2-((2-(4-bromophenylthio)quinolin-3-yl)(hydroxy)methyl)acrylate 1309389-08-9 C20H16BrNO3S
    methyl 2-((2-(4-bromophenylthio)quinolin-3-yl)(hydroxy)methyl)acrylate
    —— 1-Chloro-3-[4-[4-(3-chloro-2-hydroxypropoxy)phenyl]sulfanylphenoxy]propan-2-ol 1314090-45-3 C18H20Cl2O4S
    1-Chloro-3-[4-[4-(3-chloro-2-hydroxypropoxy)phenyl]sulfanylphenoxy]propan-2-ol
    —— (2-(1-methoxycyclohex-2-enyl)ethynyl)(phenyl)sulfane 1298087-12-3 C15H16OS
    (2-(1-methoxycyclohex-2-enyl)ethynyl)(phenyl)sulfane
    —— 5-((4-bromophenylthio)methyl)-1H-pyrazol-3(2H)-one 1227692-39-8 C10H9BrN2OS
    5-((4-bromophenylthio)methyl)-1H-pyrazol-3(2H)-one
    —— 1-methyl-3-(phenylthio)quinolinium iodide 1265087-21-5 C16H14NS*I
    1-methyl-3-(phenylthio)quinolinium iodide
    —— 2,2'-bis[(S)-4-benzylimidazolin-2-yl]diphenyl sulfide 1265177-57-8 C32H30N4S
    2,2'-bis[(S)-4-benzylimidazolin-2-yl]diphenyl sulfide
    —— 3-(Butylthio)phenylboronic acid 884868-03-5 C10H15BO2S
    3-(Butylthio)phenylboronic acid
    —— 5-bromo-2-(4-(3-trifluoromethyl-diazirin-3-yl)phenylthio)thiazole 1270931-18-4 C11H5BrF3N3S2
    5-bromo-2-(4-(3-trifluoromethyl-diazirin-3-yl)phenylthio)thiazole
    —— 2,2'-bis[(S)-1-(1-methylethyl)-4-benzylimidazolin-2-yl]diphenyl sulfide 1265177-59-0 C38H42N4S
    2,2'-bis[(S)-1-(1-methylethyl)-4-benzylimidazolin-2-yl]diphenyl sulfide
    —— 3-(Cyclohexylsulfanyl)-6-hydrazinylpyridazine 1334490-68-4 C10H16N4S
    3-(Cyclohexylsulfanyl)-6-hydrazinylpyridazine
    —— 5-(4-methoxytetrahydropyran-4-yl)-2-(4-(3-trifluoromethyl-diazirin-3-yl)phenylthio)thiazole 1270931-12-8 C17H16F3N3O2S2
    5-(4-methoxytetrahydropyran-4-yl)-2-(4-(3-trifluoromethyl-diazirin-3-yl)phenylthio)thiazole
    —— N-i-propyl-3,3-dimethoxy-2-(phenylthio)propanamide 1294897-38-3 C14H21NO3S
    N-i-propyl-3,3-dimethoxy-2-(phenylthio)propanamide
    —— 5-(4-Methoxyoxan-4-yl)-2-[4-[3-(trifluoromethyl)diazirin-3-yl]phenyl]sulfanyl-4-tritio-1,3-thiazole 1270931-13-9 C17H16F3N3O2S2
    5-(4-Methoxyoxan-4-yl)-2-[4-[3-(trifluoromethyl)diazirin-3-yl]phenyl]sulfanyl-4-tritio-1,3-thiazole
    —— N-i-propyl-3-(morpholin-4-yl)-2-(phenylthio)propenamide 1294897-03-2 C16H22N2O2S
    N-i-propyl-3-(morpholin-4-yl)-2-(phenylthio)propenamide
    —— 4-bromo-5-(4-methoxytetrahydropyran-4-yl)-2-(4-(3-trifluoromethyl-diazirin-3-yl)phenylthio)thiazole 1270931-15-1 C17H15BrF3N3O2S2
    4-bromo-5-(4-methoxytetrahydropyran-4-yl)-2-(4-(3-trifluoromethyl-diazirin-3-yl)phenylthio)thiazole
    —— N-benzyl-2-[(4R,5R)-4,5-dimethyl-1,3-dioxolan-2-yl]-2-phenylsulfanylacetamide 1294897-66-7 C20H23NO3S
    N-benzyl-2-[(4R,5R)-4,5-dimethyl-1,3-dioxolan-2-yl]-2-phenylsulfanylacetamide
    —— 4-Deuterio-5-(4-methoxyoxan-4-yl)-2-[4-[3-(trifluoromethyl)diazirin-3-yl]phenyl]sulfanyl-1,3-thiazole 1270931-21-9 C17H16F3N3O2S2
    4-Deuterio-5-(4-methoxyoxan-4-yl)-2-[4-[3-(trifluoromethyl)diazirin-3-yl]phenyl]sulfanyl-1,3-thiazole
    —— N-benzyl-2-[(4S,5S)-4,5-dimethyl-1,3-dioxolan-2-yl]-2-phenylsulfanylacetamide 1296255-11-2 C20H23NO3S
    N-benzyl-2-[(4S,5S)-4,5-dimethyl-1,3-dioxolan-2-yl]-2-phenylsulfanylacetamide
    —— 2-[(4R,5R)-4,5-dimethyl-1,3-dioxolan-2-yl]-2-phenylsulfanylacetamide 1294897-71-4 C13H17NO3S
    2-[(4R,5R)-4,5-dimethyl-1,3-dioxolan-2-yl]-2-phenylsulfanylacetamide
    —— 2-[(4R,5R)-4,5-dimethyl-1,3-dioxolan-2-yl]-N-[(1S)-1-phenylethyl]-2-phenylsulfanylacetamide 1294897-65-6 C21H25NO3S
    2-[(4R,5R)-4,5-dimethyl-1,3-dioxolan-2-yl]-N-[(1S)-1-phenylethyl]-2-phenylsulfanylacetamide